9/15/2014 ACIDS An acid -------> H+ in water Strong acids (dissociate 100%) are… HCl H2SO4 HClO4 HNO3 HBr HI hydrochloric sulfuric perchloric nitric hydrobromic hydroiodic HNO3 A SAMPLE Aqueous sodium hydroxide is added to sulfuric acid… NaOH(aq) + H2SO4(aq) NaHSO4 + HOH NaOH(aq) + H2SO4(aq) NaHSO4(aq) + HOH(l) Na++OH- + H+ +HSO4Na+ + HSO4- + HOH OH- + H+ HOH ACIDS An acid -------> H+ in water HCl(aq) ---> H+(aq) + Cl-(aq) Strong Acids in water, actually release the H+ ion which forms H3O+ (the hydronium ion) The Nature of Acids HCl H2O Cl- hydronium ion H3O+ 1 9/15/2014 Weak Acids Some WEAK ACIDS = weak electrolytes(do not dissociate 100%) Write them as molecular (do not break up) CH3CO2H or HC2H3O2 acetic acid H2CO3 carbonic acid H3PO4 phosphoric acid HF hydrofluoric acid ACIDS Nonmetal oxides can be acids CO2(aq) + H2O(l) ---> H2CO3(aq) SO3(aq) + H2O(l) ---> H2SO4(aq) and can come from burning coal and oil. BASES Base ---> OH- in water NaOH (aq) ---> Na+ (aq) + OH- (aq) NaOH is a strong base Strong Bases dissociate 100% in water 2 9/15/2014 BASES CaO(s) + H2O(l)--> Ca(OH)2(aq) STRONG BASES NaOH & KOH & LiOH {all group 1A hydroxides are strong bases although not all are common in the lab} CaO in water. Indicator shows solution is basic. Ca(OH)2, Ba(OH)2 and Sr(OH)2 are also strong bases Weak acid and strong base Write the molecular, ionic and net ionic equation for phosphoric acid reacting with a solution of potassium hydroxide. Acids dissociate one hydrogen at a time Molecular equation H3PO4 + KOH KH2PO4 + HOH To finish… H3PO4 + KOH KH2PO4 + HOH Decide what the physical state are of the products H3PO4 + KOH KH2PO4(aq) + HOH (l) The ionic equation… H3PO4 + K+ + OH- K+ + H2PO4- +HOH The net ionic equation… H3PO4 + OH- H2PO4- +HOH 3
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