1 NIR‐Red Models for Estimation of Chlorophyll‐a Concentration – Application to Aircraft and Satellite Data Wesley J. Moses1,*, Anatoly A. Gitelson1, Vladislav Saprygin2, Sergey Berdnikov2, Vasiliy Povazhnyi2, Daniela Gurlin1, and Alexander A. Gilerson3 1University of Nebraska‐Lincoln, NE, USA. 2Southern Scientific Center of the Russian Academy of Sciences, Rostov‐on‐Don, Russia 3The City College of the City University of New York, NY, USA. *Currently at Naval Research Lab, Washington, D.C. 2 NIR‐red Algorithms for Satellite Data Required Conditions • Algorithm should be – Consistently highly accurate over a wide range of chl‐a concentrations – Resistant to variations in biophysical characteristics of water – Sufficiently resistant to atmospheric effects or can be coupled with a reliable atmospheric correction procedure Application of NIR‐Red Model to Airborne Data AISA‐Eagle (Airborne Imaging Spectrometer for Applications) ‐ maximum of 256 continuous spectral channels ‐ range 400 – 970 nm ‐ max. spectral resolution 2.3 nm ‐ peak signal‐to‐noise ratio 490:1 ‐ spatial resolution 2 m at 10,000 ft above ground 3 4 Data • Five data collection campaigns on the Fremont State Lakes – 02 July, 14 July, 26 Sep, 25 Oct, and 19 Nov of 2008 Date Min. Median Max. Mean Standard Deviation 02 July 08 14 July 08 26 Sep 08 25 Oct 08 19 Nov 08 4.35 6.59 8.47 9.42 2.07 16.20 13.54 31.06 27.02 20.25 22.68 20.80 68.62 69.23 74.19 14.04 13.80 31.11 32.23 26.85 6.68 5.98 19.04 21.33 25.11 Coefficient of Number of Variation Stations 0.48 0.43 0.61 0.66 0.94 Descriptive statistics of chl-a data from the five campaigns 7 6 8 6 8 5 Two‐Band NIR‐Red Model for AISA Data 25 20 r = 0.93 15 10 02 Jul 5 y = 70.718x - 62.001 2 20 80 y = 131.63x - 117.5 60 r = 0.9 -3 2 Chl-a (mg m ) -3 Chl-a (mg m ) y = 72.764x - 63.855 r = 0.89 15 10 14 Jul 5 2 40 1.1 0 0.9 1.2 1 1.1 1.2 0.9 1.1 R 704 /R 676 R 704 /R 676 y = 108.15x - 88.981 60 r = 0.87 80 y = 156.06x - 132.17 -3 80 2 40 25 Oct 20 1.3 R 704 /R 676 Chl-a (mg m ) 1 -3 0 2 60 r = 0.92 40 19 Nov 20 0 1.1 1.3 1.5 1.7 0.8 1 R 704 /R 676 1.2 1.4 R 704 /R 676 80 -3 0.9 Chl-a (mg m ) 0.9 26 Sep 20 0 0 Chl-a (mg m ) -3 Chl-a (mg m ) 25 02-Jul 60 14-Jul 40 26-Sep 20 25-Oct 19-Nov 0 0.9 1 1.1 1.2 1.3 R 704 /R 676 1.4 1.5 1.6 1.5 6 At‐Sensor Reflectance Spectra Before Atmospheric Correction 02 Jul (a) 0.06 0.04 -1 -1 Rrs (Sr ) 0.05 Rrs (Sr ) (e) 19 Nov 0.05 0.04 0.03 0.03 0.02 0.02 0.01 400 0.01 400 500 600 700 800 900 Wavelength (nm) 600 700 800 900 Wavelength (nm) Before atmospheric correction After QUAC atmospheric correction 80 14-Jul 40 26-Sep 20 25-Oct 19-Nov 0 0.9 1 1.1 1.2 1.3 R 704 /R 676 1.4 1.5 1.6 -3 02-Jul 60 Chl-a (mg m ) 80 -3 Chl-a (mg m ) 500 60 02-Jul R2 = 0.92 40 14-Jul 26-Sep 2008 NE Calibration 20 0 0.8 1.3 1.8 25-Oct 19-Nov 2.3 R 704/R 676 (Moses 2009; Moses et al. 2012a) Chlorophyll‐a Maps from AISA‐Eagle Data 7 8 Application to Airborne Data ‐ Conclusion • MERIS NIR‐red model highly accurate, even without atmospheric correction • Relationship affected by non‐uniform atmospheric effects • Atmospheric correction by relative adjustment of input parameters resulted in conformity of the slope and offset for all the AISA images • With robust atmospheric correction, the two‐band MERIS NIR‐red model can be calibrated to accurately estimate chl‐a concentration Application of NIR‐red Algorithms to MERIS Data Data: 18 campaigns between March and October in 2008 – 2010 on the Taganrog Bay and Azov Sea Taganrog Bay Azov Sea (maps from http://maps.google.com/) 9 10 Application of NIR‐red Algorithms to MERIS Data • 18 stations from 2008 and 113 stations from 2009‐2010 • 2008 stations – for calibration • 2009‐2010 stations – for validation Min Max Median Mean 0.63 65.51 24.35 26.97 Descriptive statistics for chl‐a concentration (mg m‐3) in the calibration dataset Min Max Median Mean 1.09 107.82 22.39 31.74 Descriptive statistics for chl‐a concentration (mg m‐3) in the validation dataset Calibration of NIR‐red Algorithms with MERIS bands 11 2008 Azov Sea/Taganrog Bay MERIS 2‐Band 80 2008 NE Line -3 Azov Sea 60 Chl-a (mg m ) 80 -3 Chl-a (mg m ) MERIS 3‐Band 2008 NE Line 40 2 r = 0.95 20 Azov Sea 60 40 2 r = 0.97 20 0 0 -0.1 0 0.1 0.2 0.3 0.6 1.1 (1/R 665 - 1/R 708 ) x R 753 1.6 2.1 R 708 /R 665 Moses et al. 2009 1 1 Three‐band MERIS NIR‐red Algorithm: Chl-a 232.29[ R665 R708 R753 ] 23.174 Two‐band MERIS NIR‐red Algorithm: 1 Chl-a 61.324[ R665 R708 ] 37.94 12 Validation of NIR‐red algorithms 2008 – 2010 Azov Sea MERIS 2‐Band 120 1:1 Line 120 90 60 -3 RMSE = 6.68 mg m 30 -3 MAE = 5.12 mg m 0 0 30 60 90 120 -3 Estimated Chl-a (mg m ) In Situ Chl-a (mg m-3) In Situ Chl-a (mg m-3) MERIS 3‐Band 1:1 Line 90 60 -3 RMSE = 6.04 mg m 30 -3 MAE = 4.57 mg m 0 0 30 60 90 120 -3 Estimated Chl-a (mg m ) (Moses et al. 2012b) 13 Validation of Advanced NIR‐red Algorithms (Gilerson et al. 2010) 2008 – 2010 Azov Sea Advanced MERIS 3‐Band Advanced MERIS 2‐Band 1.124 120 1:1 Line 90 60 -3 RMSE = 5.91 mg m 30 -3 MAE = 4.71 mg m 0 30 60 90 -3 Estimated Chl-a (mg m ) 120 1.124 1:1 Line 90 60 -3 RMSE = 5.92 mg m 30 -3 MAE = 4.32 mg m 0 0 1 Chl-a 35.75 R665 R708 19.3 In Situ Chl-a (mg m-3) In Situ Chl-a (mg m-3) 120 1 1 Chl-a 113.36 R665 R708 R753 16.45 0 30 60 90 -3 Estimated Chl-a (mg m ) (Moses et al. 2012b) 120 14 Hyperspectral Imager for the Coastal Ocean (HICO) (taken from Gitelson et al. 2011b) 15 16 Challenges & Limitations Temporal Variation of Water Quality Satellite captures image in a few seconds – in situ data collection takes hours Problem is magnified when same‐day cloud‐free image is not available The effect of temporal variability is not uniform but specific to each water body 17 Challenges & Limitations Within‐Pixel Spatial Heterogeneity Point in situ data may not represent satellite pixel area (MERIS – 260 m x 290 m; MODIS– 1 km x 1km) Plot of fluorescence readings along a transect on the Azov Sea/Taganrog Bay Fluorometer Values 5 1 km 4.6 4.2 3.8 3.4 300 m 3 0 300 m 300 300 m 600 Distance (m) 900 1200 18 Challenges & Limitations Atmospheric Correction No atmospheric correction procedure worked consistently well for MODIS Data Bright Pixel Atmospheric Correction (Moore et al. 1999) gave good results for MERIS data Nevertheless, it yielded negative reflectances for several stations Conclusion • The NIR‐red models are consistently highly accurate over a wide range of chl-a concentrations, including low‐to‐ moderate values • The NIR‐red models need not be re‐parameterized for different water bodies • The two‐band MERIS NIR‐red model is well‐suited for estimating chl-a concentration in turbid productive waters using satellite data • With well‐adapted in situ data collection techniques, the NIR‐ red algorithms can be robustly calibrated • Results point to the possibility of universal NIR‐red algorithms that can be broadly applied to satellite data from inland, estuarine, and coastal waters around the globe 19 Acknowledgements • Field data collection in the Azov Sea and Taganrog Bay were conducted by teams at the Institute for Environmental Quality, Kiev, Ukraine, and the Southern Scientific Center of the Russian Academy of Sciences, Rostov‐on‐ Don, Russia Thank You! Contact: [email protected] 20
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