SECTION 1 PRODUCT AND COMPANY INFORMATION PRODUCT NAME: Lithium Carbonate PRODUCT NUMBER: 2315 CAS NUMBER: 554-13-2 SYNONYMS: Dilithium carbonate, carbonic acid, dilithium salt MANUFACTURER: Prochem, Inc. 826 Roosevelt Road Rockford, IL 61109 PHONE: FAX: TOLL FREE: 815-398-1788 815-398-1810 800-795-8788 IN CASE OF TRANSPORTATION EMERGENCY CONTACT CHEM-TREC: 1-800-424-9300 SECTION 2 HAZARDS IDENTIFICATION CLASSIFICATION OF SUBSTANCE OR MIXTURE Pictogram Warning Signal Word Hazard Statements H302 H319 Harmful if swallowed Causes serious eye irritation. Precautionary Phrases P264 P270 P280 P301 + P312 P304 + P340 P305 + P351 + P338 Wash skin thoroughly after handling Do not eat, drink, or smoke when using this product Wear protective gloves/eye protection/face protection IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present HMIS CLASSIFICATION: Health: 2 Flammability: 0 NFPA RATING: Health: 2 Fire: 0 LITHIUM CARBONATE Reactivity: 0 Reactivity Hazard: 0 PAGE 1 SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Formula: Li2CO3 Molecular Weight: 73.89 CHEMICAL NAME CAS# % Lithium carbonate 554-13-2 100 SECTION 4 FIRST AID MEASURES EYE EXPOSURE: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. SKIN EXPOSURE: Wash affected area with soap and copious amounts of water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. INHALATION: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases give oxygen and seek immediately medical assistance. INGESTION: Do NOT induce vomiting. Allow victim to rinse mouth out with water provided victim is conscious. Seek immediate medical attention. SECTION 5 FIREFIGHTING MEASURES FLASH POINT: Not applicable AUTO IGNITION TEMPERATURE: Not applicable EXPLOSION LIMITS: Not applicable EXTINGUISHING MEDIUM: Carbon dioxide, extinguishing powder, or water spray. SPECIAL FIRE FIGHTING PROCEDURES: If involved in a fire, fire fighters should be equipped with a NIOSH approved positive self-contained breathing apparatus. HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Ignites and burns fiercely when in contact with fluorine. If this product is involved in a fire, the following can be released: Carbon monoxide, carbon dioxide, and lithium oxide. SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear protective equipment and ensure adequate ventilation. Avoid raising dust. ENVIRONMENTAL PRECAUTIONS: Do not let enter drains. Do not allow to be released into environment. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP: Sweep up avoiding raising dust and place in a well-marked container for proper disposal. SECTION 7 HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING: Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. Wear suitable respiratory equipment. CONDITIONS FOR SAFE STORAGE: Keep container tightly closed. Store in a cool, well-ventilated area. Do not store above 25° C. SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION EYE PROTECTION: Always wear approved safety glasses with side shields, or safety goggles, face shield when handling a chemical substance in the laboratory. SKIN PROTECTION: Chemical resistant gloves. VENTILATION: Handle in an efficient chemical fume hood. RESPIRATOR: Approved NIOSH type P95 or type P1 particle respirator. For higher levels of protection, use type OV/AG/P99 respirator cartridges. ADDITIONAL PROTECTION: Protection to avoid contact with skin, eyes, and clothing. Safety shower and eyewash in area. Use in a controlled environment. Do not drink, eat, or smoke in area. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES COLOR AND FORM: White solid MOLECULAR WEIGHT: 73.89 BOILING POINT: 1310° C LITHIUM CARBONATE PAGE 2 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES (Cont.) MELTING POINT: 723° C SPECIFIC GRAVITY: 2.11 gm/ml VAPOR PRESSURE: Not applicable SOLUBILITY: Soluble SECTION 10 STABILITY AND REACTIVITY STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: Not available SECTION 10 STABILITY AND REACTIVITY (Cont.) INCOMPATIBILITY: Reactive with oxidizing agents and acids. DECOMPOSITION PRODUCTS: Carbon dioxide, metal oxide fume, carbon monoxide, and lithium oxide. SECTION 11 TOXICOLOGICAL DATA CARCINOGENIC EFFECTS: No components of this product present at levels greater than or equal to 0.1% is identified as a confirmed carcinogen. MUTAGENIC EFFECTS: Not available TETRATOGENIC EFFECTS: Not available To the best of our knowledge the toxicological effects of this compound have not been fully investigated. SECTION 12 ECOLOGICAL DATA Do not allow material to be released into the environment SECTION 13 DISPOSAL CONSIDERATIONS Dispose of in according to local state and federal regulations. SECTION 14 TRANSPORTATION DATA Non-hazardous material SECTION 15 REGULATORY INFORMATION SARA 313 COMPONENTS: Lithium carbonate SARA 311/312 HAZARDS: Acute health hazard MASSACHUSETTS RIGHT TO KNOW COMPONENTS: Lithium carbonate PENNSYLVANIA RIGHT TO KNOW COMPONENTS: Lithium carbonate NEW JERSEY RIGHT TO KNOW COMPONENTS: Lithium carbonate CALIFORNIA PROP. 65 COMPONENTS: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Lithium carbonate LITHIUM CARBONATE PAGE 3 SECTION 16 OTHER INFORMATION DISCLAIMER: The information herein is believed to be accurate and reliable as of the date compiled. However, Prochem, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information in this document or any use of the product based on the information. DATE PREPARED: 02/14 LITHIUM CARBONATE PAGE 4
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