Abstract #858, 223rd ECS Meeting, © 2013 The Electrochemical Society 2 Hole mobility (cm /Vs) Coulomb scattering 600 GeOx=1.2 nm EOT=1.09 nm 400 GeOx=0.27 nm EOT=0.98 nm 200 GeOx=1.4 nm EOT=1.18 nm <110>/(001) Ge pMOSFETs 0.1 1 12 10 -2 Ns (10 cm ) Fig. 1 Mobility of Ge pMOSFETs with the Al2O3/GeOx/Ge gate stacks having different GeOx ILs thicknesses. 3 11 @Ns=5x10 cm -2 2 S factor (mV/dec) factor(mV/dec) S.S. 2 1 200 1.2 nm GeOx 150 100 50 0 T . 120 S.S.(120K) 0 100 200 300 Temperature (T) 0 1 2 3 12 4 2 5 Dit (10 cm /eV) Fig. 2 The mobility of Ge pMOSFETs with Al2O3/GeOx/Ge gate stacks (@NS=5×1011 cm-2) as a function of Dit evaluated from the S. S. factors measured at 120 K. Inset t shows the temperature dependence of S factor. 4000 w/ buffer (2/5/3 nm) 3000 2 Mobility [cm /Vs] (body thickness) w/o buffer (10 nm) 2000 1000 x 1.6 x 4.2 Si MOSFETs 15 N =4x10 cm -3 A 0 12 12 2x10 13 6x10 1x10 -2 N [cm ] S Fig. 3 eff characteristics of In0.7Ga0.3As-OI MOSFETs with and without MOS interface buffer. 7000 (a) In Ga As w/ buffer 0.7 4000 T eff [cm2/Vs] MOSFETs using III-V/Ge channels with high mobility and low effective mass have been regarded as strongly important for obtaining high current drive and low supply voltage CMOS under sub 10 nm regime [1, 2]. Thus, the development of the device technologies for III-V/Ge MOSFETs has been strongly accelerated. However, fundamental device physics on electrical properties of IIIV/Ge MOSFETs has not been fully clarified yet. Among a variety of the electrical properties, understanding of limiting factors of the III-V/Ge MOS channel mobility is of paramount importance, because the purpose of introducing these devices consists in the high current drive. In this paper, thus, we address key issues for enhancing channel mobility in InGaAs/Ge MOSFETs. It is well known that superior MOS interface properties can provide higher channel mobility, because of reduction in Coulomb scattering and surface roughness scattering. We have confirmed in Ge p-MOSFETs with ultrathin GeOx interfacial layers formed by plasma post oxidation [3], as shown in Fig. 1, that the GeOx thickness can control the peak mobility in a low Ns region [4]. This fact is attributed to lower Dit near Ev, estimated from the S factor, in thicker GeOx, as shown in Fig. 2. On the other hand, we have recently found [5] that the hole mobility in Ge p-MOSFETs in a high Ns region is significantly degraded by both trapping of free holes and severe surface roughness scattering. Thus, further reductions in MOS interface defect concentration and interface roughness are expected to provide higher mobility. We have reported through Hall measurements [6] that the trapping of free electrons into interface states or slow states within the conduction band also significantly lowers electron mobility in InGaAs MOSFETs. In addition, another critical factor for the electron mobility reduction is the influence of the ultrathin body channels, which are mandatory for short channel MOSFETs. It has been reported that ultrathin Si channels severely reduce the channel mobility, because of increased body thickness fluctuation scattering [7]. This thickness fluctuation scattering becomes worse for III-V MOSFETs with lower effective mass and wider inversion-layer thickness. Thus, we have proposed MOS interface buffer channel structure, where InGaAs buffer layers sandwich InGaAs channels with higher In content [8]. This structure is expected to allow us to mitigate the influences of MOS interface defects and the channel thickness fluctuation. Actually, we have observed the significant mobility enhancement in the In0.3Ga0.7As/In0.7Ga0.3As/In0.3Ga0.7As-OI structure over single In0.7Ga0.3As-OI structures. The mobility was evaluated with changing the thickness of the channel and the buffer (Fig. 4). It is found that thickness fluctuation scattering and surface roughness scattering dominate the mobility in low and high Ns region, respectively. This work was partly supported by a Grant-in-Aid for Scientific Research (No. 23246058) from MEXT, and Innovation Research Project on Nano electronics Materials and Structures, and Research and Development 1000 800 -3 S. Takagi1, S.-H. Kim1, R. Zhang1, N. Taoka1, 2, M. Yokoyama1, and M. Takenaka1 1 The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 JAPAN 2 Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 JAPAN e-mail: [email protected] Program for Innovative Energy Efficiency Technology from NEDO. The authors would like to thank Drs. T. Yasuda, T. Maeda, W. Jevasuwan, N. Miyata, Y. Urabe and H. Takagi in AIST, Drs. M. Hata, T. Osada, O. Ichikawa, and N. Fukuhara in Sumitomo Chemical, and Dr. H. Yokoyama in NTT for their collaborations. 1/ (10 Vs/cm ) Limiting factors of channel mobility in III-V/Ge MOSFETs body T body 0.3 -1.1 = 2/3/3 nm N 1000 700 400 NS = 2/5/3 nm -0.8 S T body = 2/1/3 nm NS -0.5 at 150 K 12 1x10 12 4x10 N [cm-2] 12 7x10 S Fig. 4 eff characteristics of In0.7Ga0.3As-OI MOSFETs with a MOS interface buffer layer as a parameter of the Tbody at 150 K References [1] S. Takagi et al., Solid-State Electron. 51 (2007) 526 [2] S. Takagi et al., IEEE Trans. Electron Device 55 (2008) 21 [3] R. Zhang et al., Appl. Phys. Lett. 98 (2011) 112902 [4] R. Zhang et al., IEEE Trans. Electron Device 59 (2012) 335 [5] R. Zhang et al., presented in Tech. Dig. IEDM (2012) [6] N. Taoka et al., Tech. Dig. IEDM (2011) 610 [7] K. Uchida et al., Appl. Phys. Lett. 82 (2003) 2916 [8] S.-H. Kim et al., Appl. Phys. Exp. 5 (2012) 014201
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