Safety Data Sheet Hydrogen Peroxide, 3% Section 1 Product Name: Recommended Use: Synonyms: Distributor: Chemical Information: Chemtrec: Product Description Hydrogen Peroxide, 3% Science education applications Hydrogen Peroxide Solution Carolina Biological Supply Company 2700 York Road, Burlington, NC 27215 1-800-227-1150 800-227-1150 (8am-5pm (ET) M-F) 800-424-9300 (Transportation Spill Response 24 hours) Section 2 Hazard Identification Classification of the chemical in accordance with paragraph (d) of §1910.1200; DANGER Causes skin irritation. Causes serious eye damage. GHS Classification: Serious Eye Damage/Eye Irritation Category 1, Skin Corrosion/Irritation Category 2 Section 3 Chemical Name Water Hydrogen Peroxide Section 4 Composition / Information on Ingredients CAS # 7732-18-5 7722-84-1 % 97 3 First Aid Measures Emergency and First Aid Procedures Inhalation: In case of accident by inhalation: remove casualty to fresh air and keep at rest. Eyes: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin Contact: IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Ingestion: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Section 5 Extinguishing Media: Fire Fighting Methods and Protection: Fire and/or Explosion Hazards: Hazardous Combustion Products: Section 6 Hydrogen Peroxide, 3% Firefighting Procedures Use media suitable to extinguish surrounding fire. Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus. N/A Carbon dioxide, Carbon monoxide Spill or Leak Procedures Page 1 of 4 Safety Data Sheet Steps to Take in Case Material Is Released or Spilled: Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment recommendations found in Section 8 of this SDS. Additional precautions may be necessary based on special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred. Also consider the expertise of employees in the area responding to the spill. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. Section 7 Handling: Storage: Storage Code: Handling and Storage Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe dust/vapor. Do not get in eyes, on skin, or on clothing. Retained residue may make empty containers hazardous; use caution. Suitable for any general chemical storage. Avoid direct sunlight and heat. Green - general chemical storage Section 8 Protection Information ACGIH Chemical Name Hydrogen Peroxide (TWA) 1 ppm TWA Control Parameters Engineering Measures: Personal Protective Equipment (PPE): Respiratory Protection: Eye Protection: Skin Protection: Gloves: Section 9 (STEL) N/A Local exhaust ventilation or other engineering controls are normally required when handling or using this product to avoid overexposure. Lab coat, apron, eye wash, safety shower. No respiratory protection required under normal conditions of use. Wear chemical splash goggles when handling this product. Have an eye wash station available. Avoid skin contact by wearing chemically resistant gloves, an apron and other protective equipment depending upon conditions of use. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work. Neoprene, Nitrile Physical Data Formula: H202 (aq) Molecular Weight: 34.01 g/mol Appearance: Colorless Liquid Odor: None Odor Threshold: No data available pH: 6.0-8.0 Melting Point: No data available Boiling Point: 100 C Flash Point: No data available Flammable Limits in Air: N/A Section 10 Vapor Pressure: N/A Evaporation Rate (BuAc=1): N/A Vapor Density (Air=1): 1.2 (air = 1) Specific Gravity: 1.01 Solubility in Water: Soluble Log Pow (calculated): No data available Autoignition Temperature: No data available Decomposition Temperature: No data available Viscosity: No data available Percent Volatile by Volume: 100% Reactivity Data Reactivity: Chemical Stability: Conditions to Avoid: Incompatible Materials: Hazardous Polymerization: Section 11 Routes of Entry OSHA PEL (TWA) (STEL) 1 ppm TWA; 1.4 N/A mg/m3 TWA No data available Stable under normal conditions. None known. Water-reactive materials, Metals (powdered) Will not occur Toxicity Data Inhalation, ingestion, eye or skin contact. Hydrogen Peroxide, 3% Page 2 of 4 Safety Data Sheet Symptoms (Acute): Delayed Effects: Eye Irritation, Respiratory Irritation No data available Acute Toxicity: Chemical Name Water CAS Number 7732-18-5 Hydrogen Peroxide 7722-84-1 Carcinogenicity: Chemical Name No data available Chronic Effects: Mutagenicity: Teratogenicity: Sensitization: Reproductive: Target Organ Effects: Acute: Chronic: Oral LD50 Oral LD50 Rat 90000 mg/kg Oral LD50 Rat 910 mg/kg Oral LD50 Rat 376 mg/kg CAS Number IARC Not listed Dermal LD50 Inhalation LC50 Dermal LD50 Rat 4060 mg/kg INHALATION LC50 Rat 2 GM/M3 NTP Not listed OSHA Not listed No evidence of a mutagenic effect. No evidence of a teratogenic effect (birth defect). No evidence of a sensitization effect. No evidence of negative reproductive effects. Skin, Eyes No data available Section 12 Overview: Mobility: Persistence: Bioaccumulation: Degradability: Other Adverse Effects: Ecological Data This material is not expected to be harmful to the ecology. No data No data No data No data No data Chemical Name Water Hydrogen Peroxide CAS Number 7732-18-5 7722-84-1 Section 13 Eco Toxicity No data available 96 HR LC50 PIMEPHALES PROMELAS 16.4 MG/L 24 HR EC50 DAPHNIA MAGNA 7.7 MG/L 72 HR EC50 CHLORELLA VULGARIS 2.5 MG/L Disposal Information Disposal Methods: Dispose in accordance with all applicable Federal, State and Local regulations. Always contact a permitted waste disposer (TSD) to assure compliance. This material is not considered to be a RCRA hazardous waste. Waste Disposal Code(s): Section 14 Transport Information Ground - DOT Proper Shipping Name: Not regulated for transport by DOT Air - IATA Proper Shipping Name: Not regulated for air transport by IATA. Section 15 TSCA Status: Regulatory Information All components in this product are on the TSCA Inventory. Chemical Name CAS Number § 313 Name § 304 RQ CERCLA RQ § 302 TPQ CAA 112(2) TQ Hydrogen Peroxide 7722-84-1 No No No 1000 lb TPQ (concentratio n >52%) No Section 16 Hydrogen Peroxide, 3% Additional Information Page 3 of 4 Safety Data Sheet Revised: 09/10/2015 Replaces: 09/10/2015 Printed: 10-29-2015 The information provided in this (Material) Safety Data Sheet represents a compilation of data drawn directly from various sources available to us. Carolina Biological Supply makes no representation or guarantee as to the suitability of this information to a particular application of the substance covered in the (Material) Safety Data Sheet. Glossary ACGIH CAS CERCLA DOT IARC N/A American Conference of Governmental Industrial Hygienists Chemical Abstract Service Number Comprehensive Environmental Response, Compensation, and Liability Act U.S. Department of Transportation International Agency for Research on Cancer Not Available Hydrogen Peroxide, 3% NTP OSHA PEL ppm RCRA SARA TLV TSCA IDLH National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million Resource Conservation and Recovery Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act Immediately dangerous to life and health Page 4 of 4
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