SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name
: Pyrolysis Gasoline
Registration number
: 01-2119489289-18-0002, 01-2119489289-18-XXXX
Substance name
: naphtha (petroleum), light steam-cracked
Substance No.
: 265-187-5
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the
Substance/Mixture
: Raw material in chemical industry, Manufacture, Distribution,
Use in fuels, Use as an intermediate
1.3 Details of the supplier of the safety data sheet
Manufacturer
: Borealis Polymers Oy
P.O.Box 330, FI-06101 Porvoo, Finland
Telephone: +358 9 394900
Borealis AB
S-444 86 Stenungsund, Sweden
Telephone: +46 303 86000
Supplier
: Borealis AG
Wagramer Strasse 17-19, 1220 Vienna, Austria
Telephone: +43 1 22400 0
E-mail address
: [email protected]
1.4 Emergency telephone number
0870 600 6266 National Poisons Information Service, UK (24h)
2. Hazards identification
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)
Flammable liquids, Category 2
Aspiration hazard, Category 1
Acute toxicity, Category 4
Skin irritation, Category 2
Eye irritation, Category 2
Acute toxicity, Category 4
Germ cell mutagenicity, Category 1B
Carcinogenicity, Category 1A
H225: Highly flammable liquid and vapour.
H304: May be fatal if swallowed and enters
airways.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H340: May cause genetic defects.
H350: May cause cancer.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 1 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Reproductive toxicity, Category 2
Specific target organ toxicity - repeated
exposure, Category 1
Chronic aquatic toxicity, Category 2
Print Date 14.04.2016
H361d: Suspected of damaging the unborn child.
H372: Causes damage to organs through
prolonged or repeated exposure.
H411: Toxic to aquatic life with long lasting effects.
Classification (67/548/EEC, 1999/45/EC)
Highly flammable
Carcinogenic Category 1
Mutagenic Category 2
Toxic to Reproduction Category 3
Toxic
R11: Highly flammable.
R45: May cause cancer.
R46: May cause heritable genetic damage.
R63: Possible risk of harm to the unborn child.
R48/23/24/25: Toxic: danger of serious damage to
health by prolonged exposure through inhalation, in
contact with skin and if swallowed.
R65: Harmful: may cause lung damage if
swallowed.
R36/38: Irritating to eyes and skin.
R51/53: Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment.
Harmful
Irritant
Dangerous for the environment
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H225
H304
Highly flammable liquid and vapour.
May be fatal if swallowed and enters
airways.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
Harmful if inhaled.
May cause genetic defects.
May cause cancer.
Suspected of damaging the unborn child.
Causes damage to organs through
prolonged or repeated exposure.
Toxic to aquatic life with long lasting effects.
H312
H315
H319
H332
H340
H350
H361d
H372
H411
Precautionary statements
:
Prevention:
P202
P260
P210
P243
P280
Do not handle until all safety precautions
have been read and understood.
Do not breathe dust/ fume/ gas/ mist/
vapours/ spray.
Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
Take precautionary measures against static
discharge.
Wear protective gloves/ protective clothing/
eye protection/ face protection.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 2 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
P273
Avoid release to the environment.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take
off immediately all contaminated clothing.
Rinse skin with water/ shower.
P301 + P310
IF SWALLOWED: Immediately call a
POISON CENTER or doctor/ physician.
P331
Do NOT induce vomiting.
P391
Collect spillage.
Hazardous components
 64742-83-2
 71-43-2
 108-88-3
which must be listed on the label:
naphtha (petroleum), light steam-cracked
benzene
toluene
Additional Labelling:
Restricted to professional users.
2.3 Other hazards
Vapours may form explosive mixtures with air.
High risk of fire in case of leakage.
3. Composition/information on ingredients
3.1 Substances
Chemical nature
: Petroleum distillates
CAS-No.
Concentration [%]
EINECS-No. / ELINCS No.
Substance of unknown or variable composition, complex reaction products or biological material
(UVCB) :
naphtha (petroleum), light
64742-83-2
<= 100
steam-cracked
265-187-5
Contains :
benzene
71-43-2
30 - 50
200-753-7
toluene
108-88-3
8 - 20
203-625-9
Chemical Name
4. First aid measures
4.1 Description of first aid measures
General advice
: Where there is potential for exposure:
Restrict access to authorised persons.
Provide specific activity training to operators to minimise
exposures.
First aider needs to protect himself.
Wear respiratory protection.
Do not leave the victim unattended.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 3 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Move out of dangerous area.
Take off contaminated clothing and shoes immediately.
In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
If inhaled
: Move to fresh air.
Do not leave the victim unattended.
Keep patient warm and at rest.
Immediate medical attention is required.
If breathing is difficult, give oxygen.
No artificial respiration, mouth-to-mouth or mouth to nose. Use
suitable instruments/apparatus.
If unconscious place in recovery position.
In case of skin contact
: Wash off immediately with soap and plenty of water for at
least 15 minutes while removing all contaminated clothes and
shoes.
If skin irritation persists, call a physician.
In case of eye contact
: Remove contact lenses.
In case of eye contact, remove contact lens and rinse
immediately with plenty of water, also under the eyelids, for at
least 15 minutes.
Protect unharmed eye.
If symptoms persist, call a physician.
If eye irritation persists, consult a specialist.
If swallowed
: Do NOT induce vomiting.
If a person vomits when lying on his back, place him in the
recovery position.
Immediate medical attention is required.
Clean mouth with water and drink afterwards plenty of water.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms
: Eye contact:
Redness
Dilatation of the pupil
Skin contact:
Redness
Swelling of tissue
Inhalation:
Headache
Nausea
Cough
Breathing difficulties
discomfort in the chest
Shortness of breath
Risks
: Causes eye irritation.
Causes skin irritation.
Repeated exposure may cause skin dryness or cracking.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 4 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
May cause respiratory irritation.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment
: In case of ingestion, the stomach should be emptied by gastric
lavage under qualified medical supervision.
5. Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
: Dry powder
Carbon dioxide (CO2)
Foam
Water mist
Unsuitable extinguishing
: High volume water jet
media
5.2 Special hazards arising from the substance or mixture
Specific hazards during
firefighting
: Vapours are heavier than air and may spread along floors.
Flash back possible over considerable distance.
Fire will produce dense black smoke containing hazardous
combustion products (see section 10).
Do not allow run-off from fire fighting to enter drains or water
courses.
Vapours may form explosive mixtures with air.
5.3 Advice for firefighters
Special protective equipment
for firefighters
Further information
: Wear self-contained breathing apparatus and protective suit.
: Keep people away from and upwind of spill/leak.
Observe the risk of explosion.
Remove all sources of ignition.
Use water spray to cool unopened containers.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency proce dures
Personal precautions
: Use personal protective equipment.
Avoid inhalation of vapour or mist.
Ensure adequate ventilation, especially in confined areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Remove all sources of ignition.
6.2 Environmental precautions
Environmental precautions
: Prevent product from entering environment and drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 5 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up
: Small amounts:
Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).
Large amounts:
Dam up.
Remove from surface water (e.g. by skimming or siphoning).
6.4 Reference to other sections
For personal protection see section 8., For disposal considerations see section 13.
7. Handling and storage
7.1 Precautions for safe handling
Advice on safe handling
: The following actions are recommended: Closed systems for
handling, process and storage.
To be handled by trained personnel only.
Ensure adequate ventilation.
Container may be opened only under exhaust ventilation
hood.
Avoid splashes.
Do not use compressed air for filling, discharging or handling.
Dispose of rinse water in accordance with local and national
regulations.
Avoid inhalation of vapour or mist.
Easy access to emergency shower and eye wash facility is
required.
Advice on protection against
fire and explosion
: Keep product and empty container away from heat and
sources of ignition.
Take precautionary measures against static discharges.
To avoid ignition of vapours by static electricity discharge, all
metal parts of the equipment must be grounded.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage
areas and containers
: Keep locked up or in an area accessible only to qualified or
authorised persons.
Keep container tightly closed and in a well-ventilated place.
Suitable materials for containers:
Mild steel
Stainless steel
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Keep in properly labelled containers.
Further information on
storage conditions
: Vapours may form explosive mixtures with air.
Keep away from sources of ignition - No smoking.
Provide adequate precautions, such as electrical grounding
and bonding, or inert atmospheres.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 6 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Advice on common storage
Print Date 14.04.2016
: Keep away from incompatible materials.
See chapter 10.
Keep away from food, drink and animal feedingstuffs.
7.3 Specific end use(s)
Remarks
: Reserved for industrial and professional use.
8. Exposure controls/personal protection
8.1 Control parameters
Components
CAS-No.
Value
benzene
71-43-2
TWA
Further
information
:
Further
information
:
toluene
108-88-3
Further
information
:
TWA
:
2004-06-29
2004/37/EC
1 ppm
2005-04-06
GB EH40
50 ppm
192 mg/m3
2006-02-09
2006/15/EC
skin: Identifies the possibility of significant uptake through the skin
Indicative
100 ppm
384 mg/m3
2006-02-09
2006/15/EC
skin: Identifies the possibility of significant uptake through the skin
Indicative
TWA
Further
information
Basis
Sk: Can be absorbed through skin. The assigned substances are those for which there are
concerns that dermal absorption w ill lead to systemic toxicity.
Capable of causing cancer and/or heritable genetic damage. The identified substances include
those w hich: - are assigned the risk phrases 'R45: May cause cancer'; 'R46: may cause
heritable genetic damage'; 'R49: May cause cancer by inhalation' or - a substance or process
listed in Schedule 1 of COSHH.
Where no specific short-term exposure limit is listed, a figure three times the long-term
exposure should be used
STEL
:
Update
6: Substantial contribution to the total burden via dermal exposure possible
Skin
Carcinogens or mutagens
TWA
Further
information
Control
parameters
1 ppm
3,25 mg/m3
50 ppm
191 mg/m3
2007-08-01
GB EH40
Sk: Can be absorbed through skin. The assigned substances are those for which there are
concerns that dermal absorption w ill lead to systemic toxicity.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 7 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
STEL
Further
information
:
DNEL
benzene
toluene
100 ppm
384 mg/m3
2007-08-01
Print Date 14.04.2016
GB EH40
Sk: Can be absorbed through skin. The assigned substances are those for which there are
concerns that dermal absorption w ill lead to systemic toxicity.
: End Use: Workers
Exposure routes: Skin contact
Potential health effects: Long-term systemic effects
Value: 23,4 mg/kg bw/d
Derived minimal effect level
End Use: Workers
Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 3,25 mg/m3
Derived minimal effect level
: End Use: Workers
Exposure routes: Skin contact
Potential health effects: Long-term systemic effects
Value: 384 mg/kg bw/d
End Use: Workers
Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 192 mg/m3
PNEC
benzene
: Fresh water
Value: 1,9 mg/l
Marine water
Value: 1,9 mg/l
Intermittent use/release
Value: 1,9 mg/l
Marine sediment
Value: 33 mg/kg
Soil
Value: 4,8 mg/kg
Sewage treatment plant
Value: 39 mg/l
8.2 Exposure controls
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 8 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Engineering measures
Minimise exposure using measures such as closed systems, dedicated facilities and suitable
general / local exhaust ventilation.
Ensure safe systems of work or equivalent arrangements are in place to manage risks.
Regularly inspect, test and maintain all control measures.
Personal protective equipment
Respiratory protection
: In case of insufficient ventilation: Respirator with A2 or ABEK
filter or self-contained breathing apparatus.
Hand protection
: Wear suitable gloves:
: Viton
Break through time: > 240 min
: Neoprene
Break through time: > 10 min
: thick PVC
Eye protection
: Wear goggles and if needed face-shield.
Skin and body protection
: Wear suitable protective clothing and rubber boots.
Hygiene measures
: Ensure adequate ventilation.
Avoid and prevent all spillage, contact and exposure.
Smoking, eating and drinking should be prohibited in the
application area.
Protective measures
: Provide specific activity training to operators to minimise
exposures.
Consider the need for risk based health surveillance.
Environmental exposure controls
General advice
: Prevent product from entering environment and drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance
: liquid
Colour
: colourless, yellow, dark brown
Odour
: aromatic
Odour Threshold
: no data available
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 9 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
pH
: no data available
Melting point
: < -25 °C
Boiling range
: > 35 - 200 °C
Flash point
: < -10 °C
Flammability (solid, gas)
: Highly flammable.
Lower explosion limit
: 1,2 %(V), Benzene
Upper explosion limit
: 8,0 %(V), Benzene
Vapour pressure
: 100 hPa, 20 °C, Benzene
Relative vapour density
: 2,7, Benzene
Relative density
: ca. 0,82
Water solubility
: 0,035 - 0,16 g/l
Solubility in other solvents
: no data available
Partition coefficient: noctanol/water
: log Pow: 2,2 - 6,5
log Pow: 2,1, Benzene
Auto-ignition temperature
: 401 - 502 °C, 1013,0 hPa
Viscosity, kinematic
: 0,64 - 1,07 mm²/s, 20 °C
0,52 - 0,83 mm²/s, 40 °C
9.2 Other information
Molecular weight
: Not applicable
Surface tension
: 70,2 - 72 mN/m
10. Stability and reactivity
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
No decomposition if stored and applied as directed.
10.3 Possibility of hazardous reactions
Hazardous reactions
: Vapours may form explosive mixture with air.
10.4 Conditions to avoid
Conditions to avoid
: Observe the risk of explosion.
Keep away from heat and sources of ignition.
10.5 Incompatible materials
Materials to avoid
: Reacts violently with:
Oxidizing agents
Nitric acid
sulphuric acid
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 10 of 55
Print Date 14.04.2016
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Fluorine
Chlorine
Bromine
May attack many plastics, rubbers and coatings.
10.6 Hazardous decomposition products
Hazardous decomposition
products
: Under fire conditions:
Carbon monoxide, carbon dioxide and unburned
hydrocarbons (smoke).
11. Toxicological information
11.1 Information on toxicological effects
Product
Acute oral toxicity
: LD50: > 5.000 mg/kg, Rat, Read-across (Analogy)
Acute dermal toxicity
: LD50: > 2.000 mg/kg, Rat, Read-across (Analogy)
Skin corrosion/irritation
: Result: Irritating to skin.
Serious eye damage/eye
irritation
: Result: Irritating to eyes.
Respiratory or skin
sensitisation
: Result: Does not cause skin sensitisation.
: Result: Does not cause respiratory sensitisation.
Germ cell mutagenicity
Genotoxicity in vivo
: In vivo micronucleus test, Mouse, Bone marrow, Inhalation,
Mutagenicity (micronucleus test), Result: positive, Readacross (Analogy)
Assessment
: May cause genetic defects.
Carcinogenicity
: Information given is based on data on the components and
the toxicology of similar products.
May cause cancer.
Teratogenicity
: Information given is based on data on the components and
the toxicology of similar products.
Assessment: Suspected of damaging the unborn child.
Neurological effects
Aspiration toxicity
:
Components of the product may affect the nervous system.
: Harmful: may cause lung damage if swallowed.
Components
benzene :
Acute oral toxicity
: Lethal dose: ca. 15 ml, human, Bronchitis, Pneumonia,
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 11 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Fatality
: LD50: > 2.000 mg/kg, Rat(male), OECD Test Guideline 401
Acute inhalation toxicity
: LC50: 44,5 mg/l, 4 h, Rat, Central nervous system depression
: 61 - 65 mg/l, 5 min, human, Fatality
: 25 mg/l, 30 min, human, Fatality
: 1,6 mg/l, 1 h, human, Headache, Nausea, Dizziness
: 0,16 - 0,48 mg/l, 5 h, human, Fatigue, Headache
: 1 - 5 ppm, Odour threshold.
: 300 ppm, Odour, 100% recognition
Acute dermal toxicity
: LD50: > 8.260 mg/kg, Rabbit
Skin corrosion/irritation
: Rabbit, Result: irritating, OECD Test Guideline 404
Serious eye damage/eye
irritation
: Rabbit, Result: irritating
Respiratory or skin
sensitisation
: Mouse, Result: Did not cause sensitisation on laboratory
animals.
Germ cell mutagenicity
Genotoxicity in vitro
: Ames test, with and without metabolic activation, Result:
negative, OECD Test Guideline 471
: Chromosome aberration test in vitro, with and without
metabolic activation, Result: positive
Genotoxicity in vivo
: Mouse, Bone marrow, Inhalation, 8 weeks, Mutagenicity
(micronucleus test), Result: positive
: In vivo micronucleus test, Mouse, inhalation (vapour), OECD
Test Guideline 474, Result: positive
Assessment
: May cause genetic defects.
Carcinogenicity
: Mouse(male and female), Dose: 25 mg/kg bw/d, Exposure
time: 103 wks, Number of exposures: 1/d, 5 d/wk, Oral, OECD
Test Guideline 453
: Mouse(male and female), Dose: 300 ppm, Exposure time: 2 16 wks, Number of exposures: 6 h/d, 5 d/wk, Inhalation
May cause cancer.
Reproductive toxicity
: Rat, Number of exposures: 6 h/d, 5 d/wk, Inhalation, NOAEL:
960 mg/m3, F1: 960 mg/m3, OECD Test Guideline 415
Assessment: Animal testing did not show any effects on
fertility.
Teratogenicity
: Rat, Number of exposures: 7 h/d, Inhalation, NOAEL: 1.600
mg/m3, 32 mg/m3, OECD Test Guideline 414
Assessment: Did not show teratogenic effects in animal
experiments.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 12 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
STOT - repeated exposure
Revision Date 17.10.2014
Print Date 14.04.2016
: Rat, Oral, LOAEL: 25 mg/kg, OECD Test Guideline 408,
Changes in the blood count,
May have effects on the bone marrow, resulting in leukaemia.
: human, Inhalation, NOAEL: 11,2 mg/m3
: Assessment: Causes damage to organs through prolonged or
repeated exposure.
toluene :
Acute oral toxicity
: LD50: 5.580 mg/kg, Rat(male)
Acute inhalation toxicity
: LC50: > 20 mg/l, 4 h, Rat, OECD Test Guideline 403,
Dizziness, Loss of balance, Neurological disorders,
Vapours may cause drowsiness and dizziness.
Acute dermal toxicity
: LD50: > 5.000 mg/kg, Rabbit
Teratogenicity
: Rat, Inhalation, NOAEL: 600 ppm
STOT - repeated exposure
: Rat, Oral, NOAEL: 625 mg/kg
: Rat, Inhalation, NOAEL: 1.131 mg/m3
12. Ecological information
12.1 Toxicity
Product
Toxicity to fish
Toxicity to daphnia and other
aquatic invertebrates
Toxicity to algae
Toxicity to bacteria
: LL50: 1,1 mg/l, 96 h, Oncorhynchus mykiss (rainbow trout),
semi-static test, OECD Test Guideline 203, GLP: yes,
Read-across (Analogy)
: EC50: 1,2 mg/l, 48 h, Daphnia magna (Water flea), static test,
OECD Test Guideline 202, GLP: yes,
Read-across (Analogy)
: EC50: 1,8 mg/l, 96 h, Growth rate, Pseudokirchneriella
subcapitata (green algae), static test, OECD Test Guideline
201, GLP: yes,
Read-across (Analogy)
: NOEC: 3,75 mg/l, 72 h, Growth inhibition, QSAR,
Read-across (Analogy)
Ecotoxicology Assessment
Chronic aquatic toxicity
: Toxic to aquatic life with long lasting effects.
Components
benzene :
Toxicity to fish
: LC50: 5,3 mg/l, 96 h, Oncorhynchus mykiss (rainbow trout),
flow-through test, OECD Test Guideline 203
Toxicity to daphnia and other
: EC50: 10 mg/l, 48 h, Daphnia magna (Water flea), static test,
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 13 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
aquatic invertebrates
Revision Date 17.10.2014
Print Date 14.04.2016
Toxicity to algae
OECD Test Guideline 202,
Mobility
: EC50: 32 mg/l, 72 h, Biomass, Pseudokirchneriella
subcapitata (green algae), static test, OECD Test Guideline
201
Toxicity to bacteria
: IC50: 13 mg/l, 24 h, Nitrosomonas sp
Toxicity to fish (Chronic
toxicity)
: LOEC: 1,6 mg/l, 32 d, Pimephales promelas (fathead
minnow), flow-through test
Toxicity to daphnia and other
aquatic invertebrates
(Chronic toxicity)
: NOEC: 3 mg/l, 7 d, Ceriodaphnia Dubia (water flea), semistatic test
12.2 Persistence and degradability
Product
Biodegradability
: 7,3 - 29 %, Result: Not readily biodegradable., Exposure time:
28 d,
Read-across (Analogy)
Components
benzene :
Biodegradability
: Result: Readily biodegradable., activated sludge, OECD Test
Guideline 301F
12.3 Bioaccumulative potential
Product
Bioaccumulation
Components
benzene :
Bioaccumulation
: Bioaccumulation is unlikely. Information given is based on
data on the components and the ecotoxicology of similar
products.
: Bioconcentration factor (BCF): ca. 13, QSAR,
Bioaccumulation not expected., log Pow: 2,13
12.4 Mobility in soil
Product
Distribution among
environmental compartments
Components
benzene :
Mobility
Distribution among
environmental compartments
Physico-chemical
removability
: Adsorption/Soil, log Koc: 1,46 - 4,71, QSAR, Input data for the
components
:
:
:
:
Air, 99%
Water, 0,6%
Soil, 0,02%
Adsorption/Soil, Koc: 134,1, QSAR
: Readily degradable., Estimated atmospheric half-life:, 4 - 20
days.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 14 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
12.5 Results of PBT and vPvB assessment
Product
Assessment
: This substance is not considered to be persistent,
bioaccumulating and toxic (PBT)., This substance is not
considered to be very persistent and very bioaccumulating
(vPvB).
12.6 Other adverse effects
Product
Additional ecological
information
: Avoid release to the environment.
13. Disposal considerations
13.1 Waste treatment methods
Product
: Dispose of as hazardous waste in compliance with local and
national regulations.
European waste code:
07 01 04* (other organic solvents, washing liquids and mother
liquors)
Where possible recycling is preferred to disposal or
incineration.
14. Transport information
14.1 UN number
ADR
IMDG
IATA
: 3295
: 3295
: 3295
14.2 Proper shipping name
ADR
IMDG
IATA
: HYDROCARBONS, LIQUID, N.O.S.
(benzene, toluene)
: HYDROCARBONS, LIQUID, N.O.S.
(benzene, toluene)
: HYDROCARBONS, LIQUID, N.O.S.
(benzene, toluene)
14.3 Transport hazard class
ADR
IMDG
IATA
: 3
: 3
: 3
14.4 Packing group
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 15 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
ADR
Packaging group
Hazard Identification Number
Labels
Tunnel restriction code
IMDG
Packaging group
EmS Number
IATA
Packaging group
Revision Date 17.10.2014
:
:
:
:
Print Date 14.04.2016
II
33
3
D/E
: II
: F-E, S-D
: II
14.5 Environmental hazards
ADR
Environmentally hazardous
: yes
IMDG
Marine pollutant
: yes
IATA
Environmentally hazardous
: no
14.6 Special precautions for user
Avoid release to the environment.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Ship type
Pollution category
Remarks
: 2
: Y
: Product name in English:, Pyrolysis gasoline (containing
benzene)
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
REACH - Restrictions on the
manufacture, placing on the
market and use of certain
dangerous substances,
preparations and articles
(Annex XVII)
: benzene
Restricted to professional users.
Regulation (EC) No
649/2012 of the European
Parliament and the Council
concerning the export and
import of dangerous
chemicals
: benzene
See Annex XVII to Regulation (EC) no 1907/2006 for
Conditions of restriction
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 16 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Other regulations
Print Date 14.04.2016
: Europe.Directive 2004/37/EC on the protection of workers
from the risks related to exposure to carcinogens or mutagens
at work
Take note of Directive 94/33/EC on the protection of young
people at work.
Take note of Directive 92/85/EEC on the safety and health at
work of pregnant workers.
15.2 Chemical Safety Assessment
A Chemical Safety Assessment has been carried out for this substance.
16. Other information
Full text of R-phrases referred to under sections 2 and 3
R11
R36/38
R45
R46
R48/23/24/25
R51/53
R63
R65
Highly flammable.
Irritating to eyes and skin.
May cause cancer.
May cause heritable genetic damage.
Toxic: danger of serious damage to health by prolonged exposure
through inhalation, in contact with skin and if swallowed.
Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Possible risk of harm to the unborn child.
Harmful: may cause lung damage if swallowed.
Full text of H-Statements referred to under sections 2 and 3.
H225
H304
H312
H315
H319
H332
H340
H350
H361d
H372
H411
Highly flammable liquid and vapour.
May be fatal if swallowed and enters airways.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
Harmful if inhaled.
May cause genetic defects.
May cause cancer.
Suspected of damaging the unborn child.
Causes damage to organs through prolonged or repeated exposure.
Toxic to aquatic life with long lasting effects.
Further information
Other information
: Changes since the last version are highlighted in the margin.
This version replaces all previous versions.
The classification corresponds to the current EC listing, but is
enhanced by specialised literature data and the Company's
own information.
Issuer
: Borealis, Group Product Stewardship / Maarit Vakkala
Sources of key data used to
compile the Safety Data
Sheet
: Chemical Safety Report, High Benzene Naphthas. Lower
Olefins and Aromatics REACH Consortium, 2010
ECHA - Information on Registered Substances
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 17 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
(http://echa.europa.eu/web/guest/information-onchemicals/registered-substances)
International Chemical Safety Card, Benzene, May 2003
(http://www.inchem.org/documents/icsc/icsc/eics0015.htm)
Toxicological review of Benzene, Oct. 2002, EPA/635/R02/001F (http://www.epa.gov/iris/toxreviews/0276t r.pdf)
Summary Risk Assessment Report, Benzene 2008
(http://ecb.jrc.ec.europa.eu/documents/ExistingChemicals/RISK_ASSESSMENT/SUMMARY/benzenes um06
3.pdf)
Risk Assessment Report, Toluene 2003
(http://ecb.jrc.ec.europa.eu/DOCUMENTS/ExistingChemicals/RISK_ASSESSMENT/REPORT/toluenereport032.
pdf)
Disclaimer
To the best of our knowledge, the information contained herein is accurate and reliable as of the
date of publication; however we do not assume any liability whatsoever for the accuracy and
completeness of such information.
Borealis makes no warranties which extend beyond the description contained herein.
Nothing herein shall constitute any warranty of merchantability or fitness for a particular
purpose.
It is the customer's responsibility to inspect and test our products in order to satisfy itself
as to the suitability of the products for the customer's particular purpose. The customer is
responsible for the appropriate, safe and legal use, processing and handling of our
products.
No liability can be accepted in respect of the use of Borealis' products in conjunction with other
materials. The information contained herein relates exclusively to our products when not used in
conjunction with any third party materials.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 18 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Identified uses:
Use: Manufacture
Main User Groups
Sectors of end-use
Process categories
Environmental Release Categories
: SU 3: Industrial uses: Uses of substances as such or in
preparations at industrial sites
: SU 3, SU8, SU9: Industrial Manufacturing (all), Manufacture
of bulk, large scale chemicals (including petroleum products),
Manufacture of fine chemicals
: PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises
PROC8a: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at nondedicated facilities
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC15: Use as laboratory reagent
: ERC1, ERC4: Manufacture of substances, Industrial use of
processing aids in processes and products, not becoming part
of articles
Use: Distribution
Main User Groups
Sectors of end-use
Process categories
: SU 3: Industrial uses: Uses of substances as such or in
preparations at industrial sites
: SU 3, SU8, SU9: Industrial Manufacturing (all), Manufacture
of bulk, large scale chemicals (including petroleum products),
Manufacture of fine chemicals
: PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises
PROC8a: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at nondedicated facilities
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC9: Transfer of substance or preparation into small
containers (dedicated filling line, including weighing)
PROC15: Use as laboratory reagent
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 19 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Environmental Release Categories
Revision Date 17.10.2014
Print Date 14.04.2016
: ERC1, ERC2, ERC3, ERC4, ERC5, ERC6a, ERC6b, ERC6c,
ERC6d, ERC7: Manufacture of substances, Formulation of
preparations, Formulation in materials, Industrial use of
processing aids in processes and products, not becoming part
of articles, Industrial use resulting in inclusion into or onto a
matrix, Industrial use resulting in manufacture of another
substance (use of intermediates), Industrial use of reactive
processing aids, Industrial use of monomers for manufacture
of thermoplastics, Industrial use of process regulators for
polymerisation processes in production of resins, rubbers,
polymers, Industrial use of substances in closed systems
Use: Use as an intermediate
Main User Groups
Sectors of end-use
Process categories
Environmental Release Categories
: SU 3: Industrial uses: Uses of substances as such or in
preparations at industrial sites
: SU 3, SU8, SU9: Industrial Manufacturing (all), Manufacture
of bulk, large scale chemicals (including petroleum products),
Manufacture of fine chemicals
: PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises
PROC8a: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at nondedicated facilities
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC15: Use as laboratory reagent
: ERC6a: Industrial use resulting in manufacture of another
substance (use of intermediates)
Use: Use in fuels, Industrial use
Main User Groups
Sectors of end-use
Process categories
: SU 3: Industrial uses: Uses of substances as such or in
preparations at industrial sites
: SU 3, SU 10: Industrial Manufacturing (all), Formulation
[mixing] of preparations and/ or re-packaging (excluding
alloys)
: PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 20 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises
PROC8a: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at nondedicated facilities
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC16: Using material as fuel sources, limited exposure to
unburned product to be expected
Environmental Release Categories
: ERC7: Industrial use of substances in closed systems
Use: Use in fuels, Professional use
Main User Groups
Sectors of end-use
Process categories
Environmental Release Categories
: SU 22: Professional uses: Public domain (administration,
education, entertainment, services, craftsmen)
: SU 22: Public domain (administration, education,
entertainment, services, craftsmen)
: PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises
PROC8a: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at nondedicated facilities
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC16: Using material as fuel sources, limited exposure to
unburned product to be expected
: ERC9a, ERC9b: Wide dispersive indoor use of substances in
closed systems, Wide dispersive outdoor use of substances in
closed systems
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 21 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
1. Short title of Exposure Scenario: Manufacture
Main User Groups
Sectors of end-use
Process categories
Environmental Release Categories
: SU 3: Industrial uses: Uses of substances as such or in
preparations at industrial sites
: SU 3, SU8, SU9: Industrial Manufacturing (all), Manufacture
of bulk, large scale chemicals (including petroleum products),
Manufacture of fine chemicals
: PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises
PROC8a: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at nondedicated facilities
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC15: Use as laboratory reagent
: ERC1, ERC4: Manufacture of substances, Industrial use of
processing aids in processes and products, not becoming part
of articles
2.1 Contributing scenario controlling environmental exposure for: ERC1, ERC4:
Manufacture of substances, Industrial use of processing aids in processes and
products, not becoming part of articles
Amount used
Annual amount per site
Daily amount per site
Daily amount per site (Msafe)
: 500000 t
: 1700000 kg
: 1.800.000 kg
Environment factors not influenced by risk management
Dilution Factor (River)
: 40
Dilution Factor (Coastal Areas)
: 100
Other given operational conditions affecting environmental exposure
Continuous use/release
Number of emission days per year
: 300
Emission or Release Factor: Air
: 0,001 %
Emission or Release Factor: Water : 0 %
Emission or Release Factor: Soil
: 0,01 %
Remarks
: Risk from environmental exposure is driven by humans via
indirect exposure (primarily ingestion). If discharging to
domestic sewage treatment plant, no on-site wastewater
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 22 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
treatment required.
Technical conditions and measures / Organizational measures
Air
: Treat air emission to provide a typical removal efficiency of
(%): (Effectiveness (of a measure): 90 %)
Water
: Treat onsite wastewater (prior to receiving water discharge) to
provide the required removal efficiency of (%): (Effectiveness
(of a measure): 0 %)
Remarks
: Common practices vary across sites thus conservative
process release estimates used. Prevent discharge of
undissolved substance to or recover from onsite wastewater.
Do not apply industrial sludge to natural soils. Sludge should
be incinerated, contained or reclaimed.
Conditions and measures related to
Type of Sewage Treatment Plant
Flow rate of sewage treatment
plant effluent
Effectiveness (of a measure)
Percentage removed from waste
water
municipal sewage treatment plant
: Municipal sewage treatment plant
: 10.000 m³/d
Conditions and measures related to
Remarks
Conditions and measures related to
Remarks
external treatment of waste for disposal
: During manufacturing no waste of the substance is generated.
external recovery of waste
: During manufacturing no waste of the substance is generated.
: 95 %
: 95 %
2.2 Contributing scenario controlling worker exposure for: General measures
(carcinogens), General risk management measures applicable to all activities
PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC15: Use in closed process,
no likelihood of exposure, Use in closed, continuous process with occasional
controlled exposure, Use in closed batch process (synthesis or formulation), Use in
batch and other process (synthesis) where opportunity for exposure arises, Transfer
of substance or preparation (charging/ discharging) from/ to vessels/ large containers
at non-dedicated facilities, Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated facilities, Use as
laboratory reagent
Product characteristics
Concentration of the Substance in
Mixture/Article
Remarks
Frequency and duration of use
Remarks
: Covers the percentage of the substance in the product up to
100 % (unless stated differently).
: Liquid, vapour pressure 0.5 - 10 kPa
: Covers daily exposures up to 8 hours (unless stated
differently).
Other operational conditions affecting workers exposure
Remarks
: Assumes use at not more than 20°C above ambient
temperature. Assumes a good basic standard of occupational
hygiene is implemented.
Technical conditions and measures
Drain or remove substance from equipment prior to break-in or maintenance.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 23 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Organisational measures to prevent /limit releases, dispersion and exposure
Consider technical advances and process upgrades (including automation) for the elimination of
releases. Minimise exposure using measures such as closed systems, dedicated facilities and
suitable general / local exhaust ventilation. Clean / flush equipment , where possible, prior to
maintenance. Where there is potential for exposure: Restrict access to authorised persons. Provide
specific activity training to operators to minimise exposures. Wear suitable gloves and coveralls to
prevent skin contamination. Wear respiratory protection when its use is identified for certain
contributing scenarios. Clear up spills immediately and dispose of waste safely. Ensure safe systems
of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and
maintain all control measures. Consider the need for risk based health surveillance.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.
2.3 Contributing scenario controlling worker exposure for: General exposures (closed
systems), Outdoor
PROC1: Use in closed process, no likelihood of exposure
Technical conditions and measures
Handle substance within a closed system. Provide a good standard of general or controlled
ventilation (5 to 15 air changes per hour).
2.4 Contributing scenario controlling worker exposure for: General exposures (closed
systems), with sample collection, With occasional controlled exposure, Outdoor
PROC2: Use in closed, continuous process with occasional controlled exposure
Technical conditions and measures
Handle substance within a closed system. Sample via a closed loop or other system to avoid
exposure.
Organisational measures to prevent /limit releases, dispersion and exposure
Avoid carrying out activities involving exposure for more than 4 hours.
2.5 Contributing scenario controlling worker exposure for: General exposures (closed
systems), Use in contained batch processes
PROC3: Use in closed batch process (synthesis or formulation)
Technical conditions and measures
Handle substance within a closed system. Transfer via enclosed lines. Provide a good standard of
general ventilation (not less than 3 to 5 air changes per hour). , or:
Ensure operation is undertaken outdoors. Avoid carrying out activities involving exposure for more
than 1 hour.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 24 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
2.6 Contributing scenario controlling worker exposure for: General exposures (open
systems), Batch process, with sample collection
PROC4: Use in batch and other process (synthesis) where opportunity for exposure
arises
Technical conditions and measures
Transfer via enclosed lines. Provide a good standard of general ventilation (not less than 3 to 5 air
changes per hour). , or:
Ensure operation is undertaken outdoors. Avoid carrying out activities involving exposure for more
than 4 hours.
2.7 Contributing scenario controlling worker exposure for: Process sampling
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at dedicated facilities
Technical conditions and measures
Sample via a closed loop or other system to avoid exposure. Provide a good standard of general
ventilation (not less than 3 to 5 air changes per hour). Provide extraction ventilation at points where
emissions occur.
Organisational measures to prevent /limit releases, dispersion and exposure
Avoid carrying out activities involving exposure for more than 1 hour. Ensure operatives are trained
to minimise exposures.
2.8 Contributing scenario controlling worker exposure for: Laboratory activities
PROC15: Use as laboratory reagent
Technical conditions and measures
Provide a good standard of general or controlled ventilation (5 to 15 air changes per hour). Handle
within a fume cupboard or implement equivalent measures to minimise exposures.
2.9 Contributing scenario controlling worker exposure for: Bulk transfers, (open
systems), With potential for aerosol generation
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at dedicated facilities
Technical conditions and measures
Ensure material transfers are under containment or extract ventilation. Provide a good standard of
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 25 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
general ventilation (not less than 3 to 5 air changes per hour). , or:
Ensure operation is undertaken outdoors. Avoid carrying out activities involving exposure for more
than 4 hours.
2.10 Contributing scenario controlling worker exposure for: Bulk transfers, (closed
systems)
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at dedicated facilities
Technical conditions and measures
Handle substance within a closed system. Ensure material transfers are under containment or
extract ventilation.
Clear transfer lines prior to de-coupling. Provide a good standard of general or controlled ventilation
(5 to 10 air changes per hour).
Organisational measures to prevent /limit releases, dispersion and exposure
Avoid carrying out activities involving exposure for more than 4 hours.
2.11 Contributing scenario controlling worker exposure for: Equipment cleaning and
maintenance
PROC8a: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at non-dedicated facilities
Technical conditions and measures
Drain down and flush system prior to equipment opening or maintenance. Ensure operation is
undertaken outdoors. Clear spills immediately. , or:
Avoid carrying out activities involving exposure for more than 1 hour. Retain drain downs in sealed
storage pending disposal or for subsequent recycle.
Provide a good standard of general or controlled ventilation (5 to 10 air changes per hour).
Conditions and measures related to personal protection, hygiene and health evaluation
Wear a respirator conforming to EN140 with Type A filter or better.
2.12 Contributing scenario controlling worker exposure for: Storage, With occasional
controlled exposure, Outdoor
PROC2: Use in closed, continuous process with occasional controlled exposure
Technical conditions and measures
Sample via a closed loop or other system to avoid exposure. Store substance within a closed
system. , or:
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 26 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour). Avoid
carrying out activities involving exposure for more than 4 hours.
Avoid dip sampling. Provide a good standard of general or controlled ventilation (5 to 10 air changes
per hour).
3. Exposure estimation and reference to its source
Environment
Contributing
Scenario
Exposure
Assessment
Method
ERC1,
ERC4
Hydrocarbon
Block method,
PETRORISK
Specific
conditions
Compartment
Value
Level of
Exposure
RCR
Fresh water
0,00089
Marine water
Fresh water
sediment
Marine
sediment
0,00036
0,001
0,00041
Workers
Contributing
Scenario
Exposure
Assessment
Method
PROC1
ECETOC TRA
PROC2
ECETOC TRA
PROC3
ECETOC TRA
PROC4
ECETOC TRA
PROC8b
ECETOC TRA
PROC15
ECETOC TRA
PROC8b
ECETOC TRA
PROC8b
ECETOC TRA
PROC8a
ECETOC TRA
PROC2
ECETOC TRA
Specific conditions
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 27 of 55
Value
Level of
Exposure
RCR
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
0,01 ppm
0,34 mg/kg/day
0,50 ppm
0,14 mg/kg/day
0,70 ppm
0,03 mg/kg/day
0,56 ppm
0,69 mg/kg/day
0,35 ppm
0,69 mg/kg/day
0,30 ppm
0,03 mg/kg/day
0,63 ppm
0,69 mg/kg/day
0,90 ppm
0,69 mg/kg/day
0,35 ppm
0,14 mg/kg/day
0,21 ppm
0,14 mg/kg/day
0,01
0,01
0,50
0,01
0,70
0,00
0,56
0,03
0,35
0,03
0,30
0,00
0,63
0,03
0,90
0,03
0,35
0,01
0,21
0,01
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
4. Guidance to Downstream User to evaluate whether he works inside the
boundaries set by the Exposure Scenario
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus,
scaling may be necessary to define appropriate site-specific risk management measures.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 28 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
1. Short title of Exposure Scenario: Distribution
Main User Groups
Sectors of end-use
Process categories
Environmental Release Categories
: SU 3: Industrial uses: Uses of substances as such or in
preparations at industrial sites
: SU 3, SU8, SU9: Industrial Manufacturing (all), Manufacture
of bulk, large scale chemicals (including petroleum products),
Manufacture of fine chemicals
: PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises
PROC8a: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at nondedicated facilities
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC9: Transfer of substance or preparation into small
containers (dedicated filling line, including weighing)
PROC15: Use as laboratory reagent
: ERC1, ERC2, ERC3, ERC4, ERC5, ERC6a, ERC6b, ERC6c,
ERC6d, ERC7: Manufacture of substances, Formulation of
preparations, Formulation in materials, Industrial use of
processing aids in processes and products, not becoming part
of articles, Industrial use resulting in inclusion into or onto a
matrix, Industrial use resulting in manufacture of another
substance (use of intermediates), Industrial use of reactive
processing aids, Industrial use of monomers for manufacture
of thermoplastics, Industrial use of process regulators for
polymerisation processes in production of resins, rubbers,
polymers, Industrial use of substances in closed systems
2.1 Contributing scenario controlling environmental exposure for: ERC1, ERC2, ERC3,
ERC4, ERC5, ERC6a, ERC6b, ERC6c, ERC6d, ERC7: Manufacture of substances,
Formulation of preparations, Formulation in materials, Industrial use of processing
aids in processes and products, not becoming part of articles, Industrial use resulting
in inclusion into or onto a matrix, Industrial use resulting in manufacture of another
substance (use of intermediates), Industrial use of reactive processing aids, Industrial
use of monomers for manufacture of thermoplastics, Industrial use of process
regulators for polymerisation processes in production of resins, rubbers, polymers,
Industrial use of substances in closed systems
Amount used
Annual amount per site
Daily amount per site
: 1000 t
: 10000 kg
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 29 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Daily amount per site (Msafe)
Revision Date 17.10.2014
Print Date 14.04.2016
: 170.000 kg
Environment factors not influenced by risk management
Dilution Factor (River)
: 10
Dilution Factor (Coastal Areas)
: 100
Other given operational conditions affecting environmental exposure
Continuous use/release
Number of emission days per year
: 100
Emission or Release Factor: Air
: 0,1 %
Emission or Release Factor: Water : 0,001 %
Emission or Release Factor: Soil
: 0,001 %
Remarks
: Risk from environmental exposure is driven by humans via
indirect exposure (primarily ingestion). If discharging to
domestic sewage treatment plant, no on-site wastewater
treatment required.
Technical conditions and measures / Organizational measures
Air
: Treat air emission to provide a typical removal efficiency of
(%): (Effectiveness (of a measure): 90 %)
Water
: Treat onsite wastewater (prior to receiving water discharge) to
provide the required removal efficiency of (%): (Effectiveness
(of a measure): 0 %)
Remarks
: Common practices vary across sites thus conservative
process release estimates used. Prevent discharge of
undissolved substance to or recover from onsite wastewater.
Do not apply industrial sludge to natural soils. Sludge should
be incinerated, contained or reclaimed.
Conditions and measures related to
Type of Sewage Treatment Plant
Flow rate of sewage treatment
plant effluent
Effectiveness (of a measure)
Percentage removed from waste
water
municipal sewage treatment plant
: Municipal sewage treatment plant
: 2.000 m³/d
Conditions and measures related to
Remarks
Conditions and measures related to
Remarks
external treatment of waste for disposal
: In accordance with local and national regulations.
external recovery of waste
: In accordance with local and national regulations.
: 95 %
: 95 %
2.2 Contributing scenario controlling worker exposure for: General measures
(carcinogens), General risk management measures applicable to all activities
PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC9, PROC15: Use in closed
process, no likelihood of exposure, Use in closed, continuous process with
occasional controlled exposure, Use in closed batch process (synthesis or
formulation), Use in batch and other process (synthesis) where opportunity for
exposure arises, Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at non-dedicated facilities, Transfer of substance or
preparation (charging/ discharging) from/ to vessels/ large containers at dedicated
facilities, Transfer of substance or preparation into small containers (dedicated filling
line, including weighing), Use as laboratory reagent
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 30 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Product characteristics
Concentration of the Substance in
Mixture/Article
Remarks
: Covers the percentage of the substance in the product up to
100 % (unless stated differently).
: Liquid, vapour pressure 0.5 - 10 kPa
Frequency and duration of use
Remarks
Print Date 14.04.2016
: Covers daily exposures up to 8 hours (unless stated
differently).
Other operational conditions affecting workers exposure
Remarks
: Assumes use at not more than 20°C above ambient
temperature. Assumes a good basic standard of occupational
hygiene is implemented.
Technical conditions and measures
Drain or remove substance from equipment prior to break-in or maintenance.
Organisational measures to prevent /limit releases, dispersion and exposure
Consider technical advances and process upgrades (including automation) for the elimination of
releases. Minimise exposure using measures such as closed systems, dedicated facilit ies and
suitable general / local exhaust ventilation. Clean / flush equipment, where possible, prior to
maintenance. Where there is potential for exposure: Restrict access to authorised persons. Provide
specific activity training to operators to minimise exposures. Wear suitable gloves and coveralls to
prevent skin contamination. Wear respiratory protection when its use is identified for certain
contributing scenarios. Clear up spills immediately and dispose of waste safely. Ensure safe systems
of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and
maintain all control measures. Consider the need for risk based health surveillance.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.
2.3 Contributing scenario controlling worker exposure for: General exposures (closed
systems)
PROC1: Use in closed process, no likelihood of exposure
Technical conditions and measures
Handle substance within a closed system.
2.4 Contributing scenario controlling worker exposure for: General exposures (closed
systems), with sample collection, With occasional controlled exposure
PROC2: Use in closed, continuous process with occasional controlled exposure
Technical conditions and measures
Handle substance within a closed system. Sample via a closed loop or other system to avoid
exposure. Ensure operation is undertaken outdoors. , or:
Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour).
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 31 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
2.5 Contributing scenario controlling worker exposure for: General exposures (closed
systems), Use in contained batch processes
PROC3: Use in closed batch process (synthesis or formulation)
Technical conditions and measures
Handle substance within a closed system. Sample via a closed loop or other system to avoid
exposure. Ensure operation is undertaken outdoors.
2.6 Contributing scenario controlling worker exposure for: General exposures (open
systems), Batch process, with sample collection
PROC4: Use in batch and other process (synthesis) where opportunity for exposure
arises
Technical conditions and measures
Sample via a closed loop or other system to avoid expos ure. Ensure operation is undertaken
outdoors. , or:
Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour).
Clear transfer lines prior to de-coupling.
2.7 Contributing scenario controlling worker exposure for: Process sampling
PROC3: Use in closed batch process (synthesis or formulation)
Technical conditions and measures
Handle substance within a predominantly closed system provided with extract ventilation. Sample via
a closed loop or other system to avoid exposure. Provide a good standard of general ventilation (not
less than 3 to 5 air changes per hour).
Avoid dip sampling.
2.8 Contributing scenario controlling worker exposure for: Laboratory activities
PROC15: Use as laboratory reagent
Technical conditions and measures
Handle within a fume cupboard or implement equivalent measures to minimise exposures.
2.9 Contributing scenario controlling worker exposure for: Bulk transfers, (closed
systems)
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 32 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at dedicated facilities
Technical conditions and measures
Ensure material transfers are under containment or extract ventilation. Ensure operation is
undertaken outdoors.
Clear transfer lines prior to de-coupling.
Organisational measures to prevent /limit releases, dispersion and exposure
Avoid carrying out activities involving exposure for more than 4 hours.
2.10 Contributing scenario controlling worker exposure for: Bulk transfers, (open
systems)
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at dedicated facilities
Technical conditions and measures
Ensure material transfers are under containment or extract ventilation. Ensure operation is
undertaken outdoors.
Clear transfer lines prior to de-coupling.
Organisational measures to prevent /limit releases, dispersion and exposure
Avoid carrying out activities involving exposure for more than 4 hours.
2.11 Contributing scenario controlling worker exposure for: Drum and small package
filling
PROC9: Transfer of substance or preparation into small containers (dedicated filling
line, including weighing)
Technical conditions and measures
Provide a good standard of general or controlled ventilation (5 to 15 air changes per hour). Minimise
exposure by partial enclosure of the operation or equipment and provide extract ventilation at
openings.
Put lids on containers immediately after use.
2.12 Contributing scenario controlling worker exposure for: Equipment cleaning and
maintenance
PROC8a: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at non-dedicated facilities
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 33 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Technical conditions and measures
Drain down and flush system prior to equipment opening or maintenance. Retain drain downs in
sealed storage pending disposal or for subsequent recycle.
Transfer via enclosed lines.
Organisational measures to prevent /limit releases, dispersion and exposure
Apply vessel entry procedures including use of forced supplied air. Clear spills immediately.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear a respirator conforming to EN140 with Type A filter or better.
2.13 Contributing scenario controlling worker exposure for: Storage, With occasional
controlled exposure
PROC2: Use in closed, continuous process with occasional controlled exposure
Technical conditions and measures
Transfer via enclosed lines. Ensure operation is undertaken outdoors. Store substance within a
closed system.
Avoid dip sampling.
3. Exposure estimation and reference to its source
Environment
Contributing
Scenario
Exposure
Assessment
Method
ERC1-7
Hydrocarbon
Block method
PETRORISK
Specific
conditions
Compartment
Value
Level of
Exposure
RCR
Fresh water
0,00021
Marine water
Fresh water
sediment
Marine
sediment
0,000021
0,00025
0,000025
Workers
Contributing
Scenario
Exposure
Assessment
Method
PROC1
ECETOC TRA
PROC2
ECETOC TRA
PROC3
ECETOC TRA
Specific conditions
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 34 of 55
Value
Level of
Exposure
RCR
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
0,01 ppm
0,34 mg/kg/day
0,35 ppm
0,14 mg/kg/day
0,88 ppm
0,03 mg/kg/day
0,01
0,01
0,35
0,01
0,88
0,00
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
PROC4
ECETOC TRA
PROC3
ECETOC TRA
PROC15
ECETOC TRA
PROC8b
ECETOC TRA
PROC8b
ECETOC TRA
PROC9
ECETOC TRA
PROC8a
ECETOC TRA
PROC2
ECETOC TRA
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Print Date 14.04.2016
0,70 ppm
0,69 mg/kg/day
0,88 ppm
0,03 mg/kg/day
0,30 ppm
0,03 mg/kg/day
0,63 ppm
0,69 mg/kg/day
0,63 ppm
0,69 mg/kg/day
0,75 ppm
0,69 mg/kg/day
0,50 ppm
1,37 mg/kg/day
0,84 ppm
1,37 mg/kg/day
4. Guidance to Downstream User to evaluate whether he works inside the
boundaries set by the Exposure Scenario
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus,
scaling may be necessary to define appropriate site-specific risk management measures.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 35 of 55
0,70
0,03
0,88
0,00
0,30
0,00
0,63
0,03
0,63
0,03
0,75
0,03
0,50
0,06
0,84
0,06
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
1. Short title of Exposure Scenario: Use as an intermediate
Main User Groups
Sectors of end-use
Process categories
Environmental Release Categories
: SU 3: Industrial uses: Uses of substances as such or in
preparations at industrial sites
: SU 3, SU8, SU9: Industrial Manufacturing (all), Manufacture
of bulk, large scale chemicals (including petroleum products),
Manufacture of fine chemicals
: PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises
PROC8a: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at nondedicated facilities
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC15: Use as laboratory reagent
: ERC6a: Industrial use resulting in manufacture of another
substance (use of intermediates)
2.1 Contributing scenario controlling environmental exposure for: ERC6a: Industrial
use resulting in manufacture of another substance (use of intermediates)
Amount used
Annual amount per site
Daily amount per site
Daily amount per site (Msafe)
: 15000 t
: 50000 kg
: 180.000 kg
Environment factors not influenced by risk management
Dilution Factor (River)
: 10
Dilution Factor (Coastal Areas)
: 100
Other given operational conditions affecting environmental exposure
Continuous use/release
Number of emission days per year
: 300
Emission or Release Factor: Air
: 0,005 %
Emission or Release Factor: Water : 0,001 %
Emission or Release Factor: Soil
: 0,1 %
Remarks
: Risk from environmental exposure is driven by humans via
indirect exposure (primarily ingestion). If discharging to
domestic sewage treatment plant, no on-site wastewater
treatment required.
Technical conditions and measures / Organizational measures
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 36 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Air
Water
Remarks
Conditions and measures related to
Type of Sewage Treatment Plant
Flow rate of sewage treatment
plant effluent
Effectiveness (of a measure)
Percentage removed from waste
water
Revision Date 17.10.2014
Print Date 14.04.2016
: Treat air emission to provide a typical removal efficiency of
(%): (Effectiveness (of a measure): 80 %)
: Treat onsite wastewater (prior to receiving water discharge) to
provide the required removal efficiency of (%): (Effectiveness
(of a measure): 0 %)
: Common practices vary across sites thus conservative
process release estimates used. Prevent discharge of
undissolved substance to or recover from onsite wastewater.
Do not apply industrial sludge to natural soils. Sludge should
be incinerated, contained or reclaimed.
municipal sewage treatment plant
: Municipal sewage treatment plant
: 2.000 m³/d
: 95 %
: 95 %
Conditions and measures related to external treatment of waste for disposal
Remarks
: This substance is consumed during use and no waste of the
substance is generated.
Conditions and measures related to external recovery of waste
Remarks
: This substance is consumed during use and no waste of the
substance is generated.
2.2 Contributing scenario controlling worker exposure for: General measures
(carcinogens), General risk management measures applicable to all activities
PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC15: Use in closed process,
no likelihood of exposure, Use in closed, continuous process with occasional
controlled exposure, Use in closed batch process (synthesis or formulation), Use in
batch and other process (synthesis) where opportunity for exposure arise s, Transfer
of substance or preparation (charging/ discharging) from/ to vessels/ large containers
at non-dedicated facilities, Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated facilities, Use as
laboratory reagent
Product characteristics
Concentration of the Substance in
Mixture/Article
Remarks
Frequency and duration of use
Remarks
: Covers the percentage of the substance in the product up to
100 % (unless stated differently).
: Liquid, vapour pressure 0.5 - 10 kPa
: Covers daily exposures up to 8 hours (unless stated
differently).
Other operational conditions affecting workers exposure
Remarks
: Assumes use at not more than 20°C above ambient
temperature. Assumes a good basic standard of occupational
hygiene is implemented.
Technical conditions and measures
Drain or remove substance from equipment prior to break-in or maintenance.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 37 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Organisational measures to prevent /limit releases, dispersion and exposure
Consider technical advances and process upgrades (including automation) for the elimination of
releases. Minimise exposure using measures such as closed systems, dedicated facilit ies and
suitable general / local exhaust ventilation. Clean / flush equipment, where possible, prior to
maintenance. Where there is potential for exposure: Restrict access to authorised persons. Provide
specific activity training to operators to minimise exposures. Wear suitable gloves and coveralls to
prevent skin contamination. Wear respiratory protection when its use is identified for certain
contributing scenarios. Clear up spills immediately and dispose of waste safely. Ensure safe systems
of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and
maintain all control measures. Consider the need for risk based health surveillance.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.
2.3 Contributing scenario controlling worker exposure for: General exposures (closed
systems), Outdoor
PROC1: Use in closed process, no likelihood of exposure
Technical conditions and measures
Handle substance within a closed system. Provide a good standard of general or controlled
ventilation (5 to 15 air changes per hour).
2.4 Contributing scenario controlling worker exposure for: General exposures (closed
systems), with sample collection, With occasional controlled exposure, Outdoor
PROC2: Use in closed, continuous process with occasional controlled exposure
Technical conditions and measures
Handle substance within a closed system. Sample via a closed loop or other system to avoid
exposure.
Organisational measures to prevent /limit releases, dispersion and exposure
Avoid carrying out activities involving exposure for more than 4 hours.
2.5 Contributing scenario controlling worker exposure for: General exposures (closed
systems), Use in contained batch processes
PROC3: Use in closed batch process (synthesis or formulation)
Technical conditions and measures
Handle substance within a closed system. Transfer via enclosed lines. Provide a good standard of
general ventilation (not less than 3 to 5 air changes per hour). , or:
Ensure operation is undertaken outdoors. Avoid carrying out activities involving exposure for more
than 1 hour.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 38 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
2.6 Contributing scenario controlling worker exposure for: General exposures (open
systems), Batch process, with sample collection
PROC4: Use in batch and other process (synthesis) where opportunity for exposure
arises
Technical conditions and measures
Transfer via enclosed lines. Provide a good standard of general ventilation (not less than 3 to 5 air
changes per hour). , or:
Ensure operation is undertaken outdoors. Avoid carrying out activities involving exposure for more
than 4 hours.
2.7 Contributing scenario controlling worker exposure for: Process sampling
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at dedicated facilities
Technical conditions and measures
Sample via a closed loop or other system to avoid exposure. Provide a good standard of general
ventilation (not less than 3 to 5 air changes per hour). Provide extraction ventilation at points where
emissions occur.
Organisational measures to prevent /limit releases, dispersion and exposure
Avoid carrying out activities involving exposure for more than 1 hour. Ensure operatives are trained
to minimise exposures.
2.8 Contributing scenario controlling worker exposure for: Laboratory activities
PROC15: Use as laboratory reagent
Technical conditions and measures
Provide a good standard of general or controlled ventilation (5 to 15 air changes per hour). Handle
within a fume cupboard or implement equivalent measures to minimise exposures.
2.9 Contributing scenario controlling worker exposure for: Bulk transfers, (open
systems), With potential for aerosol generation
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at dedicated facilities
Technical conditions and measures
Ensure material transfers are under containment or extract ventilation. Provide a good standard of
general ventilation (not less than 3 to 5 air changes per hour). , or:
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 39 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Ensure operation is undertaken outdoors. Avoid carrying out activities involving exposure for more
than 4 hours.
2.10 Contributing scenario controlling worker exposure for: Bulk transfers, (closed
systems)
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at dedicated facilities
Technical conditions and measures
Handle substance within a closed system. Ensure material transfers are under containment or
extract ventilation.
Clear transfer lines prior to de-coupling. Provide a good standard of general or controlled ventilation
(5 to 10 air changes per hour).
Organisational measures to prevent /limit releases, dispersion and exposure
Avoid carrying out activities involving exposure for more than 4 hours.
2.11 Contributing scenario controlling worker exposure for: Equipment cleaning and
maintenance
PROC8a: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at non-dedicated facilities
Technical conditions and measures
Drain down and flush system prior to equipment opening or maintenance. Ensure operation is
undertaken outdoors. Clear spills immediately. , or:
Avoid carrying out activities involving exposure for more than 1 hour. Retain drain downs in sealed
storage pending disposal or for subsequent recycle.
Provide a good standard of general or controlled ventilation (5 to 10 air changes per hour).
Conditions and measures related to personal protection, hygiene and health evaluation
Wear a respirator conforming to EN140 with Type A filter or better.
2.12 Contributing scenario controlling worker exposure for: Storage, With occasional
controlled exposure, Outdoor
PROC2: Use in closed, continuous process with occasional controlled exposure
Technical conditions and measures
Sample via a closed loop or other system to avoid exposure. Store substance within a closed
system. , or:
Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour). Avoid
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 40 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
carrying out activities involving exposure for more than 4 hours.
Avoid dip sampling. Provide a good standard of general or controlled ventilation (5 to 10 air changes
per hour).
3. Exposure estimation and reference to its source
Environment
Contributing
Scenario
Exposure
Assessment
Method
ERC6a
Hydrocarbon
Block method,
PETRORISK
Specific
conditions
Compartment
Value
Level of
Exposure
RCR
Fresh water
0,0011
Marine water
Fresh water
sediment
Marine
sediment
0,00011
0,0012
0,00012
Workers
Contributing
Scenario
Exposure
Assessment
Method
PROC1
ECETOC TRA
PROC2
ECETOC TRA
PROC3
ECETOC TRA
PROC4
ECETOC TRA
PROC8b
ECETOC TRA
PROC15
ECETOC TRA
PROC8b
ECETOC TRA
PROC8b
ECETOC TRA
PROC8a
ECETOC TRA
PROC2
ECETOC TRA
Specific conditions
Value
Level of
Exposure
RCR
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
0,01 ppm
0,34 mg/kg/day
0,50 ppm
0,14 mg/kg/day
0,70 ppm
0,03 mg/kg/day
0,56 ppm
0,69 mg/kg/day
0,35 ppm
0,69 mg/kg/day
0,30 ppm
0,03 mg/kg/day
0,63 ppm
0,69 mg/kg/day
0,90 ppm
0,69 mg/kg/day
0,35 ppm
0,14 mg/kg/day
0,21 ppm
0,14 mg/kg/day
0,01
0,01
0,50
0,01
0,70
0,00
0,56
0,03
0,35
0,03
0,30
0,00
0,63
0,03
0,90
0,03
0,35
0,01
0,21
0,01
4. Guidance to Downstream User to evaluate whether he works inside the
boundaries set by the Exposure Scenario
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 41 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus,
scaling may be necessary to define appropriate site-specific risk management measures.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 42 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
1. Short title of Exposure Scenario: Use in fuels, Industrial use
Main User Groups
Sectors of end-use
Process categories
Environmental Release Categories
: SU 3: Industrial uses: Uses of substances as such or in
preparations at industrial sites
: SU 3, SU 10: Industrial Manufacturing (all), Formulation
[mixing] of preparations and/ or re-packaging (excluding
alloys)
: PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises
PROC8a: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at nondedicated facilities
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC16: Using material as fuel sources, limited exposure to
unburned product to be expected
: ERC7: Industrial use of substances in closed systems
2.1 Contributing scenario controlling environmental exposure for: ERC7: Industrial
use of substances in closed systems
Amount used
Annual amount per site
Daily amount per site
Daily amount per site (Msafe)
: 25000 t
: 83000 kg
: 130.000 kg
Environment factors not influenced by risk management
Dilution Factor (River)
: 10
Dilution Factor (Coastal Areas)
: 100
Other given operational conditions affecting environmental exposure
Continuous use/release
Number of emission days per year
: 300
Emission or Release Factor: Air
: 0,05 %
Emission or Release Factor: Water : 0,001 %
Emission or Release Factor: Soil
: 0%
Remarks
: Risk from environmental exposure is driven by humans via
indirect exposure (primarily inhalation). If discharging to
domestic sewage treatment plant, no on-site wastewater
treatment required.
Technical conditions and measures / Organizational measures
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 43 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Air
Water
Remarks
Conditions and measures related to
Type of Sewage Treatment Plant
Flow rate of sewage treatment
plant effluent
Effectiveness (of a measure)
Percentage removed from waste
water
Revision Date 17.10.2014
Print Date 14.04.2016
: Treat air emission to provide a typical removal efficiency of
(%): (Effectiveness (of a measure): 95 %)
: Treat onsite wastewater (prior to receiving water discharge) to
provide the required removal efficiency of (%): (Effectiveness
(of a measure): 0 %)
: Common practices vary across sites thus conservative
process release estimates used. Prevent discharge of
undissolved substance to or recover from onsite wastewater.
Do not apply industrial sludge to natural soils. Sludge should
be incinerated, contained or reclaimed.
municipal sewage treatment plant
: Municipal sewage treatment plant
: 2.000 m³/d
: 95 %
: 95 %
Conditions and measures related to external treatment of waste for disposal
Remarks
: This substance is consumed during use and no waste of the
substance is generated.
Conditions and measures related to external recovery of waste
Remarks
: This substance is consumed during use and no waste of the
substance is generated.
2.2 Contributing scenario controlling worker exposure for: General measures
(carcinogens), General risk management measures applicable to all activities
PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC16: Use in closed process,
no likelihood of exposure, Use in closed, continuous process with occasional
controlled exposure, Use in closed batch process (synthesis or formulation), Use in
batch and other process (synthesis) where opportunity for exposure arises, Transfer
of substance or preparation (charging/ discharging) from/ to vessels/ large containers
at non-dedicated facilities, Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated facilities, Using material
as fuel sources, limited exposure to unburned product to be expected
Product characteristics
Concentration of the Substance in
Mixture/Article
Remarks
Frequency and duration of use
Remarks
: Covers the percentage of the substance in the product up to
100 % (unless stated differently).
: Liquid, vapour pressure 0.5 - 10 kPa
: Covers daily exposures up to 8 hours (unless stated
differently).
Other operational conditions affecting workers exposure
Remarks
: Assumes use at not more than 20°C above ambient
temperature. Assumes a good basic standard of occupational
hygiene is implemented.
Technical conditions and measures
Drain or remove substance from equipment prior to break-in or maintenance.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 44 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Organisational measures to prevent /limit releases, dispersion and exposure
Consider technical advances and process upgrades (including automation) for the elimination of
releases. Minimise exposure using measures such as closed systems, dedicated facilities and
suitable general / local exhaust ventilation. Clean / flush equipment, where possible, prior to
maintenance. Where there is potential for exposure: Restrict access to authorised persons. Provide
specific activity training to operators to minimise exposures. Wear suitable gloves and coveralls to
prevent skin contamination. Wear respiratory protection when its use is identified for certain
contributing scenarios. Clear up spills immediately and dispose of waste safely. Ensure safe systems
of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and
maintain all control measures. Consider the need for risk based health surveillance.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.
2.3 Contributing scenario controlling worker exposure for: Bulk transfers
PROC4: Use in batch and other process (synthesis) where opportunity for exposure
arises
Technical conditions and measures
Handle substance within a predominantly closed system provided with extract ventilation. Provide a
good standard of general or controlled ventilation (5 to 15 air changes per hour).
2.4 Contributing scenario controlling worker exposure for: Drum/batch transfers
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at dedicated facilities
Technical conditions and measures
Use drum pumps. Provide a good standard of general or controlled ventilation (5 to 15 air changes
per hour).
Organisational measures to prevent /limit releases, dispersion and exposure
Avoid carrying out activities involving exposure for more than 1 hour.
2.5 Contributing scenario controlling worker exposure for: General exposures (closed
systems)
PROC1: Use in closed process, no likelihood of exposure
Technical conditions and measures
Handle substance within a closed system.
2.6 Contributing scenario controlling worker exposure for: General exposures (closed
systems), With occasional controlled exposure
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 45 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
PROC2: Use in closed, continuous process with occasional controlled exposure
Technical conditions and measures
Handle substance within a predominantly closed system provided with extract ventilation. Provide a
good standard of general ventilation (not less than 3 to 5 air changes per hour).
2.7 Contributing scenario controlling worker exposure for: General exposures (closed
systems), Batch process
PROC3: Use in closed batch process (synthesis or formulation)
Technical conditions and measures
Handle substance within a predominantly closed system provided with extract ventilation. Provide a
good standard of general or controlled ventilation (5 to 15 air changes per hour).
2.8 Contributing scenario controlling worker exposure for: General exposures (open
systems), (closed systems)
PROC16: Using material as fuel sources, limited exposure to unburned product to be
expected
Technical conditions and measures
Handle substance within a predominantly closed system provided with extract ventilation.
2.9 Contributing scenario controlling worker exposure for: General exposures (open
systems), (closed systems), Batch process
PROC3: Use in closed batch process (synthesis or formulation)
Technical conditions and measures
Handle substance within a predominantly closed system provided with extract ventilation. Provide a
good standard of general or controlled ventilation (5 to 15 air changes per hour).
2.10 Contributing scenario controlling worker exposure for: Equipment maintenance
PROC8a: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at non-dedicated facilities
Technical conditions and measures
Drain down system prior to equipment opening or maintenance. Provide a good standard of general
ventilation (not less than 3 to 5 air changes per hour).
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 46 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Organisational measures to prevent /limit releases, dispersion and exposure
Clear spills immediately. Retain drain downs in sealed storage pending disposal or for subsequent
recycle.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear a respirator conforming to EN140 with Type A filter or better.
2.11 Contributing scenario controlling worker exposure for: Vessel and container
cleaning
PROC8a: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at non-dedicated facilities
Technical conditions and measures
Drain down and flush system prior to equipment opening or maintenance. Provide extraction
ventilation at points where emissions occur.
Organisational measures to prevent /limit releases, dispersion and exposure
Clear spills immediately. Retain drain downs in sealed storage pending disposal or for subsequent
recycle.
2.12 Contributing scenario controlling worker exposure for: Storage
PROC1: Use in closed process, no likelihood of exposure
Technical conditions and measures
Store substance within a closed system.
2.13 Contributing scenario controlling worker exposure for: Storage, With occasional
controlled exposure
PROC2: Use in closed, continuous process with occasional controlled exposure
Technical conditions and measures
Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour). Store
substance within a closed system. Ensure material transfers are under containment or extract
ventilation.
2.14 Contributing scenario controlling worker exposure for: Disposal of wastes
PROC8a: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at non-dedicated facilities
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 47 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Technical conditions and measures
Ensure material transfers are under containment or extract ventilation.
Organisational measures to prevent /limit releases, dispersion and exposure
Avoid carrying out activities involving exposure for more than 15 minutes.
3. Exposure estimation and reference to its source
Environment
Contributing
Scenario
Exposure
Assessment
Method
ERC7
Hydrocarbon
Block method,
PETRORISK
Specific
conditions
Compartment
Value
Level of
Exposure
RCR
Fresh water
0,0018
Marine water
Fresh water
sediment
Marine
sediment
0,00018
0,0021
0,00021
Workers
Contributing
Scenario
Exposure
Assessment
Method
PROC4
ECETOC TRA
PROC8b
ECETOC TRA
PROC1
ECETOC TRA
PROC2
ECETOC TRA
PROC3
ECETOC TRA
PROC16
ECETOC TRA
PROC3
ECETOC TRA
PROC8a
ECETOC TRA
PROC8a
ECETOC TRA
PROC1
ECETOC TRA
PROC2
ECETOC TRA
PROC8a
ECETOC TRA
Specific conditions
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 48 of 55
Value
Level of
Exposure
RCR
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
0,60 ppm
0,69 mg/kg/day
0,60 ppm
0,69 mg/kg/day
0,01 ppm
0,03 mg/kg/day
0,70 ppm
0,14 mg/kg/day
0,75 ppm
0,03 mg/kg/day
0,50 ppm
0,03 mg/kg/day
0,75 ppm
0,03 mg/kg/day
0,70 ppm
2,74 mg/kg/day
0,50 ppm
0,14 mg/kg/day
0,01 ppm
0,03 mg/kg/day
0,70 ppm
0,14 mg/kg/day
0,50 ppm
0,14 mg/kg/day
0,60
0,03
0,60
0,03
0,01
0,00
0,70
0,01
0,75
0,00
0,50
0,00
0,75
0,00
0,70
0,12
0,50
0,01
0,01
0,00
0,70
0,01
0,50
0,01
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
4. Guidance to Downstream User to evaluate whether he works inside the
boundaries set by the Exposure Scenario
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus,
scaling may be necessary to define appropriate site-specific risk management measures.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 49 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
1. Short title of Exposure Scenario: Use in fuels, Professional use
Main User Groups
Sectors of end-use
Process categories
Environmental Release Categories
: SU 22: Professional uses: Public domain (administration,
education, entertainment, services, craftsmen)
: SU 22: Public domain (administration, education,
entertainment, services, craftsmen)
: PROC1: Use in closed process, no likelihood of exposure
PROC2: Use in closed, continuous process with occasional
controlled exposure
PROC3: Use in closed batch process (synthesis or
formulation)
PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises
PROC8a: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at nondedicated facilities
PROC8b: Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated
facilities
PROC16: Using material as fuel sources, limited exposure to
unburned product to be expected
: ERC9a, ERC9b: Wide dispersive indoor use of substances in
closed systems, Wide dispersive outdoor use of substances in
closed systems
2.1 Contributing scenario controlling environmental exposure for: ERC9a, ERC9b:
Wide dispersive indoor use of substances in closed systems, Wide dispersive
outdoor use of substances in closed systems
Amount used
Annual amount per site
Daily amount per site
Daily amount per site (Msafe)
: 50 t
: 140 kg
: 3.300 kg
Environment factors not influenced by risk management
Dilution Factor (River)
: 10
Dilution Factor (Coastal Areas)
: 100
Other given operational conditions affecting environmental exposure
Continuous use/release
Number of emission days per year
: 365
Emission or Release Factor: Air
: 1%
Emission or Release Factor: Water : 0,001 %
Emission or Release Factor: Soil
: 0,001 %
Remarks
: Risk from environmental exposure is driven by humans via
indirect exposure (primarily inhalation). Negligible air
emissions as process operates in a contained system.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 50 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Technical conditions and measures / Organizational measures
Air
: Treat air emission to provide a typical removal efficiency of
(%): (Effectiveness (of a measure): 0 %)
Water
: Treat onsite wastewater (prior to receiving water discharge) to
provide the required removal efficiency of (%): (Effectiveness
(of a measure): 0 %)
Soil
: Soil emission controls are not applicable as there is no direct
release to soil.
Remarks
: Common practices vary across sites thus conservative
process release estimates used. Prevent discharge of
undissolved substance to or recover from onsite wastewater.
Conditions and measures related to
Type of Sewage Treatment Plant
Flow rate of sewage treatment
plant effluent
Effectiveness (of a measure)
Percentage removed from waste
water
municipal sewage treatment plant
: Municipal sewage treatment plant
: 2.000 m³/d
: 95 %
: 95 %
Conditions and measures related to external treatment of waste for disposal
Remarks
: This substance is consumed during use and no waste of the
substance is generated.
Conditions and measures related to external recovery of waste
Remarks
: This substance is consumed during use and no waste of the
substance is generated.
2.2 Contributing scenario controlling worker exposure for: General measures
(carcinogens), General risk management measures applicable to all activities
PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC16: Use in closed process,
no likelihood of exposure, Use in closed, continuous process with occasional
controlled exposure, Use in closed batch process (synthesis or formulation), Use in
batch and other process (synthesis) where opportunity for exposure arises, Transfer
of substance or preparation (charging/ discharging) from/ to vessels/ large containers
at non-dedicated facilities, Transfer of substance or preparation (charging/
discharging) from/ to vessels/ large containers at dedicated facilities, Using material
as fuel sources, limited exposure to unburned product to be expected
Product characteristics
Concentration of the Substance in
Mixture/Article
Remarks
Frequency and duration of use
Remarks
: Covers the percentage of the substance in the product up to
100 % (unless stated differently).
: Liquid, vapour pressure 0.5 - 10 kPa
: Covers daily exposures up to 8 hours (unless stated
differently).
Other operational conditions affecting workers exposure
Remarks
: Assumes use at not more than 20°C above ambient
temperature. Assumes a good basic standard of occupational
hygiene is implemented.
Technical conditions and measures
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 51 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
Drain or remove substance from equipment prior to break-in or maintenance.
Organisational measures to prevent /limit releases, dispersion and exposure
Consider technical advances and process upgrades (including automation) for the elimination of
releases. Minimise exposure using measures such as closed systems, dedicated facilities and
suitable general / local exhaust ventilation. Clean / flush equipment , where possible, prior to
maintenance. Where there is potential for exposure: Restrict access to authorised persons. Provide
specific activity training to operators to minimise exposures. Wear suitable gloves and coveralls to
prevent skin contamination. Wear respiratory protection when its use is identified for certain
contributing scenarios. Clear up spills immediately and dispose of waste safely. Ensure safe systems
of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and
maintain all control measures. Consider the need for risk based health surveillance.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.
2.3 Contributing scenario controlling worker exposure for: Bulk transfers
PROC4: Use in batch and other process (synthesis) where opportunity for exposure
arises
Technical conditions and measures
Ensure material transfers are under containment or extract ventilation. Provide a good standard of
general or controlled ventilation (5 to 15 air changes per hour). Clear transfer lines prior to decoupling.
2.4 Contributing scenario controlling worker exposure for: Drum/batch transfers
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at dedicated facilities
Technical conditions and measures
Use drum pumps or carefully pour from container. Provide a good standard of general or controlled
ventilation (5 to 15 air changes per hour). Ensure material transfers are under containment or extract
ventilation.
2.5 Contributing scenario controlling worker exposure for: Dipping, immersion and
pouring
PROC8b: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at dedicated facilities
Technical conditions and measures
Use drum pumps or carefully pour from container. Ensure material transfers are under containment
or extract ventilation. Ensure operation is undertaken outdoors. , or:
Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour). Avoid
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 52 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
carrying out activities involving exposure for more than 1 hour.
2.6 Contributing scenario controlling worker exposure for: General exposures (closed
systems)
PROC1: Use in closed process, no likelihood of exposure
Technical conditions and measures
Handle substance within a closed system.
2.7 Contributing scenario controlling worker exposure for: General exposures (closed
systems), With occasional controlled exposure
PROC2: Use in closed, continuous process with occasional controlled exposure
Technical conditions and measures
Handle substance within a predominantly closed system provided with extract ventilation. Provide a
good standard of general or controlled ventilation (5 to 15 air changes per hour).
Organisational measures to prevent /limit releases, dispersion and exposure
Avoid carrying out activities involving exposure for more than 4 hours.
2.8 Contributing scenario controlling worker exposure for: General exposures (open
systems), (closed systems), Batch process
PROC3: Use in closed batch process (synthesis or formulation)
Technical conditions and measures
Handle substance within a predominantly closed system provided with extract ventilation. Provide a
good standard of general or controlled ventilation (5 to 15 air changes per hour).
2.9 Contributing scenario controlling worker exposure for: General exposures (open
systems), (closed systems)
PROC16: Using material as fuel sources, limited exposure to unburned product to be
expected
Technical conditions and measures
Handle substance within a predominantly closed system provided with extract ventilation. Provide a
good standard of general or controlled ventilation (5 to 15 air changes per hour).
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 53 of 55
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Print Date 14.04.2016
2.10 Contributing scenario controlling worker exposure for: Equipment cleaning and
maintenance
PROC8a: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at non-dedicated facilities
Technical conditions and measures
Drain down and flush system prior to equipment opening or maintenance. Provide a good standard
of general or controlled ventilation (5 to 15 air changes per hour).
Organisational measures to prevent /limit releases, dispersion and exposure
Clear spills immediately. Retain drain downs in sealed storage pending disposal or for subsequent
recycle.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear a respirator conforming to EN140 with Type A filter or better.
2.11 Contributing scenario controlling worker exposure for: Vessel and container
cleaning
PROC8a: Transfer of substance or preparation (charging/ discharging) from/ to
vessels/ large containers at non-dedicated facilities
Technical conditions and measures
Drain down system prior to equipment opening or maintenance. Provide a good standard of general
or controlled ventilation (5 to 15 air changes per hour).
Organisational measures to prevent /limit releases, dispersion and exposure
Clear spills immediately. Retain drain downs in sealed storage pending disposal or for subsequent
recycle.
Conditions and measures related to personal protection, hygiene and health evaluation
Wear a respirator conforming to EN140 with Type A filter or better.
2.12 Contributing scenario controlling worker exposure for: Storage
PROC1: Use in closed process, no likelihood of exposure
Technical conditions and measures
Store substance within a closed system.
3. Exposure estimation and reference to its source
Environment
Contributing
Exposure
Specific
Compartment
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 54 of 55
Value
Level of
RCR
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Pyrolysis Gasoline
Version 10.3
Revision Date 17.10.2014
Scenario
Assessment
Method
ERC9a,
ERC9b
Hydrocarbon
Block method,
PETRORISK
conditions
Print Date 14.04.2016
Exposure
Fresh water
0,00002
Marine water
Fresh water
sediment
Marine
sediment
< 0,000001
0,000013
< 0,000001
Workers
Contributing
Scenario
Exposure
Assessment
Method
PROC4
ECETOC TRA
PROC8b
ECETOC TRA
PROC8b
ECETOC TRA
PROC1
ECETOC TRA
PROC2
ECETOC TRA
PROC3
ECETOC TRA
PROC16
ECETOC TRA
PROC8a
ECETOC TRA
PROC8a
ECETOC TRA
PROC1
ECETOC TRA
Specific conditions
Value
Level of
Exposure
RCR
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
Inhalation
Dermal
0,60 ppm
0,69 mg/kg/day
0,60 ppm
0,34 mg/kg/day
0,28 ppm
0,34 mg/kg/day
0,01 ppm
0,34 mg/kg/day
0,72 ppm
0,14 mg/kg/day
0,75 ppm
0,34 mg/kg/day
0,60 ppm
0,34 mg/kg/day
0,30 ppm
0,14 mg/kg/day
0,60 ppm
0,14 mg/kg/day
0,01 ppm
0,34 mg/kg/day
0,60
0,03
0,60
0,01
0,28
0,01
0,01
0,01
0,72
0,01
0,75
0,01
0,60
0,01
0,30
0,01
0,60
0,01
0,01
0,01
4. Guidance to Downstream User to evaluate whether he works inside the
boundaries set by the Exposure Scenario
Guidance is based on assumed operating conditions which may not be applicable to all sites; thus,
scaling may be necessary to define appropriate site-specific risk management measures.
Borealis AG | Wagramer Strasse 17-19 | 1220 Vienna | Austria
Telephone +43 1 224 00 0 | Fax +43 1 22 400 333
FN 269858a | CCC Commercial Court of Vienna | Website www.borealisgroup.com
Page 55 of 55