Chapter 9 Balancing Equations Chemical Equations – Balance equations and indicate the type of reaction 1. 2Ca + O2 -----> 2CaO 2. ZnSO4 + (NH4)2 S-----> (NH4)2SO4 + ZnS 3. 2KI + Cl2 -----> 2KCl + I2 4. 2C2H6 + 5O2 -----> 4CO2 + 6H2O 5. C + H2O -----> CO + H2 6. CaO + H2O -----> Ca(OH)2 7. HCl + NaOH ------> NaCl + H2O 8. BaCl2 + H2SO4 -----> BaSO4 + 2HCl 9. 2Al2O3 -----> 4Al + 4O2 10. 2Al + 6HCl -----> 2AlCl3 + 3 H2 11. 2NaHCO3 -----> Na2CO3 + H2O + CO2 12. Mg + 2HCl -----> H2 + MgCl2 13. C2H8 + 4O2 -----> 2CO2 + 4 H2O 14. 2Al + 3H2SO4 -----> Al2(SO4)3 + 3H2 15. CuO + H2 -----> H2O + Cu 16. N2 + 3H2 -----> 2NH3 17. Cl2 + 6KOH -----> 5KCl + KClO3 + 3H2O 18. 2C2H6 + 7 O2 -----> 4CO2 + 6H2O 19. C6H8O6 + 5 O2 -----> 6CO2 + 4H2O 20. 2Bi(NO3)3 + 3 H2S -----> Bi2S3 + 6HNO3 H. Cannon, C. Clapper and T. Guillot Klein High School Balancing Equations Composition/Synthesis Reactions Balance the following: 1. 2Al + 3Cl2 ---> 2AlCl3 2. 4Na + O2 ----> 2Na2O 3. MgO + H2O Mg(OH)2 4. 2 H2O + O2 ----> 2H2O2 5. 2S + 3O2 ---> 2SO3 6. 2H2 + O2 ---> 2H2O 7. Li2O + H2O ---> 2LiOH 8. H2 + S ---> H2S 9. H2 + Cl2 ---> 2HCl 10. 2Mg + O2 ---> 2MgO 11. 4Fe +3 O2 ---> 2Fe2O3 12. 4P + 5O2 ---> 2P2O5 13. S + O2 ---> SO2 14. N2 + O2 ---> 2NO 15. 2SO2 + O2 ---> 2SO3 16. magnesium metal when heated with nitrogen gas reacts to produce solid magnesium nitride 3Mg + N2 Mg3N2 17. solid lithium reacts with oxygen to form lithium oxide 4Li + O2 2Li2O 18. solid sodium reacts with oxygen to form sodium peroxide 2Na + O2 Na2)2 9-2 HC/CC/TG KHS Balancing Equations Balance the following and identify reaction type: 1. H2O2 ---> H2O + O2 2. C12H22O11 + O2 ---> C O2 + H2O 3. H2O ----> H2 + O2 4. Al + Cl2 ---> AlCl3 5. HgO ---> Hg + O2 6. Mg(ClO3)2 ---> MgCl2 + O2 7. CuO ---> Cu + O2 8. RbCl + O2 ---> RbClO4 9. CaCO3 ---> CaO + CO2 10. KClO3 ---> KCl + O2 11 Al2O3 ---> Al + O2 12. Li2O + H2O ---> LiOH 13. KNO3 ---> KNO2 + O2 14. NaHCO3 ---> Na2CO3 + H2O + CO2 15. Al(NO3)3 ----> Al + N2 + O2 16. P2O5 + H2O H3PO4 17. NH4NO2 ---> N2 + H2O 18. SO2 + O2 ---> SO3 19. H2SO4 ---> H2O + SO3 20. NH4NO3 ---> H2O + N2O 21. Calcium sulfite decomposes to produce calcium oxide and sulfur dioxide 9-3 HC/CC/TG KHS Balancing Equations Predicting Reactions Write balanced equations to indicate the products of the following reactions between the given reactants? 1. Al + Cu(NO3)2 ---> 2. Fe (III) + CuCl2 ---> 3. Zn + HCl ---> 4. Br2 + NaI ---> 5. Al + SnCl2 ---> 6. Li + H2O ---> 7. Na + H2O ---> 8. Cu(II) + NaCl ---> 9. Ag + NaCl ----> 10. Br2 + NaCl ----> 11. Zn + NiCl2 ---> 12. CuO + H2 ---> 13. Al + Cu(NO3)2 ---> 14. Ca + H2O ---> 4. Fe + CuSO4 ---> Fe2(SO4)3 + Cu 15. Fe+3 + CuSO4 16. Cl2 + KI ---> 17. Mg + H2SO4 ---> 18. Cr+3 + HCl ---> 19. Cu (II) + AgNO3 ---> 20. Mg + HCl ---> 9-4 HC/CC/TG KHS Balancing Equations Balance the following: 1. BaCl2 + H3PO4 ---> Ba3(PO4)2 + HCl 2. H2SO4 + KOH ---> K2SO4 + H2O 3. AgNO3 + H2S ---> Ag2S + HNO3 4. Na + O2 ----> Na2O 5. KOH + CO2 ---> K2CO3 + H2O 6. Ca(OH)2 + HC2H3O2 ----> Ca(C2H3O2)2 + H2O 7. Pb(C2H3O2)2 + K2CrO4 ----> PbCrO4 + KC2H3O2 8. Pb(NO3)2 + Na2CrO4 ---> PbCrO4 + NaCO3 9. H2 + Cl2 ---> HCl 10. PbCl2 + HNO3 ---> Pb(NO3)2 + HCl 11. AlCl3 + LiOH ---> Al(OH)3 + LiCl 12. H2O2 ---> H2O + O2 13. C6H12O6 + O2 ---> C O2 + H2O 14. Ba(OH)2 + CO2 ---> BaCO3 + H2O 15. CaC2 + H2O ---> Ca(OH)2 + C2H2 16. Fe + O2 ---> Fe2O3 17. HCl + AgNO3 ---> HNO3 + AgCl 18. NaHCO3 ---> Na2CO3 + H2O + CO2 19. Ca(OH)2 + H2SO4 ----> CaSO4 + H2O 20. PdCl2 + HNO3 ---> Pd(NO3)2 + HCl 21. PCl5 + H2O -----> H3PO4 + HCl 22. Na2O + P4O10 -----> Na3PO4 9-5 HC/CC/TG KHS Balancing Equations 23. P4O10 + 6H2O -----> 4H3PO4 24. 3CaCO3 + 2H3PO4 -----> Ca3(PO4)2 + 3CO2 + 3H2O 25. 3MnO2 + 4Al -----> 2Al2O3 _ 3Mn 26. C2H6O + 3O2 ------> 2CO2 + 3H2O 27. 2Al(ClO3)3 -----> 2AlCl3 + 9O2 28. 2 KClO3 -----> 2KCl + 3O2 29. Al2O3 + 3H2O -----> 2 Al(OH)3 30. 2Na + H2O -----> Na2O + H2 31. Br2 + 2NaI -----> 2NaBr + I2 32. 2 Cu+1 + FeCl2 -----> 2CuCl + Fe 33. Ba + H2O -----> BaO + H2 34. 2Al + 6HC2H3O2 -----> 2Al(C2H3O2)3 + 3H2 35. Br2 + 2NaCl -----> 2NaBr + Cl2 36. Cu + NaCl -----> CuCl + Na 37. 2Au+1 + NiSO4 -----> Ni + Au2SO4 38. Cl2 + 2NaI -----> 2NaCl + I2 39. Mg + H2O -----> MgO + H2 40. Zn + NiCl2 -----> ZnCl2 + Ni 9-6 HC/CC/TG KHS Balancing Equations Predict the balanced outcome of the following 1. Chlorine gas and potassium iodide Cl2 + 2KI 2KCl + I2 2. Combustion of sucrose (C12H22O11) C12H22O11 + 12O2 12CO2 + 11H2O 3. Decompostion of potassium chlorate 2KCLO3 2KCl + 3O2 4. Combustion of ethane (C2H6) 2C2H6 + 9O2 4CO2 + 6H2O 5. Aluminum chloride reacts with lithium hydroxide AlCl3 + 3LiOH Al(OH)3 + 3LiCl 6. Displacement of iron from ferric oxide by magnesium Fe2O3 +3 Mg 3 MgO + 2Fe 7. Decomposition of aluminum oxide 2Al2O3 4Al + 3O2 8. Combustion of butene (C4H8) C4H8 + 6O2 4CO2 + 4H2O 9. Decomposition of hydrogen peroxide H2O2 H2 + O2 10. Combination of sulfur and oxygen S + O2 SO2 11. Combustion of C8H18 2C8H18+ 25O2 16CO2 + 18H2O 12. Displacement reaction between iron (III) oxide and aluminum Fe2O3 + 2Al Al2O3 + 2Fe 13. Combustion of C2H5OH C2H5OH + 3O2 2CO2 + 3H2O 14. Reaction of lead (II) nitrate with phosphoric acid 3Pb(NO3)2 + 2H3PO4 Pb3(PO4)2 + 6HNO3 15. Combustion of pentene (C5H10) 2C5H10 + 15O2 10CO2 + 10H2O 16. Decompostion of sodium bicarbonate 2NaHCO2 Na2O + CO2 + H2O 17. Combustion of C6H6 2C2H6 + 7O2 4CO2 + 6H2O 18. Reaction between calcium hydroxide and sulfuric acid Ca(OH)2 + H2SO4 CaSO4 + 2H2O 19. Reaction between silicon tetrafluoride and water SiF4 + 2H2O 4 HF + SiO2 20. Combustion of C4H10 2C4H10 + 13O2 8CO2 + 10H2O 9-7 HC/CC/TG KHS Balancing Equations Exercise 7 Balance the following: 1. C2H6 + O2 ---> CO2 + H2O 2. C4H8 + O2 ---> CO2 + H2O 3. C8H18 + O2 ----> CO2 + H2O 4. C2H5OH + O2 ---> CO2 + H2O 5. C5H10 + O2 ---> CO2 + H2O 6. C6H6 + O2 ---> CO2 + H2O 7. C4H10 + O2 ---> CO2 + H2O 8. C3H8 + O2 ----> CO2 + H2O 9. C6H8O6 + O2 ---> CO2 + H2O 10. C4H8 + O2 ---> CO2 + H2O Write the equation for the following reactions: 1. zinc plus chlorine 2. sodium hydroxide and potassium 3. silver plus sulfur 4. magnesium and calcium chloride 5. bromine plus sodium 6. mercury (II) oxide and zinc 7. phosphorus plus oxygen 8. gold (III) sulfide and platinum (IV) 9. aluminum and iodine 10. mercury I oxide decomposes 11. hydrogen and oxygen 12. sodium hydroxide and potassium nitrate 9-8 HC/CC/TG KHS Balancing Equations 13. carbon and chlorine 14. iron (III) acetate and calcium sulfate 15. copper(II) and nitrogen 16. cupric oxide and stannic chloride 17. iron (III) and sulfur 18. platinum (II) phosphite and strontium bromide 19. carbon plus excess oxygen 20. tin (II) chloride and sodium fluoride 21. iron (III) and copper (II) sulfate 22. plumbic chlorate and potassium sulfide 23. aluminum and silver nitrate 24. nickel(II) oxalate and ferric dichromate 25. mercury (I) and silver nitrate 26. beryllium sulfide and sodium bromide 27. strontium iodide and fluorine 28. aluminum oxide and potassium iodide 29. chlorine and silver iodide 30. calcium nitrate and sodium acetate 31. nitric acid and sodium citrate 32. aluminum oxide and manganese (IV) sulfite 9-9 HC/CC/TG KHS Balancing Equations Types of Reactions Lab In this experiment you will cause several reactions to occur. From your tests, observations and powers of deduction, you will be able to (1) describe the products; (2) name the products: (3) identify the “type” of reaction: and (4) balance the chemical equation for the reaction. Reaction 1: Place one heaping spoonful of potassium chlorate in a dry test tube. Clamp at a 45-degree angle to a ring stand. Heat with a Bunsen burner, slowly at first, until it melts and then starts to give off a colorless gas (looks like smoke). Light a wood splint, let it burn a few second, and then blow it out. Then quickly hold the glowing splint jus inside the mouth of the test tube. The splint busting into flame again verifies the presence of oxygen. There is a pinkish-white solid that remains in the test tube. Reaction 2: Put 2 squirts of copper (II) sulfate solution in a test tube. Place a shine strip of zinc metal in the test tube and observe for several minutes. (Go on to another section and return.) Pour off the liquid into the sink, but dump the solids on a paper towel. Remove the leftover zinc (save for Reaction 6) and inspect the precipitate, which is a finely divided powder. Another product remains dissolved in the solution. Reaction 3: Obtain a 2-cm length of magnesium ribbon. Holding one end with the crucible tongs, ignite the other end in a Bunsen burner flame. WEAR GOGGLESAND DO NOT LOOK DIRECTLY A THE FLAME! Hold the magnesium over the base of the ring stand as it burns. With what in the air is the magnesium reacting? Describe the product. Reaction 4: To a test tube, add one squirt of a solution of potassium chromate and one squirt of a solution of barium chloride. Swirl to mix. Describe the precipitate that forms. Reaction 5: place one large spoonful of sodium bicarbonate in a dry metal crucible. Place in a triangle on a ring on a ring stand; partly cover with a watch glass, leaving enough space open at one edge to insert a wood splint. Heat with a Bunsen burner, slowly at first, until it starts to give off a colorless gas. Light a wood splint, let it burn a few second, DO NOT BLOW OUT. Insert the lit end into the crucible. The flame being extinguished verifies the presence of carbon dioxide. Observe any deposit on the watch glass. There is a white solid that remains in the crucible. Reaction 6: Put the zinc strip from Reaction 2 back in a test tube and add 2 squirts of dilute hydrochloric acid (HCl). Cover the test tube with your thumb for one or two minutes until you feel some pressure. Light a match and hold it (still lit) over the mouth of the test tube to test for flammability, which indicates hydrogen gas. This test may be repeated as long as gas is being produced. Pour the unused acid down the sink. Save and leftover zinc and throw away in the wastebasket. 9-10 HC/CC/TG KHS Balancing Equations Chapter 9 Activity Series of Metals Lithium Potasiium Barium Calcium Sodium Magnesium Aluminum Zinc Iron Nickel Tine Lead (Hydrogen) Copper Mercury Silver Gold Li K Ba Ca Na Mg Al Zn Fe Decreasing activity Ni Sn Pb (H)* Cu Hg Ag Au *Metals from Li to Na will replace H from acids and water. From Mg to Fe they will replace hydrogen from acids only. ACTIVITY SERIES OF NONMETALS F2 Cl2 Br2 Decreasing Activity I2 9-11 HC/CC/TG KHS
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