Chapter 15 Review Student: ___________________________________________________________________________ 1. Which is not a characteristic property of acids? A. tastes sour B. turns litmus from blue to red C. reacts with metals to yield CO2 gas D. neutralizes bases E. reacts with carbonates to yield CO2 gas 2. Which is the formula for the hydronium ion? A. OHB. H2O C. H3O+ D. H3OE. H2O+ 3. In the reaction H2CO3 + H2O A. H2CO3 and H2O. B. HCO3- and H2CO3. C. H2O and H3O+. D. H3O+ and H2CO3. E. H2O and HCO3-. 4. In the reaction HSO4-(aq) + OH-(aq) HCO3- + H3O+, the Brønsted acids are SO42-(aq) + H2O(l), the conjugate acid-base pairs are A. Row 1 B. Row 2 C. Row 3 D. Row 4 E. Row 5 5. Identify the conjugate base of HPO42- in the reaction HCO3- + HPO42A. H2O B. HCO3C. H2CO3 D. PO43E. none of these 6. Identify the conjugate base of HClO3 in the reaction ClO3- + HSO4A. ClO3B. HSO4C. OHD. H3O+ E. SO42- 7. H2CO3 + PO43- HClO3 + SO42- Identify the conjugate acid of SO42- in the reaction CO32- + HSO4A. CO32B. HSO4C. OHD. H3O+ E. SO42- HCO3- + SO42- 8. Which one of these statements about strong acids is true? A. All strong acids have H atoms bonded to electronegative oxygen atoms. B. Strong acids are 100% ionized in water. C. The conjugate base of a strong acid is itself a strong base. D. Strong acids are very concentrated acids. E. Strong acids produce solutions with a higher pH than weak acids. 9. What is the concentration of H+ in a 2.5 M HCl solution? A. 0 B. 1.3 M C. 2.5 M D. 5.0 M E. 10 .M 10. The OH- concentration in a 1.0 × 10-3 M Ba(OH)2 solution is A. 0.50 × 10-3 M. B. 1.0 × 10-3 M. C. 2.0 × 10-3 M. D. 1.0 × 10-2 M. E. 0.020 M. 11. What is the H+ ion concentration in a 4.8 × 10-2 M KOH solution? A. 4.8 × 10-2 M B. 1.0 × 10-7 M C. 4.8 × 10-11 M D. 4.8 × 10-12 M E. 2.1 × 10-13 M 12. What is the OH- ion concentration in a 5.2 × 10-4 M HNO3 solution? A. 1.9 × 10-11 M B. 1.0 × 10-7 M C. 5.2 × 10-4 M D. zero E. 1.0 × 10-4 M 13. Determine the pH of a KOH solution made by mixing 0.251 g KOH with enough water to make 1.00 × 102 mL of solution. A. 1.35 B. 2.35 C. 7.00 D. 11.65 E. 12.65 14. Calculate the H+ ion concentration in lemon juice having a pH of 2.4. A. 4.0 × 10-2 M B. 250 M C. 0.38 M D. 4.0 × 10-3 M E. 12 M 15. Calculate the pH of a 1.6 M KOH solution. A. 1.60 B. -0.20 C. 0.20 D. 14.20 E. 13.80 16. Calculate the hydrogen ion concentration in a solution of fruit juice having a pH of 4.25. A. 1.0 × 10-14 M B. 5.6 × 10-5 M C. 4.0 × 10-25 M D. 2.5 × 10-4 M E. 5.6 × 10-4 M 17. The pH of a Ba(OH)2 solution is 10.00. What is the H+ ion concentration of this solution? A. 4.0 × 10-11 M B. 1.6 × 10-10 M C. 1.3 × 10-5 M D. 1.0 × 10-10 M E. 10 .M 18. Diet cola drinks have a pH of about 3.0, while milk has a pH of about 7.0. How many times greater is the H3O+ concentration in diet cola than in milk? A. 2.3 times higher in diet cola than in milk B. 400 times higher in diet cola than in milk C. 0.43 times higher in diet cola than in milk D. 1,000 times higher in diet cola than in milk E. 10,000 times higher in diet cola than in milk 19. The pOH of a solution is 9.60 Calculate the hydrogen ion concentration in this solution. A. 2.5 × 10-10 M B. 6.0 × 10-9 M C. 4.0 × 10-5 M D. 2.4 × 10-4 M E. 1.0 × 10-14 M 20. Which solution will have the lowest pH? A. 0.10 M HCN B. 0.10 M HNO3 C. 0.10 M NaCl D. 0.10 M H2CO3 E. 0.10 M NaOH 21. Which one of these responses is true with regard to a 0.1 M solution of a weak acid HA? A. [H+] > [A-] B. pH = 1.0 C. [H+] < [A-] D. pH > 1.0 E. [OH-] > [H+] 22. Acid strength decreases in the series HI > HSO4- > HF > HCN. Which of these anions is the weakest base? A. IB. SO42C. FD. CN23. Acid strength increases in the series: HCN < HF < HSO4-. Which of these species is the strongest base? A. H2SO4 B. SO42C. FD. CN E. HSO424. Acid strength decreases in the series: HNO3 > HF > CH3COOH. Which of these species is the strongest base? A. NO3B. CH3COOC. FD. CH3COOH 25. Which of these acids is the strongest? A. H2SeO3 B. H2TeO3 C. H2SO3 26. Arrange the acids HOCl, HClO3, and HClO2 in order of increasing acid strength. A. HOCl < HClO3 < HClO2 B. HOCl < HClO2 < HClO3 C. HClO2 < HOCl < HClO3 D. HClO3 < HOCl < HClO2 E. HClO3 < HClO2 < HOCl 27. Arrange the acids HBr, H2Se, and H3As in order of increasing acid strength. A. HBr < H2Se < H3As B. HBr < H3As < H2Se C. H2Se < H3As < HBr D. H3As< H2Se < HBr E. H3As< HBr < H2Se 28. When comparing acid strength of binary acids HX, as X varies within a particular group of the periodic table, which one of these factors dominates in affecting the acid strength? A. bond strength B. electron withdrawing effects C. percent ionic character of the H-X bond D. solubility E. Le Châtelier's principle 29. Which one of these net ionic equations represents the reaction of a strong acid with a weak base? A. H+(aq) + OH-(aq) → H O(aq) 2 B. H+(aq) + CH NH (aq) → CH NH +(aq) 3 2 3 3 C. OH-(aq) + HCN(aq) → H O(aq) + CN-(aq) 2 D. HCN(aq) + CH NH (aq) → CH NH + (aq)+ CN-(aq) 3 2 3 3 30. Which one of these net ionic equations represents the reaction of a strong acid with a strong base? A. H+(aq) + OH-(aq) → H O(aq) 2 B. H+(aq) + CH NH (aq) → CH NH +(aq) 3 2 3 3 C. OH-(aq) + HCN(aq) → H O(aq) + CN-(aq) 2 D. HCN(aq) + CH NH (aq) → CH NH +(aq) + CN-(aq) 3 2 3 3 31. Which one of these equations represents the reaction of a weak acid with a weak base? A. H+(aq) + OH-(aq) → H O(aq) 2 B. H+(aq) + CH NH (aq) → CH NH +(aq) 3 2 3 3 C. OH-(aq) + HCN(aq) → H O(aq) + CN-(aq) 2 D. HCN(aq) + CH NH (aq) → CH NH +(aq) + CN-(aq) 3 2 3 3 32. Which one of these equations represents the reaction of a weak acid with a strong base? A. H+(aq) + OH-(aq) → H O(aq) 2 B. H+(aq) + CH NH (aq) → CH NH +(aq) 3 2 3 3 C. OH-(aq) + HCN(aq) → H O(aq) + CN-(aq) 2 D. HCN(aq) + CH NH (aq) → CH NH +(aq) + CN-(aq) 3 2 3 3 33. Predict the direction in which the equilibrium will lie for the reaction H2CO3 + F- HCO3- + HF. Ka1( H2CO3) = 4.2 × 10-7; Ka(HF) = 7.1 × 10-4 A. to the right B. to the left C. in the middle 34. Predict the direction in which the equilibrium will lie for the reaction H2SO4(aq). H3PO4(aq) + HSO4-(aq) H2PO4-(aq) + H2SO3(aq) + HCO3- (aq) HSO3-(aq) + Ka1(H3PO4) = 7.5 × 10-3; Ka(H2SO4) = very large A. to the right B. to the left C. in the middle 35. Predict the direction in which the equilibrium will lie for the reaction H2CO3(aq). Ka1(H2SO3) = 1 × 10-2; Ka1(H2CO3) = 4.2 × 10-7 A. to the right B. to the left C. in the middle 36. Which of the following yields a basic solution when dissolved in water? A. NO2 B. P4O10 C. K2O D. NaCl E. SO2 37. Which of the following yields an acidic solution when dissolved in water? A. NO2 B. LiOH C. K2O D. NaCl E. Ca(OH)2 38. Hard water deposits (calcium carbonate) have built up around your bathroom sink. Which one of these substances would be most effective in dissolving the deposits? A. ammonia B. bleach (sodium hypochlorite) C. lye (sodium hydroxide) D. vinegar (acetic acid) 39. In the reaction CaO(s) + SO (g) CaSO3(s), 2 A. O2- acts as a Lewis base, and SO2 acts as a Lewis acid. B. Ca2+ acts as a Lewis base, and SO42- acts as a Lewis acid. C. SO42- acts as a Lewis base, and SO2 acts as a Lewis acid. D. SO2 acts as a Lewis base, and O2- acts as a Lewis acid. E. SO2 acts as a Lewis base, and Ca2+ acts as a Lewis acid. 40. Which of these species will act as a Lewis acid? A. NH3 B. NH4+ C. H2O D. BF3 E. F41. Which of these species is a Lewis acid, but not a Brønsted acid? A. HCN B. CO32C. OHD. ClE. Al3+ 42. Find the pH of a 0.135 M aqueous solution of periodic acid (HIO4), for which Ka = 2.3 × 10-2. A. 1.25 B. 3.28 C. 1.17 D. 1.34 E. 1.64 43. For H3PO4, Ka1 = 7.3 × 10-3, Ka2 = 6.2 × 10-6, and Ka3 = 4.8 × 10-13. An aqueous solution of NaH2PO4 therefore would be A. neutral. B. basic. C. acidic. 44. For H3PO4, Ka1 = 7.3 × 10-3, Ka2 = 6.2 × 10-6, and Ka3 = 4.8 × 10-13. An aqueous solution of Na3PO4 therefore would be A. neutral. B. basic. C. acidic. 45. An aqueous solution of KCl would be A. neutral. B. basic. C. acidic. 46. Which one of these salts will form a neutral solution on dissolving in water? A. NaCl B. KNO2 C. NaCN D. NH4NO3 E. FeCl3 47. Which one of these salts will form a basic solution on dissolving in water? A. NaCl B. KCN C. NaNO3 D. NH4NO3 E. FeCl3 48. In 0.10 M KCN, the chemical species with the highest concentration (except H2O) is A. Na+. B. CN-. C. H3O+(or H+). D. OH-. E. K+. 49. What is the pH of a 0.20 M solution of NH4Cl? [Kb(NH3) = 1.8 × 10-5] A. 3.74 B. 4.98 C. 6.53 D. 9.02 E. 10.25 50. Consider the weak bases below and their Kb values: Arrange the conjugate acids of these weak bases in order of increasing acid strength. A. C5H5NH+ < C6H7OH < C2H5NH B. C6H7OH < C5H5NH+ < C2H5NH C. C5H5NH+ < C2H5NH3+ < C6H7OH D. C6H7OH < C2H5NH3+< C5H5NH+ E. C2H5NH3+< C5H5NH+ < C6H7OH 51. Which response gives the products of hydrolysis of KF? A. KOH + HF B. OH- + HF C. KOH + H+ + FD. KH + F- + OHE. No hydrolysis occurs. 52. Which one of these salts will form a basic solution upon dissolving in water? A. NaCl B. NaNO2 C. NH4NO3 D. KBr E. AlCl3 53. Which one of the following salts will form an acidic solution on dissolving in water? A. LiBr B. NaF C. KOH D. FeCl3 E. NaCN 54. The equilibrium constant for the reaction C6H5COOH(aq) + CH3COO-(aq) C6H5COO-(aq) + CH3COOH(aq) -5 is 3.6 at 25°C. If Ka for CH3COOH is 1.8 × 10 , what is the acid dissociation constant for C6H5COOH? A. 5.0 × 10-6 B. 6.5 × 10-5 C. 2.3 × 10-4 D. 8.3 × 10-5 E. 5.6 ×10-6 Chapter 15 Review Key 1. Which is not a characteristic property of acids? A. tastes sour B. turns litmus from blue to red C. reacts with metals to yield CO2 gas D. neutralizes bases E. reacts with carbonates to yield CO2 gas Difficulty: Easy Raymond - 015 Acids... #1 2. Which is the formula for the hydronium ion? A. OHB. H2O C. H3O+ D. H3OE. H2O+ Difficulty: Easy Raymond - 015 Acids... #2 3. In the reaction H2CO3 + H2O A. H2CO3 and H2O. B. HCO3- and H2CO3. C. H2O and H3O+. D. H3O+ and H2CO3. E. H2O and HCO3-. HCO3- + H3O+, the Brønsted acids are Difficulty: Easy Raymond - 015 Acids... #3 4. In the reaction HSO4-(aq) + OH-(aq) are A. B. C. D. E. 5. SO42-(aq) + H2O(l), the conjugate acid-base pairs Row 1 Row 2 Row 3 Row 4 Row 5 Identify the conjugate base of HPO42- in the reaction A. B. C. D. E. HCO3- + HPO42H2O HCO3H2CO3 PO43none of these Difficulty: Medium Raymond - 015 Acids... #4 H2CO3 + PO43- Difficulty: Medium Raymond - 015 Acids... #5 6. Identify the conjugate base of HClO3 in the reaction A. B. C. D. E. ClO3- + HSO4ClO3HSO4OHH3O+ SO42- HClO3 + SO42- Difficulty: Medium Raymond - 015 Acids... #9 7. Identify the conjugate acid of SO42- in the reaction A. B. C. D. E. CO32- + HSO4CO32HSO4OHH3O+ SO42- HCO3- + SO42- Difficulty: Medium Raymond - 015 Acids... #10 8. 9. 10. 11. 12. 13. Which one of these statements about strong acids is true? A. All strong acids have H atoms bonded to electronegative oxygen atoms. B. Strong acids are 100% ionized in water. C. The conjugate base of a strong acid is itself a strong base. D. Strong acids are very concentrated acids. E. Strong acids produce solutions with a higher pH than weak acids. What is the concentration of H+ in a 2.5 M HCl solution? A. 0 B. 1.3 M C. 2.5 M D. 5.0 M E. 10 .M The OH- concentration in a 1.0 × 10-3 M Ba(OH)2 solution is A. 0.50 × 10-3 M. B. 1.0 × 10-3 M. C. 2.0 × 10-3 M. D. 1.0 × 10-2 M. E. 0.020 M. What is the H+ ion concentration in a 4.8 × 10-2 M KOH solution? A. 4.8 × 10-2 M B. 1.0 × 10-7 M C. 4.8 × 10-11 M D. 4.8 × 10-12 M E. 2.1 × 10-13 M What is the OH- ion concentration in a 5.2 × 10-4 M HNO3 solution? A. 1.9 × 10-11 M B. 1.0 × 10-7 M C. 5.2 × 10-4 M D. zero E. 1.0 × 10-4 M Determine the pH of a KOH solution made by mixing 0.251 g KOH with enough water to make solution. A. 1.35 B. 2.35 C. 7.00 D. 11.65 E. 12.65 Difficulty: Medium Raymond - 015 Acids... #13 Difficulty: Easy Raymond - 015 Acids... #16 Difficulty: Medium Raymond - 015 Acids... #17 Difficulty: Medium Raymond - 015 Acids... #20 Difficulty: Medium Raymond - 015 Acids... #22 1.00 × 102 mL of Difficulty: Medium Raymond - 015 Acids... #28 14. Calculate the H+ ion concentration in lemon juice having a pH of 2.4. A. 4.0 × 10-2 M B. 250 M C. 0.38 M D. 4.0 × 10-3 M E. 12 M Difficulty: Medium Raymond - 015 Acids... #29 15. Calculate the pH of a 1.6 M KOH solution. A. 1.60 B. -0.20 C. 0.20 D. 14.20 E. 13.80 Difficulty: Medium Raymond - 015 Acids... #37 16. 17. 18. Calculate the hydrogen ion concentration in a solution of fruit juice having a pH of 4.25. A. 1.0 × 10-14 M B. 5.6 × 10-5 M C. 4.0 × 10-25 M D. 2.5 × 10-4 M E. 5.6 × 10-4 M The pH of a Ba(OH)2 solution is 10.00. What is the H+ ion concentration of this solution? A. 4.0 × 10-11 M B. 1.6 × 10-10 M C. 1.3 × 10-5 M D. 1.0 × 10-10 M E. 10 .M Diet cola drinks have a pH of about 3.0, while milk has a pH of about 7.0. How many times concentration in diet cola than in milk? A. 2.3 times higher in diet cola than in milk B. 400 times higher in diet cola than in milk C. 0.43 times higher in diet cola than in milk D. 1,000 times higher in diet cola than in milk E. 10,000 times higher in diet cola than in milk Difficulty: Medium Raymond - 015 Acids... #40 Difficulty: Medium Raymond - 015 Acids... #46 greater is the H3O+ Difficulty: Medium Raymond - 015 Acids... #47 19. The pOH of a solution is 9.60 Calculate the hydrogen ion concentration in this solution. A. 2.5 × 10-10 M B. 6.0 × 10-9 M C. 4.0 × 10-5 M D. 2.4 × 10-4 M E. 1.0 × 10-14 M Difficulty: Medium Raymond - 015 Acids... #52 20. Which solution will have the lowest pH? A. 0.10 M HCN B. 0.10 M HNO3 C. 0.10 M NaCl D. 0.10 M H2CO3 E. 0.10 M NaOH Difficulty: Medium Raymond - 015 Acids... #54 21. Which one of these responses is true with regard to a 0.1 M solution of a weak acid HA? A. [H+] > [A-] B. pH = 1.0 C. [H+] < [A-] D. pH > 1.0 E. [OH-] > [H+] Difficulty: Medium Raymond - 015 Acids... #55 22. 23. Acid strength decreases in the series HI > HSO4- > HF > HCN. Which of these anions is the weakest base? A. IB. SO42C. FD. CN- -. Difficulty: Medium Raymond - 015 Acids... #56 Acid strength increases in the series: HCN < HF < HSO4 Which of these species is the strongest base? A. H2SO4 B. SO42C. FD. CN E. HSO4Difficulty: Medium Raymond - 015 Acids... #58 24. Acid strength decreases in the series: HNO3 > HF > CH3COOH. Which of these species is the strongest base? A. NO3B. CH3COOC. FD. CH3COOH Difficulty: Medium Raymond - 015 Acids... #60 25. Which of these acids is the strongest? A. H2SeO3 B. H2TeO3 C. H2SO3 Difficulty: Medium Raymond - 015 Acids... #61 26. Arrange the acids HOCl, HClO3, and HClO2 in order of increasing acid strength. A. HOCl < HClO3 < HClO2 B. HOCl < HClO2 < HClO3 C. HClO2 < HOCl < HClO3 D. HClO3 < HOCl < HClO2 E. HClO3 < HClO2 < HOCl Difficulty: Medium Raymond - 015 Acids... #62 27. Arrange the acids HBr, H2Se, and H3As in order of increasing acid strength. A. HBr < H2Se < H3As B. HBr < H3As < H2Se C. H2Se < H3As < HBr D. H3As< H2Se < HBr E. H3As< HBr < H2Se Difficulty: Medium Raymond - 015 Acids... #64 28. When comparing acid strength of binary acids HX, as X varies within a particular group of the periodic table, which one of these factors dominates in affecting the acid strength? A. bond strength B. electron withdrawing effects C. percent ionic character of the H-X bond D. solubility E. Le Châtelier's principle Difficulty: Medium Raymond - 015 Acids... #66 29. Which one of these net ionic equations represents the reaction of a strong acid with a weak base? A. H+(aq) + OH-(aq) → H O(aq) 2 B. H+(aq) + CH NH (aq) → CH NH +(aq) 3 2 3 3 C. OH-(aq) + HCN(aq) → H O(aq) + CN-(aq) 2 D. HCN(aq) + CH NH (aq) → CH NH + (aq)+ CN-(aq) 3 2 3 3 Difficulty: Medium Raymond - 015 Acids... #67 30. Which one of these net ionic equations represents the reaction of a strong acid with a strong base? A. H+(aq) + OH-(aq) → H O(aq) 2 B. H+(aq) + CH NH (aq) → CH NH +(aq) 3 2 3 3 C. OH-(aq) + HCN(aq) → H O(aq) + CN-(aq) 2 D. HCN(aq) + CH NH (aq) → CH NH +(aq) + CN-(aq) 3 2 3 3 Difficulty: Medium Raymond - 015 Acids... #68 31. Which one of these equations represents the reaction of a weak acid with a weak base? A. H+(aq) + OH-(aq) → H O(aq) 2 B. H+(aq) + CH NH (aq) → CH NH +(aq) 3 2 3 3 C. OH-(aq) + HCN(aq) → H O(aq) + CN-(aq) 2 D. HCN(aq) + CH NH (aq) → CH NH +(aq) + CN-(aq) 3 2 3 3 Difficulty: Medium Raymond - 015 Acids... #69 32. Which one of these equations represents the reaction of a weak acid with a strong base? A. H+(aq) + OH-(aq) → H O(aq) 2 B. H+(aq) + CH NH (aq) → CH NH +(aq) 3 2 3 3 C. OH-(aq) + HCN(aq) → H O(aq) + CN-(aq) 2 D. HCN(aq) + CH NH (aq) → CH NH +(aq) + CN-(aq) 3 2 3 3 33. Predict the direction in which the equilibrium will lie for the reaction H2CO3 + F- Difficulty: Medium Raymond - 015 Acids... #70 HCO3- + HF. Ka1( H2CO3) = 4.2 × 10-7; Ka(HF) = 7.1 × 10-4 A. to the right B. to the left C. in the middle 34. Predict the direction in which the equilibrium will lie for the reaction H2SO4(aq). H3PO4(aq) + Difficulty: Medium Raymond - 015 Acids... #71 HSO4-(aq) H2PO4-(aq) + H2SO3(aq) + Difficulty: Medium Raymond - 015 Acids... #72 HCO3- (aq) HSO3-(aq) + Ka1(H3PO4) = 7.5 × 10-3; Ka(H2SO4) = very large A. to the right B. to the left C. in the middle 35. Predict the direction in which the equilibrium will lie for the reaction H2CO3(aq). Ka1(H2SO3) = 1 × 10-2; Ka1(H2CO3) = 4.2 × 10-7 A. to the right B. to the left C. in the middle Difficulty: Medium Raymond - 015 Acids... #73 36. Which of the following yields a basic solution when dissolved in water? A. NO2 B. P4O10 C. K2O D. NaCl E. SO2 Difficulty: Medium Raymond - 015 Acids... #76 37. Which of the following yields an acidic solution when dissolved in water? A. NO2 B. LiOH C. K2O D. NaCl E. Ca(OH)2 Difficulty: Medium Raymond - 015 Acids... #77 38. Hard water deposits (calcium carbonate) have built up around your bathroom sink. Which one of these substances would be most effective in dissolving the deposits? A. ammonia B. bleach (sodium hypochlorite) C. lye (sodium hydroxide) D. vinegar (acetic acid) Difficulty: Medium Raymond - 015 Acids... #78 39. In the reaction CaO(s) + SO2(g) CaSO3(s), A. O2- acts as a Lewis base, and SO2 acts as a Lewis acid. B. Ca2+ acts as a Lewis base, and SO42- acts as a Lewis acid. C. SO42- acts as a Lewis base, and SO2 acts as a Lewis acid. D. SO2 acts as a Lewis base, and O2- acts as a Lewis acid. E. SO2 acts as a Lewis base, and Ca2+ acts as a Lewis acid. Difficulty: Medium Raymond - 015 Acids... #80 40. Which of these species will act as a Lewis acid? A. NH3 B. NH4+ C. H2O D. BF3 E. FDifficulty: Medium Raymond - 015 Acids... #81 41. 42. Which of these species is a Lewis acid, but not a Brønsted acid? A. HCN B. CO32C. OHD. ClE. Al3+ Find the pH of a 0.135 M aqueous solution of periodic acid (HIO4), for which Ka = 2.3 × 10-2. A. 1.25 B. 3.28 C. 1.17 D. 1.34 E. 1.64 Difficulty: Medium Raymond - 015 Acids... #82 Difficulty: Medium Raymond - 015 Acids... #83 43. For H3PO4, Ka1 = 7.3 × 10-3, Ka2 = 6.2 × 10-6, and Ka3 = 4.8 × 10-13. An aqueous solution of NaH2PO4 therefore would be A. neutral. B. basic. C. acidic. Difficulty: Medium Raymond - 015 Acids... #90 44. For H3PO4, Ka1 = 7.3 × 10-3, Ka2 = 6.2 × 10-6, and Ka3 = 4.8 × 10-13. An aqueous solution of Na3PO4 therefore would be A. neutral. B. basic. C. acidic. Difficulty: Medium Raymond - 015 Acids... #91 45. An aqueous solution of KCl would be A. neutral. B. basic. C. acidic. Difficulty: Medium Raymond - 015 Acids... #92 46. Which one of these salts will form a neutral solution on dissolving in water? A. NaCl B. KNO2 C. NaCN D. NH4NO3 E. FeCl3 Difficulty: Medium Raymond - 015 Acids... #93 47. Which one of these salts will form a basic solution on dissolving in water? A. NaCl B. KCN C. NaNO3 D. NH4NO3 E. FeCl3 Difficulty: Medium Raymond - 015 Acids... #94 48. 49. In 0.10 M KCN, the chemical species with the highest concentration (except H2O) is A. Na+. B. CN-. C. H3O+(or H+). D. OH-. E. K+. What is the pH of a 0.20 M solution of NH4Cl? [Kb(NH3) = 1.8 × 10-5] A. 3.74 B. 4.98 C. 6.53 D. 9.02 E. 10.25 Difficulty: Medium Raymond - 015 Acids... #95 Difficulty: Medium Raymond - 015 Acids... #96 50. Consider the weak bases below and their Kb values: Arrange the conjugate acids of these weak bases in order of increasing acid strength. A. C5H5NH+ < C6H7OH < C2H5NH B. C6H7OH < C5H5NH+ < C2H5NH C. C5H5NH+ < C2H5NH3+ < C6H7OH D. C6H7OH < C2H5NH3+< C5H5NH+ E. C2H5NH3+< C5H5NH+ < C6H7OH Difficulty: Medium Raymond - 015 Acids... #98 51. Which response gives the products of hydrolysis of KF? A. KOH + HF B. OH- + HF C. KOH + H+ + FD. KH + F- + OHE. No hydrolysis occurs. Difficulty: Medium Raymond - 015 Acids... #100 52. Which one of these salts will form a basic solution upon dissolving in water? A. NaCl B. NaNO2 C. NH4NO3 D. KBr E. AlCl3 Difficulty: Medium Raymond - 015 Acids... #101 53. 54. Which one of the following salts will form an acidic solution on dissolving in water? A. LiBr B. NaF C. KOH D. FeCl3 E. NaCN The equilibrium constant for the reaction C6H5COOH(aq) + CH3COO-(aq) -5 is 3.6 at 25°C. If Ka for CH3COOH is 1.8 × 10 , what is the acid dissociation constant A. 5.0 × 10-6 B. 6.5 × 10-5 C. 2.3 × 10-4 D. 8.3 × 10-5 E. 5.6 ×10-6 Difficulty: Medium Raymond - 015 Acids... #104 C6H5COO-(aq) + CH3COOH(aq) for C6H5COOH? Difficulty: Medium Raymond - 015 Acids... #110 Chapter 15 Review Summary Category Difficulty: Easy Difficulty: Medium Raymond - 015 Acids... # of Questions 4 50 54
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