KEY Unit 2: Nature and Structure of Matter Test Review 1. Define the following terms: a. Chemical property – describe the ability of a substance to undergo a change that transforms it into a new substance (how a substance reacts to something) b. Physical property – property that can be measured or detected without changing the composition of an object (appearance, odor, color, texture, density, melting point) c. Intensive property – property of matter that is independent of quantity (it doesn’t matter how much of something you have, only what the identity of the substance is) d. Extensive property – property of matter that is quantity dependent (changes based on how much of the substance you have) 2. Identify the described properties as Physical (P) or Chemical (C) and Intensive (I) or extensive (E). a. odorless P, I e. soft, silver-white P, I b. mass of 5.00 grams P, E f. reacts violently with water C, I c. tarnishes rapidly in air C, I g. reacts with acid C, I d. boiling point of 883 C P, I 3. Identify the major contribution of each of the following to current atomic theory (be sure to include any model that they proposed and the experiment that they did): a. Dalton – developed the basis for the modern atomic theory i. All matter is composed of tiny particles called atoms. TRUE ii. Atoms of an element are identical in size, mass and other properties. FALSE (isotopes) iii. Atoms cannot be created, destroyed or subdivided. FALSE (subatomic particles) iv. Atoms of different elements can combine in simple whole number ratios to form compounds. TRUE v. In chemical reactions, atoms are combined, separated or rearranged. TRUE b. Rutherford - Gold foil experiment- expected all of the radiation to pass through and was very surprised when some of the particles were deflected - led to the discovery of the NUCLEUS (centrally located positive charge) and the concept that the atom is mostly empty space. Also discovered the proton and neutron. c. Bohr - His atomic model (planetary model) had atoms built up of successive orbital shells of electrons. Electrons move between shells based on specific amounts of energy being lost or gained. d. Electron Cloud Model- This model is based on quantum mechanics which states that you cannot know the speed and location of a particle. So this model shows the most probable location of the electrons. 4. Be sure that you know how to graph and how to find slope. Density Graph Mass (g) 1.67 1.71 1.71 0.91 0.68 Slope: Mass (g) Data: Volume (cm3) 1.6 1.79 1.7 0.95 0.635 The slope of this graph represents the density (mass/volume). Volume (cm3) This substance could be: a) Gasoline (.7 g/mL) b) Water (1 g/mL) c) Magnesium (1.7 g/cm3) 5. Complete the following chart: Nuclear Atomic Isotope Name Symbol Number Carbon-13 Nitrogen - 17 Boron - 11 Francium - 223 13 11 223 # of Protons # of Neutrons # of Electrons C 6 13 6 7 6 N 7 17 7 10 7 B 5 11 5 6 5 Fr 87 223 87 136 87 6 17 7 Mass Number 5 87 6. An element consists of three naturally occurring isotopes with the following mass numbers: 24, 25 and 26. The relative abundances of these three isotopes are 78.70, 10.13 and 11.17 percent respectively. Calculate the average atomic mass and identify the element. Show your work! (24 x .7870) + (25 x .1013) + (26 x .1117) = 24.3247 amu – Magnesium 7. The modern periodic table is arranged according to increasing atomic number. 8. The atomic number is equal to the number of protons. 9. The mass number is equal to the protons + neutrons. 10. Electrons in the outermost energy level are known as valence electrons and are available to be lost, gained or shared when molecules are formed. 11. Write the full and shorthand electron configurations for a. Beryllium i. 1s22s2 ii. [He] 2s2 b. Germanium i. 1s22s22p63s23p64s23d104p2 ii. [Ar] 4s23d104p2 c. i. ii. [Kr] 5s24d10 Cadmium 1s22s22p63s23p64s23d104p65s24d10 d. Plutonium i. 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p67s25f6 ii. [Rn] 7s25f6 12. Write the electron dot diagrams for the following a. Sodium b. Phosphorus c. Krypton d. Magnesium 13. Fill in the following electromagnetic spectrum: nm nm 14. Describe the relationship between the following variables: a. Wavelength and Frequency Inversely related b. Frequency and Energy Directly related c. Speed of different types of electromagnetic radiation Constant 15. Briefly describe what happens that allows you to see colors in the flame test lab. Heat energy from the flame is added to the atom, causing the electron to jump up to its excited state. As the electron falls back to its ground state, it releases a photon of a specific energy. This energy relates to a frequency and wavelength, which identifies the type/color of radiation. 16. What is the energy of a quantum of light with a frequency of 4.31 X 1014 1/s or Hz? 17. A certain violet light has a wavelength of 413 nm. What is the frequency of the light? 18. What is the energy of light with a wavelength of 662 nm?
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