APT-17 2017SouthCarolinaPest ManagementHandbook Table of Measurements and Conversions Standard Measure Length: 1 ft = 12 in 1 yd = 3 ft 1 mi = 5,280 ft 1 mph = 88 ft/1 min Area: 1 sq in = 0.007 sq ft 1 sq ft = 144 sq in 1 sq yd = 1,296 sq in = 9 sq ft 1 ac = 43,560 sq ft = 4,840 sq yd Volume: 1 tsp = 0.17 fl oz 1 tbs = 3 tsp 1 fl oz = 2 tbs = 6 tsp 1 cup = 8 fl oz = 16 tbs 1 pt = 2 cups = 16 fl oz 1 qt = 2 pt = 32 fl oz 1 gal = 4 qt = 8 pt = 128 fl oz = 231 cu in Note: To convert liquid ounces to gallons, multiply by 0.0078125(.008) Weight: 1 oz = 0.0625 lb 1 lb = 16 oz 1 ton = 2,000 lb 1 gal of water = 8.34 lb Metric Conversion Length: 1 in = 25.4 mm = 2.54 cm 1 ft = 304.8 mm = 30.48 cm 1 yd = 914.4 mm = 91.44 cm = 0.914 m 1 mi = 1,609 m = 1.61 km 1 mm = 0.03937 in 1cm = 0.394 in = 0.0328 ft 1 m = 39.37 in = 3,281 ft 1 km = 3,281 ft = 0.621 mi Area: 1 sq in = 6.45 sq cm 1 sq ft = 929 sq cm 1 sq yd = 8,361 sq cm = 0.8361 sq m 1 ac = 4,050 sq m = 0.405 h 1 sq m = 1,550 sq in = 10.76 sq ft 1 h = 107,600 sq ft = 2.47 ac Volume: 1 fl oz = 29.5 ml = 0.0295 L 1 pt = 437 ml = 0.437 L 1 qt = 945 ml = 0.945 L 1 gal = 3,785 ml = 3.785 L 1 ml = 0.033 fl oz 1 L = 33.8 fl oz = 2.112 pt = 1.057 qt = 0.264 gal Weight: 1 oz = 28.35 g 1 lb = 454 g = 0.4536 kg 1 ton = 907 kg 1 gal of water = 3.786 kg 1 g = 0.035 oz 1 kg = 35.27 oz = 2.205 Lb Concentration: 1 part per million (ppm)= 1 milligram/liter = 1 milligram/kilogram 1 percent = 10 grams/liter 0.1 percent = 1,000 milligrams/liter 0.01 percent = 100 milligrams/liter 0.001 percent = 10 milligrams/liter Concentration: 1 part per million (ppm)= 0.00001 percent = 0.013 oz in 100 gal of water 1 percent = 10,000 ppm 0.1 percent = 1,000 ppm 0.01 percent = 100 ppm 0.001 percent = 10 ppm Temperature: To convert degrees Celsius (°C) to degrees Fahrenheit (°F): multiply by 1.8 and add 32. Example: 30 degrees °C = 86 degrees °F. (30x1.8+32) To convert degrees Fahrenheit (°F) to degrees Celsius (°C): subtract 32 multiply by 0.56. Example: 50 degrees °F = 10 degrees °C (50‐32x0.56). Abbreviations: ac = Acre; cm = Centimeter; fl oz = Fluid ounce; ft = Foot or Feet; g = Gram; gal = Gallon; h = Hectare (1h = 10,000 square meters); in = Inch; kg = Kilogram; km = Kilometer; L = Liter; lb = Pound; mi = Mile; oz = Ounce; pt = Pint; m = Meter; mg = Milligram; min = Minute; ml = Milliliter; mm = Millimeter; qt = Quart; sq = Square; tbs = Tablespoon; tsp = Teaspoon; yd = Yard. South Carolina Pest Management Handbook for Field Crops - 2017 2017SouthCarolina PestManagementHandbook The Pest Management Handbook is a set of recommendations developed by Clemson University Extension pest management specialists and university researchers for South Carolina growers. These recommendations were derived from various sources of information available to these contributors at times prior to publishing this handbook and represent their current views on managing field crop pests based on pesticide labels, their own research or experience, and/or a number of other sources. The chemical recommendations provided here are based on pesticide active ingredients. Pesticide products mentioned here are for applicator convenience and are examples only; their mention is not product endorsement. Pesticide products not mentioned here may also be efficacious and their absence from these recommendations does not necessarily mean that they are not also effective pest management tools. These recommendations are not meant to be an exhaustive recommendation, and associated comments, given here are in all cases are superseded by the pesticide product labels. It is your responsibility as a pesticide user to read and follow the instructions on the product label in deciding your pesticide purchases and in their use, including mix/loading of the product, application, clean‐up, and the disposal of unwanted product, rinsates, and clean empty product containers. The 2017 Pest Management Handbook is also available as an electronic copy on the Clemson University Extension web site under Row Crops section. The web site address is: http://www.clemson.edu/extension/rowcrops/ South Carolina Pest Management Handbook for Field Crops - 2017 2017TECHINCALCONTRIBUTORS MikeMarshall ExtensionWeedSpecialist,2017PMHEditor EdistoResearchandEducationCenter 64ResearchRoad Blackville,SC29817 (803)284‐3343x228 [email protected] JeremyGreene ExtensionEntomologist EdistoResearchandEducationCenter 64ResearchRoad Blackville,SC29817 (803)284‐3343x228 [email protected] BobBellinger ExtensionEntomologist ClemsonUniversity 107LongHall Clemson,SC29634 (864)656‐5042 [email protected] FrancisReay‐Jones ExtensionEntomologist PeeDeeResearchandEducationCenter 2200PocketRoad Florence,SC29506 (843)662‐3526x208 [email protected] JohnMueller ExtensionPlantPathologist EdistoResearchandEducationCenter 64ResearchRoad Blackville,SC29817 (803)284‐3343x273 [email protected] DanAnco ExtensionPeanutSpecialist EdistoResearchandEducationCenter 64ResearchRoad Blackville,SC29817 (803)284‐3343x261 [email protected] PaulPeterson ResearchPlantPathologist PeeDeeResearchandEducationCenter 2200PocketRoad Florence,SC29506 (843)307‐2966 [email protected] JenniferTsuruda ExtensionApiculturist ClemsonUniversity 109FBarreHall Clemson,SC29634 (864)656‐2218 [email protected] CoryHeaton StateWildlifeSpecialist SandhillResearchandEducationCenter 900ClemsonRoad Columbia,SC29229 (803)699‐3190 [email protected] JayCrouch AreaAgronomyAgent NewberryCountyExtensionOffice 1860WilsonRoad Newberry,SC29108 (803)276‐1091x113 [email protected] BrianBeer AreaLivestockAgent LancasterCountyExtensionOffice 107SouthFrenchStreet Lancaster,SC29721 (803)283‐3302x115 [email protected] South Carolina Pest Management Handbook for Field Crops - 2017 TABLEOFCONTENTS Introduction SprayerCalibration....................................................................................................................................................................1 SprayerDriftManagement.....................................................................................................................................................4 SprayerCleaning.........................................................................................................................................................................4 HerbicideAdjuvants..................................................................................................................................................................6 PesticideSafety............................................................................................................................................................................6 PesticideResistanceManagement......................................................................................................................................7 PesticideApplicationRecordkeeping................................................................................................................................9 HoneybeeStewardship..........................................................................................................................................................10 RelativeToxicityofPesticidestoHoneybees...............................................................................................................12 ModeofActionforHerbicides............................................................................................................................................15 CropReplantandRotationGuideFollowingHerbicideApplication..................................................................17 Corn WeedControlinCorn.............................................................................................................................................................22 CornInsectControl..................................................................................................................................................................55 Cotton WeedControlinCotton..........................................................................................................................................................77 CottonInsectManagement................................................................................................................................................105 CottonDiseaseControl........................................................................................................................................................119 CottonNematodeControl..................................................................................................................................................123 Forages GrassForageWeedControl...............................................................................................................................................126 PastureandHayInsectManagement............................................................................................................................144 GrainSorghum WeedControlinGrainSorghum.....................................................................................................................................150 GrainSorghumInsectControl..........................................................................................................................................160 Peanut WeedControlinPeanut......................................................................................................................................................168 PeanutInsectControl..........................................................................................................................................................185 PeanutDiseaseManagement............................................................................................................................................190 PeanutNematodeControl..................................................................................................................................................202 SmallGrains WeedControlinSmallGrains..........................................................................................................................................203 SmallGrainInsectControl.................................................................................................................................................212 SmallGrainDiseaseControl..............................................................................................................................................218 Soybean WeedControlinSoybean...................................................................................................................................................221 SoybeanInsectControl.......................................................................................................................................................255 SoybeanDiseaseControl....................................................................................................................................................265 SoybeanNematodeControl...............................................................................................................................................271 Sunflower WeedControlinSunflower...............................................................................................................................................273 Tobacco WeedControlinTobacco...................................................................................................................................................279 TobaccoInsectControl........................................................................................................................................................283 TobaccoDiseaseManagement.........................................................................................................................................293 TobaccoNematodeManagement...................................................................................................................................302 AquaticWeedControl...............................................................................................................................................................303 Farm‐StoredGrainInsectManagement.........................................................................................................................309 South Carolina Pest Management Handbook for Field Crops - 2017 INTRODUCTION SPRAYERCALIBRATION distancewhichmatchesthenozzlespacing on your boom (for broadcast sprays) or row spacing you use (for band applications). The distance should be measuredinafieldtypicalofthoseyouwill bespraying,ratherthanasmoothsurface. 2. Selectagearandenginespeedcombination which will allow you to comfortably drive across your fields and develop adequate spraypressurefortheparticularnozzleson your rig. Drive the measured distance at your preselected gear and engine speed combinationandrecordthetimerequired todrivethedistanceinseconds.Toimprove precision, you may want to time two or moreseparaterunsandtaketheaverageof tworuns. MikeMarshall,ExtensionWeedSpecialist Accurate application of pesticides is essential to adequately control target pests, avoid excessive crop injury, and minimize chemical costs and harm to the environment. This has become even more critical in recent years as some pesticide use rates go from pounds per acre to fractions of one ounce per acre. Unfortunately, sprayer calibration is often neglectedoravoided.Therearemanywaysto calibrate a sprayer, some more difficult than others. If you have a reliable method with which you are comfortable, stick with it. The following is a guide to a straightforward method. Sprayercalibrationshouldbedonewithclean water, not with the chemical mix in the spray system. Before you calibrate your sprayer, thoroughlycleanit.Also,besuretocheckfor nozzleoutputuniformity,asdefectsoruneven wear will cause some nozzles to put out significantlymorethanothersofthesametype. To do this, catch and measure the output of each nozzle for a specific length of time (30 seconds, 1 minute, etc.) and determine the average output per nozzle (total combined outputofallnozzlesdividedbythenumberof nozzles). Discard and replace any nozzle that variesmorethan5percentfromtheaverage. 1/128acremethod: Thisisperhapsthemostfrequentlyusedand quickest method of calibration. It involves measuring a specific driving distance rather thananarea.Followthesestepstocalibrateby the1/128acremethod. 1. Table1.Distancecalibrationtableforsprayers Nozzle Distance Nozzle Distance orRow totimefor orRow totimefor spacing calibratio spacing calibratio (inches n(feet) (inches n(feet) ) ) 40 102 26 157 38 107 24 170 36 113 22 185 34 120 20 204 32 127 18 227 30 136 16 255 28 146 14 291 3. Measure a specific distance in a field according to table 1. Select a driving 1 Park the sprayer and, using a measuring cuporbucket,catchthesprayoutputfrom asinglenozzleforthelengthoftimeittook youtodrivethemeasureddistanceinstep one.Besurethatthesprayerisrunningat thesameenginespeedandspraypressure. Note:Forbandingrigswhereyouusedrow spacingtodeterminethedistanceinstep1 and where more than one nozzle is South Carolina Pest Management Handbook for Field Crops - 2017 directedtotherow,catchtheoutputforall nozzlesdirectedtoasinglerow. 4. The total amount of water, measured in ounces,collectedpernozzleorrowinstep 3equalsgallonsperacre(GPA). Determining how much herbicide product toaddtothespraytank: Nowthatyouhavesuccessfullycalibratedyour sprayer, the next step is to determine how much chemical you need to add to the tank. all non‐uniform nozzles (and yes there were some!) 1. 2. 3. Dividethetankcapacitybygallonsperacre to get the number of acres a full tank can spray: [Tankcapacity(gallons)÷GPA]=Number ofacrescoveredbyonefulltank 1. 4. Multiply the recommended pesticide rate fromthelabel(pt/A,oz/A,lb/A,etc.)bythe number of acres covered by a full tank (fromstep1.) 3. Note: All pesticide rates in this handbook are given as broadcast rates. For band applications,youmustadjusttherateusing the following formula: [BandWidth×BroadcastRate]÷RowWidth =BandRate Examplesofcalibration&howmuchtoput inthetank. BroadcastApplication: Youplantospraygenericglyphosateherbicide, plusanonionicsurfactantforburn‐downprior toplantingcotton.Yoursprayerhasauniform nozzle spacing of 18 inches. You have thoroughlycleanedyoursprayerandreplaced 2. [500galtank÷20GPA]=25acrescovered byonetankload So,1qt/A×25acres=25quarts(~6.25 gallons)ofglyphosatepertankload Whataboutthesurfactant: 500gal×(1qt/100gal)=5qts.surfactant perspraytankload. BandApplication: You plan to apply Staple herbicide plus nonionic surfactant in a 19 inch band on 38 inch rows. Your banding rig is set up with threenozzlesdirectedtothebandoneachrow. 2 FromTable1,notethatthedistanceto driveis227feet.Measurethisdistance inthefieldtobesprayed. Setyourthrottleanddrivethe227feet for several runs. Let’s say that it took youanaverageof39secondstodrive thisdistance. Now, at the same engine speed and at your desired spray pressure, and with your sprayer standing still, catch the output in ounces for 39 seconds from anyonenozzle,theaveragetimeittook yourrigtotravelthe227feet.Youcatch 20 ounces during the 39 second time period.Therefore,yoursprayeroutput is20GPA. After reading the generic glyphosate label and the weed control recommendations for cotton, you decide to spray glyphosate at 1 qt/A, plusanonionicsurfactantat1qt/100 gallonsofspraymix.Let’sassumeyou have a 500‐gallon spray tank. How many acres will one tank load cover? South Carolina Pest Management Handbook for Field Crops - 2017 Yoursprayerhasbeenthoroughlycleaned,and the nozzles are uniform in output, after replacingthoseoutofrange. (GPA)underthehoodneedstomatchasclose as possible to the GPA of your post‐directed band. The hooded rig is set up to use two nozzlespost‐directingona13inchbandand hasthreenozzlesunderthehoodsprayinga 25inchband. Scenario1:Onepumpapplyingonetankmix. Usingthechartagain,thedistancetotravel fora38inchrowis107feet.Youmeasure your course drive it several times. Let’s assumeittookanaverageof18seconds. 2. Park the sprayer and at the same engine speed and your desired pressure, collect theoutputofeachofthethreenozzlesfor 18seconds.Ifthecombinedtotaloutputof the three nozzle band cluster is, for example,25ounces,thesprayerisapplying 25gallonsperacre. 3. Now, let’s say your sprayer has a 200 gallontank.ThebroadcastrateforStaple is2.2floz/A,andnonionicsurfactantis tobeaddedat1qt/100gal.ofspraymix. [200galtank÷25GPA]=8acrescovered pertank 1. Thedistancetotravelfora38inchrowis 107 feet (Table 1). You measure your courseanddriveit.Let’sassumeittookan averageof18seconds. 2. Park the sprayer and at the same engine speed and at the desired pressure, and collect the output of the three nozzles under the hood for 18 seconds. Combine the output of the three nozzles and measure. The combined total, for example 20 ounces, equals the application rate in GPA.Inthiscaseyourhoodsareapplyingat 20GPA. 3. Next, with your sprayer running at the sameenginespeedandpressure,collectthe outputofthetwopost‐directingnozzles. Combine the output from these two nozzlesandmeasure.Thecombinedtotal, for example 13 ounces, equals the applicationrateinGPA.Inthiscasethepost directingnozzlesareapplyingat13GPA. 4. Remember, you want the application rate tobethesameforboththepost‐directedand hooded application. To accomplish this, decide which application rate fits your particular needs. In this example we will assumethat13GPApost‐directedisideal. To get your hooded application to be 13 GPA,insteadof20GPA,reducethesizeof thespraytipsunderthehoodandre‐runthe calibration procedure. Continue this processuntilyourhoodedapplicationrate and post‐directed application rate are similar. Scenario 2. Two (2) pumps applying separatetankmixes. 1. 4. Now,reducetheratefora19inchband: [19inchband÷38inchbroadcast]×2.2 oz/AStapleproduct=1.1oz/AStaple Therefore:8acres×1.1floz/A=8.8floz Stapleneededpertank Surfactantneededpertankis,200gallon tank×(1qtsurfactant/100gallonspray).=2 qts.nonionicsurfactantpertank Note: the surfactant rate in this example is calculatedbasedonamountpervolumeofspray mix, rather than amount per acre, it is calculated the same as for broadcast applications. Post‐DirectedandHoodApplications: Youplantouseahoodedsprayertomakepost‐ directed and hooded applications in your 38 inch row cotton. Given, the gallon per acre 3 South Carolina Pest Management Handbook for Field Crops - 2017 From Table 1, the distanceto travel for a 38 inch row is 107 feet. Your course is measuredandyoudriveit.Let’sassumeit took 18 seconds. 2. Park the sprayer and at the same engine speed and desired pressure, collect the outputofthethreenozzlesunderthehood for18seconds.Combinetheoutputofthe threenozzlesandmeasure.Thecombined total, for example 18 ounces, equals the application rate in GPA. In this case the hoods are applying at 18 GPA. 3. Next,withthesprayerrunningatthesame enginespeedanddesiredpressure,collect the output of the two post‐directing nozzles. Combine the output from these two nozzles and measure. The combined total, for example 15 ounces, equals the applicationrateinGPA.Inthiscasethepost directingnozzlesareapplyingat15GPA. 4. Remember,youwanttheapplicationrateto be the same for both the post‐directed and hooded application. To accomplish this, decide which application rate fits your particular needs. In this example we will assumethat15GPApost‐directedisideal. To get your hooded application to be 15 GPA instead of 18 GPA, you have two (2) options. a) First reduce the pressure for the pump applyingunderthehood.Caution:Besure thatafterreducingthepressurethespray tip still produces an acceptable spray pattern. Repeat the calibration procedure. Continue this process until your hooded application rate and post‐directed applicationratearesimilar. b) The second option is to change to a smaller spray tip size under the hood to reduce the application rate to 15 GPA. Repeatthecalibrationprocedure.Continue thisprocessuntilyourhoodedapplication rateandpost‐directedapplicationrateare similar. 1. SPRAYDRIFTMANAGEMENT MikeMarshall,ExtensionWeedSpecialist READthePESICIDELABELforinstructions onpreventingdrift! Useascoarseaspraypatternaspossible. Useasolidconeorflatfanspraynozzletip insteadofahollowconetip. Use a low spray pressure. Be sure your nozzles will maintain pattern at a lower pressure. Don’t apply pesticides under windy or gusty conditions. Read your label for max speeds! Useahand‐heldanemometertodetermine windspeedatthelocationandtimeofyour applications. Determinewinddirection. Don’t spray when the wind is less than 3 mph to avoid spraying in thermal inversions. Maintainrequiredbufferzones. Useanapplicationmethodandformulation thatislesslikelytocausedrift. Use drift control/drift reduction agents in yourtankmix. If possible, don’t spray when the temperatureisabove90–95OF. Know your surroundings, especially the location and distance of sensitive crops, sensitivesites. Asanapplicator,YOUareresponsibleforwherethe chemicalsfromyourapplicationsgo! SPRAYERCLEANING MikeMarshall,ExtensionWeedSpecialist Smallamountsofpesticidesleftinsprayerscan cause serious damage if applied to sensitive crops.Forexample,tracesofgrowthregulator typeherbicidesusedforpastureweedcontrol, 4 South Carolina Pest Management Handbook for Field Crops - 2017 including 2,4‐D, Banvel, Weedmaster, Crossbow,etc.,cancreateseriousproblemsif accidentlyappliedtosensitivebroadleafcrops includingtobacco,cotton,tomatoesandother sensitive plants. Most of these herbicides, particularlytheesterformulationsof2,4‐Dand Crossbow,aredifficulttothoroughlywashout ofasprayer.Therefore,werecommendusinga dedicatedsprayerforapplicationofpastureand brushcontrolherbicides. The sulfonylureas and imidazolinones herbicides, including Accent, Classic, Exceed, Staple,andScepter,havealsocreatedsprayer cleaning challenges. These herbicides have a high unit activity (a small amount of product thatisleftinthesprayerisveryactiveonaper acre basis). Small amounts of these materials cause serious damage to non‐target, susceptible crops. Other products, including Valor SX, have specific clean‐out instructions outlined on the label and should be followed explicitly to prevent subsequent contaminationofsensitivecrops. Yourtankisonlyonepartofthesprayer.You candoanexcellentjobofcleaningthetank,but if chemical residues are left in the hoses, strainers,andpump,seriouscropdamagecan stilloccur.Pesticidescanbeabsorbedintothe lines,inadditiontopolyethyleneorfiberglass tanks,wheretheycanremainforalongtime. Some dry flowable and wettable powder formulationsbuilduponthebottomsofspray tanks,particularlyinsprayerswithinadequate agitation. The longer a spray mix is left in the system, the greater is the potential contamination problem the next time you use thesprayerunit.Sprayersshouldbecleaned as soon as practical and herbicide spray mixturesshouldneverbeallowedtodryin thesprayer. Personal protective equipment that is recommeded on the pesticide label for that product should be worn during clean‐up. Do notcleansprayersnearwells,sinkholes,creeks or other surface water, or near desirable vegetation. Many herbicide labels have sprayer cleanup recommendations on the label. For example, Valor product label recommends a specific tankmixcleanerproduct(Valenttankcleaner) after each use of a flumioxazin containing product. Other products recommend adding householdammoniaat1gallonofammoniafor each 100 gallons of water. Ammonia is also usefulforremoving2,4‐Desterresiduesleftin thesprayerbecauseammoniachangestheless solubleesterintoamorehighlywatersoluble ammonium salt of 2,4‐D. Many commercial tankcleanersareavailableandmostdoagood job, if properly used, of cleaning a sprayer. They are just like ammonia in that plenty of waterandproperprocedurearerequired. Sprayercleaningprocedure: 1. 2. 3. 4. 5. 5 Drainthesprayequipment.Thoroughly rinsethetankandflushhoses,boomand nozzleswithcleanwater.Loosenand physicallyremoveanyvisibledeposits. Fillthesprayerwithcleanwaterandadd householdammonia(onegallonofa3% activeammoniaproductforevery100 gallonsofwater).Flushthehoses,boom andnozzles.Shut‐offtheboomandthen top‐offthetankwithwater.Letthe materialcirculateforatleast15minutes, andthenflushthehoses,boomand nozzlesagain.Drainthetank. Removescreens,strainers,andtips;clean inabucketofwater. Repeatstep2. Thoroughlyrinsethetank,hoses,boom andnozzles. South Carolina Pest Management Handbook for Field Crops - 2017 Important: Remember to clean all other associated application equipment. Personal protectiveequipment,asprescribedonthelabel, shouldbewornduringtheclean‐upprocessand do not clean sprayers near wells, sink holes, creeksorothersurfacewater,orneardesirable vegetation. Stickers:Adjuvantsthatpromoteadherenceof herbicides to the plant foliage. They reduce runoff potential during application and wash offbyrainfall.Theseareusuallyblendedwith wettingagentstoprovidebettercoverageand arecalledspreader‐stickers. AntifoamingAgents:Thesematerialsreduce foam in a sprayer system so that pumps and nozzlescanoperateeffectively. Compatibility Agents: Aid in holding herbicides in solution when mixed with pesticidesorfertilizers. Crop Oils: These are non‐phytotoxic light petroleum or vegetable oils that contain surfactants.Usemuch likeasurfactant.Hasa tendencytoburncroptissue.Choosecropoil whichcontains80%orgreateroil,andtherest assurfactantsoremulsifiers. DriftControlAgents:Materialsusedtoreduce the number of fine particles in the spray patternwhichcouldresultindriftdamage. HERBICIDEADJUVANTS MikeMarshall,ExtensionWeedSpecialist SprayAdditives Asprayadditiveisanysubstanceaddedtoan herbicide tank mix to enhance performance. Adjuvants are classified on the basis of their use rather than chemistry. Adjuvants include surfactants, emulsifiers, wetting agents, stickers, de‐foamers, compatibility agents, cropoils,anddriftcontrolagents. TypesofSprayAdditives: Surfactants (surface‐active‐agent): Are used toimproveemulsifying,dispersing,spreading, wetting,orothersurfacemodifyingproperties of a liquid. Three types of surfactants are emulsifiers,wettingagents,stickers.Choosea non‐ionic surfactant based on composition. A surfactant with 80% or greater active ingredientisagoodchoice. Emulsifiers: Substances that promote suspensionofoneliquidinanother.Theyare mostcommonlyusedtodisperseoilinwater. These are usually contained in the herbicide packageformulation. Wetting agents: Reduce interfacial tensions between surfaces that would normally repel each other. These allow a spray solution to spread and adhere better to waxy cuticles of plants.Nonionicsurfactants(NIS)arethetype usually added to a spray tank. They are good dispersing agents, stable in cold water, and havelowtoxicitytoplantsandanimals. PESTICIDESAFETY RobertBellinger,SafetyEducationCoordinator PesticideStorageTips Areyoudoingthese? o Store your pesticides in a detached structure? o Haveastoragebuildingwithasoundroof? o Have a storage building with a sound, liquid‐prooffloor? o Store your pesticides in their original container? o Have pesticides you store with intact, readablelabels? o Store your pesticides separately from gasoline,otherfuelsandsolvents? 6 South Carolina Pest Management Handbook for Field Crops - 2017 Properly rinse procedure your empty pesticidecontainers! The proper rinse procedure requires that youplanahead! Readandfollowlabeldirections! Wear the required protective clothing and equipment. Rinse containers immediately after emptying because pesticides will dry or solidify quickly and become difficult to remove. Consider the volume of the rinsate when fillingthesprayertank.Leaveenoughroom in the sprayer tank to accommodate the rinsatebeforefillingthetank. Have back‐flow protection when filling the sprayertankandrinsingthecontainer. You have two acceptable ways to rinse emptypesticidecontainers: 1)Triple‐rinsingor 2) Pressure‐rinsing (jet‐rinsing) using a device specifically manufactured to wash container interiors. Triple‐rinsecontainerinstructions: Allow empty pesticide container to drain into the sprayer tank for at least 30 seconds. Fill container one‐quarter full of clean water or appropriate spray rinse diluent. Replace cap securely and roll, swirl and shake the contents vigorously for at least onefullminutetorinseallsurfaces! Remove container cap and empty rinsate intothespraytank.Allowthecontainerto drainforatleast30seconds. Repeatthefill,shakeanddrainprocedure two(2)moretimes,usingcleanwater. Properly dispose of the rinsed containers as soon as possible. Dispose of caps with thecontainersunlessrecycling. Plastic and plastic‐lined bags can be triple‐rinsed.Forpaperandfiberbagsand similar containers, completely empty the contents into the tank. Open both ends of the container to remove any remaining pesticideandtopreventreuse. Howtopressure‐rinsecontainers: Allow the empty pesticide container to drain into the sprayertankfor atleast 30 seconds. Hold the container upside down over the sprayer tank opening so that rinsate will run into the sprayer tank. For ease and safety, puncture through the bottom of metal containers and through the side of plasticcontainerswithappropriatetoolor pressure‐rinsing nozzle‐follow specific manufacturerdirections. Thoroughly rinse the empty container for the time interval recommended by the pressure‐rinsenozzlemanufacturer,butno lessthan30seconds,usingatleast40psi waterpressure. Properlydisposeofyourrinsedcontainers as soon as possible. Dispose of caps with containers,unlessrecycling. PESTICIDERESISTANCE MANAGEMENT RobertG.Bellinger,ExtensionEntomologist Repeated use of pesticides – herbicides, insecticides, fungicides, nematicides, rodenticides,andothers‐canleadtoresistance intherespectivepestpopulations.Applicators are encouraged to rotate products with differing modes of action within a crop year. Many pesticide labels now give detailed guidance. Resistance may be defined as “a heritable change in the sensitivity of a pestpopulation that is reflected in the repeated failure of a producttoachievetheexpectedlevelofcontrol when used according to the label recommendationforthatpestspecies”. 7 South Carolina Pest Management Handbook for Field Crops - 2017 Resistancearisesthroughtheover‐useand/or misuseofapesticideagainstapestspeciesand resultsfromtheselectionofresistantformsof the pest and the resulting evolution of pest populationsthatareresistanttothatpesticide and its mode of action (MoA). Pesticides do NOTcausethemutationsforresistance. In the majority of cases, not only does resistance render the selecting compound much less effective but it often also confers cross‐resistance to other chemically related compounds. Cross‐resistance occurs when resistance to one pesticide confers resistance toanotherpesticide,evenwherethepesthas notbeenexposedtothelatterproduct. The objective of successful Pesticide Resistance Management is to delay the evolutionofpestresistancetopesticides,orto help regain susceptibility in pest populations inwhichresistancehasalreadyarisen. Because many pest populations are usually largeinsizeandquicklyreproduce(especially mites,manyinsectsandmostplantpathogens), thereisalwaysariskthatpesticideresistance mayevolvequickly,especiallywhenpesticide aremisusedorover‐used. Ifyouobtainlesscontrolofapestwithagiven pesticide than you are accustomed to, or believeisreasonabletoexpect,firstchecktobe sure that you applied the pesticide properly accordingtothelabelinstructions.Ifyoumade your application properly, next consider if there were any extreme environmental conditions–veryhot,verycool,heavyrain,etc. Ifnoneoftheseconditionsexisted,orarenot believed to have an effect on the product’s performance, then pesticide resistance is a possibility. Doing everything you can to delay pesticide resistance is important for the obvious reasons.Thereisnotverymuchnewchemistry comingtoallowustoswitchtonewpesticide modes of action. For instance, there have not been any significant new modes of action for herbicidesinaboutthreedecades.Whilenew herbicide products are coming onto the market, often in conjunction with herbicide resistant crop varieties, the herbicides themselves are some of the oldest herbicides wehave,forinstance2,4‐D. There are several ways to delay pesticide resistance. The best is to use Integrated Pest Management(IPM)andtouseeconomicinjury thresholds to determine when to apply a pesticide(s). Other methods include rotating crops to prevent buildup of the same pest populations over time, to use the lowest effective rate or rate recommended by the pesticidelabeloraknowledgeableexpert,and makespotorperimeterapplicationsonsmall or defined pest populations. When using pesticides,rotatepesticidemodesofactionby rotatingpesticidechemicalfamilies. For most growers, however, knowing what pesticides to use to do this has been difficult because of a lack of knowledge of the many different modes of action. Until recently pesticide labels did not provide much informationtoassistinthesedecisions. To help growers and others combat pesticide resistance a number of national and international resistance action committees have been formed by the pesticide industry andotherstoaddresstheproblemofpesticide resistance.Thesecommitteesarebasedonthe different major pesticide groups. So, for herbicides there is an Herbicide Resistance Action Committee (HRAC), an Insecticide Resistance Action Committee (IRAC) for insecticides, a Fungicide Resistance Action Committee (FRAC) for fungicides, and so on. These committees have studied the modes of actionoftherespectivepesticidefamiliesand developedasystemtohelpgrowersandothers 8 South Carolina Pest Management Handbook for Field Crops - 2017 PESTICIDEAPPLICATION RECORDKEEPING betterselectpesticidesfromdifferentpesticide chemicalfamiliestoallowuserstoeffectively rotate the modes of action and thus combat pesticide resistance in their pests. This information is now appearing on pesticide labels.Inadditiontothesystemdevelopedby the respective Action Resistance Committees, manypesticidemanufacturersarebeginningto supplyinformationonresistancemanagement on their labels in sections titled “Resistance Management”. Todate,genericpesticideproductstendnotto have as much information as brand name pesticide products. When you want to rotate modes of action against your pests, first make sure that whatever pesticide you select is labeled for your intended use. Next, look for a pesticide group number on the label, or a statement indicating the pesticide group. Using these pesticide group numbers, you do not have to know or understand the complex modes of action of these chemicals, you just have to select a product(s) with a different group number that is labeled for your pest management need. Examples of group numberswhentheyappearonpesticidelabels are usually in the upper right hand corner of thelabel,looklikethis: GROUP 4A INSECTICIDE GROUP 3 HERBICIDE GROUP 11 FUNGICIDE RobertBellinger,PesticideSafetyCoordinator CertifiedPrivateApplicatorsarerequiredto keeprecordsoftheirapplicationsofRestricted Use Pesticides (RUPs). This federal requirementisadministeredbytheUSDAand in South Carolina is enforced by the DepartmentofPesticideRegulation. Theinformation–“dataelements”–required to be kept are actually minimal. Private Applicators will likely want to record more information on their applications, all of their applications, to help with their present and futurepestmanagementefforts.Goodrecords help you trouble‐shoot application problems andduplicatepestmanagementsuccesses. The data elements required to be kept on eachRUPapplicationare: The brand/product/trade name of the pesticide EPAproductRegistrationNumber Totalamountofpesticideproductapplied Sizeofareaorthenumberofunitstreated CroporSiteappliedto Actuallocationoftheapplication Dateofapplication:Month,Day,Year Certified applicator name and license number Recordsmustbemadewithin14daysofeach application of an RUP. Records must be maintained for a minimum of two (2) years fromthedateoftheapplication. Spot treatments: Spot applications aresmall applicationswhichtotallessthan1/10thofan acre,andtheyaremadeinthesameday.Spot 9 South Carolina Pest Management Handbook for Field Crops - 2017 cropsinSouthCarolinaareheavilydependent on honey bees for good pollination. Annual farmcashreceiptsofcropsharvestedinSouth Carolinathataredependentonhoneybeesfor pollination are estimated at $25 million. This does not include home‐grown vegetables and fruits and plants for wildlife that are highly dependentonbeesforpollination.Someofthe fruitsandvegetablesthatarehighlydependent onbeesforpollinationareapples,cantaloupes, cucumbers, squash, strawberries, and watermelon. Use integrated pest management recommendations whenever possible to minimize harmful effects to our beneficial insects.Manypesticidesareextremelytoxicto bees.Thosepesticidesthataretoxicorhighly toxic to bees will have a bee protection warningstatementonthelabel.Thepesticide applicator should always review the product label directions carefully before each use and followtheguidelinestoprotectourpollinators, which include native bees as well as honey bees. Keep in mind that even herbicides and fungicidescanhavenegativeeffectsoninsect pollinators and can have synergistic effects whencombinedwithotherpesticides. It is not only the formulation of the chemical pesticide that is important, applicators must also be aware of the proper dose. Pesticides shouldbeusedonlywhennecessary,especially if flowering plants are present or nearby and are attractive to bees. Select the least toxic pesticidetogetthejobdonewhenpossibleand usetheleasthazardousmethodofapplication. Granular pesticide formulations are safest. Directed sprays applied with ground equipment are the next safest method for applying pesticides to protect bees. Aerially applieddustsorspraysarethemostlikelyto contact bees and cause problems. Apply pesticideswhentheairiscalmtoreducedrift into areas where bees may be foraging or nesting.Ifapesticideapplicationisnecessary, applications do not apply to nurseries or greenhouses. ForSpottreatmentsyoumustrecord: Dateofapplication‐month,day,year Brandorproductname EPARegistrationNumber Totalamountofpesticideapplied Location of the pesticide application, designated as “spot application” with a shortdescription. Recordkeepingtips: Record all three (3) identifiers for your RUP. They’reallonthelabel! TheProductorBrand(Trade)name The Common Chemical name of the activeingredients TheEPARegistrationNo. KeepadditionalinformationthatwillhelpYOU better achieve YOUR pest and pesticide managementobjectives.Forinstance,amount of water used, spray pump pressure, boom height, nozzle spacing tip used, tractor speed or rpms, other equipment settings, and weather information such as temperature, rainfallthe24hoursbeforeand24hoursafter the application, wind speed (recorded at the site of the application at the time of the application), notes on any application problems, and any other information that wouldbeusefultoyou. Youarerequiredtokeeprecordsofanyworker or handler pesticide safety training you conduct or have conducted for your ag employees. HONEYBEESTEWARDSHIP JenniferTsuruda,ExtensionApiculturist Honeybeesareourmostbeneficialinsect.The estimatedvalueofhoneybeepollinationinthe US is $14 billion. Many commercially grown 10 South Carolina Pest Management Handbook for Field Crops - 2017 apply in the evening when bees are not present.Ifmanagedbeecoloniesarepresent,it is best to give the beekeeper plenty of notice (3‐4 days if possible) of your intentions. The beekeeper has the option to relocate their beehivesifadjacentfieldsaretobesprayed.If therearemanybeehivesorhivesthatcannot bemovedonshortnotice,thebeekeepermay cover their beehives with wet burlap for no longerthan2days.Itwillbenecessaryforthe beekeeper to spray covered hives with water and keep the burlap wet, especially in hot weather. Beekeepers are advised to cooperate with growers in the area to help protect bees and are encouraged to have a contract with the landowner. Beekeepers should scout the area before bee colony placement to gain a good understanding of local farming practices, especially the use of highly toxic pesticides. Beekeepers are ill advised to place their coloniesinhighpestdensityareas,astheymay require multiple pesticide applications. An exampleiscottongrowingareaswherevarious pests are expected. Beekeepers should post their name and contact information in the apiary or on colonies for identification purposes.Informationontherelativetoxicities of insecticides and miticides (used in specific crops)tohoneybeesandnaturalenemiesmay befoundatwww.ipm.ucdavis.edu. Mosquito abatement programs should take intoconsiderationtheprotectionofourinsect pollinators.Manyofthepesticidesusedtokill mosquitoes will also kill honey bees. Beekeepers are urged to contact county officials who manage mosquito abatement programs to inform them of the location of their apiaries, so their honey bees can be protected. Clemson University has started a bee stewardship program to facilitate communication between beekeepers and pesticide applicators and prevent accidental poisoningofhoneybees.Beekeeperscanmap their hive locations and licensed pesticide applicators can access this information when they have an application planned. The applicatorcanthencontactthebeekeepersin theareaoravoidapplyingpesticidesnearthe hives.Interestedindividualsfrombothsidesof thisissueareencouragedtoreadmoreabout the program on the Clemson University Beekeeping website and can sign up for the programthereaswell. 11 South Carolina Pest Management Handbook for Field Crops - 2017 RELATIVEHONEYBEESENSITIVITYTOWARDPESTICIDES JenniferTsuruda,ExtensionApiculturist PESTICIDETOXICITYTOWARDHONEYBEES GroupIHighlyToxic:Severebeelossesareexpectedifthefollowingpesticidesareappliedtofloweringcropsorweeds whichareattractivetobeesorwhenthesepesticidesareappliednearabeehive.Thesepesticideswillremainhazardous toforagingbeesforupto24hoursorlongerafterapplication. abamectin(Agri‐Mek,Zephyr) acephate(Orthene,Address) aminocarb(Matacil) arsenicals avemectin(AVID) azinphosmethyl(Guthion) bendiocarb(Ficam) benzenehexachloride(BHC) bifenthrin(Brigade,Capture) bifenazate(Acramite) bonyl(Swat) calciumarsenate carbaryl(Sevin,Sevin80S,Sevin carbofuran(Furadan) carbosulfan(Vantage) XLR‐Plus) chlordane chlorpyrifos(Dursban,Eradex, chlorethoxyfos(Fortress) Lorsban) clofentezine(Apollo) clothianidin(Poncho600) crotoxyphos(Cyodrin) cyfluthrin(Baythroid) cyhalothrin(Karate,Warrior) cypermethrin(Ammo,Cymbush) d‐phenothrin(Sumithrin) decamethrin(Decis) deltamethrin(Decis) diazinon(Diazinon,Spectracide) dichlorvos(DDVP,Vapona) dicrotophos(Bidrin) dimethoate(Cygon,Dimethoate, Rebelate) emamectin(Proclaim) endosulfan(Thiodan) EPN esfenvalerate(Asana) ethylparathion(Parathion) famoxadone(Famoxate) famphur(Famphos) fenitrothion(Sumithion)) fenpropathrin(Danitol,Dasanit) fensulfothion(Dasanit) fenthion(Baytex) fenvalerate(Ectrin,Pydrin) fipronil flucythrinate(PayOff) famoxadone(Famoxate) formetanate(Carzol) gamma‐cyhalothrin,(Proaxis) heptachlor hexythiazox(Savey) imidacloprid(Admire,Provado) imidan indoxacarb(Avaunt,Steward) lambda‐cyhalothrin(Commodore, leadarsenate lindane(BHC) Warrior) LPOS(Sulfotine,RAIDTVK) malathion(Cythion,ULV) methamidophos(Monitor, Tameron) methidathion(Supracide) methiocarb(Mesurol) methomyl(Lannate,Nudrin) methprene methylparathion(Penncap‐M) methylparathionEC mevinphos(Phosdrin) mexacarbate(Zectran) monocrotophos(Azodrin) naled(Dibrom)2 omethoate(Folimat) oxamyl(Vydate>1lb/A) parathion phenthoate(Cidial) phenamiphos(NemacurP) permethrin(Ambush,GardStar, phorate(ThimetEC) phosdrin Pounce) phosmet(Imidan) phosphamidon(Dimecron) polymer‐encapsulatedmethyl parathion(Penncap‐M) prallethrin(ETOH) proparite(Omite) propoxur(Baygon) pyridaben(Pyramite) pyrazophos(Afugan) resmethrin(Synthrin,SPB‐1382) spinosid(XDE‐105,Tracer) tebufenozide(Confirm) TEPP2 tetrachlorvinphos(Appex,Gardona) thiamethoxam(Actara,Platinum) tralomethrin(Scout) zeta‐cypermethrin(Fury,Mustang) 12 South Carolina Pest Management Handbook for Field Crops - 2017 PESTICIDETOXICITYTOWARDHONEYBEES(cont) GroupIIModeratelyHazardous:Thesecanbeusedaroundbeesifdosage,timing,andmethodofapplicationare correct,butshouldnotbeapplieddirectlyonbeesinthefieldordirectedatthehive. aldicarb(Temik) aspon(ASP‐51) aldicarbsulfoxide acetamiprid(Assail) aluminumphosphide(Phostoxin) Bacillusthuringiensis(Di‐Beta) bifenazate(Floramite) binapacryl biothion carbaryl(SevinXLRformulation, carbanolate(Banol) carbophenothion(Trithion) Sevinmol) chlorfeninphos(Sopona) coumaphos(Agridip,Asunthol,Co‐ crotoxyphos(Ciodrin) Ral) cypermethrin(Ammo) cyromazine(Trigard) DDT deltamethrin(Decis) demeton(Systox) demeton‐s‐methyl(Metasystox) diatomaceousearth(Diatect) disulfoton(Di‐Syston) dichlofenthion dioxathion(Delnav) DSMA emamectinbenzoate(Proclaim) endosulfan(Thiodan<0.5lb/A, endrin ethion(Ethodan) Thionex) ethoprop(Mocap) ethyulan(Perthane) fluvalinate(Mavrik) fonofos(Dyfonate) formetanate(Carzol) fundal(Galecron) malathion(Cythion,ULV<3fl oz/A) methyldemeton(Metasystox) mirex MSMA neem(Azatin,Neemix) oilsprays(superiortype) oxamyl(Vydate<0.5lb/A) oxydemeton‐methyl(MetasystoxR) paraquat perthane phorate(Thimet) phosalone(Zolone) pirimicarb(Pirimor) profenfox(Curacron) propamocarb(Carbamult) propamocarbhydrochloride(Banol) pymetrozine(Fulfill) Pyramat pyrethrum pyriproxyfen(Esteem) RDE(Rhonthane) ronnel(Co‐Ral,Korlan) sabadilla spinosad(SpinTor,ConserveSC, sulprofos(Bolstar) stirofos(Rabon) Entrust) sumithrin(Anvillollo) summeroil tartaremetic TDE temephos(Abate) terbufos(Counter) trichlronate(Agritox) thiacloprid(Calypso,YRC‐2894) thiamethoxam(Actara,Platinum) thiazopyr(Mandate,Visor) thiodicarb(Larvin) trichoronate(Agritox) zephyr 13 South Carolina Pest Management Handbook for Field Crops - 2017 PESTICIDETOXICITYTOWARDHONEYBEES(cont) GroupIIIRelativelyNonhazardous:Thesecanbeusedaroundbeeswithaminimumriskofinjury. allethrin(Pynamin) amitraz(Mitac) amitrole avermectin(Agr‐Mek) azadirachtin(Align) azoxystrobin(Abound) Bacillusthuringiensis(Biobit) DiPel,Full‐Bac,Javelin,MVP) Baculovirusheliothis Beauveria(Mycotrol) benomyl(Benlate) binapacryl(Morocide) bordeauxmixture bromopropylate(Acarol) bromoxynil capsaicin(HotPepperWax) captan carbaryl(SevinG,BaitG) carbofuran(FuradanG) chloramben chlorbenzide(Mitox) chlorobenzilate(Acaraben) chlordimeform(Fundal) chlorobenzilate(Acaraben) chlorothalonil(Bravo) coppercompounds(Kocide) copperoxychloridesulphate copper8‐quinolinolate coppersulfate(Monohydrated) cryolite(Cryolite,Kryocide) cyromazine(Trigard) dalapon dazomet(Mylone) demeton(Systox) dexon diazinon(DiazinonG) dicamba(BanvelD) dichlone(Phygon) dicofol(Kelthane) difolatan diflubenzuron(Dimilin) dimite(DMC) dinobuton(Dessin) dinocap(Karathane) diquat disulfoton(Di‐SystonG) dodine(Cyprex) dyrene endothall EPTC(Eptam) ethephon(Ethrel) ethion(Ethion) ethoprop(MocapG) fenbutatin‐oxide(Vendex) fenhexamid(Elevate) fenson(Murvesco) ferbam fluvalinate(Mavrik,Spur) folpet(Phaltan) garlicbarrier genite923 glyodin(Glyoxide) heliothispolyhedrosisvirus hexythiazox(Savey) kaolin(Surround) karathane(Dinocap) kepone malathion(MalathionG) menazon(Saphos) mancozeb(DithaneM‐45) maneb(DithaneM‐22) MCPA menazon(Saphos) metaldehyde(MetaldehydeBait) methoprene(Altosid) methoxychlor(Marlate) metiram(Polyram)‐F1 monuron(Telvar) myclobutanil(Rally) nabam(Parzate) nemagon neotran nicotine nicotinesulfate ovex oxythioquinox(Morestan) pentac propargite(Omite) pyrethrum(natural) pyrimidinamine(Vangard) pyriproxyfen(Esteen) rotenone(Rotenone) ryania(Rynodine) sabadilla silvex simazine(Princep) soap(M‐Pede) sulfur tebufenozide(Confirm) TDE(Rhothane) tetradifon(Tedion) tetram thioquinox(Eradex) thiram(Arasan) toxaphene trichlorfon(Dylox) trifloxystrobin(Flint) vendex zineb(Dithane) ziram 2,4‐D 2,4‐DB 2,4,5‐T Fungicides Mevinphos(Phosdrin*),Naled(Dibrom*),andTEPPhaveshortresidualactivityandkillonlythebeescontactedattimeoftreatmentorshortly thereafter.Theyareusuallysafetousewhenbeesarenotinflight;theyarenotsafetousearoundcolonies. 3Not all strains of Bacillus thuringiensis insecticides are safe for bees. The label for XenTari® (Valent BioSciences), with active ingredient B. thuringiensisaizawai,reads"Thisproductishighlytoxictohoneybeesexposedtodirecttreatment.Donotapplythisproductwhilebeesareactively visitingthetreatmentarea." 4List or information derived in part from Delaplane, K., University of Georgia, Tarpy, D., North Carolina State University, Fell, R., Virginia Tech, Johansen,C.A.andMayer,D.F.PollinationProtection.1990,WicwasPress;BulletinE‐53‐W,Hunt,G.J.,PurdueUniversity;EnvironmentalEntomology 33(5):1151‐1154. 1 2 14 South Carolina Pest Management Handbook for Field Crops - 2017 MODEOFACTIONFORHERBICIDES MikeMarshall,ExtensionWeedSpecialist MODEOFACTION(MOA)FORHERBICIDES Siteof Action Group 1 MOA ChemicalFamily (ies) Howitkillstheplant Product Examples ACCase Inhibitors Arloxyphenoxy propionate(FOPS) Blocks the first step in fatty acid synthesis in grasses, broadleaves are naturally resistant to thefopsanddimsduetoaninsensitiveACCase enzyme. FOPS: Assure II, FusiladeDX DIMS: Select MAX, Poast Plus SU:Accent, Classic, Beacon IMI:Cadre, Raptor, Scepter PM:Staple Cyclohexanedione (DIMS) 2 ALSInhibitors Sulfonylurea(SU) Blockstheproductionofbranchedchainamino acids (isoleucine, leucine, and valine) in the plant. Plant death occurs due to insufficient Imidazonlinone(IMI) branchedchainaminoacidlevelsatthegrowing points. Pyrimidines(PM) 3 4 Microtubule Protein Inhibitor Synthetic Auxins Dinitroaniline(DNA) Phenoxy(PX) BenzoicAcid(BA) Interferes with the alignment of the spindle apparatus during mitosis and prevents normal celldivisioninroottissue. Synthetic auxins mimic the natural plant hormoneIAA.Theseherbicidesaffectcellwall plasticity and nucleic acid metabolism which leadstoinhibitedcelldivisionandgrowthinthe meristemregions(growingpoints). CarboxylicAcid(CA) 5 Photosystem IIInhibitor Triazine(TZ) Triazinone(TN) 6 Nitriles(NT) 7 Benzothiadiazinones (BZ) Ureas(UR) 8 9 Fatty Acid/Lipid Biosynthesis Inhibitor EPSPSynthase Inhibitor Thiocarbamate(TB) Glycines(GC) PS II herbicides inhibit photosynthesis by bindingtotheQB‐bindingsiteontheD1protein of the photosystem II complex in the chloroplast.ItblockselectronflowfromQAto QBandstopsCO2fixationandproductionofATP and NADPH2 which is the energy needed for NT:Buctril plant growth and development. Plant death occursduetoexcessfreeradicalsdestroyingcell BZ: membranes. Basagran UR:Lorox, Direx, Cotoran Mostsusceptibleplantsfailtoemergefromthe TB:Tillam soil.Germinationisnotinhibitedbutgrowthof grass coleoptiles/broadleaf epicotyls ceases belowsoilsurface Glycines inhibit EPSP synthase enzyme which GC: leads to the depletion of the aromatic amino Glyphosate acidstryptophan,tyrosine,andphenylalanine. 15 DNA:Prowl, Treflan, Sonolan PX:2,4‐D, 2,4‐DB BA:Clarity, Banvel, Status CA:Stinger, Milestone TZ: Atrazine, Simazine, Caparol TN:Sencor South Carolina Pest Management Handbook for Field Crops - 2017 MODEOFACTION(MOA)FORHERBICIDEFAMILIES(cont) Siteof Action Group 10 12 13 28 14 15 22 MOA ChemicalFamily (ies) Glutamine Synthesis Inhibitor PhosphinicAcids (PA) Howitkillstheplant Phosphinicacidsinhibittheactivityof glutamine synthetase which converts glutamateandammoniatoglutamine. Accumulation of ammonia to lethal levelsdestroysplantcellsandtissue. Phytoene Pyridazinone(PZ) Pyridazinone inhibits the phytoene Desaturase desaturase enzyme in the carteniod Inhibitor biosynthesispathway Isoxazolidinone inhibits the 1‐deoxy‐ DOXP Isoxazolidinone D‐xyulose 5‐phosphate synthase synthase (IA) (DOXP),akeycomponentintheplastid Inhibitor isoprenoidbiosynthesispathway. Pyrazole and triketones inhibit the 4‐ HPPD Pyrazole(PA) hydroxyphenyl‐pyruvate dioxygenase inhibitor (4‐HPPD) which affects carotenoid biosynthesis. Triketone(TE) These herbicide families deplete the carotenoid (accessory pigments in photosynthesis) pool that protects chlorophyll in the plant which results inacharacteristicbleaching(white)of theplanttissue. PPO Diphenylether These herbicides inhibit the inhibitors (DE) photoporphyrinogen oxidase (PPO), an enzyme that is responsible for N‐ chlorophyll and heme biosynthesis. phenylphthalimide PPO inhibition leads to accumulation (NP) of PPIX (protoporphyrin IX) which Arytriazinone creates free radical oxygen in the cell (AT) anddestroyscellmembranes. VLFA Chloroacetamide Acetamidesareherbicidesthatinhibit inhibitors (CA) very long chain fatty acid synthesis (VLFA) in shoot tissue during germinationofsensitiveplants. Photosystem Bipyridyliums Bipyridyliums are herbicides that IInhibitor (BP) capture electrons fromphotosystem I complex in the chloroplast and are reduced to form herbicide free radicals. These free radicals destroy cellmembranes. 16 ProductExamples PA:Liberty PZ:Solicam,Zorial, Brake IA:Command PA:Balance,Corvus TE:Callisto,Impact, Laudis DE:Flexstar,Reflex, Blazer,Cobra NP:Resource,Valor AT:Spartan,Aim,Cadet CA:DualMagnum, Intrro,Warrant,Outlook, Parrlay,Zidua BP:Gramoxone,Reward South Carolina Pest Management Handbook for Field Crops - 2017 CROPREPLANTGUIDELINESFOLLOWING HERBICIDEAPPLICATION MikeMarshall,ExtensionWeedSpecialist Wheat Tobacco Sunflower Peanuts Grain Sorghum Cotton Corn Soybeans M=months,D=days,Spring=Thespringfollowingapplication,‐‐‐=noinformation Aatrex Acuron Accent/Q Achieve Aim Anthem AnthemATZ Armezon AssureII AuthorityMTZ AxialXL Axiom BalanceFlexx Banvel/Clarity Basagran Beacon Beyond BicepIIMagnum Boundary Breakfree BreakfreeATZ Buctril Bullet/Lariat Cadet Cadre Callisto Canopy Caparol Capreno Cinch CinchATZ Clarity 8floz/A 16floz/A 24floz/A 25‐64floz/A Classic Cobra Command Corvus Cotoran4L Crusher Dawn 0D 0D 0D 30D 0D 0D 0D 0D 120D 10/41M 90D 0D 0D 120D ‐‐‐ 14D 0D4/8.5M5 0D 4M 0D 0D 30D 0D 0D 9M 0D 10M Spring 0D 0D 0D 0D 0D 120D 120D 8M None 9M 0D 8M 0D 10M Spring 10M 10M 106D 0D 4M Spring 9M 0D 12M 90D 8M 10M 120D ‐‐‐ 8M 9M Spring 8M Spring Spring 30D Spring Spring 18M 10M 10M Spring 10M 0D Spring 21D 120D 120D 120D 7M None 0D 10M 0D 1M 0D 0D 10M 10M 30D 0D 18M Spring 9M 120D 18/122M 90D 12M 6M 120D ‐‐‐ 8M 9M 0D 12M Spring Spring 30D 0D Spring 18M 0D 10M Spring 10M 0D 0D 15D 120D 120D 120D 9M None 9M 17M 9M 10M 18M 17 Spring 10M 10M 106D 0D 4M Spring 9M 120D 12M 90D 12M 11M 120D ‐‐‐ 8M 9M Spring 12M Spring 15M 30D Spring Spring 0D 10M 8M Spring 11M 0D Spring 120D 120D 120D 120D 6M None 9M 11M 8M 1.5M 10M Spring 10M 15D 106D 0D 0D Spring 9M 0D 0D 90D 0D 6M 120D ‐‐‐ 8M 0D Spring 12M Spring Spring 30D Spring 0D 9M 10M 0D Spring 10M 0D Spring 14D 28D 120D 120D 0D None 0D 9M 9M 1M 0D Spring 18M 10M 106D 0D 4M Spring 9M 0D 12M 90D 12M 6M 120D ‐‐‐ 8M 0D4/9M5 Spring 12M Spring 15M 30D Spring Spring 26M 10M 18M Spring 18M 0D Spring 120D 120D 120D 120D 18M None 12M 17M 12M 10M 18M Spring 18M 10M 106D 12M 18M Spring 18M 120D 12M 90D 12M 18M 120D ‐‐‐ 8M 9M Spring 12M Spring 15M 30D Spring Spring 9M 10M 10M Spring 12M Spring Spring 120D 120D 120D 120D 9M None 0D 17M 12M 10M 18M Spring 4M 4M 30D 0D 4M Spring 3M 120D 4M 0D 7D/4M3 4M 120D ‐‐‐ 3M 0D4/3M5 Spring 4.5M 4M 15M 30D Spring Spring 4M 120D 4M Spring 4M 4.5M Spring 15D 30D 45D 120D 3M None 12M 4M 3M 3M 4M South Carolina Pest Management Handbook for Field Crops - 2017 Wheat Tobacco Sunflower Soybeans Peanuts Grain Sorghum Corn Cotton CropReplantandRotationRestrictionsGuideforHerbicides(cont) M=months,D=days,Spring=Thespringfollowingapplication,‐‐‐=noinformation Define Degree DegreeXtra Devrinol Direx/Diuron USEPATTERN16 USEPATTERN27 LAYBY Distinct Dual8E DualMagnum DualIIMagnum Envive Envoke ET/ETX Evik Expert Express Fierce 3.0oz/A 3.75oz/A Finesse Firestorm FirstRate FirstShot Flexstar FlexstarGT/GT3.5 FulTimeNXT FusiladeDX Fusion Gangster Glyphosate Goal/GoalTender GramoxoneSL GuardsmanMax HalexGT Harnass HarmonyExtra HarmonyGT/XP Harness HarnessXtra HornetWDG Huskie Impact Instigate Interline Intrro KeystoneNXT Laudis 0D 0D 0D 12M 4M Spring Spring 30D 12M 12M 12M 8M 7M 0D 11M 0D 14D 4M Spring Spring 12M 4M Spring Spring 30D 12M 12M 12M 10M 7M 0D 11M Spring 14D 7D8/1M9 45D9/30D8 30D 14M 0D 9M 14D 10M 10M 0D 60D 60D 9M 0D 10M 0D 0D 0D 0D 21D 0D 0D Spring 0D 9M 0D 0D 0D ‐‐‐ 0D 0D 2M Spring10 0D 9M 14D 0D 0D Spring 0D 0D 9M 0D 7D 0D Spring 10M 7D 21D 7D Spring Spring 18M Spring10 9M 10M 0D ‐‐‐ Spring 10M 12M 0D 0D 12M 4M Spring Spring 30D 12M 12M 12M 12M 7M 30D 11M 0D 14D 18M 18M Spring10 0D 9M 14D 10M 10M Spring 60D 60D 9M 0D 10M 0D 0D 0D 45D 21D 0D 0D Spring 12M 4M 9M 10M 180D ‐‐‐ Spring 10M 12M Spring Spring 12M 4M 12M 12M 120D 12M 12M 12M 8M 7M 30D 11M Spring 45D 4M 4M Spring10 0D 9M 45D 10M 10M Spring 0D 0D 9M 0D 60D 0D Spring 10M 45D 45D 45D Spring Spring 18M Spring 9M 18M 180D ‐‐‐ Spring 18M 18 0D 0D Spring 12M 4M 12M 12M 30D 12M 12M 12M 0D 7M 0D 11M Spring 14D 0D 0D 6M11 0D 0D 7D 0D 0D Spring 0D 0D 0D 0D 7D 0D Spring 10M 0D 14D 0D Spring Spring 10.5M 4M 9M 10M 0D ‐‐‐ Spring 8M 12M Spring Spring 12M 4M 12M 12M 120D 12M 12M 12M 18M 18M 30D 11M Spring 45D 4M 4M Spring10 0D 30M 45D 18M 18M Spring 0D 0D 30M 0D 60D 0D Spring 10M 45D 45D 45D Spring 24M 18M 9M 9M 10M 180D ‐‐‐ Spring 18M 12M 0D Spring 0D 4M 12M 12M 120D Spring Spring Spring 10M 7M 30D 11M Spring 45D 18M 18M Spring10 0D 18M 45D 18M 18M Spring 0D 0D 30M 1M 60D 0D 24M 10M 45D 45D 45D Spring 24M 18M Spring10 18M 18M 180D ‐‐‐ Spring 18M 12M Spring 4M 180D 4M 12M 12M 30D 4.5M 4.5M 4.5M 4M 3M 0D 3M Spring 0D 30D 2M 4M 0D 4M 0D 4M 4M 4M 60D 60D 3M 0D 10M 0D Spring 120D 7D 0D 0D 4M Spring 4M 1M 3M 4M 70D ‐‐‐ 4M 4M South Carolina Pest Management Handbook for Field Crops - 2017 CropReplantandRotationRestrictionsGuideforHerbicides(cont) LaybyPro12 0‐0.6lbai 0.61‐1.0lbai 1.01‐1.6lbai 1.61‐2.2lbai Leadoff Liberty280SL Linex/Lorox Lumax Marksman MCPA Micro‐Tech MSMA NIC‐IT Nimble Optill Option Osprey Outlook ParallelPCS Parazone Peak Poast/PoastPlus PowerFlex/HL Prefix Prowl/ProwlH2O Pursuit Python Raptor Quelex Reflex RealmQ ReportExtra Resicore ResolveDF 1.0oz/A 2.0oz/A ResolveQ/Q(mp) 1.25oz/A 2.5oz/A ResolveSG 1.0oz/A 2.0oz/A Resource RevulinQ Rhythm Sandea Wheat Tobacco Sunflower M=months,D=days,Spring=Thespringfollowingapplication,‐‐‐=noinformation 4M 4M 4M 4M 4M 4M 4M 8M 12M 8M 8M 4M 4M 4M 8M 12M 8M 12M 4M 4M 4M 12M 12M 12M 12M 8M 8M 8M 0D 1M 10M 10M 1M 10M 10M 0D 0D 180D 180D 0D 180D 180D 0D 0D 0D 4M 0D 4M 4M 0D Spring Spring Spring Spring 18M 18M 0D Spring 0D Spring Spring Spring 24M None None None None None None None None None None None None None None None None None None None None None 0D 10M 18M 18M 15D 10M 18M 21D 21D 21D 45D 14D 45D 45D 8.5M 18M 18M 4M 0‐1M13 18M 9.5M 7D 60D 60D 60D 14D 60D 60D 12M 90D 10M 90D 90D 30D 10M 0D Spring Spring 0D 0D Spring Spring 12M 12M 12M 12M 12M 12M Spring 0D 0D 0D 0D 0D 0D 0D 1M 10M 1M 10M 10M 22M 18M 30D 0D 30D 0D 0D 30D 0D 9M 9M 9M 9M 5M 9M 12M 10M 1M 18M 10M 0M 18M 18M Spring 0D 10M 0D 0D 0D 0D 8.5M 18M 18M 0D 0D 18M 9.5M 0D 18M 12M 4M 0D 18M 9M 8.5M 9M 9M 9M 0D 9M 9M 3M 3M 3M 9M 3M 3M 15M 10M 0D 10M 10M 0D 18M 18M 0D 10M 10M 10M 10M 10M 10M 1814M 18M 1814/415M ‐‐‐ 616/1814M ‐‐‐ ‐‐‐ 0D 18M 10.5M 18M 10.5M 18M 18M 0D 10M 10M 18M 10M 10M 18M 0D 10M 18M 18M 10M 10M 18M 0D 1M 10M 10M 10M 10M 10M 0D 10M 18M 18M 10M 10M 18M 0D 1M 10M 18M 10M 10M 18M 0D 10M 18M 18M 10M 10M 18M 0D 30D 30D 30D 0D 30D 30D 0D 10M 10M 10M 10M 10M 10M 8M 0D 18M 10M 0D 18M 18M 1M 4M 2M 6M 9M 18M 36M 19 Soybeans Peanuts Grain Sorghum Corn Cotton 3M 4M 8M 12M 3M 70D 4M 4.5M 10M None None None 8M 0D 4M 60D 7D 4M 4.5M 0D 0D 30D 30D 4.5M 4M 4M 4M 3M 0D 4M 4M 017/418M 4M 3M 3M 3M 3M 4M 4M 30D 4M 4M 2M South Carolina Pest Management Handbook for Field Crops - 2017 20 Wheat Soybeans Peanuts M=months,D=days,Spring=Thespringfollowingapplication,‐‐‐=noinformation 9.5M 18M 11M 11M 0D 18M 0D 120D 0D 120D 120D 120D None None None None None None 0D 0D 0D 0D 0D Spring 0D 1.5M 0D 4M 0‐1M19 4M 1‐2M19 0D 3M 0D 5M 5M 0D 4M 0D 6M 2‐3M19 6M 10M 1M 18M 10M 1M 0D 10M 10M 18M 18M 10M 0D Spring Spring Spring 0D 0D 0D 10M 12‐18M20 12M 12M 0D 30M 10M 12M 10M 12D 0D 0D 4M 12M 10M 4M 0D 0D 0D 18M 12M 18M 10.5M 18M 10M 0D 24M 10M 10M 10M 7D 120D 120D 120D 120D 120D 0D 10M 10M 18M 15D 10M 0D 10M 10M 18M 15D 10M 10M 10M 10M 18M 10M 10M 0D 10.5M 10.5M 10.5M 10.5M 10.5M 100D 100D 100D 100D 100D 100D 0D 10M 10M 18M 15D 10M 18M 10M 18M 0D 0D 30M 7M 7M 7M 7M 7M 18M 0D 26M 12M 26M Spring 18M 0D Spring 0D Spring Spring Spring 0D Spring 0D Spring Spring Spring 9M 9M 9M 9M 0D 30M 7M 8M 9M 30M 0D 30M None None None None None None 0D Spring Spring Spring Spring Spring 5M 0D 5M 0D 0D 0D 10M 18M 18M 18M 0D 18M 100D 100D 100D 0D 0D 100D 7‐30D21 7‐28D22 30D 0D 0D 30D 7‐30D21 7‐28D22 30D 0D 0D 30D 14‐30D21 2M 30D 0D 0D 2M 10M 10M 10M 18M 0D 10M 18M 30M 18M 30M 0D 30D 0D Spring 0D Spring 1M23‐2M24 Spring 2M23‐3M24 0D Spring 0D Spring Spring 0D 0D 0D Spring 0D Spring 0D 18M 12M 10.5M 10.5M 10.5M Tobacco Scepter Sentrallas Select/SelectMAX Sequence Sharpen 1.0oz/A 2.0oz/A 3.0oz/A Solida 1.0oz/A 2.0oz/A Sonalan Sonic Spartan SpartanCharge Stanza StapleLX Status Steadfast SteadfastQ SteadfastATZ Stinger Storm Stout Strongarm Suprend SureStartII Surpass SurpassNXT SurveilCo‐Pack SynchronyXP Tillam TopNotch Treflan Trivence UltraBlazer ValorSX/ValorEZ 1.0oz/A 1.5‐2.0oz/A 2.1‐3.0oz/A ValorXLT SoilpH<7.0 SoilpH>7.0 Verdict 10‐12oz/A 13‐15oz/A Warrant WideMatch Grain Sorghum Corn Cotton Sunflower CropReplantandRotationRestrictionsGuideforHerbicides(cont) 9.5M 120D None Spring 4M 5M 6M 18M 18M Spring 30M 0D 0D 18M 10M 120D 18M 18M 18M 10.5M 100D 18M 18M 7M 26M Spring Spring 30M 9M None Spring 5M 18M 100D 30D 30D 2M 10M 18M Spring Spring Spring 10.5M 3M 0D None 4.5M 0D 0D 0D 3M 4M Spring 4M 4M 4M 4M 6M 120D 4M 4M 8M 0D 40D 4M 4M 3M 4M 4M 4M 3M 3M None 4M 5M 4M 40D 30D 30D 2M 4M 4M 4M 4M 4M 0D South Carolina Pest Management Handbook for Field Crops - 2017 Xtendimax 11floz/Aorless 22‐33floz/A 34‐44floz/A Yukon WideMatch Zest Zidua 1.0oz/A 2.0oz/A 3.0oz/A 4.0oz/A ZiduaPRO 2,4‐D 2,4‐DB M=months,D=days,Spring=Thespringfollowingapplication,‐‐‐=noinformation 0D 0D25/2126D 15D 120D 0D27/14D 120D 120D 0D 120D 120D 120D 120D 0D25/120D 0D27/28D 0D 120D 120D 120D 120D 0D25/120D 0D27/120D 30D 4M 2M 6M 9M 18M ‐‐‐‐ 0D 18M 12M 10.5M 10.5M 10.5M 10.5M 0D 10M 18M 10M 15D 11M 10M 18M 4M 0D 4M 6M 1M 0D 18M 4M 0D 4M 6M 2M 0D 18M 4M 0D 4M 10M 4M 0D 18M 4M 4M 4M 12M 4M 0D 8.5M 18M 18M 4M 30D 18M 18M Onlyreplantinthesamegrowingseasonwithcropsregisteredfor2,4‐Duse Onlyreplantinthesamegrowingseasonwithcropsregisteredfor2,4‐DBuse Wheat Tobacco Soybeans Peanuts Grain Sorghum Cotton Corn Sunflower CropReplantandRotationRestrictionsGuideforHerbicides(cont) 15D 30‐45D 45‐60D 2M 0D 4M 1M 1M 4M 6M 4M 1Fieldcornmaybeplanted4monthsafterAuthorityMTZwasappliedat14oz/Aorless. 2Grainsorghummaybeplanted12monthsafterAuthorityMTZwasappliedat20oz/Aorless. 3Rotationis7dayswhenratesof10oz/AofAxiomorlesshavebeenapplied;otherwise,wait4monthstoplantwheat. 4Clearfieldcorn,sunflower,andwheat 5Non‐Clearfieldcorn,sunflower,andwheat 6DIREXUSEPATTERN1=BandedDIREXPreemergenceorPostemergenceapplicationonly 7DIREXUSEPATTERN2=BandedDIREXPreemergenceandPostemergenceorBroadcastDIREXPreemergence(andpreplant)or BroadcastDIREXpreemergenceplusBandedDIREXpostemergenceapplications. 8Reducedtillageproduction. 9Conventionaltillageproduction. 10Afieldbioassaymustbeconductedforcropsnotlistedonthelabel.Toconductafieldbioassay,plantstripsofthecropyouwant togrowtheseasonfollowingherbicideapplicationandmoniterforcropsafety. 11STStolerantsoybeansonly 12CroprotationintervalsarebasedonthecumulativeamountofDIURONinLAYBYPROappliedtoasiteinthepreceding12 months. 13Usethelongerintervalwithintherangeslistedforcropsgrownoncoarsetexturedsoilswithorganicmatterlessthan2.0%. 14Applicationratesabove0.4oz/A;followthe18‐monthrotationintervalforgrainsorghum,non‐STStolerantsoybeans,andfield corn. 15Applicationrates0.2to0.4oz/A;followthe4‐monthrotationintervalforgrainsorghum. 16Applicationrates0.2to0.5oz/A;followthe6‐monthrotationifplantingSTStolerantsoybeans. 17Applicationrates0.2to0.4oz/A;nowaitingintervalforwheat. 18Applicationrates0.5oz/A;followingthe4‐monthrotationintervalforwheat. 19Usethelongerintervalwithintherangeslistedforreplantingsoybeans(i.e.,2monthsforcoarsetexturedsoilswithorganic matterlessthan2.0%anda1monthforcoarsetexturedsoilswithorganicmattergreaterthanorequalto2.0%) 20Cottonmaybeplantedafter12monthswhereSONICwasappliedatratesof5oz/Aorlessandmeetthefollowingconditions: medium/finesoils;pH<7.2;andrainfallorirrigationexceed15inchesafterapplication. 21Forcorn:Plantaminimumof14days(minimumorstrip‐till)or30daysafterVALORSX(conventionaltillagesystem) 22For cotton: After Valor SX (2.0 oz/A or less) application, conduct strip till operation a minimum of 7 days before planting (regardless of crop residue levels). After conducting strip‐till operation, apply Valor SX herbicide a minimum of 28 days before planting(<30%cropresiduelevels)or21daysbeforeplanting(>30%cropresiduelevels). 23Forcoarsetexturedsoilswithlessthan2%organicmatter 24Allothersoiltypes. 25BollgardIIXtendFlexcottonvarietiesonly. 26A minimum accumulation of 1 inch of rainfall or overhead irrigation and a waiting interval of 21 days following XTENDIMAX applicationpriortoplantingcotton. 27RoundupReady2Xtendsoybeanvarietiesonly. 21
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