Facies (2010) 56:157–172 DOI 10.1007/s10347-009-0192-6 O R I G I N A L A R T I CL E Carbonate mud mounds, conglomerates, and sea-level history in the Katian (Upper Ordovician) of central Sweden Mikael Calner · Oliver Lehnert · Michael Joachimski Received: 30 October 2008 / Accepted: 21 April 2009 / Published online: 15 May 2009 © Springer-Verlag 2009 Abstract The Katian (Upper Ordovician) facies succession of the Siljan district, central Sweden, records some of the most prominent environmental changes in the Ordovician of Baltoscandia. These changes include two separate phases of major sea-level drawdown that were of basinwide and presumably global importance. The Wrst regression and lowstand terminated an entire generation of carbonate mud mounds (the Kullsberg Limestone) and resulted in the formation of polymict carbonate conglomerates (Skålberg Limestone) belonging to the Amorphognathus superbus Zone. New stable isotope data from the Amtjärn quarry shows that this is immediately after the peak of the Guttenberg Carbon Isotope Excursion (GICE), which reaches a 13C peak value at 3.3‰ in the uppermost Amorphognathus tvaerensis Conodont Zone. A second major regression and sea-level lowstand is manifested by palaeokarst morphologies in the Slandrom Limestone, which formed close in time to the comparably minor Waynesville positive carbon excursion in the basal Amorphognathus ordovicicus Conodont Zone. The widespread exposure associated with this latter lowstand terminated carbonate production in much of the basin, and, during the subsequent Xooding, organic-rich, graptolitic shale formed across most of Baltoscandia. The two corresponding M. Calner (&) GeoBiosphere Science Centre, Lund University, Sölvegatan 12, 223 62 Lund, Sweden e-mail: [email protected] O. Lehnert · M. Joachimski GeoCenter Northern Bavaria, University of Erlangen-Nürnberg, Schloßgarten 5, 91054 Erlangen, Germany e-mail: [email protected] sequence boundaries are amalgamated at the top of truncated carbonate mud mounds in the Siljan district, resulting in a pronounced Middle Katian hiatus in the immediate mound areas. Keywords GICE · Conglomerates · Black shale · Glaciation · Katian · Siljan district · Sweden Introduction The Katian and Hirnantian stages (Upper Ordovician) are today recognized as time intervals with repeated changes in the global carbon cycle, inferably reXecting climatic changes on a global scale (Bergström et al. 2007). Recent studies by Kaljo et al. (2004, 2007), Bergström (2007), and Bergström et al. (2007, 2009a, 2009b) on 13C chemostratigraphy have summarized up to six positive 13C excursions through this interval (Bergström et al. 2009a, Wg. 2). The oldest of these excursions, the ChatWeldian (Early Katian) Guttenberg Isotope Carbon Excursion (GICE) was originally identiWed by Hatch et al. (1987) and has subsequently been discussed from Laurentia also by Patzkowsky et al. (1997) and Ludvigson et al. (2004). The array of associated changes in fauna and facies during this event were Wrst summarized from Baltoscandia by Jaanusson (1976). It has more recently been detailed by Ainsaar et al. (1999, 2004), almost exclusively based on sections in the East Baltic area, and collectively referred to as the ‘Middle Caradoc Facies and Faunal Turnover’. The causes for the carbon cycle anomaly and the biotic event are not yet fully understood, although several authors have proposed climatic cooling and/or a glaciation in this stratigraphic interval (e.g., Ainsaar et al. 2004; Tobin et al. 2005; Saltzman and Young 2005). In Baltoscandia, the GICE is followed by 123 158 three, or possibly four, positive 13C excursions in the Katian before the prominent and well-known Hirnantian Isotope Carbon Excursion (HICE; Marshall et al. 1997; Kaljo et al. 2001, 2004; Ainsaar et al. 2004). These smaller excursions have subsequently been identiWed in Upper Ordovician type strata of North America, and partly correlated with the East Baltic record, and were named the Kope, Fairview, Waynesville and Whitewater 13C excursions by Bergström et al. (2007, Fig. 1; 2009a, Wg. 2). The recurrent Upper Ordovician 13C excursion has challenged the hypothesis of an isolated brief glacial episode in the latest Ordovician (Brenchley et al. 1994, 2003) and the timing for the onset of Icehouse conditions following the long Lower Palaeozoic Greenhouse period (e.g., Kaljo et al. 2003a, 2003b; Ainsaar et al. 2004; Saltzman and Young 2005). However, the shift from Icehouse to Greenhouse in this time interval is a matter of debate and oxygen-isotope studies on conodont apatite by Buggisch et al. (2008) show no correlation between positive shifts in 13C and cooling, of which the latter is expressed by increasing values in 18O. Instead, the GICE is a period of warming according to 18O data, but has been interpreted as a cooling event based on the carbon isotope shift (e.g., Young et al. 2005). Detailed studies of the environmental evolution during the corresponding time interval are therefore important in gauging the relative eVects of diVerent stable isotope excursions. Investigations on the environmental evolution during the Katian in Sweden are few and the aim with this paper is to present new sedimentary and stable isotope data from sections in the classical Siljan district of central Sweden, representing the Central Baltoscandian Confacies Belt of Jaanusson (1976; Scandinavian basin of Ainsaar et al. 2004) and the cratonic interior of Baltoscandia (Fig. 1). We concentrate on a stratigraphical interval encompassing the Kullsberg Limestone, Skålberg Limestone, Slandrom Limestone, Fjäcka Shale, and the Jonstorp Formation, and our data set mainly derives from the classical and now abandoned quarry at Amtjärn. Comparison is made to nearby localities as well as with the Borenshult-1 drillcore from Östergötland (Calner and Lehnert 2008; Fig. 1). The recent recognition of the beginning of the GICE in the lowermost Kullsberg Limestone (Bergström et al. 2009b; see also data in Tobin et al. 2005) has provided initial information about the time relationship between mound growth and this global positive carbon excursion. Additional, complementary stable-isotope data from the upper Kullsberg Limestone are presented herein to help constrain the precise timing of mound formation and termination. Geological setting and local stratigraphy The Lower Palaeozoic succession in the Siljan district is preserved in an impressive Middle Devonian astrobleme 123 Facies (2010) 56:157–172 with a diameter calculated at ca. 65–75 km [see review by Henkel and Aaro (2005) and the recent International Geological Congress 2008 Field excursion guide no. 10 by Lindström et al. (2008)]. Radiometric dating methods have more recently conWrmed the close coincidence in time between this impact event at 376.8 § 1.7 Ma and the Frasnian–Famennian mass extinction event (Reimold et al. 2005). Strata in the remaining ring structure are generally steeply inclined or slightly overturned. Fault planes with a few meters of vertical displacement or even overthrusting of entire formations are evident in several of the abandoned or still-active quarries in the area. The Upper Ordovician part of the succession (Fig. 2) is typiWed by the development of two separate carbonate mud mound generations separated by a thin veneer of shale and argillaceous carbonates formed in an open-marine, relatively shallow intracratonic sea. The carbonate mud mounds are conWned to the Upper Sandbian through Lower Katian Kullsberg Limestone and the Upper Katian to Hirnantian Boda Limestone, respectively (see Jaanusson 1982; Ebbestad et al. 2007; Fig. 2). The mounds range in thickness from several tens to more than 100 m and have diameters of several hundreds to more than 1,000 m, the Boda mounds being markedly larger than the Kullsberg mounds (Jaanusson 1982, p. 27; see also Bergström et al. 2004a). In spite of the impressive size of the mounds, both generations and the intervening bedded limestone can be studied in individual quarries in the Siljan district. The overall stratigraphical relationship between the Kullsberg carbonate mounds and the adjacent strata was outlined in brief by Jaanusson (1982). He noted that the oldest beds that rest on the carbonate mound Xank facies was a ‘nodular, argillaceous calcarenite’, which he referred to as the Skålberg Limestone (see Jaanusson 1973, 1982, p. 27). Towards the top of the mounds, these strata were successively replaced by the Moldå Limestone, the Slandrom Limestone, and the Fjäcka Shale, the latter draping the mound (Jaanusson 1982). Accordingly, the stratigraphical framework associated with the mounds varies between diVerent localities depending on what part of the mound is exposed. This stratigraphical relationship, with successively younger units overlying the mounds towards their tops, was explained by Jaanusson (1982) as a postmortem burial of the mound without the inXuence of any relative sea-level changes: ‘when the growth of a mound had ceased, deposition on the top of the mound did not resume until the level of surrounding sediments began to approach the level of the mound top’ (Jaanusson 1982, p. 26–27). Hence, the higher parts of the mounds should be associated with a hiatus––due to non-deposition–– that increase in magnitude towards the top. These younger units have traditionally been considered as inter-mound facies (e.g., Jaanusson 1982, p. 29). As shown herein, this is an unfortunate term because most of these strata formed after Facies (2010) 56:157–172 159 Fig. 1 Location of the Siljan district in central Sweden and Ordovician palaeogeography of Baltoscandia. a Map of the Siljan astrobleme with the ring-shaped distribution of Palaeozoic rocks. b Distribution of the Kullsberg and Boda carbonate mud mounds and the location of the quarries investigated for this study (a, b are modiWed from Ebbestad et al. 2007). c General palaeogeographical reconstruction of the Baltoscandian basin showing the position of the Siljan district and the Borenshult-1 core in Östergötland (modiWed from Nielsen 2004; Stouge 2004). Note that all investigated locations belong to a deeper part of the basin––the Central Baltoscandian Confacies Belt of Jaanusson (1976, 1995) the termination of the Kullsberg mounds and there is no evidence for the existence of productive mounds during their formation. Accordingly, since these sediments were not produced by the mounds this is an ‘inter-mound facies’ only in a geographical sense. An updated review on the Ordovician geology and biostratigraphy of the Siljan district was presented by Ebbestad et al. (2007). A detailed summary of Ordovician conodont biostratigraphy and its relation to published carbon isotope stratigraphic work in the Siljan area is given by Bergström (2007). Methods The south entrance section at the Amtjärn quarry was documented. As far as the relationships between the mound and enclosing facies are concerned, this is at present the best exposure with the most complete stratigraphy. About 50 representative rock samples from the diVerent stratigraphical units were collected for preparation of polished slabs. Another 43 small rock samples (sample series AMT1–AMT44) were collected for wholerock analysis of stable carbon isotopes. The isotope samples 123 160 Facies (2010) 56:157–172 Fig. 2 Stratigraphic framework of the Late Sandbian through Hirnantian of the Siljan district and correlation of this international stratigraphic standard with the regional zonation (grey shading denotes hiatuses). See Bergström (2007) for a recent discussion on the conodont biostratigraphy of this interval and Ebbestad et al. (2007, Fig. 3) for full references to the non-conodont zonation. ModiWed from Ebbestad et al. (2007) were drilled from these samples using a micro-drill. Stable-isotope analyses were performed using a Kiel III device connected to a ThermoFinnigan 252 mass spectrometer at the Geocenter of Northern Bavaria, in Erlangen, Germany. 13C and 18O values are reported in per mil relative to V-PDB (Vienna Peedee belemnite). Accuracy and precision of the carbon-isotope measurements were checked by replicate analysis of standards NBS19 and laboratory standards. Reproducibility was better than §0.05‰ (1). For comparison, coeval strata were studied and sampled in various detail at the nearby Kullsberg and Skålberget quarries as well as at the locality Fjäcka, the latter representing facies formed at a greater distance from any mound structure (this locality was treated by Ainsaar et al. 2004). Comparison is also made to the Borenshult-1 core in Östergötland, which has been recovered to function as a reference section for studies on the Upper Ordovician of Sweden (Calner and Lehnert 2008). A series of papers from Baltica (e.g., Ainsaar et al. 1999, 2004; Bergström et al. 2009b; Kaljo et al. 2003a, 2003b, 2004, 2007; Meidla et al. 2004; Schmitz and Bergström 2007) have clearly illustrated the value of carbon-isotope stratigraphy for basinwide correlations across the diVerent facies boundaries. It has similarly been demonstrated that some of the events may well be correlated to Laurentian basins (Saltzman et al. 2003; Kaljo et al. 2004; Young et al. 2005; Bergström et al. 2007). For this reason, carbon-isotope stratigraphy is herein used for correlations to other sections in Sweden and the East Baltic. 123 General facies relationships at Amtjärn quarry The bulk of the Kullsberg Limestone in the Siljan district is formed by high-relief, stromatactis-bearing carbonate mud mounds that are composed of a massive and pure micritic core with a halo of fossiliferous, stratiWed pelmatozoan wackestone, packstone and grainstone Xank beds (Hadding 1941; Jaanusson 1982; Riding 2002; Tobin et al. 2005). The facies relationship between one of the carbonate mud mounds and the adjacent strata is excellently illustrated in the Amtjärn quarry. The Kullsberg carbonate mud mound core facies is now excavated but originally attained a length of ca. 260 m and a thickness of 34–35 m (Thorslund 1935). Mapping of the southern part of this quarry for the present study conWrms the general stratigraphical observations of Jaanusson (1982) although we hesitate to apply the term Moldå Limestone to any of the strata (because of lack of strata similar to the Moldå Limestone in its type section at Fjäcka). The currently exposed succession includes, from below, the Kullsberg Limestone (Xank facies), Skålberg Limestone, Slandrom Limestone, Fjäcka Shale and the lower portions of the Jonstorp Formation (Figs. 3, 4). The uppermost ca. 6 m of the underlying Dalby Limestone have previously been exposed (Thorslund and Jaanusson 1960, their Ludibundus beds in Wg. 12; Bergström 2007, p. 37) on top of the quarry and just west of the measured section, but this exposure is not readily accessible. The thick Kinnekulle K-bentonite, which deWnes the upper boundary of the Dalby Limestone in many places in Sweden, has not been documented from the Amtjärn quarry (S. M. Bergström, pers. comm. August 2008) where the contact between the Dalby Limestone and the Kullsberg Limestone is gradational (Bergström 2007). Facies (2010) 56:157–172 161 Fig. 3 Field-based sketch showing the narrow gully that forms the southern entrance section at the Amtjärn quarry and the identiWed rock units. Strata are tilted by about 90° with successively younger strata exposed to the east. Black dots in the map illustrate sampling levels for carbon-isotope analyses (sample series AMT1–AMT44 in Fig. 5; samples 1–12 were taken in the southern part of the main quarry whereas samples 13–44 were taken in the southern wall of the southern entrance section, with some overlap). Encircled letters with arrow indicate the position of the camera for photographs a–i in Fig. 4. Note also that this Wgure is used as a base for interpretation of the larger-scale stratigraphical relationships in Fig. 9. The proWle to the right was measured along the southern wall and thus illustrates only the upper part of the section, starting near the reference clay between units A and B (see Fig. 5 for a full section) Facies and chemostratigraphy at the south entrance section Overview photographs of the studied sections are shown in Fig. 4, whereas the measured proWle and 13C data are presented in Fig. 5. Kullsberg Limestone The Kullsberg Limestone is well exposed in the western wall of the main quarry (Fig. 4a), in the south-western most part of the main quarry (Fig. 4b), and in the western parts, including the high-wall, of the south entrance section. The strata are thin to thick bedded and the dominating lithofacies is a medium to coarse-grained pelmatozoan wackestone to packstone with a dark greenish matrix (Fig. 6a, b). Bedding planes often yield abundant larger fossil fragments and disarticulated macro-fossils, notably brachiopods and bryozoans showing little or no abrasion. This main part of the Kullsberg Limestone has 13C values concentrated around 2‰ with a slight increase in the uppermost two meters of unit A (Fig. 5). The uppermost 1.70 m of the Kullsberg Limestone show notably thicker bedding than underlying strata and are mainly composed of a reddish-colored skeletal grainstone (unit B in Fig. 3; Fig. 6d). The lowermost part of this grainstone unit yields small-scale, irregular stromatactis with two clearly vis- ible cement zonations (Fig. 6c; see Tobin et al. 2005 for a description of stromatactis in the Kullsberg Limestone). This uppermost meter of the Kullsberg Limestone yields the acme of the GICE with a maximum 13C value of 3.3‰ (Fig. 3). Recent work in North America shows conclusively that the entire GICE is within the Amorphognathus tvaerensis conodont Zone (e.g., Young et al. 2005) and the same seems to be the case also in Baltoscandia where the index conodonts are very scarce in the critical interval (S. M. Bergström written comm. 2009; see also Bergström 2007). Accordingly, based on carbon isotope stratigraphy also the youngest parts of the Kullsberg Limestone at the Amtjärn section belong to the upper Amorphognathus tvaerensis conodont Zone and not in the Amorphognathus superbus Zone as shown in the stratigraphic charts of the volume by Ebbestad et al. (2007). The boundary to the overlying Skålberg Limestone is disconformable. Skålberg Limestone The Skålberg Limestone belongs to the Amorphognathus superbus Zone, has a patchy distribution in the Siljan district, and has previously been reported as a tectonic breccia or a slump breccia (Bergström 2007). The unit is only a few meters thick and may thin out over short distances within a quarry (Jaanusson 1982). It is currently poorly exposed in the type section at the Skålberget quarry, but well exposed at Amtjärn. 123 162 123 Facies (2010) 56:157–172 Facies (2010) 56:157–172 䉳 Fig. 4 Photo-plate showing the main lithological units at the Amtjärn quarry. a View from southeast of the western quarry wall, exposing steeply dipping crinoidal packstone facies of the lower Kullsberg Limestone. b Lowermost portion of the studied section (younger strata towards the left). The northern opening to the south entrance section is in the left-most part of the photo. White dots illustrate the positions of stable isotope samples 1–12 (the sample to the far right being sample no. 1, AMT1). c Lower part of the studied section. The complex bedding in the upper part of C2 and enclosing C1 and C3 units suggests minor tectonic overprint in this part of the succession. d Middle part of the studied section, mainly showing the well-bedded Slandrom Limestone (D1–D3). Note the successive, upward increase in bed as well as parasequence thicknesses. Hammer for scale. e Detail of C3 conglomerate. The large clast below hammer is 0.64 m across. f Detail of the two lowermost parasequences in the Slandrom Limestone. g Detail of the uppermost part of unit C2 represented by skeletal packstone with abundant solution vugs and rust. h Detail of C1 conglomerate. Note matrix-supported fabric and rounded lithoclasts. Several of the clasts in the photograph are also shown in Fig. 6. i Detail of the graptolitiferous Fjäcka Shale Based on the overwhelming majority of rounded clasts that are matrix-supported, we re-interpret this deposit as a conglomerate, although with local inclusions of breccia. At Amtjärn, the Skålberg Limestone can be subdivided into three subunits, represented by a lower, 1.20-m-thick polymict carbonate para-conglomerate (C1), a middle, well-bedded and 1.75-m-thick pelmatozoan packstone-grainstone unit (C2), and an upper, 2.20-m-thick polymict carbonate para-conglomerate (C3). Clast size in the two conglomerate units is generally 5–15 cm, but rarely ranges up to ca. 1 m in the C3 unit (cf. Fig. 4e). Clast shape is variable but generally rounded to subrounded, sometimes with oblate forms. A small portion of the clasts is highly angular and still retains the form of a broken stratum. In the C1 unit, the clast composition is generally a medium to coarse-grained pelmatozoan wackestone or packstone that sometimes show weathering-induced alteration of the matrix. In addition to these lithologies, the C3 conglomerate unit includes clasts of glauconitic, skeletal grainstone. The form and lithology of a set of lithoclasts are shown in Fig. 6g–l (see also Fig. 4e, h). The middle pelmatozoan packstone-grainstone unit (C2) can be further diVerentiated in three subunits, herein informally named a, b, and c (Fig. 5). The lowermost unit (a) is a pelmatozoan packstone that closely resembles the pelmatozoan-rich Xank facies of the Kullsberg mounds (cf. Fig. 6a, b, e). This unit is overlain by a pelmatozoan grainstone unit (b) with abundant, rust-Wlled solution vugs in the upper part. The b-unit is also topped by a rusty, pitted surface (Fig. 4g) that may be a disconformity surface. The c-unit is a packstone rich in pelmatozoan and bryozoan skeletal fragments (Fig. 7a). The 13C values decline in the C1 and C3 units and show a small peak in the interjacent C2 unit. 163 Slandrom Limestone The Slandrom Limestone is 3.02 m thick in the south entrance section and strikingly well bedded (Fig. 4d, f). The lithology is generally a massive, pale olive green, grey or brown, very Wne grained mudstone to packstone with a Wne bioclastic hash originating from pelmatozoans and trilobites (Fig. 7a–e). The limestone alternates with thin beds of calcareous mudstone and greenish, calcareous shale. Other beds are nearly devoid of skeletal grains and are very similar to the so-called ‘aphanitic limestone’ (a very dense, evenly textured and extremely Wne grained limestone) reported from the Slandrom Limestone elsewhere in Baltoscandia. These plain-looking lithologies also include thin, horizontal, and calciteWlled vugs. Based on the variation in bed thickness and argillaceous content, this unit can be separated into three parasequences (D1–D 3; Fig. 4d, f). The 13C values range from ca. 0.3–1.2‰, showing an increase in values upwards with the highest 13C values observed in the uppermost parasequence (D3; Fig. 5). At Fjäcka, in the north-eastern part of the Siljan district, the thickness of the Slandrom Limestone is 7.20 m. The primary bedding is partly disrupted and especially the upper ca. 2 m of the unit has a splintery appearance with sharp, angular facets and easily falls apart. From this upper part, spar-Wlled solution pipes are evident from cut and polished surfaces. Similarly, solution pipes and meteoric diagenesis is observed also in the Borenshult-1 core in which the Slandrom Limestone is only ca. 1 m thick. Fjäcka Shale The Slandrom Limestone is sharply overlain by the Fjäcka Shale, which is 5.8 m thick at Amtjärn and consists of dark brown to black, graptolitiferous shale (Fig. 4i). The lowermost part is slightly calcareous. In the northern part of the nearby Kullsberg quarry the Fjäcka Shale overlies a Kullsberg mound with a conspicuous unconformity (Fig. 8). Jonstorp Formation (lower part) Only the lowermost ca. 4 m of the Jonstorp Formation were studied and sampled. The lowermost 0.5 m (f in Fig. 3) is a Wne-grained skeletal wackestone (Fig. 7e) that is nearly identical to the lithology of the Slandrom Limestone. Above this thin unit, the Jonstorp Formation is represented by a greyish-green, nodular pelmatozoan wackestone (Fig. 7f), very similar to the lower Jonstorp Formation in e.g., the Borenshult-1 core in Östergötland. 123 164 Fig. 5 Sedimentary proWle and 13C record from the southern entrance section of the Amtjärn quarry showing close relationship between mound termination and the peak of the GICE. Black data points denote samples taken in the southern part of the main quarry (samples 1–12) whereas red data points denote samples taken in the southern wall of the southern entrance section (samples 13–44). Note that the Skålberg conglomerates occur within the falling limb of the GICE. Note also strongly negative 13C values in the topmost part of the Slandrom Limestone, inferably due to meteoric diagenesis at this level. A local, provisional sequence stratigraphic framework is included: HST highstand systems tract, FSST falling stage systems tract, LST lowstand systems tract, TST transgressive systems tract. Correlation to other areas, where palaeokarst occurs at the top of the Slandrom Limestone suggest that the transgressive surface at the top of that formation at Amtjärn also is a sequence boundary 123 Facies (2010) 56:157–172 Facies (2010) 56:157–172 Fig. 6 Photo-plate showing carbonate facies types at the Amtjärn quarry (units A–C3). a Argillaceous, greenish pelmatozoan wackestone (dense) typical for the Xank facies of the Kullsberg Limestone (unit A). b Greenish pelmatozoan wackestone (Kullsberg Limestone, unit A). c Reddish, skeletal packstone-grainstone with well-developed stromatactis in the youngest Kullsberg Limestone Xank facies (lowermost unit B). d Pelmatozoan grainstone of the Kullsberg Limestone (unit B). e Pelmatozoan wackestone of the Skålberg Limestone (lower unit C2). f Pelmatozoan grainstone of the 165 Skålberg Limestone (lower unit C2). g Skeletal wackestone lithoclast of the C1 conglomerate. h Weathered pelmatozoan wackestone–packstone lithoclast of the C1 conglomerate. i Pelmatozoan wackestone lithoclast of the C1 conglomerate. j Pelmatozoan packstone lithoclast with joints (C1 conglomerate). k Glauconitic pelmatozoan grainstone lithoclast of the C2 conglomerate. l Pelmatozoan wackestone lithoclast of the C2 conglomerate. The color variegation in samples d and f is due to later weathering. Scale bars 1 cm 123 166 Fig. 7 Photo-plate showing carbonate facies types at the Amtjärn quarry (units D–G). a Pelmatozoan-bryozoan packstone from uppermost part of C2-unit. b Bioturbated, skeletal packstone from the Slandrom Limestone (D2-unit). c Skeletal wackestone from the Slandrom 123 Facies (2010) 56:157–172 Limestone (D2-unit). d Aphanitic limestone from the Slandrom Limestone (top of D3-unit). e Skeletal wackestone from the lowermost Jonstorp Formation (F-unit). f Skeletal wackestone with dark-greenish argillaceous partings from the lowermost Jonstorp Formation (G-unit) Facies (2010) 56:157–172 167 Fig. 8 A clear-cut truncation of the Kullsberg carbonate mud mounds is locally evident. The photograph shows a conspicuous unconformity between one of the mounds and the overlying Fjäcka Shale (overlain by Quaternary gravel). Two sequence boundaries previously reported from open-shelf facies in Baltoscandia are amalgamated here (see text). Note that it is primarily the Xank facies of the mound that is exposed here. The cut-out strata here and elsewhere in mound facies of central Sweden inferably formed the Skålberg conglomerates. Northern wall in the Kullsberg quarry. The part of the section seen on the photo is about 6 m high Interpretation of the facies succession cally lower on the peripheral mound Xank facies (e.g., at Amtjärn and Skålberget). Importantly, the micro-facies variety of the lithoclasts (e.g., bioturbated skeletal wackestone, glauconitic grainstone, and pelmatozoan packstone) in the conglomerates implies that a series of diVerent depositional environments were subaerially exposed. This provides further evidence for a major sea-level fall. The roundness of the cobbles similarly implies that they were reworked in extremely shallow water for a prolonged time (perhaps on the shoreline created by exposure of the mound), although encrustations, which could possibly be expected, have not been identiWed. The clasts that are conspicuously angular or still retain a stratum form were obviously not heavy reworked and are interpreted to reXect a short transport of collapsed strata, possibly due to karstiWcation. The large size (ca. 0.5–1.0 m) of some of these clasts suggests that the depositional slope along the margins of the partly exposed mound was relatively steep. Thorslund (1932) brieXy investigated the unconformity at Kullsberg quarry and reported several vertical Wssures that penetrated the mounds. These Wssures were interpreted to be of tectonic origin (Thorslund 1932, p. 154; Jaanusson The local depositional conditions and the position of the studied section relative the (now excavated) mound core can be understood simply by reconstructing the map of the southern entrance section. Such reconstruction clearly shows how the Skålberg, Slandrom, and Fjäcka Formations can be traced laterally into or over the previous mound structure (Fig. 9). Accordingly, the measured succession in the south entrance section represents the proximal mound Xank facies as well as the strata that formed during (the conglomerates) and after (the Slandrom Limestone) exposure and termination of the mound. This discussion instead focuses on the depositional history in terms of relative sea level. The angular unconformity at the Kullsberg quarry (Fig. 8), and a disconformity at the same level at the Skålberget quarry (Jaanusson 1982, p. 29), provides evidence for substantial weathering and erosion of the Kullsberg mounds before deposition of the Fjäcka Shale. Accordingly, the most signiWcant strata in the region from a depositional point of view are the Skålberg conglomerates because they rest disconformably and (palaeo) topographi- 123 168 Facies (2010) 56:157–172 Fig. 9 Inferred stratigraphical relationships based on the Amtjärn quarry. The southern entrance section is in the rightmost part of the Wgure. The Wgure gives an idealized interpretation of the stratigraphy developed in the nearby Kullsberg and Skålberget quarries 1982, p. 27). However, the authors described the Wssures as a few centimeters to a little more than one decimeter thick and Wlled with Fjäcka Shale that displayed a micro-brecciated texture when studied with a hand lens. The Wssures displayed widenings and the contacts to the shale were sharp (Thorslund 1932, pp. 148–149). One Wssure that Thorslund never got the chance to study in the Weld (reported by Isberg 1917, p. 217 and seen by quarry workers) was even wider and penetrated the entire Kullsberg mound as well as associated bedded limestone. Also, this Wssure was Wlled with Fjäcka Shale showing primary bedding planes and well-preserved fossils as well as a limestone breccia (Thorslund 1932, p. 150). We have not been able to re-study these Wssures but, based on Thorslund’s description and our own observations on the facies succession, we put forward that these Wssures may represent karst structures, although more detailed studies are needed to really test this hypothesis. The partly disrupted bedding associated with the Skålberg conglomerates at Amtjärn and Wssures within lithoclasts (Fig. 6j) are herein interpreted as a later tectonic overprint of the succession. The overlying Slandrom Limestone yields Wrm evidence for a second regression and subaerial exposure. We have identiWed abundant palaeokarst morphologies in the Slandrom Limestone at Fjäcka as well as in the Borenshult-1 core. Fresh-water diagenesis at this stratigraphical level is further supported by strongly negative carbon isotope values in the Borenshult-1 core, at Amtjärn (herein; Fig. 5), as well as at Fjäcka and in the Jurmala-R1 core in Latvia (Ainsaar et al. 2004, Fig. 6). Interpretation of the Katian sea-level history We propose two phases of regression and sea-level lowstand during the studied time interval. The Wrst regression is expressed by the prominent facies change at the contact 123 between the Kullsberg Limestone and the Skålberg Limestone and occurred immediately after the peak of the GICE in the upper Amorphognathus tvaerensis Conodont Zone (based on biostratigraphy of Bergström 2007). The relationship between the Kullsberg mounds and sea level has previously been discussed by several authors and their common conclusion is that the mounds formed in shallow water or as a response to sea-level lowering: 1. Dronov and Holmer (1999) made an early attempt to subdivide the Ordovician of Baltoscandia in depositional sequences. They included the Kullsberg Limestone in their Kegel sequence but did not provide clear data whether it was a transgressive or regressive unit although they mentioned that the coeval strata in Estonia belonged to the shallowest part of the sequence. 2. Nielsen (2004) states that the argillaceous upper part of the Skagen Limestone and local Kullsberg Limestone signals the Frognerkilen Lowstand Event in the uppermost part of the Diplograptus foliaceus graptolite Zone (Nielsen 2004, p. 88). We argue that these strata rather formed during the preceding Keila Drowning Event and that the conspicuous Frognerkilen Lowstand Event is reXected by the Skålberg Limestone only. See Owen et al. (1990, pp. 22–23) for deWnition of the Frognerkilen Formation in the Oslo-Asker type district of Norway. 3. Tobin et al. (2005) investigated the oxygen isotopic composition of well-preserved marine cements in the Kullsberg Limestone and suggested an up to 15°C decrease in sea water temperature coinciding with mound formation. If this extraordinarily high value is correct, these data can only be explained by a glaciation and thus lowering of the sea level. 4. Cherns and Wheeley (2007, p. 457) interpreted the Kullsberg mounds as formed during cooling of climate and regression. This interpretation was based on general facies-similarities with the younger Boda Event and with regard to the regional geology. Facies (2010) 56:157–172 In contrast to these published studies, we suggest that the Kullsberg mounds formed during a transgression and sealevel highstand, but that they were abruptly terminated by a regression that started shortly after the peak of the GICE (Fig. 5). Arguments for mound growth during transgression and sea-level highstand There is now a good understanding of how the mounds relate to the development of the GICE. The 13C data of Bergström et al. (2009b) indicate that the beginning of the GICE is in the lowermost Kullsberg Limestone, whereas our data show that the peak of the GICE is in the uppermost meter of the mound-Xank facies. It can therefore be concluded that the mounds grew and attained their large sizes during the build-up or rising limb of GICE. 13C correlation of the strata at Amtjärn quarry to areas where sedimentation was not aVected by mound growth shows that this part of GICE and, thus, the Kullsberg mounds correlate perfectly with sedimentary facies reXecting a deepening of the depositional environment. This is the case at the nearby Fjäcka locality, but also in the more remotely located Borenshult-1 core in Östergötland in which the common grainstone facies of the Dalby Limestone is succeeded by more argillaceous strata in the uppermost ca. 3.5 m of the unit. This argillaceous facies continues above the Kinnekulle K-Bentonite where it is referred to as the Skagen Limestone. A small conglomerate of limestone clasts at the top of the Skagen in the Borenshult-1 core marks a sequence boundary without any evidence of preceding shallowing. In addition, 18O data based on conodont apatite from coeval strata in Kentucky and Minnesota including the GICE point to a warming event after a short-term cooling connected with the mega-eruption producing the Deicke K-bentonite (Buggisch et al. 2008, and unpublished data of Buggisch), which represents one of the major volcanic ashfalls in Phanerozoic history (Bergström et al. 2004b). In addition to these data, there are other aspects that are of primary importance when sea-level changes in carbonate-dominated successions are discussed. First, due to the interaction of so disparate controlling factors as ecology of the carbonate-producing biota, available accommodation space, and diagenesis, carbonate systems are most productive during transgressions and sea-level highstands (e.g., Schlager 1991). This is particularly true for tropical Xattopped carbonate platforms, but is likely to also be important in open-shelf settings because the environmental criteria (e.g., light, nutrients) are principally the same. Secondly, true regressions result in generally thin lithosomes independent of the depositional system (although lowstand strata may be thick in clastic depositional systems). This became obvious when Weld-based sequence stratigraphy became 169 important in the 1990s. It was realized that many regressive units had been overlooked because of the low temporal resolution of seismic stratigraphy and a new systems tract was therefore introduced (falling stage systems tract). Thin regressive lithosomes are particularly documented for carbonate-dominated successions because carbonates lithify early and are easily dissolved under subaerial conditions. Carbonate production is also suppressed by the associated inXux of terrigenous materials and shallowing of the photic zone during regressions. For these reasons, carbonate systems export very little sediment to the basin when exposed. Therefore it seems logical that larger mounds or bioherms and aggrading successions of limestone rarely represent a sea-level lowering but a sea-level rise. Arguments for mound termination during a regression and age of the sequence boundary The evidence for a regression and exposure in the latest stage of mound growth is based primarily on the deposition of the conglomerates of the Skålberg Limestone. The existence of some hiatus between the erosive top of the mound and the basal conglomerate of the Skålberg Limestone seems therefore reasonable. Our new 13C data from Amtjärn together with unpublished 13C data from the Borenshult-1 core show that the ‘Skålberg lowstand’ correlates with a conglomerate at the top of the Skagen Limestone in Östergötland and with the sequence boundary reported at the Keila-Oandu stage boundary in the East Baltic area by Ainsaar et al. (2004, pp. 122–123). This boundary is associated with substantial erosion and a hiatus in the northern Estonian shelf sections (Fig. 1), whereas the correlative conformity is interpreted as being the transgressive surface at the base of the Variku and Mossen Formations in the Livonian basin (Ainsaar et al. 2004, p. 123). Being a time-line, this sequence boundary can therefore be dated as of early Middle Katian age. Palaeokarst in the Slandrom Limestone The palaeokarst identiWed in the Slandrom Limestone at Fjäcka needs to be discussed in brief here because the associated unconformity is exposed a few meters above the Skålberg unconformity in several places, e.g., in the Amtjärn and Skålberget quarries. The palaeokarst denotes a second substantial environmental change in the Katian, which is also manifested by the carbon isotope record (the 2nd Late Caradoc positive carbon excursion of Kaljo et al. 2007 and the Waynesville positive carbon excursion of Bergström et al. 2007). The palaeokarst is immediately overlain by the conspicuously brownish-black, organic-rich Fjäcka Shale (formed during the early Amorphognathus ordovicicus chron) across wide areas of Baltoscandia and 123 170 this abrupt shift in facies certainly reXects one of the most impressive environmental changes in the Ordovician succession of the continent (Calner and Lehnert 2008). In most locations, the Skålberg unconformity and the karst-related unconformity at the top of the Slandrom Limestone is separated by at least a few meters of strata, e.g., at Amtjärn, in the Borenshult-1 core, and in the East Baltic area Ainsaar et al. (2004). They are, however, amalgamated at the top of truncated carbonate mud mounds in the Siljan district, resulting in a pronounced Middle Katian hiatus in the immediate mound areas. For this reason, it is not yet possible to judge whether the vertical Wssures in the Kullsberg mounds were formed during the Wrst or the second lowstand or if they formed during the Wrst and were further reworked/widened during the second lowstand. Since the inWll is reported to be Fjäcka Shale, however, available data suggest formation during the second lowstand when the Slandrom Limestone was subjected to karst weathering. Conclusions The studied interval represents an extraordinary succession of strata and yields some of the most pronounced facies shifts in the Ordovician of Baltoscandia. Our study gives evidence for at least two separate phases of regression in the Katian of the Siljan district, and suggests that erosion locally removed substantial parts of the stratigraphic record. The study provides a basis for reconstruction of Katian sea-level history in Central Baltoscandia: • The Wrst regression and sea-level lowstand is implied by the conglomerates of the Skålberg Limestone. They rest disconformably on the peripheral mound-Xank facies of the Kullsberg mounds and topographically well below the truncated top of the mounds. The variation in lithoclast composition suggests exposure of several subenvironments in proximity of the mounds. The conglomerates belong to the Amorphognathus superbus Zone and formed immediately after the peak of the GICE, reaching a 13C peak value of 3.3‰ in the uppermost Amorphognathus tvaerensis Conodont Zone. • The second regression and sea-level lowstand is evidenced by palaeokarst morphologies in the Slandrom Limestone (at Fjäcka) that formed close in time to the Waynesville positive carbon excursion in the basal Amorphognathus ordovicicus Conodont Zone. This palaeokarst has been identiWed also in the Borenshult-1 core in Östergötland, but not at Amtjärn where coeval strata might be cut out. • Based on carbon-isotope records the two sequence boundaries in the Siljan district are likely to correlate 123 Facies (2010) 56:157–172 with two sequence boundaries previously reported from the East Baltic area by Ainsaar et al. (2004, Fig. 7). Hence, they are of basin regional importance. • The reported conglomerates and palaeokarst morphologies are of particular interest because they formed in a relatively deep part of the basin, the Central Baltoscandian Confacies Belt, and thereby imply signiWcant sealevel lowstands. • These sea-level lowstands may reXect a series of Upper Ordovician glaciations and put additional support to an early start of the Late Ordovician through Early Silurian Icehouse period. Acknowledgments We are grateful to Stig M. Bergström, Jan-Ove Ebbestad and Åsa Frisk for many interesting discussions on the Upper Ordovician stratigraphy of Sweden. Valuable comments from the reviewers Stig M. Bergström and Patrick McLaughlin further improved the manuscript. MC acknowledges the Swedish Research Council (VR) for support over many years and Crafoord for a grant to recover the Borenshult-1 drillcore. OL and MJ are grateful to the support by the Deutsche Forschungsgemeinschaft (DFG grant to W. Buggisch, Bu 312/59). References Ainsaar L, Meidla T, Martma T (1999) Evidence for a widespread carbon isotopic event associated with late Middle Ordovician sedimentological and faunal changes in Estonia. Geol Mag 136:49–62. doi:10.1017/S001675689900223X Ainsaar L, Meidla T, Martma T (2004) The Middle Caradoc facies and faunal turnover in the Late Ordovician Baltoscandian palaeobasin. Palaeogeogr Palaeoclimatol Palaeoecol 210:119–133. doi:10.1016/j.palaeo.2004.02.046 Bergström SM (2007) The Ordovician conodont biostratigraphy in the Siljan region, south-central Sweden: a brief review of an international reference standard. In: Ebbestad J-OR, Wickström LM, Högström ES (eds) 9th meeting of the working group on Ordovician Geology of Baltoscandia, Field Guide And Abstracts. Sveriges geologiska undersökning, Rapporter och meddelanden 128:26–41 Bergström SM, Löfgren A, Grahn Y (2004a) The stratigraphy of the Upper Ordovician carbonate mounds in the subsurface of Gotland. GFF 126:289–296 Bergström SM, HuV WD, Saltzman MR, Kolata DR, Leslie SA (2004b) The greatest volcanic ash falls in the Phanerozoic. Sediment Rec 2:4–8 Bergström SM, Young S, Schmitz B, Saltzman MR (2007) Upper Ordovician (Katian) 13C chemostratigraphy: a transatlantic comparison. Acta Palaeontol Sin 46:37–39 Bergström SM, Chen X, Gutiérrez-Marco JC, Dronov A (2009a) The new chronostratigraphic classiWcation of the Ordovician System and its relations to major regional series and stages and to 13C chemostratigraphy. Lethaia 42:1–11. doi:10.1111/j.1502-3931. 2008.00136.x Bergström SM, Schmitz B, Saltzman MR, HuV WD (2009b) The Upper Ordovician Guttenberg 13C excursion (GICE) in North America and Baltoscandia: occurrence, chronostratigraphic signiWcance, and palaeoenvironmental relationship. Geol Soc Am Spec Paper (in press) Brenchley PJ, Marshall JD, Carden GA, Robertson DBR, Long DGF, Meidla T, Hints L, Anderson TF (1994) Bathymetric and isotopic Facies (2010) 56:157–172 evidence for a short-lived Late Ordovician glaciation in a greenhouse period. Geology 22:295–298. doi:10.1130/0091-7613 (1994)022<0295:BAIEFA>2.3.CO;2 Brenchley PJ, Carden GA, Hints L, Kaljo D, Marshall JD, Martma T, Meidla T, Nõlvak J (2003) High-resolution stable isotope stratigraphy of Upper Ordovician sequences: constraints on the timing of bioevents and environmental changes associated with mass extinction and glaciation. Geol Soc Am Bull 115:89–104. doi:10.1130/0016-7606(2003)115<0089:HRSISO>2.0.CO;2 Buggisch W, Joachimski M, Lehnert O (2008) Late Ordovician (Turinian–ChatWeldian) climate of Laurentia. In: 7th Baltic stratigraphical conference. Tallinn, May 2008. Abstracts and Field Guide: 13 Calner M, Lehnert O (2008) A Wrst report on the Upper Ordovician stratigraphy of the Borenshult-1 core, Motala, Sweden. In: 7th Baltic stratigraphical conference 17–18 May 2008, Tallinn, Estonia. Abstracts and Field Guide, p 14 Cherns L, Wheeley JR (2007) A pre-Hirnantian (Late Ordovician) interval of global cooling––the Boda event reassessed. Palaeogeogr Palaeoclimatol Palaeoecol 251:449–460. doi:10.1016/j. palaeo.2007.04.010 Dronov A, Holmer E (1999) Depositional sequences in the Ordovician of Baltoscandia. Acta Univ Carol Geol 43:133–136 Ebbestad J-OR, Wickström LM, Högström ES (eds) (2007) In: 9th meeting of the working group on Ordovician Geology of Baltoscandia (WOGOGOB), Field Guide and Abstracts. Sveriges geologiska undersökning, Rapporter och meddelanden 128:1–110 Hadding A (1941) The pre-Quaternary sedimentary rocks of Sweden VI, reef limestones. Lunds universitets årsskrift, Ny följd, afdelning 2(37):1–137 Hatch JR, Jacobson SR, Witzke BJ, Risatti JB, Anders DE, Watney WL, Newell KD, Vuletich AK (1987) Possible late Middle Ordovician organic carbon isotope excursion: evidence from Ordovician oils and hydrocarbon source rocks, mid-continent and east-central United States. Am Assoc Pet Geol Bull 71:1342–1354 Henkel H, Aaro S (2005) Geophysical investigations of the Siljan impact structure––a short review. In: Koeberl C, Henkel H (eds) Impact tectonics. Springer, Berlin Heidelberg New York, pp 247–283 Isberg O (1917) Bidrag till kännedomen om Leptaenakalkens stratigraW. Geol Foren Stockh Forh 39:199–235 Jaanusson V (1973) Aspects of carbonate sedimentation in the Ordovician of Baltoscandia. Lethaia 6:11–34. doi:10.1111/j.15023931.1973.tb00871.x Jaanusson V (1976) Faunal dynamics in the Middle Ordovician (Viruan) of Baltoscandia. In: Bassett MG (ed) The Ordovician System: Proceedings of a Palaeontological Association symposium, Birmingham September 1974, CardiV, pp 301–326 Jaanusson V (1982) The Siljan district. In: Bruton DL, Williams SH (eds) IV International symposium on the Ordovician System. Field excursion guide, vol 279. Paleontological contributions from the University of Oslo, pp 15–42 Jaanusson V (1995) Confacies diVerenciation and upper Middle Ordovician correlation in the Baltoscandian basin. In: Proceedings of the Estonian Academy of Sciences. Geology 44:73–86 Kaljo D, Hints L, Martma T, Nõlvak J (2001) Carbon isotope stratigraphy in the latest Ordovician of Estonia. Chem Geol 175:49–59. doi:10.1016/S0009-2541(00)00363-6 Kaljo D, Martma T, Männik P, Viira V (2003a) Implications of Gondwana glaciations in the Baltic Late Ordovician and Silurian and a carbon isotopic test of environmental cyclicity. Bull Soc Geol Fr 174:59–66. doi:10.2113/174.1.59 Kaljo D, Martma T, Männik P, Viira V (2003b) Implications of Gondwana glaciations in the Baltic Late Ordovician and Silurian and a carbon isotopic test of environmental cyclicity. Bull Soc Geol Fr 174:59–66. doi:10.2113/174.1.59 171 Kaljo D, Hints L, Martma T, Nõlvak J, Oraspõld A (2004) Late Ordovician carbon isotope trend in Estonia, its signiWcance in stratigraphy and environmental analysis. Palaeogeogr Palaeoclimatol Palaeoecol 210:165–185. doi:10.1016/j.palaeo.2004.02.044 Kaljo D, Martma T, Saadre T (2007) Post-Hunnebergian Ordovician carbon isotope trend in Baltoscandia, its environmental implications and some similarities with that of Nevada. Palaeogeogr Palaeoclimatol Palaeoecol 245:138–155. doi:10.1016/ j.palaeo.2006.02.020 Lindström M, Schmitz B, Sturkell E, Ormö J (2008) Palaeozoic impact craters. 33rd international geological congress, Oslo. Excursion guide no. 10, p 54 Ludvigson GA, Witzke BJ, Gonzalez LA, Carpenter SJ, Schneider CL, Hasiuk F (2004) Late Ordovician (Turinian–ChatWeldian) carbon isotope excursions and their stratigraphic and paleoceanographic signiWcance. Palaeogeogr Palaeoclimatol Palaeoecol 210:187– 214. doi:10.1016/j.palaeo.2004.02.043 Marshall JD, Brenchley PJ, Mason P, WolV GA, Astini RA, Hints L, Meidla T (1997) Global carbon isotopic events associated with mass extinction and glaciation in the Late Ordovician. Palaeogeogr Palaeoclimatol Palaeoecol 132:195–210. doi:10.1016/S00310182(97)00063-1 Meidla T, Ainsaar L, Backman J, Dronov A, Holmer L, Sturesson U (2004) Middle-Upper Ordovician carbon isotope record from Västergötland (Sweden) and East Baltic. In: Hints O, Ainsaar L (eds) WOGOGOB 2004 Conference materials. Tartu University Press, Tartu, pp 67–68 Nielsen AT (2004) Ordovician sea level changes: a Baltoscandian perspective. In: Webby BD, Paris F, Droser M, Percival I (eds) The Great Ordovician diversiWcation event. Columbia University Press, New York, pp 84–93 Owen AW, Bruton DL, Bockelie JF, Bockelie TG (1990) The Ordovician successions of the Oslo Region, Norway. Norges geologiske undersokelse, Spec Publ 4, p 54 Patzkowsky ME, Slupik LM, Arthur MA, Pancost RD, Freeman KH (1997) Late Middle Ordovician environmental change and extinction: Harbinger of the Late Ordovician or continuation of Cambrian patterns? Geology 25:911–914. doi:10.1130/00917613(1997)025<0911:LMOECA>2.3.CO;2 Reimold WU, Kelley SP, Sherlock SC, Henkel H, Koeberl C (2005) Laser Argon dating of melt breccias from the Siljan impact structure: implications for possible relationship to Late Devonian extinction events. Meteorit Planet Sci 40:591–607 Riding R (2002) Structure and composition of organic reefs and carbonate mud mounds: concepts and categories. Earth Sci Rev 58:163–231. doi:10.1016/S0012-8252(01)00089-7 Saltzman MR, Bergström SM, HuV WD, Kolata DK (2003) Conodont and graptolite biostratigraphy and the Ordovician (Early ChatWeldian, Middle Caradocian) 13C excursion in North America and Baltoscandia: implications for the interpretation of the relations between Millbrig and Kinnekulle K-bentonites. In: Proceedings of the 9th international symposium on the Ordovician System. San Juan, Argentina, pp 137–142 Saltzman MR, Young SA (2005) Long-lived glaciation in the Late Ordovician? Isotopic and sequence-stratigraphic evidence from Laurentia. Geology 33:109–112. doi:10.1130/G21219.1 Schlager W (1991) Depositional bias and environmental change– important factors in sequence stratigraphy. Sediment Geol 70:109–130. doi:10.1016/0037-0738(91)90138-4 Schmitz B, Bergström SM (2007) Chemostratigraphy in the Swedish Upper Ordovician: regional signiWcance of the Hirnantian 13C excursion (HICE) in the Boda Limestone of the Siljan region. GFF 129:133–140 Stouge S (2004) Ordovician siliciclastics and carbonates of Öland, Sweden. In: Munnecke A, Servais T, Schulbert C (eds) International Symposium on “Early Palaeozoic Palaeogeography and 123 172 Palaeolimate” (IGCP 503), 1–3 September 2004, Erlangen, Germany. Erlanger Geol Abh, SB 5:91–111 Thorslund P (1932) Om sprickfyllnaderna i kalkreven inom Siljansområdet. Geol Foren Stockh Forh 54:147–164 Thorslund P (1935) Über den Brachiopodenschiefer und den jüngeren RiVkalk in Dalarne. Nova Acta Regio Societas Sci Upsaliensis 4(9):1–50 Thorslund P, Jaanusson V (1960) The Siljan district, road-log. In: Thorslund P, Jaanusson V (eds) The Cambrian, Ordovician, and Silurian in Västergötland, Närke, Dalarna, and Jämtland, 27–35, International geological congress XXI session, Guide to excursions NOS A23 and C18 123 Facies (2010) 56:157–172 Tobin KJ, Bergström SM, De La Garza P (2005) A mid-Caradocian (453 Ma) drawdown in atmospheric pCO2 without ice sheet development? Palaeogeogr Palaeoclimatol Palaeoecol 226:187– 204. doi:10.1016/j.palaeo.2005.05.010 Young SA, Saltzman MR, Bergström SM (2005) Upper Ordovician (Mohawkian) carbon isotope (13C) stratigraphy in eastern and central North America: regional expression of a perturbation on the global carbon cycle. Palaeogeogr Palaeoclimatol Palaeoecol 222:53–76. doi:10.1016/j.palaeo.2005.03.008
© Copyright 2026 Paperzz