Fossil Fuels SUSTNABL.com 1 Fossil Fuels Fossil Fuels Index Page Number Title Chapter 1 -What is Fossil Fuel 4 Chapter 2 -How Does Fossil Fuel Formed 9 Chapter 3 -Oil Well 16 Chapter 4 -Types of well 28 Chapter 5 -Limits and alternatives of Fossil Fuels 34 Chapter 6 -Advantage and Disadvantage of Fossil Fuels 40 Chapter 7 -Which Countries Produce The Most Fossil Fuels 42 56 References SUSTNABL.com 3 Fossil Fuels Chapter 1 – what is Fossil Fuel? Fossil fuels, including coal, oil and natural gas, are currently the world’s primary energy source. Formed from organic material over the course of millions of years, fossil fuels have fueled U.S. and global economic development over the past century. Yet fossil fuels are finite resources and they can also irreparably harm the environment. According to the Environmental Protection Agency, the burning of fossil fuels was responsible for 79 percent of U.S. greenhouse gas emissions in 2010. These gases insulate the planet, and could lead to potentially catastrophic changes in the earth’s climate. Technologies such as Carbon Capture and Storage (CCS) may help reduce the greenhouse gas emissions generated by fossil fuels, and nuclear energy can be a zero-carbon alternative for electricity generation. But other, more sustainable solutions exist: energy efficiency and renewable energy. Oil Oil is the world’s primary fuel source for transportation. Most oil is pumped out of underground reservoirs, but it can also be found imbedded in shale and tar sands. Once extracted, crude oil is processed in oil refineries to create fuel oil, gasoline, liquefied petroleum gas, and other nonfuel products such as pesticides, fertilizers, pharmaceuticals, and plastics. SUSTNABL.com 4 Fossil Fuels The United States leads the world in petroleum consumption at 19.05 million barrels per day as of 2014. Net petroleum imports for the U.S. were 4.5 million barrels per day. Top exporters to the United States include Canada, Mexico, Saudi Arabia, Venezuela, and Nigeria. Oil poses major environmental problems, and the world’s heavy reliance on it for transportation makes it difficult to reduce consumption. Besides the environmental degradation caused by oil spills and extraction, combustion of oil releases fine particulates which can lead to serious respiratory problems, and is a major source of greenhouse gas emissions. Indeed, petroleum is responsible for 42 percent of greenhouse gas emissions in the United States. Heavier crude oils, especially those extracted from tar sands and shale, require the use of energy intensive methods that result in more emissions and environmental degradation compared to conventional oil. As conventional oil from underground reservoirs runs out, more oil producers are turning to unconventional sources such as tar sands and oil shale. Coal Coal is primarily used to generate electricity and is responsible for 39 percent of the electric power supply in the United States in 2014 (down from half in 2007). The United States produces around 11.5 percent of the world’s total with Wyoming, West Virginia, Kentucky, Pennsylvania, and Texas leading in SUSTNABL.com 5 Fossil Fuels production. China is the global leader in coal production, responsible for 45 percent of world supply. The combustion of coal releases air pollutants such as acid rain-inducing sulfur dioxide, nitrogen oxides (NOx), and mercury. The mining process can also be very damaging to the environment, often resulting in the destruction of vegetation and top-soil. Rivers and streams can also be destroyed or contaminated by mine wastes. The combustion of coal is responsible for 32 percent of the greenhouse gas emissions in the United States. The premise of “clean coal” has recently been promoted as a way to use this abundant energy source without damaging the environment. Carbon capture and storage (CCS), where carbon is separated from coal and injected underground for long term storage, could theoretically be used to mitigate the coal industry’s greenhouse gas emissions. However, CCS has yet to be proven as a safe or realistic way to reduce greenhouse gas emissions from commercial power plants and the environmental and health costs of mining remain. Natural Gas Natural gas comprised 27 percent of U.S. energy use in 2014 and is most commonly used to produce heat or electricity for buildings or industrial processes. Less than two percent SUSTNABL.com 6 Fossil Fuels of U.S. natural gas is used as a transportation fuel, typically for bus fleets. Natural gas is also used to produce fertilizer, paints, and plastics. The United States produces around 19.8 percent of the world’s natural gas and consumes about21.5 percent. Natural gas is most commonly transported by pipeline, which makes Canada the key exporter to the United States, while Russia remains the main supplier for much of Europe. Increasingly, however, natural gas is being transported by ship in a liquefied form (LNG) to meet greater global demand for the fuel. Natural gas burns cleaner than coal and oil, with almost zero sulfur dioxide emissions and far fewer nitrogen oxide and particulate emissions. Natural gas releases almost 30 percent less carbon dioxide than oil and 43 percent less than coal. However, natural gas is still responsible for 27 percent of greenhouse gas emissions in the United States. Natural gas, which is primarily composed of methane (CH4), is also generated by the decomposition of municipal waste in landfills and manure from livestock production. Methane is a greenhouse gas that is more than 20 times as potent as carbon dioxide. Capturing and burning the gas to produce usable heat and power prevents the methane from being released from the landfill or feedlot into the atmosphere directly. Fossil Fuel Alternatives: Energy Efficiency and Renewable SUSTNABL.com 7 Fossil Fuels Energyز. Despite current U.S. dependence on fossil fuels, several options exist to begin the necessary transition away from a harmful fossil fuel economy. Improving the energy efficiency of buildings, vehicles, industrial processes, appliances and equipment is the most immediate and cost effective way to reduce energy use. Planning communities where people can safely and conveniently use public transit, walk, or bike, instead of using private vehicles, also reduces energy demand. Finally, there are several alternative resources that can supply clean, renewable energy to replace fossil fuels, including water, biomass, wind, geothermal, and solar. SUSTNABL.com 8 Fossil Fuels Chapter 2 – How Does Fossil Fuel Formed Fossil fuels are fuels formed by natural processes such as anaerobic decomposition of buried dead organisms. The age of the organisms and their resulting fossil fuels is typically millions of years, and sometimes exceeds 650 million years. Fossil fuels contain high percentages of carbon and include petroleum, coal, and natural gas. Other commonly used derivatives include kerosene and propane. Fossil fuels range from volatile materials with low carbon: hydrogen ratios like methane, to liquids like petroleum, to nonvolatile materials composed of almost pure carbon, like anthracite coal. Methane can be found in hydrocarbon fields either alone, associated with oil, or in the form of methane clathrates. The theory that fossil fuels formed from the fossilized remains of dead plants by exposure to heat and pressure in the Earth’s crust over millions of years was first introduced by Georgius Agricola in 1556 and later by Mikhail Lomonosov in the 18th century. The Energy Information Administration estimates that in 2007 the primary sources of energy consisted of petroleum 36.0%, coal 27.4%, and natural gas 23.0%, amounting to an 86.4% share for fossil fuels in primary energy consumption in the world. Non-fossil sources in 2006 included nuclear 8.5%, hydroelectric 6.3%, and others (geothermal, solar, tidal, wind, SUSTNABL.com 9 Fossil Fuels wood, waste) amounting to 0.9%. World energy consumption was growing about 2.3% per year. Although fossil fuels are continually being formed via natural processes, they are generally considered to be non-renewable resources because they take millions of years to form and the known viable reserves are being depleted much faster than new ones are being made. The use of fossil fuels raises serious environmental concerns. The burning of fossil fuels produces around 21.3 billion tonnes (21.3gigatonnes) of carbon dioxide (CO2) per year, but it is estimated that natural processes can only absorb about half of that amount, so there is a net increase of 10.65 billion tonnes of atmospheric carbon dioxide per year (one tonne of atmospheric carbon is equivalent to 44/12 or 3.7 tonnes of carbon dioxide). Carbon dioxide is one of the greenhouse gases that enhances radiative forcing and contributes to global warming, causing the average surface temperature of the Earth to rise in response, which the vast majority of climate scientists agree will cause major adverse effects. A global movement towards the generation of renewable energy is therefore under way to help reduce global greenhouse gas emissions. SUSTNABL.com 10 Fossil Fuels Origin Since oil fields are located only at certain places on earth only a select group of countries are oil-independent; the other countries depend on the oil-production capacities of these countrieزs. Petroleum and natural gas are formed by the anaerobic decomposition of remains of organisms including phytoplankton and zooplankton that settled to the sea (or lake) bottom in large quantities under anoxic conditions, millions of years ago. Over geological time, this organic matter, mixed with mud, got buried under heavy layers of sediment. The resulting high levels of heat and pressure caused the organic matter to chemically alter, first into a waxy material known as kerogen which is found in oil shales, and then with more heat into liquid and gaseous hydrocarbons in a process known as catagenesis. There is a wide range of organic, or hydrocarbon, com- SUSTNABL.com 11 Fossil Fuels pounds in any given fuel mixture. The specific mixture of hydrocarbons gives a fuel its characteristic properties, such as boiling point, melting point, density, viscosity, etc. Some fuels like natural gas, for instance, contain only very low boiling, gaseous components. Others such as gasoline or diesel contain much higher boiling components. Terrestrial plants, on the other hand, tend to form coal and methane. Many of the coal fields date to the Carboniferous period of Earth’s history. Terrestrial plants also form type III kerogen, a source of natural gas. Importance A petrochemical refinery inGrangemouth, Scotland, UK Fossil fuels are of great importance because they can be burned (oxidized to carbon dioxide and water), producing SUSTNABL.com 12 Fossil Fuels significant amounts of energy per unit weight. The use of coal as a fuel predates recorded history. Coal was used to run furnaces for the melting of metal ore. Semi-solid hydrocarbons from seeps were also burned in ancient times, but these materials were mostly used for waterproofing and embalming. Commercial exploitation of petroleum, largely as a replacement for oils from animal sources (notably whale oil), for use in oil lamps began in the 19th century. Natural gas, once flared-off as an unneeded byproduct of petroleum production, is now considered a very valuable resource.[14] Natural gas deposits are also the main source of the element helium. Heavy crude oil, which is much more viscous than conventional crude oil, and tar sands, where bitumen is found mixed with sand and clay, are becoming more important as sources of fossil fuel.[15] Oil shale and similar materials are sedimentary rocks containing kerogen, a complex mixture of high-molecular weight organic compounds, which yield synthetic crude oil when heated (pyrolyzed). These materials have yet to be exploited commercially.[16] These fuels can be employed in internal combustion engines, fossil fuel power stations and other uses. Prior to the latter half of the 18th century, windmills and SUSTNABL.com 13 Fossil Fuels watermills provided the energy needed for industry such as milling flour, sawing wood or pumping water, and burning wood or peat provided domestic heat. The wide scale use of fossil fuels, coal at first and petroleum later, to fire steam engines enabled the Industrial Revolution. At the same time, gas lights using natural gas or coal gas were coming into wide use. The invention of the internal combustion engine and its use in automobiles and trucks greatly increased the demand for gasoline and diesel oil, both made from fossil fuels. Other forms of transportation, railways and aircraft, also required fossil fuels. The other major use for fossil fuels is in generating electricity and as feedstock for the petrochemical industry. Tar, a leftover of petroleum extraction, is used in construction of roads. Reserves An oil well in the Gulf of Mexico SUSTNABL.com 14 Fossil Fuels Levels of primary energy sources are the reserves in the ground. Flows are production of fossil fuels from these reserves. The most important part of primary energy sources are the carbon based fossil energy sources. Coal, oil, and natural gas provided 79.6% of primary energy production during 2002 (in million tonnes of oil equivalent (mtoe)) (34.9+23.5+21.2). Levels (proved reserves) during 2005–2006 • Coal: 997,748 million short tonnes (905 billion metric tonnes),[17] 4,416 billion barrels (702.1 km3) of oil equivalent • Oil: 1,119 billion barrels (177.9 km3) to 1,317 billion barrels (209.4 km3) • Natural gas: 6,183–6,381 trillion cubic feet (175–181 trillion cubic meters), 1,161 billion barrels (184.6×109 m3) of oil equivalent Flows (daily production) during 2006 • Coal: 18,476,127 short tonnes (16,761,260 metric tonnes), 52,000,000 barrels (8,300,000 m3) of oil equivalent per day • Oil: 84,000,000 barrels per day (13,400,000 m3/d) • Natural gas: 104,435 billion cubic feet (2,963 billion cubic metres), 19,000,000 barrels (3,000,000 m3) of oil equivalent per day SUSTNABL.com 15 Fossil Fuels Chapter 3 – Oil Well An oil well is a boring in the Earth that is designed to bring petroleum oil hydrocarbons to the surface. Usually some natural gas is produced along with the oil. A well that is designed to produce mainly or only gas may be termed a gas well. History Bottom Part of an Oil Drilling Derrick in Brazoria County, Texas (Harry Walker Photograph, circa 1940) The earliest known oil wells were drilled in China in 347 CE. These wells had depths of up to about 240 metres (790 ft.) and were drilled using bits attached to bamboo poles. The oil was burned to evaporate brine and produce salt. By the 10th century, extensive bamboo pipelines connected oil wells with salt springs. The ancient records of China and Japan are said SUSTNABL.com 16 Fossil Fuels to contain many allusions to the use of natural gas for lighting and heating. Petroleum was known as burning water in Japan in the 7th century. According to Kasem Ajram, petroleum was distilled by the Persian alchemist Muhammad ibn Zakarīya Rāzi (Rhazes) in the 9th century, producing chemicals such as kerosene in the alembic (al-ambiq), and which was mainly used for kerosene lamps. Arab and Persian chemists also distilled crude oil in order to produce flammable products for military purposes. Through Islamic Spain, distillation became available in Western Europe by the 12th century.[2] Some sources claim that from the 9th century, oil fields were exploited in the area around modern Baku, Azerbaijan, to produce naphtha for the petroleum industry. These fields were described by Marco Polo in the 13th century, who described the output of those oil wells as hundreds of shiploads. When Marco Polo in 1264 visited the Azerbaijani city of Baku, on the shores of the Caspian Sea, he saw oil being collected from seeps. He wrote that “on the confines toward Geirgine there is a fountain from which oil springs in great abundance, in as much as a hundred shiploads might be taken from it at one time.” SUSTNABL.com 17 Fossil Fuels 1904 oil well fire at Bibi-Eibat In North America, the first commercial oil well entered operation in Oil Springs, Ontario in 1858, while the first offshore oil well was drilled in 1896 at the Summerland Oil Field on the California Coast. The earliest oil wells in modern times were drilled percussively, by repeatedly raising and dropping a cable tool into the earth. In the 20th century, cable tools were largely replaced with rotary drilling, which could drill boreholes too much greater depths and in less time. The record-depth Kola Borehole used non-rotary mud motor drilling to achieve a depth of over 12,000 metres (39,000 ft.). Until the 1970s, most oil wells were vertical, although lithological and mechanical imperfections because most wells to deviate at least slightly from true vertical. However, modern SUSTNABL.com 18 Fossil Fuels directional drilling technologies allow for strongly deviated wells which can, given sufficient depth and with the proper tools, actually become horizontal. This is of great value as the reservoir rocks which contain hydrocarbons are usually horizontal, or sub-horizontal; a horizontal wellbore placed in a production zone has more surface area in the production zone than a vertical well, resulting in a higher production rate. The use of deviated and horizontal drilling has also made it possible to reach reservoirs several kilometers or miles away from the drilling location (extended reach drilling), allowing for the production of hydrocarbons located below locations that are either difficult to place a drilling rig on, environmentally sensitive, or populated. Life of a well A schematic of a typical oil well being produced by a pump jack, which is used to produce the remaining recoverable oil SUSTNABL.com 19 Fossil Fuels after natural pressure is no longer sufficient to raise oil to the surface. The creation and life of a well can be divided up into five segments: •Planning •Drilling •Completion •Production •Abandonment Drilling The well is created by drilling a hole 12 cm to 1 meter (5 in to 40 in) in diameter into the earth with a drilling rig that rotates a string with a bit attached. After the hole is drilled, sections of steel pipe (casing), slightly smaller in diameter than the borehole, are placed in the hole. Cement may be placed between the outside of the casing and the borehole known as the annulus. The casing provides structural integrity to the newly drilled wellbore, in addition to isolating potentially dangerous high pressure zones from each other and from the surface. With these zones safely isolated and the formation protected by the casing, the well can be drilled deeper (into potentially more-unstable and violent formations) with a smaller SUSTNABL.com 20 Fossil Fuels bit, and also cased with a smaller size casing. Modern wells often have two to five sets of subsequently smaller hole sizes drilled inside one another, each cemented with casing. To drill the well Well Casing • The drill bit, aided by the weight of thick walled pipes called “drill collars” above it, cuts into the rock. There are different types of drill bit; some cause the rock to disintegrate by compressive failure, while others shear slices off the rock as the bit turns. • Drilling fluid, a.k.a. “mud”, is pumped down the inside of the drill pipe and exits at the drill bit. The principal components of drilling fluid are usually water and clay, but it also typically contains a complex mixture of fluids, solids and chemicals that must be carefully tailored to provide the correct physical and chemical characteristics required to safely drill the well. SUSTNABL.com 21 Fossil Fuels Particular functions of the drilling mud include cooling the bit, lifting rock cuttings to the surface, preventing destabilization of the rock in the wellbore walls and overcoming the pressure of fluids inside the rock so that these fluids do not enter the wellbore. Some oil wells are drilled with air or foam as the drilling fluid. Mud log in process, a common way to study the lithology when drilling oil wells • The generated rock “cuttings” are swept up by the drilling fluid as it circulates back to surface outside the drill pipe. The fluid then goes through “shakers” which strain the cuttings from the good fluid which is returned to the pit. Watching for abnormalities in the returning cuttings and monitoring pit volume or rate of returning fluid are imperative to catch “kicks” early. A “kick” is when the formation pressure at the depth of the bit is more than the hydrostatic head of the mud above, which if not controlled temporarily by closing the blowout SUSTNABL.com 22 Fossil Fuels and ultimately by increasing the density of the drilling fluid would allow formation fluids and mud to come up through the annulus uncontrollably. • The pipe or drill string to which the bit is attached is gradually lengthened as the well gets deeper by screwing in additional 9 m (30 ft.) sections or “joints” of pipe under the Kelly or top drive at the surface. This process is called making a connection, or “tripping”. Joints can be combined for more efficient tripping when pulling out of the hole by creating stands of multiple joints. A conventional triple, for example, would pull pipe out of the hole three joints at a time and stack them in the derrick. Many modern rigs, called “super singles”, trip pipe one at a time, laying it out on racks as they go. This process is all facilitated by a drilling rig which contains all necessary equipment to circulate the drilling fluid, hoist and turn the pipe, control down hole, remove cuttings from the drilling fluid, and generate on-site power for these operations. Completion SUSTNABL.com 23 Fossil Fuels Modern drilling rig in Argentina After drilling and casing the well, it must be ‘completed’. Completion is the process in which the well is enabled to produce oil or gas. In a cased-hole completion, small holes called perforations are made in the portion of the casing which passed through the production zone, to provide a path for the oil to flow from the surrounding rock into the production tubing. In open hole completion, often ‘sand screens’ or a ‘gravel pack’ is installed in the last drilled, uncased reservoir section. These maintain structural integrity of the wellbore in the absence of casing, while still allowing flow from the reservoir into the wellbore. Screens also control the migration of formation sands into production tubulars and surface equipment, which can cause washouts and other problems, particularly from unconsolidated sand formations of offshore fields. After a flow path is made, acids and fracturing fluids may be pumped into the well to fracture, clean, or otherwise prepare and stimulate the reservoir rock to optimally produce hydrocarbons into the wellbore. Finally, the area above the reservoir section of the well is packed off inside the casing, and connected to the surface via a smaller diameter pipe called tubing. This arrangement provides a redundant barrier to leaks of hydrocarbons as well as allowing damaged sec- SUSTNABL.com 24 Fossil Fuels tions to be replaced. Also, the smaller cross-sectional area of the tubing produces reservoir fluids at an increased velocity in order to minimize liquid fallback that would create additional back pressure, and shields the casing from corrosive well fluids. In many wells, the natural pressure of the subsurface reservoir is high enough for the oil or gas to flow to the surface. However, this is not always the case, especially in depleted fields where the pressures have been lowered by other producing wells, or in low permeability oil reservoirs. Installing a smaller diameter tubing may be enough to help the production, but artificial lift methods may also be needed. Common solutions include down hole pumps, gas lift, or surface pump jacks. Many new systems in the last ten years have been introduced for well completion. Multiple packer systems with frac ports or port collars in an all in one system have cut completion costs and improved production, especially in the case of horizontal wells. These new systems allow casings to run into the lateral zone with proper packer/frac port placement for optimal hydrocarbon recovery. Production The production stage is the most important stage of a well’s life; when the oil and gas are produced. By this time, the oil rigs and work over rigs used to drill and complete the well SUSTNABL.com 25 Fossil Fuels have moved off the wellbore, and the top is usually outfitted with a collection of valves called a Christmas tree or production tree. These valves regulate pressures, control flows, and allow access to the wellbore in case further completion work is needed. From the outlet valve of the production tree, the flow can be connected to a distribution network of pipelines and tanks to supply the product to refineries, natural gas compressor stations, or oil export terminals. As long as the pressure in the reservoir remains high enough, the production tree is all that is required to produce the well. If the pressure depletes and it is considered economically viable, an artificial lift method mentioned in the completions section can be employed. Workovers are often necessary in older wells, which may need smaller diameter tubing, scale or paraffin removal, acid matrix jobs, or completing new zones of interest in a shallower reservoir. Such remedial work can be performed using workover rigs – also known as pulling units, completion rigs or “service rigs” – to pull and replace tubing, or by the use of well intervention techniques utilizing coiled tubing. Depending on the type of lift system and wellhead a rod rig or flushby can be used to change a pump without pulling the tubing. Enhanced recovery methods such as water flooding, steam flooding, or CO2 flooding may be used to increase reservoir pressure and provide a “sweep” effect to push hydrocarbons SUSTNABL.com 26 Fossil Fuels out of the reservoir. Such methods require the use of injection wells (often chosen from old production wells in a carefully determined pattern), and are used when facing problems with reservoir pressure depletion, high oil viscosity, or can even be employed early in a field’s life. In certain cases – depending on the reservoir’s geomechanics – reservoir engineers may determine that ultimate recoverable oil may be increased by applying a water flooding strategy early in the field’s development rather than later. Such enhanced recovery techniques are often called “tertiary recovery”. SUSTNABL.com 27 Fossil Fuels Chapter 4 - Types of well A natural gas well in the southeast Lost, California, US. Fossil-fuel wells come in many varieties. By produced fluid, there can be wells that produce oil, wells that produce oil and natural gas, or wells that only produce natural gas. Natural gas is almost always a byproduct of producing oil, since the small, light gas carbon chains come out of solution as they undergo pressure reduction from the reservoir to the surface, similar to uncapping a bottle of soda pop where the carbon dioxide effervesces. Unwanted natural gas can be a disposal problem at the well site. If there is not a market for natural gas near the wellhead it is virtually valueless since it must be piped to the end user. Until recently, such unwanted gas was burned off at the well site, but due to environmental concerns this practice is becoming less common. Often, unwanted (or ‘stranded’ gas without a market) gas is pumped SUSTNABL.com 28 Fossil Fuels back into the reservoir with an ‘injection’ well for disposal or repressurizing the producing formation. Another solution is to export the natural gas as a liquid. Gas to liquid, (GTL) is a developing technology that converts stranded natural gas into synthetic gasoline, diesel or jet fuel through the Fischer-Tropsch process developed in World War II Germany. Such fuels can be transported through conventional pipelines and tankers to users. Proponents claim GTL fuels burn cleaner than comparable petroleum fuels. Most major international oil companies are in advanced development stages of GTL production, e.g. the 140,000 bbl/d (22,000 m3/d) Pearl GTL plant in Qatar, scheduled to come online in 2011. In locations such as the United States with a high natural gas demand, pipelines are constructed to take the gas from the wellsite to the end consumer. Raising the derrick Another obvious way to classify oil wells is by land or off- SUSTNABL.com 29 Fossil Fuels shore wells. There is very little difference in the well itself. An offshore well targets a reservoir that happens to be underneath an ocean. Due to logistics, drilling an offshore well is far more costly than an onshore well. By far the most common type is the onshore well. These wells dot the Southern and Central Great Plains, Southwestern United States, and are the most common wells in the Middle East. Another way to classify oil wells is by their purpose in contributing to the development of a resource. They can be characterized as: • Wildcat wells are drilled where little or no known geological information is available. The site may have been selected because of wells drilled some distance from the proposed location but on a terrain that appeared similar to the proposed site. • Exploration wells are drilled purely for exploratory (information gathering) purposes in a new area, the site selection is usually based on seismic data, satellite surveys etc. Details gathered in this well includes the presence of Hydrocarbon in the drilled location, the amount of fluid present and the depth at which oil or/and gas occurs. • Appraisal wells are used to assess characteristics (such as flow rate, reserve quantity) of a proven hydrocarbon accumulation. The purpose of this well is to reduce uncertainty about the characteristics and properties of the hydrocarbon present in the field. SUSTNABL.com 30 Fossil Fuels • Production wells are drilled primarily for producing oil or gas, once the producing structure and characteristics are determined. • Development wells are wells drilled for the production of oil or gas already proven by appraisal drilling to be suitable for exploitation. • Abandoned well are wells permanently plugged in the drilling phase for technical reasons? Oil extraction in Boryslav in 1909 At a producing well site, active wells may be further categorized as: • Oil producers producing predominantly liquid hydrocarbons, but mostly with some associated gas. • Gas producers producing almost entirely gaseous hydrocarbons. • water injectors injecting water into the formation to maintain reservoir pressure, or simply to dispose of water pro- SUSTNABL.com 31 Fossil Fuels duced with the hydrocarbons because even after treatment, it would be too oily and too saline to be considered clean for dumping overboard offshore, let alone into a fresh water resource in the case of onshore wells. Water injection into the producing zone frequently has an element of reservoir management; however, often produced water disposal is into shallower zones safely beneath any fresh water zones. • Aquifer producers intentionally producing water for re-injection to manage pressure. If possible this water will come from the reservoir itself. Using aquifer produced water rather than water from other sources is to preclude chemical incompatibility that might lead to reservoir-plugging precipitates. These wells will generally be needed only if produced water from the oil or gas producers is insufficient for reservoir management purposes. • Gas injectors injecting gas into the reservoir often as a means of disposal or sequestering for later production, but also to maintain reservoir pressure. Lahee classification • New Field Wildcat (NFW) – far from other producing fields and on a structure that has not previously produced. • New Pool Wildcat (NPW) – new pools on already producing structure. • Deeper Pool Test (DPT) – on already producing structure and pool, but on a deeper pay zone. • Shallower Pool Test (SPT) – on already producing structure and pool, but on a shallower pay zone. SUSTNABL.com 32 Fossil Fuels • Outpost (OUT) – usually two or more locations from nearest productive area. • Development Well (DEV) – can be on the extension of a pay zone, or between existing wells (Infill). SUSTNABL.com 33 Fossil Fuels Chapter 5 - Limits and alternatives of Fossil Fuels P. E. Hodgson, a Senior Research Fellow Emeritus in Physics at Corpus Christi College, Oxford, expects the world energy use is doubling every fourteen years and the need is increasing faster still and he insisted in 2008 that the world oil production, a main resource of fossil fuel, is expected to peak in ten years and thereafter fall. The principle of supply and demand holds that as hydrocarbon supplies diminish, prices will rise. Therefore, higher prices will lead to increased alternative, energy supplies as previously uneconomic sources become sufficiently economical to exploit. Artificial gasoline and other renewable energy sources currently require more expensive production and processing technologies than conventional petroleum reserves, but may become economically viable in the near future. Different alternative sources of energy include nuclear, hydroelectric, solar, wind, and geothermal. One of the more promising energy alternatives is the use of inedible feed stocks and biomass for carbon dioxide capture as well as biofuel. While these processes are not without problems, they are currently in practice around the world. Biodiesels are being produced by several companies and source of great research at several universities. Some of the SUSTNABL.com 34 Fossil Fuels most common and promising processes of conversion of renewable lipids in to usable fuels is through hydro treating and decarboxylation. Environmental effects Global fossil carbon emission by fuel type, 1800–2007. Note: Carbon only represents 27% of the mass of CO2 The U.S. holds less than 5% of the world’s population, but due to large houses and private cars, uses more than a quarter of the world’s supply of fossil fuels. In the United States, more than 90% of greenhouse gas emissions come from the combustion of fossil fuels. Combustion of fossil fuels also produces other air pollutants, such as nitrogen oxides, sulfur dioxide, volatile organic compounds and heavy metals. According to Environment Canada: “The electricity sector is unique among industrial sectors in SUSTNABL.com 35 Fossil Fuels its very large contribution to emissions associated with nearly all air issues. Electricity generation produces a large share of Canadian nitrogen oxides and sulphur dioxide emissions, which contribute to smog and acid rain and the formation of fine particulate matter. It is the largest uncontrolled industrial source of mercury emissions in Canada. Fossil fuel-fired electric power plants also emit carbon dioxide, which may contribute to climate change. In addition, the sector has significant impacts on water and habitat and species. In particular, hydro dams and transmission lines have significant effects on water and biodiversity.”[25] Carbon dioxide variations over the last 400,000 years, showing a rise since the industrial revolution. According to U.S. Scientist Jerry Mahlman and USA Today: Mahlman, who crafted the IPCC language used to define levels of scientific certainty, says the new report will lay the blame at the feet of fossil fuels with “virtual certainty,” mean- SUSTNABL.com 36 Fossil Fuels ing 99% sure. That’s a significant jump from “likely,” or 66% sure, in the group’s last report in 2001, Mahlman says. His role in this year’s effort involved spending two months reviewing the more than 1,600 pages of research that went into the new assessment. Combustion of fossil fuels generates sulfuric, carbonic, and nitric acids, which fall to Earth as acid rain, impacting both natural areas and the built environment. Monuments and sculptures made from marble and limestone are particularly vulnerable, as the acids dissolve calcium carbonate. Fossil fuels also contain radioactive materials, mainly uranium and thorium, which are released into the atmosphere. In 2000, about 12,000 tonnes of thorium and 5,000 tonnes of uranium were released worldwide from burning coal. It is estimated that during 1982, US coal burning released 155 times as much radioactivity into the atmosphere as the Three. Burning coal also generates large amounts of bottom ash and fly ash. These materials are used in a wide variety of applications, utilizing, for example, about 40% of the US production. Harvesting, processing, and distributing fossil fuels can also create environmental concerns. Coal mining methods, particularly mountaintop removal and strip mining, have neg- SUSTNABL.com 37 Fossil Fuels ative environmental impacts, and offshore oil drilling poses a hazard to aquatic organisms. Oil refineries also have negative environmental impacts, including air and water pollution. Transportation of coal requires the use of diesel-powered locomotives, while crude oil is typically transported by tanker ships, each of which requires the combustion of additional fossil fuels. Environmental regulation uses a variety of approaches to limit these emissions, such as command-and-control (which mandates the amount of pollution or the technology used), economic incentives, or voluntary programs. An example of such regulation in the USA is the “EPA is implementing policies to reduce airborne mercury emissions. Under regulations issued in 2005, coal-fired power plants will need to reduce their emissions by 70 percent by 2018.” In economic terms, pollution from fossil fuels is regarded as a negative externality. Taxation is considered one way to make societal costs explicit, in order to ‘internalize’ the cost of pollution. This aims to make fossil fuels more expensive, thereby reducing their use and the amount of pollution associated with them, along with raising the funds necessary to counteract these factors. According to Rodman D. Griffin, “The burning of coal and oil SUSTNABL.com 38 Fossil Fuels have saved inestimable amounts of time and labor while substantially raising living standards around the world”.Although the use of fossil fuels may seem beneficial to our lives, this act is playing a role on global warming and it is said to be dangerous for the future. Moreover, these environmental pollutions impacts on the human beings because its particles of the fossil fuel on the air cause negative health effects when inhaled by people. These health effects include premature death, acute respiratory illness, aggravated asthma, chronic bronchitis and decreased lung function. So, the poor, undernourished, very young and very old, and people with preexisting respiratory disease and other ill health, are more at risk. SUSTNABL.com 39 Fossil Fuels Chapter 6 – Advantage and Disadvantage of Fossil Fuels Advantages of Fossil Fuels 1. Well Developed The technology we use to harness the energy in fossil fuels is well developed. The main reason for this is that fossil fuels have been used to power our world for many decades. 2. Cheap and Reliable Fossil fuels are cheap and reliable sources of energy. They are excellent types of fuel to use for the energy base-load, as opposed to some of the more unreliable energy sources such as wind and solar. Disadvantages of Fossil Fuels 1. Contribute to Global Warming Fossil fuels are not green sources of energy. In fact, they contain high amounts of carbon and have been blamed for being the main contributor to global warming. 2. Non-Renewable SUSTNABL.com 40 Fossil Fuels Fossil fuels are non-renewable energy sources. This means that there is a finite amount of fossil fuels available and the reserves are not replenished naturally. This is not entirely correct, as fossil fuels are products of millions of years of natural processes such as anaerobic decomposition of organic matter. The thing is, as opposed to renewable energy sources such as wind and solar, it takes millions of years before the formation of fossil fuels takes place in any noteworthy quantities. 3. Unsustainable We are spending our fossil fuel reserves in a non-sustainable manner. Luckily, this forces us to think different when it comes to energy, which results in the growth of renewable and green sources of energy. 4. Incentivized One of the major reasons why fossil fuels are as cheap is a history of government incentives. Coal, natural gas and petroleum received $4.22 billion most in direct subsidies – solar got $1.13 billion. 5. Accidents Happen They are not nearly as serious as accidents related to nuclear power, but on the other hand, fossil fuels will never have the safety of solar and wind. The picture above is from the Deep-water Horizon oil spill in the Gulf of Mexico. SUSTNABL.com 41 Fossil Fuels Chapter 7 -Which Countries Produce the Most Fossil Fuels? Which country takes the most fossil fuels out of the ground? The answer to this question is relatively predictable: China. Today China is the world’s biggest consumer of energy and the vast majority of that comes from burning coal mined in China itself. Little surprise then that China is number one in terms of taking fossil fuels out of the ground. However, absolute numbers can obscure as much as they can enlighten. 1.3 billion People live in China, but only 30 million live in Saudi Arabia. Yet, if people want to say there is a lot of wind power in Texas, Scotland or anywhere else they inevitably reach for the cliche “The Saudi Arabia of Wind”. What really matters then is both how many fossil fuels a country takes out of the ground in absolute terms, but also SUSTNABL.com 42 Fossil Fuels in per-capita terms. Such numbers can be instructive. If you produce a rather large number of fossil fuels, then you might be not overly enthusiastic about the potential of global climate treaty to limit their use. So, which countries lead the world in extracting fossil fuels from the ground? First things first. There are three types of fossil fuel: oil, coal and natural gas. The first is a liquid, the second a solid and the third a gas. So, how do we measure the total amount of oil, coal and gas each country extracts? Calculating their total weight is one option, but this runs into an obvious problem. If you burn a tonne of oil it will release significantly more energy than if you burn a tonne of coal. However, the heat released when you burn a tonne of coal gets close to something that we can use to reasonably compare the extraction of oil, coal and natural gas. A tonne of oil releases approximately 42 gigajoules (GJ) of energy. This lets us define a “tonne of oil equivalent” (toe) measure. In other words one toe of coal or natural gas is the amount of coal or natural gas that will release the equivalent energy of one tonne of oil (42 GJ). This comparison has drawbacks, as does any metric. Many things can be done with oil, coal or natural gas. However, for a variety of reasons, engineering and economic, we do not do everything with all fuels. You cannot fly a Boeing 747 with SUSTNABL.com 43 Fossil Fuels coal or natural gas. Similarly, oil is almost never used for the production of electricity or steel. So, the economic value of each fuel is largely ignored by this measure. Likewise, it does not directly measure greenhouse gas emissions, which some may deem to be a more important measure of fossil fuel extraction. These caveats made, I will now go through each fossil fuel in turn, before adding it all up, and then finally making a brief comparison of fossil fuel production with fossil fuel consumption. All production and consumption statistics quoted below are annual numbers for 2013. Fossil fuel production and consumption data are taken from BP’s statistical review of world energy, and population data is taken from the excellent Gapminder website. Oil Oil has been the world’s largest source of energy for the last half century. And the top three oil producers are Saudi Arabia, Russia and America, between them producing around 38% of the world’s oil. In total, the world’s 15 largest oil producing nations (shown below) produce 80% of the world’s oil. SUSTNABL.com 44 Fossil Fuels On a per-capita basis things are somewhat different. America and Russia, the number two and three nations in terms of total production, drop out of the top 15. At the top is Kuwait, which produces just over 50 tonnes of oil per-person each year. This is approximately twenty times higher than annual per-capita oil consumption in America, and in excess of one hundred times annual per-capita oil consumption China. The only developed nations in the top 15 are Norway and Canada, and unsurprisingly the list is dominated by Middle Eastern countries. God, if he exists, appears to have placed most of the oil in just the wrong spot. SUSTNABL.com 45 Fossil Fuels Coal Global coal production and consumption is now dominated by China, which produces and consumes approximately half of the world’s coal. And China dominates growth in coal as well, with its production doubling in the last decade and making up 70% of the global increase in coal production over that period. In addition, other major sources of coal production growth such as Australia and Indonesia are major exporters to China. So, globally if you are thinking about coal you should really be thinking about China. SUSTNABL.com 46 Fossil Fuels However, China’s per-capita coal production is much more mediocre than the above graph implies. After all, there are over 1.3 billion people living China. In per-capita terms China produces less coal than America, a reminder that China hass a long way to go before catching up with America. And Australia’s coal production per-person is perhaps most startling. Astonishingly it produces almost eight times more coal per-person than China, and produces three times more than any other country. SUSTNABL.com 47 Fossil Fuels Natural Gas America and Russia are by far the world’s two largest producers of natural gas, accounting for almost 39% of the world’s annual output. The world’s top 15 countries produce 78% of the world’s natural gas, a similar percentage to that seen with oil. Qatar is the world’s fourth biggest producer of natural gas, yet its population is only 2 million. A country with 0.03% of the world’s population therefore produces 5.4% of the world’s SUSTNABL.com 48 Fossil Fuels natural gas. And it is therefore by a long way the world’s biggest producers of natural gas on a per-capita basis. Norway is similarly impressive, producing five times more natural gas on a per-capita basis than any other developed country, and ranking fourth globally. Densely populated Holland also has notably high natural gas production, a result of production from the vast Groningen gas field, which was discovered in the 1950s. The history of natural gas production in Holland may be instructive for how things will play out with shale gas in similarly densely populated Britain. SUSTNABL.com 49 Fossil Fuels Total Fossil Fuel Production Unsurprisingly, the three largest producers of fossil fuels are China, America and Russia, with Saudi Arabia being the fourth largest producer of fossil fuels over all. And fossil fuel production is a largely non-European affair – only Norway appears in the top 15. In fact, the United Kingdom is the next ranked European country at number 26. The top 15 countries extract 78% of the world’s fossil fuels, and only four of the top 15 are developed countries. SUSTNABL.com 50 Fossil Fuels Because of its vast natural gas production, Qatar has the world’s largest per-capita fossil fuel production. In total, Qatar’s per-capita fossil fuel production is just under 120 toe. For comparison, typical developed countries consume just over 3 toe in fossil fuels per-capita each year. Middle Eastern Countries dominate the list of the biggest per-capita fossil fuel producers, making up half of the top 15. Again, there is a lack of European countries, with only Norway appearing in the top 20. And despite being the top two countries in absolute fossil fuel production, America (19th) and China (34th) do not rank very high in per-capita terms. SUSTNABL.com 51 Fossil Fuels And what about consumption? Some of the world’s biggest consumers of fossil fuels, such as Japan and South Korea, are missing from all of the above lists. So, I will finish by making a brief comparison between the top 15 countries in terms of fossil fuel production and fossil fuel consumption. The top 3 producers of fossil fuels – China, America and Russian – are also the top 3 consumers of fossil fuels. However, of the world’s 15 biggest consumers of fossil fuels, 6 are not among the 15 biggest producers of fossil fuels. Unsurprisingly, they are almost all developed economies: Japan, Germany, South Korea, Brazil, United Kingdom and Italy. SUSTNABL.com 52 Fossil Fuels Differences in the production and consumption of fossil fuels can perhaps best be illustrated using the ratio between national fossil fuel production and consumption. This is an approximate measure of self-sufficiency. Though, a far from fool-proof one. A country can produce an excess of one fossil fuel, but still be fundamentally dependent on imports for another fossil fuel. An example is Holland, which produces an excess of natural gas, but is highly dependent on imports for coal and oil. Despite its limitations, this measure shows the wide global variation in how self-sufficient countries are. The world’s biggest producers and consumers, China and America, are both very similar. Each country has a production: consumption ratio of just over 0.75, and they are both largely self-sufficient in terms of coal, but import large amounts of oil. SUSTNABL.com 53 Fossil Fuels Almost every developed country consumes more fossil fuels than it exports. In fact, Canada, Australia and Norway are the only developed economies that produce more fossil fuels than they consume. Norway produces 10 times more fossil fuels than it consumes, a ratio that is higher than any other country. This astonishingly high ratio is achieved both by its high per-capita production of fossil fuels, but also by generating almost 100% of its electricity using hydro-electric dams. In contrast, developed economies such as Japan, South Korea and France produce essentially no fossil fuels, and are almost 100% dependent on imports. These differences in production and consumption of fossil fuels will play a significant role in determining how countries treat international climate negotiations. It is no surprise that influential groups in Canada and Australia oppose any serious efforts to limit global carbon emissions. Similarly, China’s relatively high levels of self-dependence are largely reliant on China’s extensive coal reserves. China will not be able to significantly expand its consumption of oil or natural gas without a massive increase in imports or the expansion of fracking in China. These realities are now leading China to consider a huge expansion of plants which will convert coal to synthetic gas and oil, which will inevitably increase carbon emissions. In contrast, American energy policy appears to be based SUSTNABL.com 54 Fossil Fuels around the contradictory goal of reducing the amount of fossil fuels consumed in America, while increasing the amount of of fossil fuels extracted in America. And America is not alone, with Britain similarly considering a massive expansion of shale gas extraction, while reducing consumption of fossil fuels. These complex realities will make the future of national fossil fuel production and consumption difficult to predict. SUSTNABL.com 55 Fossil Fuels Reference http://www.eesi.org/topics/fossil-fuels/description http://energyinformative.org/fossil-fuels-pros-andcons/ http://www.theenergycollective.com/robertwilson190/447121/who-produces-most-fossil-fuels https://en.wikipedia.org/wiki/Fossil_fuel https://en.wikipedia.org/wiki/Oil_well SUSTNABL.com 56
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