HOMEWORK # 1 KEY Chapter 1 5. An incandescent light bulb converts electrical energy into light energy. Yet it also releases a significant amount of energy as heat. The law of conservation of energy is observed, since the sum of heat and light energy produced is equal to the electrical energy consumed. 9. (a) a soft drink is a mixture (water + dissolved components, carbonic acid, CO2 gas). (b) water is a compound, H2 O (c) air is a mixture of gases (and often particulate pollution) (d) chicken noodle soup is a heterogeneous mixture of broth, noodles, grease, etc. (e) pure table salt is a compound, sodium chloride (NaCl). However, many commercially available samples of table salt are a mixture of sodium chloride with other materials. (f) popcorn is a mixture of popped & unpopped kernels, oil, salt. But even if you pick out all the unpopped kernels and eat it oil & salt free, looking at the nutrition information reveals that popcorn is a mixture of many things, including fiber and carbohydrates. (g) Aluminum foil is an element (aluminum). 25. (a) not exact (probably measured) (b) exact (counted) (c) exact (counted to the nearest penny) (d) not exact (obtained by measurement) (e) not exact (obtained by measurement) (f) exact (although of questionable accuracy, counted) 35. 16 gallons x 41. (a) mass of H2 O volume of H2 O 4 quarts x 1 Liter 1 gallon 1.057 quarts x $0.325 = 1 Liter 2 sig figs = $19.67 $20 = 91.44 g – 73.91 g = 17.53 g H2 O = 17.53 g H2 O x 1 cm3 1.0000 g = (b) mass of unknown liquid = 88.42 g - 73.91 g = 14.51 g density of unknown liquid = 14.51 g 17.53 cm3 = 0.8277 g/ cm3 17.53 cm3 Chapter 2 13. (a) (b) (c) (d) (e) magnesium chloride copper (II) nitrate lithium sulfate calcium hydroxide iron (II) sulfate 15. (a) (b) (c) (d) (e) Na2 S Al2 (SO4 )3 Na3 PO4 Mg(NO3 )2 Fe2 (CO3 )3 27. (a) Ca S O4 1(40.078) = 1(32.066) = 4(15.9994) = 40.078 32.066 63.9976 136.142 amu (b) C4 H10 4(12.011) = 10(1.0079) = 48.044 10.0790 58.123 amu (c) C6 H8 S O2 N2 6(12.011) = 8(1.0079) = 1(32.066) = 2(15.9994) = 2(14.0067) = 72.066 8.0632 32.066 31.9988 28.0134 172.207 amu (d) 3U 14O 2P 29. 3(238.0289) = 14(15.9994) = 2(30.9738) = 8.575 g Ne 20.1797 g Ne per mole = 714.0867 223.9916 61.9476 1000.0259 amu 0.4249 mole Ne 39. (a) 1.24 mol C6 H12 O6 x 6.022 x 1023 molecules = 7.47 x 1023 C6 H12 O6 molecules 1mol C6 H12 O6 7.47 x 1023 C6 H12 O6 molecules x 6 C atoms = 1 C6 H12 O6 molecule 4.48 x 1024 C atoms 7.47 x 1023 C6 H12 O6 molecules x 12 H atoms = 1 C6 H12 O6 molecule 8.96 x 1024 H atoms 7.47 x 1023 C6 H12 O6 molecules x 6 O atoms = 1 C6 H12 O6 molecule 4.48 x 1024 O atoms 3.31 x 1019 C6 H12 O6 molecules x 6 C atoms = 1 C6 H12 O6 molecule 1.99 x 1020 C atoms 3.31 x 1019 C6 H12 O6 molecules x 12 H atoms = 1 C6 H12 O6 molecule 3.97 x 1020 H atoms 3.31 x 1019 C6 H12 O6 molecules x 6 O atoms = 1 C6 H12 O6 molecule 1.99 x 1020 O atoms (b) (c) 0.275 g C6 H12 O6 x 1 mol C6 H12 O6 180.16 g x 6.022 x 1023 molecules 1mol C6 H12 O6 = 9.19 x 1020 C6 H12 O6 molecules 9.19 x 1020 C6 H12 O6 molecules x 6 C atoms = 1 C6 H12 O6 molecule 5.51 x 1021 C atoms 9.19 x 1020 C6 H12 O6 molecules x 12 H atoms = 1 C6 H12 O6 molecule 1.10 x 1022 H atoms 9.19 x 1020 C6 H12 O6 molecules x 6 O atoms = 1 C6 H12 O6 molecule 5.51 x 1021 O atoms Chapter 3
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