energies Article Performance Characteristics of PTC Elements for an Electric Vehicle Heating System Yoon Hyuk Shin 1 , Seung Ku Ahn 2 and Sung Chul Kim 3, * 1 2 3 * Green Car Power System R&D Division, Korea Automotive Technology Institute, 74 Yongjung-ri, Pungse-myun, Dongnam-gu, Chonan-si, Chungnam 330-912, Korea; [email protected] R&D Center, 67-2 Sangdaewon-dong, Jungwon-gu, Seongnam-si, Kyeonggi 462-120, Korea; [email protected] School of Mechanical Engineering, Yeungnam University, 280 Daehak-ro, Gyeongsan-si, Gyeongbuk 712-749, Korea Correspondence: [email protected]; Tel.: +82-53-810-2572; Fax: +82-53-810-4627 Academic Editors: Samuel Gendebien and Vincent Lemort Received: 6 July 2016; Accepted: 30 September 2016; Published: 11 October 2016 Abstract: A high-voltage positive temperature coefficient (PTC) heater has a simple structure and a swift response. Therefore, for cabin heating in electric vehicles (EVs), such heaters are used either on their own or with a heat pump system. In this study, the sintering process in the manufacturing of PTC elements for an EV heating system was improved to enhance surface uniformity. The electrode production process entailing thin-film sputtering deposition was applied to ensure the high heating performance of PTC elements and reduce the electrode thickness. The allowable voltage and surface heat temperature of the high-voltage PTC elements with thin-film electrodes were 800 V and 172 ◦ C, respectively. The electrode layer thickness was uniform at approximately 3.8 µm or less, approximately 69% less electrode materials were required compared to that before process improvement. Furthermore, a heater for the EV heating system was manufactured using the developed high-voltage PTC elements to verify performance and reliability. Keywords: performance characteristics; positive temperature coefficient (PTC) element; screen printing; sputtering; electric vehicle; high voltage 1. Introduction The automobile industry is striving to replace internal combustion engine vehicles with environmentally friendly electric vehicles (EVs) to address global energy depletion and environmental pollution. The one-charge driving range of EVs must be improved to boost EV use by reducing battery power consumption, which requires the development of a highly efficient EV heating system [1,2]. Apart from powering the vehicle engine, the EV heating system accounts for the majority of energy consumption; therefore, some recent studies have applied high-efficiency heat pumps for heating to improve the driving range of EVs [3–5]. The performance of heat pump systems tends to deteriorate at low temperatures and in open air. A high-voltage positive temperature coefficient (PTC) heater has a simple structure and a swift response; hence, for cabin heating in EVs, such heaters have been used on their own or with a heat pump system [6–8]. The PTC element used in a high-voltage heater is an electric heat source that ensures safety by not exceeding the design temperature. It is universally used in vehicle heating systems. Moreover, to maximize the advantages of the PTC elements’ swift response, securing the performance and reliability of the high-voltage PTC element by considering the driving environment and the characteristics of repeated operations is becoming increasingly crucial as air heaters that directly heat the air flowing into the vehicle are being actively adopted for EV heating. Energies 2016, 9, 813; doi:10.3390/en9100813 www.mdpi.com/journal/energies Energies 2016, 9, 813 Energies 2016, 9, 813 2 of 9 2 of 9 Cen and Wang [9] investigated the current PTC element manufacturing process and developed Cen and Wang [9] investigated the current PTC element manufacturing process and developed PTC elements with enhanced heating performance and durability. The raw material composition of PTC elements with enhanced heating performance and durability. The raw material composition of any any element PTC element strongly influences PTC characteristics such as temperature and resistance. PTC strongly influences PTC characteristics such as temperature and resistance. Accordingly, Accordingly, a uniform mixture can element ensure performance. stable element performance. Therefore, the physical a uniform mixture can ensure stable Therefore, the physical mixture process mixture process and the forming equipment’s compressive force, which ensures adequate and uniform and the forming equipment’s compressive force, which ensures adequate and uniform density and density and time inside are the crucial furnace, crucial and must [10]. be improved optimizes theoptimizes sintering the timesintering inside the furnace, andare must be improved Moreover,[10]. the Moreover, the PTC heating elements must ensure surface flatness for ease of packaging. PTC heating elements must ensure surface flatness for ease of packaging. In particular, particular, the the electrode production process, which is on based on existing screen methods, printing In electrode production process, which is based existing screen printing methods, must be toimproved to element ensure PTC element and performance and electrical and to must be improved ensure PTC performance electrical durability and todurability reduce electrode reduce electrode material cost. The physical and material characteristics of the electrode part of the material cost. The physical and material characteristics of the electrode part of the PTC element, which PTC element, which is different a structure connecting different materials, strongly affect and the reliability; element’s is a structure connecting materials, strongly affect the element’s performance performance and reliability; improving this Furthermore, process is the most difficult. Furthermore, screen improving this process is the most difficult. screen printing consumes the electrode printing consumes the electrode material, which is expensive, and material, which is expensive, and producing a uniform electrode producing a layer on the uniform electrode element’s surface layer on the element’s surface is difficult. is difficult. Therefore, this improved the sintering process process in in the the PTC PTC element element manufacturing manufacturing to to Therefore, this study study improved the sintering enhance surface uniformity. The electrode production process entailing thin‐film sputtering enhance surface uniformity. The electrode production process entailing thin-film sputtering deposition deposition was applied to ensure the heating performance of the PTC elements and to reduce the was applied to ensure the heating performance of the PTC elements and to reduce the amount of amount of electrode material required. In addition, a heater an EV system using was electrode material required. In addition, a heater for an EV heatingfor system washeating manufactured manufactured using the developed high‐voltage PTC elements to verify their performance. the developed high-voltage PTC elements to verify their performance. 2. Fabrication of PTC Element 2. Fabrication of PTC Element The by forming a structure The PTC PTC element element was was manufactured manufactured by forming a structure stacked stacked with with electrode electrode layers layers to to transmit ceramic materials (Figure 1). TheThe technical development of the transmit power power to to semiconductive semiconductive ceramic materials (Figure 1). technical development of key the processes for the element, namely sintering and electrode production, are detailed herein. key processes for the element, namely sintering and electrode production, are detailed herein. Figure 1. Schematic of the positive temperature coefficient (PTC) element manufacturing process. Figure 1. Schematic of the positive temperature coefficient (PTC) element manufacturing process. 2.1. Sintering 2.1. Sintering The outer component of the PTC element for heating was manufactured from a compound The outer component of the PTC element for heating was manufactured from a compound containing barium titanate (BaTiO3), additional raw materials, and binder using a press device. containing barium titanate (BaTiO3 ), additional raw materials, and binder using a press device. Subsequently, the component was sintered in a furnace of at least 1300 °C to combine the Subsequently, the component was sintered in a furnace of at least 1300 ◦ C to combine the compounds compounds and increase its rigidity. The surface flatness of the plate‐type element may deteriorate and increase its rigidity. The surface flatness of the plate-type element may deteriorate because of because of thermal deformation. However, the PTC elements for heaters must smoothly conduct thermal deformation. However, the PTC elements for heaters must smoothly conduct heat through heat through contact. Therefore, the temperature distribution uniformity of each PTC element must contact. Therefore, the temperature distribution uniformity of each PTC element must be ensured be ensured inside the furnace to enhance the surface flatness of the PTC elements during sintering. inside the furnace to enhance the surface flatness of the PTC elements during sintering. Appropriate Appropriate plates were used for layering inside the furnace (Figure 2) to minimize the distortion plates were used for layering inside the furnace (Figure 2) to minimize the distortion of the PTC of the PTC element during sintering. Silicon carbide (SiC), which has a high thermal conductivity, element during sintering. Silicon carbide (SiC), which has a high thermal conductivity, was used as was used as the material for the base plate to enhance the temperature distribution uniformity the material for the base plate to enhance the temperature distribution uniformity within the furnace. within the furnace. The SiC base plate also minimized bending and thickness variations by further equalizing the PTC element’s sintering temperature distribution. Energies 2016, 9, 813 3 of 9 The SiC base plate also minimized bending and thickness variations by further equalizing the PTC element’s sintering temperature distribution. Energies 2016, 9, 813 3 of 9 Energies 2016, 9, 813 3 of 9 Figure 2. Schematic of the PTC element sintering process. Figure 2. Schematic of the PTC element sintering process. Figure 2. Schematic of the PTC element sintering process. After sintering, the flatness and thickness variations of the PTC elements were measured After the flatness andand thickness variations of the PTC elements were measured (Figure 3). After sintering, sintering, the flatness thickness variations of the PTC elements were measured (Figure 3). Table 1 lists the characteristics for each sintering process and the corresponding Table 1 lists characteristics each sinteringfor process the corresponding measurement results. (Figure 3). the Table 1 lists the for characteristics each and sintering process and the corresponding measurement results. When SiC was used as the base plate material, thickness variation reduced by When SiC was used as the base plate material, thickness variation reduced by approximately 60% measurement results. When SiC was used as the base plate material, thickness variation reduced by approximately 60% compared with that obtained when aluminum oxide (Al2O3) was used; this compared with that when aluminum oxide when (Al2 O3aluminum ) was used;oxide this result of this the approximately 60% obtained compared with that obtained (Al2Ois3) indicative was used; result is indicative of the enhanced flatness of the PTC elements. enhanced flatness of the PTC elements. result is indicative of the enhanced flatness of the PTC elements. Figure 3. Measuring PTC element thickness. Figure 3. Measuring PTC element thickness. Figure 3. Measuring PTC element thickness. Table 1. Specifications of the conventional and improved positive temperature coefficient (PTC) Table 1. Specifications of the conventional and improved positive temperature coefficient (PTC) element sintering processes. Table 1. Specifications of the conventional and improved positive temperature coefficient (PTC) element element sintering processes. sintering processes. Specifications of Sintering Process Parameter Specifications of Sintering Process Conventional Method Improved Method Parameter Specifications of Sintering Process Conventional Method Improved Method Parameter Sintering temperature (°C) 1310 1310 Conventional1310 Method Improved1310 Method Sintering temperature (°C) Base plate Al2O3 SiC ◦ Base plate ( C) SiC Sintering temperature 1310Al2O3 1310 Thermal conductivity (W/m∙K) 25.0 77.5 Base plate Al2 O325.0 SiC77.5 Thermal conductivity (W/m∙K) Thickness variation of the PTC element (mm) 0.05 Thermal conductivity (W/m·K) 25.0 0.15 77.5 Thickness variation of the PTC element (mm) 0.15 0.05 3 Size of the PTC element (mm ) 28.5 × 12.9 × 2.1 (length × width × thickness) Thickness variation of the PTC element (mm) 0.15 0.05 3 Size of the PTC element (mm ) 28.5 × 12.9 × 2.1 (length × width × thickness) 28.5 × 12.9 × 2.1 (length × width × thickness) Size of the PTC element (mm3 ) 2.2. Electrode Production 2.2. Electrode Production 2.2. Electrode Production Producing electrodes on the element surface is the most critical procedure in the Producing electrodes on the element surface is the most critical procedure in the manufacturing of PTC elements for heaters. To enhance element performance by improving contact Producing electrodes on the element surface is the most critical procedure in the manufacturing manufacturing of PTC elements for heaters. To enhance element performance by improving contact between materials to reduce the cost of the base materials in the electrode layer, this study of PTC elements for and heaters. To enhance element performance by improving contact between materials between materials and to reduce the cost of the base materials in the electrode layer, this study actively applied the sputtering method instead of the existing screen printing method as shown in and to reduce the cost of the base materials in the electrode layer, this study actively applied the actively applied the sputtering method instead of the existing screen printing method as shown in Figure 4. Table 2 details the specifications of the sputtering equipment. The electrode layer inputs sputtering method instead of the existing screen printing method as shown in Figure 4. Table 2 details Figure 4. Table 2 details the specifications of the sputtering equipment. The electrode layer inputs electric energy into the PTC element. The performance and durability of the electrode is dependent the specifications of the sputtering equipment. The electrode layer inputs electric energy into the PTC electric energy into the PTC element. The performance and durability of the electrode is dependent on the characteristics of its core because of it the is formed at is the surface, where heater’s thermal element. The performance and durability electrode dependent on thethe characteristics of its on the characteristics of its core because it is formed at the surface, where the heater’s thermal energy is released. Electrode layers must be adequately thick (at least 10 μm) to withstand the energy is released. Electrode layers must be adequately thick (at least 10 μm) to withstand the voltage induced during screen printing. The characteristics of electrode layers composed of metallic voltage induced during screen printing. The characteristics of electrode layers composed of metallic materials (e.g., Ag and Al) differ from those composed of ceramic materials (e.g., BaTiO3). materials (e.g., Ag and Al) differ from those composed of ceramic materials (e.g., BaTiO3). Energies 2016, 9, 813 4 of 9 core because it is formed at the surface, where the heater’s thermal energy is released. Electrode layers must be adequately thick (at least 10 µm) to withstand the voltage induced during screen printing. The characteristics of electrode layers composed of metallic materials (e.g., Ag and Al) differ from thoseEnergies 2016, 9, 813 composed of ceramic materials (e.g., BaTiO3 ). 4 of 9 Energies 2016, 9, 813 4 of 9 Figure 4. Schematic of the improved electrode patterning method. Figure 4. Schematic of the improved electrode patterning method. Figure 4. Schematic of the improved electrode patterning method. Table 2. Specifications of the thin‐film deposition (sputtering) equipment. Table 2. Specifications of the thin-film deposition (sputtering) equipment. 3) Chamber size (m 3015 × 2450 × 3700 (width × height × depth) Table 2. Specifications of the thin‐film deposition (sputtering) equipment. Substrate rotation 28 axes (80 rpm) 3015 × 2450 × 3700 (width × height × depth) Chamber size (m3 )3 Chamber size (m ) 3015 × 2450 × 3700 (width × height × depth) Substrate rotation 28 axes (80 rpm) Pump Cryo pump (22 inch) 2ea Substrate rotation Pump Cryo28 axes (80 rpm) pump (22 Cathode power (kW) 20 inch) 2ea Pump Cryo pump (22 inch) 2ea Cathode power (kW) 20 Input voltage (V) DC 380 Input voltage (V) DC 380 Cathode power (kW) 20 Vacuum gauge (Torr) 1 × 10 –760 −−6 6 –760 Vacuum gauge (Torr) 1 × 10 Input voltage (V) DC 380 Vacuum gauge (Torr) 1 × 10−6–760 Figure 5 presents the cross‐sections of the PTC elements manufactured through the existing Figure presents the cross-sections of sputtering the PTC elements through existing screen screen 5 printing method and the new method. manufactured Compared with screen the printing, the Figure 5 presents the cross‐sections of the PTC elements manufactured through the existing printing method and the new sputtering method.use Compared with screen printing, thecontact sputtering sputtering method reduced electrode material by approximately 69%. Moreover, screen printing method and the new sputtering method. Compared with screen printing, the uniformity of the electrode improved. method reduced electrode material use by approximately 69%. Moreover, contact uniformity of the sputtering method reduced electrode material use by approximately 69%. Moreover, contact electrode improved. uniformity of the electrode improved. (a) (b) Figure 5. Electrode thickness of PTC elements fabricated through (a) screen printing and (b) sputtering. (a) (b) Figure 5. Electrode thickness of PTC elements fabricated through (a) screen printing and (b) sputtering. 3. Performance Characteristics of the PTC Element Figure 5. Electrode thickness of PTC elements fabricated through (a) screen printing and (b) sputtering. The variations in the resistance of the high‐voltage PTC element prototypes manufactured 3. Performance Characteristics of the PTC Element 3. Performance Characteristics of the PTC Element through both electrode production processes were measured as a function of temperature by using The variations in the resistance of the high‐voltage PTC element prototypes manufactured the experimental devices shown in Figure 6. The resulting characteristic curves are presented in The variations in the resistance of the high-voltage PTC element prototypes manufactured through both electrode production processes were measured as a function of temperature by using Figure 7 and summarized in Table 3. The temperature at which resistance sharply increases is called the both experimental devices shown processes in Figure 6. The measured resulting characteristic curves are presented through electrode production were as a function of temperature byin using the switching temperature or the Curie temperature (Tc). It is the most representative parameter of Figure 7 and summarized in Table 3. The temperature at which resistance sharply increases is called the experimental devices shown in Figure 6. The resulting characteristic curves are presented any temperature‐resistance characteristic curve and is generally defined as the temperature at in the switching temperature or the Curie temperature (T c). It is the most representative parameter of Figure 7 andthe summarized intwo Table 3. The at whichor resistance sharply is called which resistance is times the temperature minimum resistance the resistance at increases the reference any temperature‐resistance characteristic curve and is generally defined as the temperature at the switching temperature or the Curie temperature (T ). It is the most representative parameter temperature (25 °C). The operating Tc range during sputtering (~175 °C) is almost equal to that of c which the resistance is two times the minimum resistance or the resistance at the reference during screen printing, which indicates curve that proposed approach can realize the operation range any temperature-resistance characteristic and is generally defined as the temperature at which temperature (25 °C). The operating Tc range during sputtering (~175 °C) is almost equal to that required for EV heating. Moreover, the resistance temperature‐resistance characteristics of the prototype the resistance is two times the minimum or the resistance at the reference temperature during screen printing, which indicates that proposed approach can realize the operation range ◦ C) is3) fabricated through sputtering (prototypes C and (~175 D in Table are similar those fabricated (25 ◦ C). The operating Tc range during sputtering almost equalto toof that screen required for EV heating. Moreover, the temperature‐resistance characteristics the during prototype through screen printing (prototypes A and B). fabricated through sputtering (prototypes C and D in Table 3) are similar to those fabricated through screen printing (prototypes A and B). Energies 2016, 9, 813 5 of 9 printing, which indicates that proposed approach can realize the operation range required for EV heating. Moreover, the temperature-resistance characteristics of the prototype fabricated through sputtering (prototypes C and D in Table 3) are similar to those fabricated through screen printing (prototypes A and B). Energies 2016, 9, 813 5 of 9 Energies 2016, 9, 813 5 of 9 Figure 6. Measuring the temperature‐resistance characteristics of the PTC elements. Figure 6. Measuring the temperature-resistance characteristics of the PTC elements. Figure 6. Measuring the temperature‐resistance characteristics of the PTC elements. Figure 7. Temperature‐resistance characteristics of high‐voltage PTC element prototypes Figure 7. Temperature‐resistance characteristics of high‐voltage PTC element prototypes manufactured through screen printing and sputtering. Figure 7. Temperature-resistance characteristics of high-voltage PTC element prototypes manufactured manufactured through screen printing and sputtering. through screen printing and sputtering. Table 3. Temperature‐resistance characteristics of the PTC elements fabricated through screen Table 3. Temperature‐resistance characteristics of the PTC elements fabricated through screen printing and sputtering. Tableprinting and sputtering. 3. Temperature-resistance characteristics of the PTC elements fabricated through screen printing and sputtering. Screen‐Printed Electrode Layer Thin‐Film Electrode Layer Parameter Screen‐Printed Electrode Layer Thin‐Film Electrode Layer A B C D Parameter A B C D Layer Screen-Printed Electrode3.25 Layer Thin-Film Electrode Initial resistance (kΩ) 3.00 3.32 2.98 Parameter Initial resistance (kΩ) 3.00 3.25 3.32 2.98 Minimum resistance value (kΩ) 0.89 0.76 A 0.77 B0.79 C D Minimum resistance value (kΩ) 0.77 0.79 0.89 0.76 Maximum resistance value (kΩ) 4564 4784 4775 4450 Initial resistance (kΩ) 3.004564 3.25 3.32 2.98 Maximum resistance value (kΩ) 4784 4775 4450 Tc (°C) value (kΩ) 175 Minimum resistance 0.77 0.79 0.89 0.76 Tc (°C) 175 Maximum resistance value (kΩ) 4564 4784 4775 4450 A device to estimate the allowable voltage and heat‐generating temperature was fabricated ◦ T to ( C) 175 temperature was fabricated A device estimate allowable voltage and heat‐generating (Figure 8) to cexamine the the improvements in surface solidity, electrode layer contact, and PTC (Figure 8) to examine the improvements in surface solidity, electrode layer contact, and PTC element surface uniformity resulting from the thin‐film electrode production process. Power element surface uniformity resulting from the thin‐film electrode production process. Power sockets in contact with both sides of the PTC element were inserted within the Al contact tube and A device to estimate the allowable voltage and heat-generating temperature was fabricated sockets in contact with both sides of the PTC element were inserted within the Al contact tube and connected to the power supplier to permit power. (Figure 8) to examine the improvements in surface solidity, electrode layer contact, and PTC element connected to the power supplier to permit power. surface uniformity resulting from the thin-film electrode production process. Power sockets in contact with both sides of the PTC element were inserted within the Al contact tube and connected to the power supplier to permit power. Energies 2016, 9, 813 6 of 9 Energies 2016, 9, 813 6 of 9 Figure 8. Schematic of the device estimating the allowable voltage and heat‐generating temperature Figure 8. Schematic of the device estimating the allowable voltage and heat-generating temperature of of the high‐voltage PTC element prototype. the high-voltage PTC element prototype. The allowable voltage was estimated at room temperature (25 ± 1 °C). Voltages of 800 and 850 The allowable voltage was estimated at room temperature (25 ± 1 ◦ C). Voltages of 800 and 850 V V were applied for more than 300 s. The results are summarized in Table 4. At the reference voltage were applied for more than 300 s. The results are summarized in Table 4. At the reference voltage of of 800 V, the high‐voltage PTC element prototypes did not exhibit any damages that could be seen 800 V, the element prototypes not exhibit any than damages could be that seen the with with the high-voltage naked eye. PTC Furthermore, resistance did variation was less 10%, that confirming theprototypes meet the performance requirements for use in EV heaters. naked eye. Furthermore, resistance variation was less than 10%, confirming that the prototypes A performance contact thermometer was used to measure the element’s surface heat temperature at room meet the requirements for use in EV heaters. temperature and 330 or 350 V. The results are summarized in Table 5. The measured surface heat Table 4. Allowable voltage for the PTC element prototype for both electrode production processes. temperatures were approximately 170 °C, which is the target temperature at 300 V for use in EV heaters. Screen-Printed Electrode Layer Thin-Film Electrode Layer Table 4. Allowable voltage for the PTC element prototype for both electrode production processes. Parameter A Parameter Initial resistance (kΩ) Input 800 V Initial resistance (kΩ) Resistance after voltage withstanding test (kΩ) Input 800 V Resistance after voltage Input 850 V withstanding test (kΩ) Test duration (s)Input 850 V Test duration (s) B Screen‐Printed Electrode Layer 3.00 A 3.25 B 3.29 3.00 3.43 3.25 3.29 3.34 3.61 3.43 3.34 3.61 300 300 C D Thin‐Film Electrode Layer 3.32 C 2.98 D 3.47 3.32 3.152.98 3.47 3.52 3.223.15 3.52 3.22 A contact thermometer was used to measure the element’s surface heat temperature at room Table 5. Surface temperature estimations for the PTC element prototypes. temperature and 330 or 350 V. The results are summarized in Table 5. The measured surface heat temperatures were approximately 170 ◦ C, which is the targetPrototype temperature at 300 V for use in EV heaters. Parameter A B C D Input voltage (V) 330 350 330 350 330 350 330 350 Table 5. Surface temperature estimations for the PTC element prototypes. Surface temperature (°C) 172.1 178.3 173.9 179.4 171.2 178.6 172.4 179.2 Parameter 4. Performance and Reliability of the PTC Heater A Input voltage (V) 4.1. Heating Performance ◦ Surface temperature ( C) 330 172.1 350 178.3 330 173.9 Prototype B C 350 179.4 330 171.2 D 350 178.6 330 172.4 350 179.2 An electric heater was manufactured to evaluate the performance of the developed PTC element as a heating system. Figure 9 presents the schematic design and a photograph of the test 4. Performance and Reliability of the PTC Heater device used to measure the heating capacity, efficiency, and pressure drop of the high‐voltage heater. The temperature of the inlet and outlet air from the wind tunnel device was measured at 4.1. Heating Performance 24 different locations using a ±0.1 °C–resolution T‐type thermocouple. Temperature and An electric was manufactured to evaluate the performance the developed PTC element pressure data heater were collected using a data logger (Gantner) under of the following experimental asconditions: input power voltage of 330 V, inlet air temperature of 0 °C, and inlet air flow rate of a heating system. Figure 9 presents the schematic design and a photograph of the test device used to measure the heating capacity, efficiency, and pressure drop of the high-voltage heater. The temperature 300 kg/h. These factors mirror the characteristics of the air volume exiting a vehicle’s Heating, of Ventilation and Air Conditioning (HVAC) system blower during winter. the inlet and outlet air from the wind tunnel device was measured at 24 different locations using a ±0.1 ◦ C–resolution T-type thermocouple. Temperature and pressure data were collected using a data logger (Gantner) under the following experimental conditions: input power voltage of 330 V, inlet air temperature of 0 ◦ C, and inlet air flow rate of 300 kg/h. These factors mirror the characteristics of the air volume exiting a vehicle’s Heating, Ventilation and Air Conditioning (HVAC) system blower during winter. Energies 2016, 9, 813 Energies 2016, 9, 813 7 of 9 7 of 9 (a) (b) Figure 9. Schematic fabricated for evaluating heating heating Figure 9. Schematic of of the the test test equipment equipment and and prototype prototype heater heater fabricated for evaluating performance. (a) Schematic diagram of the test equipment [5]; (b) Prototype heater. performance. (a) Schematic diagram of the test equipment [5]; (b) Prototype heater. Heat transfer by air, power consumption, and pressure drop were measured by evaluating Heat transfer by air, power consumption, and pressure drop were measured by evaluating the the performance of the four high‐voltage prototype heaters. Efficiency was defined as the ratio performance of the four high-voltage prototype heaters. Efficiency was defined as the ratio of the of the heating capacity of the heater to its power consumption (Equation (1)). The results are heating capacity of the heater to its power consumption (Equation (1)). The results are summarized in summarized in Table 6. The heating capacity and efficiency were on average 4.63 kW and 0.952, Table 6. The heating capacity and efficiency were on average 4.63 kW and 0.952, respectively, thereby respectively, thereby meeting the performance requirements for use as electric heaters in EV meeting the performance requirements for use as electric heaters in EV heating systems. The pressure heating systems. The pressure drop was 82.8 Pa on average, which is acceptable. drop was 82.8 Pa on average, which is acceptable. C m (T T ) η CPP× m. × ( Too − Ti ) i V I η= (1) (1) V×I Table 6. Results of heating performance experiments. Table 6. Results of heating performance experiments. Parameter Prototype Heater Prototype Heater Parameter A A B Input voltage (V) 331.3 Input voltage (V) 331.3 330.8 Input current (A) 14.7 Input current (A) 14.7 14.7 Power consumption (kW) 4.86 4.85 Power consumption (kW) 4.86 Heating capacity (kW) 4.61 4.59 Heating capacity (kW) 4.61 Pressure drop (Pa) 83.4 Pressure drop (Pa) 83.4 82.4 Energy efficiency 0.944 0.946 Energy efficiency 0.944 B C 330.8 331.3 14.7 14.6 4.85 4.85 4.59 4.68 82.9 82.4 0.964 0.946 C D 331.3 330.9 14.6 14.7 4.85 4.86 4.68 4.63 82.9 82.6 0.953 0.964 D 330.9 14.7 4.86 4.63 82.6 0.953 Energies 2016, 9, 813 8 of 9 4.2. Reliability Vibration and thermal shock test reliability tests were conducted in compliance with the relevant test conditions for PTC heaters (IEC60068-2-6 and IEC60068-2-14, respectively). Tables 7 and 8 present the heating performance results before and after the vibration and thermal shock reliability tests, respectively. After the vibration and thermal shock tests, the heating performance of the prototype heaters decreased by a maximum of 6.1% and 5.3%, respectively, which is much less than that allowed (10%). Moreover, after the reliability tests, the overall performance of the prototype heater reduced by only 5%. Overall, these results prove the high reliability of the developed prototypes. Table 7. Prototype characteristics before and after the vibration test. PTC Heater Parameter Input voltage (V) Input current (A) Power consumption (kW) Heating capacity (kW) Pressure drop (Pa) Energy efficiency Before After A B A0 B0 331.3 14.7 4.86 4.61 83.4 0.944 330.8 14.7 4.85 4.59 82.4 0.946 330.3 14.6 4.82 4.35 83.7 0.903 329.9 14.7 4.84 4.31 83.5 0.890 Table 8. Prototype characteristics before and after the thermal shock test. PTC heater Parameter Input voltage (V) Input current (A) Power consumption (kW) Heating capacity (kW) Pressure drop (Pa) Energy efficiency Before After A B A0 B0 331.3 14.6 4.85 4.68 82.9 0.964 330.9 14.7 4.86 4.63 82.6 0.953 330.3 14.7 4.85 4.43 84.0 0.913 330.4 14.6 4.84 4.45 83.1 0.918 5. Conclusions This study improved the sintering process to enhance surface uniformity in the manufacturing process of PTC elements for use in EV heating systems. An electrode production process using thin-film sputtering deposition was applied to ensure the heating performance of PTC elements and reduce electrode material use. In addition, a heater for an EV heating system was manufactured using the developed high-voltage PTC elements to verify their performance. The study conclusions are as follows: (1) The proposed method realized an electrode layer of uniform thickness not exceeding 3.8 µm and reduced electrode material use by approximately 69%. (2) The allowable voltage and surface heat temperature of the high-voltage PTC elements developed with the thin-film electrode were 800 V and 172 ◦ C, respectively, which is adequate for use in high-voltage heaters. (3) The results of vibration and thermal shock testing were within the standard range, confirming that the developed heater was adequately reliable for use in EV vehicles. Acknowledgments: This study was performed as a part of the Energy Technology Development project sponsored by the Ministry of Trade, Industry and Energy and was supported by the 2016 Yeungnam University Research Grant. In addition, support from E-Gun Technology is greatly appreciated. Energies 2016, 9, 813 9 of 9 Author Contributions: Sung Chul Kim and Yoon Hyuk Shin organized the overall experimental evaluations and result analysis. Seung Ku Ahn commented on the results and conclusions. All the authors also reviewed the manuscript. Conflicts of Interest: The authors declare no conflict of interest. Nomenclature Cp I . m Tc Ti To V η specific heat of air (J/kg·K) current (A) mass flow rate of air (kg/s) Curie temperature (◦ C) inlet air temperature (◦ C) outlet air temperature (◦ C) input voltage (V) energy efficiency References 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. Yokoyama, A.; Osaka, T.; Imanishi, Y.; Sekiya, S. Thermal management system for electric vehicles. SAE Int. 2011, 4. [CrossRef] Lee, J.T.; Kwon, S.J.; Lim, Y.; Chon, M.S.; Kim, D. Effect of air-conditioning on driving range of electric vehicle for various driving modes. SAE Int. 2013. 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