Name_____________________________________ Period___ Practice Final 1st Semester 2011-2012 Chemistry 1 USE YOUR SPECIAL SHEET. YOU WILL HAVE ONE ON YOUR FINAL!!!! Use your notes and textbook if that is helpful. Properties of Matter 1. State whether the following are observations or inferences and qualitative or quantitative: a. A block of aluminum weighs 5.2 g b. A block of aluminum has rust on one end c. When exposed to a flame, aluminum heats rapidly 2. State whether the following are physical or chemical changes: • Blue ink from a piece of paper turns water blue • An electric current is passed through copper metal • Sugar dissolves in hot coffee 3. What is the mass of a cube that has a density of 0.9g/ml and a volume of 20ml? 4. State whether the following are homogeneous mixtures, heterogeneous mixtures, compounds or elements • salt water • Hydrogen gas • gold • Water and oil mixed together 5. Explain the difference between an endothermic and exothermic reaction 6. State whether the following are Chemical or Physical properties • Iron can bend when exposes to extreme heat • Pennies corrode when left out in the rain • Alkali metals are highly reactive in the presence of water History 7. What did the Greek model of the atom look like? 8. Draw a picture of Thomson’s and Rutherford’s models. How are they different? 9. Draw a picture showing how “light” helped Bohr understand that Hydrogen atoms have energy levels. Atoms/Atomic Model 10. If chlorine has 2 naturally occurring isotopes, Cl-35 at 75% and Cl-37 at 25%, what is the atomic mass of the element? 11. What is the relationship between the wavelength, frequency, and energy of electromagnetic waves? 12. What is the speed of electromagnetic waves? What is the equation for speed, frequency and wavelength? 13. Draw the Electromagnetic Spectrum of white light from lowest to highest energy 14. Explain why hydrogen emits 3 different colors when subject to electromagnetic radiation. Draw a picture to illustrate this 15. Draw the Bohr model AND Lewis Dot structure for the following element: a. a. F b. Ca 16. Fill in the following Chart: Element/Charge Atomic Number Na 11 Mass Number 23 Al3+ 28 239 94 S 2- # of Protons # of Neutrons # of Electrons 15 16 18 18 17. Why does ionization energy increase as you go from left to right across a period? 18. Why does atomic radius increase as you go from top to bottom of the periodic table? 19. Name 4 properties of Metals and Nonmetals: 20. Do metals normally gain or lose electrons when forming bonds? Why? 21. Name 5 of the “Families”. Give an example of an element in each group and give a reason why is is in that particular family. 22. Name 2 properties of Ionic compounds: 23. Name 2 properties of covalent compounds: 24. Write the following for each ionic compound: Cation Charge Anion Charge Formula Magnesium Bromide Copper (II) Nitrate Aluminum Sulfate 25. Write the names for the following ionic compounds: • Na2SO4 • FeCl2 • Mg3(PO4)2 26. Fill in the appropriate blanks for the following molecular compounds • Dicarbon Tetrachloride ____________________ • Hexane ____________________ • ____________________ N2I2 • ____________________ SiO2 27. Draw the Lewis Dot structure for the following molecular compounds: • State whether it is polar or Nonpolar • Include the shape or bond angle of each compound NH3 CO2 CH3F 28. Complete, balance and state the type of reaction for the following: b. ____ Ca(OH)2 + ____ Al2(SO4)3 ____ CaSO4 + ____ Al(OH)3 Type of reaction: _____________ c. ____ CH4 + ____ O2 ____CO2 + ____H2O Type of reaction: _____________ 29. Write the balanced equation out for the following word equations. Also state the type of reaction: When isopropanol (C3H8O) burns in oxygen, carbon dioxide, water, and heat are produced. When dissolved beryllium chloride reacts with dissolved silver nitrate in water, aqueous beryllium nitrate and silver chloride powder are made. 30. Circle whether the following are acids or bases, and write the chemical equation for the following when dissociated in water HCl - Acid/Base H2SO4 – Acid/Base KOH – Acid/Base 31. Write the chemical equation for the neutralization of KOH with HCl d. Why is it a neutralization Reaction? 32. What is the principle reason why substances like oxygen have a low boiling point, but salt has a very high melting point? 33. Draw a “general” graph of temperature over time, for the heating of solid Lauric Acid before, during, and after its melting point. 34. Give three qualitative properties and one quantitative the property of acids and bases? 35. How do catalysts, temperature increases, and concentration increases allow chemical reactions to occur more quickly? 36. Draw a graph showing how raising the temperature of a sample increases the rate of reaction. Include: Collision Energy, # of particles, and Activation energy. 37. Why does the addition of a catalyst increase the rate of reaction? Practice Final Answers Chemistry 1 USE YOUR SPECIAL SHEET. YOU WILL HAVE ON ON YOUR FINAL!!!! Use your notes and textbook if that is helpful. Properties of Matter 1. State whether the following are observations or inferences and qualitative or quantitative: a. A block of aluminum weighs 5.2 g b. A block of aluminum has rust on one end c. When exposed to a flame, aluminum heats rapidly Quantitative Observation Inference Qualititive Observation Qualitative 2. State whether the following are physical or chemical changes: a. Blue ink from a piece of paper turns water blue b. An electric current is passed through copper metal c. Sugar produces heat and gasses in the presence of sulfuric Acid. Physical Physical Chemical 3. What is the mass of a cube that has a density of 0.9g/ml and a volume of 20ml? Mass = Density x Volume = 0.9 g/mL x 20 mL = 18 grams 4. State whether the following are homogeneous mixtures, heterogeneous mixtures, compounds or elements a. salt water homogeneous mixture b. Water Vapor Compound c. Gold Element d. Water and oil mixed together Heterogeneous Mixture 5. Explain the difference between an endothermic and exothermic reaction Exothermic = A reaction that releases energy Endothermic = A reaction that absorbs energy 6. State whether the following are Chemical or Physical properties a. b. c. Iron can bend when exposes to extreme heat Pennies corrode when left out in the rain Alkali metals are highly reactive in the presence of water Physical Chemical Chemical History 7. What did the Greek model of the atom look like? Earth Wind Fire Water 8. Draw a picture of Thomson’s and Rutherford’s models. How are they different? 9. Draw a picture showing how “light” helped Bohr understand that Hydrogen atoms have energy levels. Atoms/Atomic Model 10. If chlorine has 2 naturally occurring isotopes, Cl-35 at 75% and Cl-37 at 25%, what is the atomic mass of the element? Atomic Mass = = = (mass of isotope 1)(% abundance isotope 1) + (mass of isotope 2)(% abundance isotope 2) +etc… (35 amu x .75) + (37 amu x .25) 35.5 amu 11. What is the relationship between the wavelength, frequency, and energy of electromagnetic waves? As wavelength ↑ Frequency and Energy ↓ As wavelength ↓ Frequency and Energy ↑ 12. What is the speed of electromagnetic waves? What is the equation for speed, frequency and wavelength? The Speed of light= = c= λν c 3 x 108 m/s 13. Draw the Electromagnetic Spectrum of white light from lowest to highest energy 14. Explain why hydrogen emits 3 different colors when subject to electromagnetic radiation. Draw a picture to illustrate this 15. Draw the Bohr model AND Lewis Dot structure for the following element: a. F b. Ca Will go over in class if needed 16. Fill in the following Chart: Element/Charge Na P3Al3+ Pu S2- Atomic Number 11 15 13 94 16 Mass Number 23 31 28 239 34 # of Protons 11 15 13 94 16 # of Neutrons 12 16 15 145 18 # of Electrons 11 18 10 94 18 17. Why does ionization energy increase as you go from left to right across a period? As you go across the periodic table from left to right the following contributes to the increase in ionization energy: Atomic Numbers increase (meaning the number of protons) and consequently electron numbers increase as well Therefore, there is a greater attraction between the nucleus and the electron cloud because of the increase in electric charge. 18. Why does atomic radius increase as you go from top to bottom of the periodic table? As you go from top to bottom within a family on the periodic table the following contributes to the increase in atomic radius: Each period increase means the increase of an energy level. An electron in the highest energy level is “shielded” from the attraction of the nucleus by the inner electron energy levels. 19. Name 4 properties of Metals: Good conductor of electricity and heat On the left of the PT Typically solid at room temp Shiny, luster, malleable Lose electrons to form positively charged atoms Usually between 1 and 4 valence electrons 20. Do metals normally gain or lose electrons when forming bonds? Why? Metals lose electrons more easily because: They have a large atomic radius They have a low ionization energy It is easier to lose electrons rather than gain in order to have a stable noble gas configuration (rule of 8). 21. Name 5 of the “Families”. Give an example of an element in each group and give a reason why it is in that particular family. Alkali Metal Alkaline Earth Metal Transition Metals Halogens Nobel Gasses 22. Name 2 properties of Ionic compounds: High melting point Typically dissolves in water Conducts electricity when dissolved 23. Name 2 properties of covalent compounds: Any Phase Made of nonmetals Do not conduct electricity. 24. Write the following for each ionic compound: Cation Charge Na Mg Fe Cl Ar Ends in s1 Ends in s2 Ends with d Ends in p5 Ends in p6 (full valence shell) Hard Solids Made of metals and non metals Anion Charge Formula a. Magnesium Bromide Mg 2+ Br- MgBr2 b. Copper (II) Nitrate Cu 2+ NO3- Cu(NO3)2 Al 3+ SO42- Al2(SO4)3 c. Aluminum Sulfate 25. a. b. c. Write the names for the following ionic compounds: Na2SO4 Sodium Sulfate FeCl2 Iron II Chloride Mg3(PO4)2 Magnesium Phosphate 26. Fill in the appropriate blanks for the following molecular compounds a. Dicarbon Tetrachloride C2Cl4 b. Hexane C6H14 c. Dinitrogen diiodide N2I2 d. Silicon Dioxide SiO2 27. Draw the Lewis Dot structure for the following molecular compounds: a. Give the shape and bond angle of each a. NH3 b. Polar 107.3 Trigonal Pyramidal Non-Polar 180 Linear CO2 c. CH3F Polar 109.5 Tetrahedral Will go over in class if needed 28. Complete, balance and state the type of reaction for the following: 3Ca(OH)2 + ____Al2(SO4)3 2Al(OH)3 + 3CaSO4 Type of reaction: Double Displacement ____ CH4 + 2 O2 CO2 + 2H2O Type of reaction: Combustion 29. Write the balanced equation out for the following word equations. Also state the type of reaction: When isopropanol (C3H8O) burns in oxygen, carbon dioxide, water, and heat are produced. 2C3H8O(l) + 9O2(g)+ 6CO2(g) + 8H2O(g) When dissolved beryllium chloride reacts with dissolved silver nitrate in water, aqueous beryllium nitrate and silver chloride powder are made. BeCl2(aq) + 2AgNO3(aq) Be(NO3)2(aq) + 2AgCl(s) 30. Circle whether the following are acids or bases, and write the chemical equation for the following when dissociated in water a. HCl - Acid/Base b. H2SO4 – Acid/Base c. KOH – Acid/Base 31. Write the chemical equation for the neutralization of KOH with HCl HCl(aq) + KOH(aq) H2O(l) + KCl(aq) Why is it a neutralization Reaction? Assuming the acid and base are of equal concentrations and volumes, the acid and base ions become water while the Metal and nonmetal ions become an aqueous salt. 32. What is the principle reason why substances like oxygen have a low boiling point, but salt has a very high melting point? The attraction between the molecules through electrostatic forces (charge) Ionic compounds have a greater attraction of charge, while nonpolar molecules, like oxygen, have relatively little charge to attract to one another. 33. Draw a “general” graph of temperature over time, for the heating of solid Lauric Acid before, during, and after its melting point. 34. Give three qualitative properties and one quantitative the property of acids and bases? Acids Bases H+ or H3O+ ions OHSour Slippery feeling Dissolve metal and carbonates Does not dissolve Metal or Carbonates Litmus blue turns red Litmus red turns blue pH < 7 pH > 7 35. How do catalysts, temperature increases, and concentration increases allow chemical reactions to occur more quickly? Temperature: By increasing temperature there are more molecules that are moving at or above the Activation Energy. Therefore, there is a greater probability of collision between these molecules and the reaction speed is increased. Concentration: By increasing concentration there are more molecules that are moving at or above the Activation Energy. Therefore, there is a greater probability of collision between these molecules and the reaction speed is increased. Catalyst: The addition of a catalyst decreases the activation energy allowing there to be more molecules moving at or above the Activation Energy. Therefore, there is a greater probability of collision between these molecules and the reaction speed is increased. 36. Draw a graph showing how raising the temperature of a sample increases the rate of reaction. Include: Collision Energy, # of particles, and Activation energy. 37. Why does the addition of a catalyst increase the rate of reaction? A catalyst lowers the activation energy. There will be a greater amount of particles colliding at or above activation energy (Ea), thus increasing the chances of a reaction to occur. A catalyst does not affect the concentration or temperature.
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