April
Safety Subject
OSHA’s New Hazard
Communication Standard
• Safety Data Sheets (SDS) contain information about hazardous chemicals that
all employees need to know and will now have a specified 16 section format
• SDS must be readily available to employees exposed to chemicals
• Know where your SDS book is located and designate one person in your office
to keep it updated
• Labels: Chemical manufacturers and importers will be required to provide a
label that includes a harmonized signal word, pictogram, and hazard statement
for each hazard class and category. Precautionary statements must also be
provided.
• All chemical containers must be properly labeled
Copy Ready! Articles and Art Volume 17 Workplace Hygiene 1
Know The Chemicals You Work With
You don’t have to be working
in an industrial setting to be
harmed by chemicals. If you
work in an office around a
photocopier or if you work
around solvents in a print
shop, you are working with
potentially harmful
chemicals.
Know the chemicals you
work with. There is lots of
information available. You
should read the container
label carefully. It will give
you important information
about the chemical, including
first aid advice.
For further and more detailed
information, find and read
the Material Safety Data
Sheet (MSDS) on a particular
chemical. If you do not
understand the MSDS, ask
your supervisor to go over it
with you.
Chemicals should be labelled
and stored according to the
manufacturer’s instructions.
They should be in
recommended containers,
clearly marked and kept in
specially designated, well
ventilated approved storage
areas. Incompatible
chemicals should be stored
away from each other
because of chemical reactions
they could cause. Certain
combinations might cause
toxic gases, fires or
explosions.
Some chemicals
require you wear
Personal Protective
Equipment (PPE) to
guard against
exposure. This might
involve certain types
of body protection,
footwear, gloves, eye
protection or
respirators. Your
supervisor can instruct
on the right kind of
PPE for the chemicals
you handle. When in
doubt, check the
Material Safety Data
Sheet (MSDS).
Do not handle or mix
chemicals unless you are
qualified and permitted to do
so.
Make sure you follow all
instructions and safety
precautions precisely.
Know which chemicals are
flammable and keep them
away from all sources of
ignition. This includes
matches, electrical circuits,
sparks from mechanical
processes and pilot lights.
Become familiar with what to
do in chemical emergencies.
Know the proper procedure
to clean up chemicals when
they spill: know how to put
out a chemical fire.
You should know the location
and procedures to use
eyewash and safety shower
stations in case you or
someone else is exposed to
chemicals. Ask your
supervisor for information
and training.
If you know the safety
precautions for working with
workplace chemicals, you will
protect yourself from harm. Take
the time to become informed
about the substances you work
with, the right PPE to wear, the
right way to handle chemicals,
and what to do in case of
chemical emergencies.
HYGIENE
WORKPLACE
The information presented in Copy Ready! has been compiled from various sources which are believed to be reliable. However, it cannot be assumed that all acceptable
measures are contained in this article nor that additional measures may not be required under particular or exceptional circumstances, or your own company procedures, or
by federal, state/provincial and local law. Copy Ready! is intended for in-house use only — commercial reproduction is a violation of our copyright agreement.
For a complete catalog of Bongarde Communications Ltd. products please call 1-800-667-9300 or visit us at www.safetysmart.com.
© MCMXCVIII Bongarde Communications Ltd.
#H1117
Global Harmonization System:
Impact on OSHA’s Hazard
Communication Standard
by Byron Bombay and Rich Gaul
Before you begin
O Survey your workplace and identify the chemical
and other substances that employees may handle.
O Review your hazard communication program with
your employees. Ensure they understand the potential hazards associated with these materials and
how to handle them properly and protect themselves.
Introduction
Chemicals are and have been a major part of our lives
for many years. Today, companies ship chemicals from
one country to another and even one continent to another. We see more and more chemicals manufactured
across the world each year.
Currently, there is no universal method to communicate
chemical hazard information throughout the world. This
may cause problems for the business community when
shipping chemical products from one country to another. It may also cause serious safety concerns when vital
information is missing or misunderstood by the people
using the chemicals or in an emergency situation. It
can even prove hazardous to the general population in
some extreme situations.
The GHS will provide universal guidelines for chemical
hazard communication information. For example, GHS
will use pictograms (universal symbols) on all product
labels. These pictograms will provide quick and easy
hazard recognition. The GHS standardizes label elements so that they all have the same five basic pieces
of information:
O A signal word;
O A hazard statement;
O Precautionary statements;
O A product identifier;
O Name of the manufacturer or supplier.
Help is on the way
The solution is the Globally Harmonized System (GHS),
a universal system for chemical hazard communication.
In 2002, the World Summit on Sustainable Development
encouraged countries to adopt the new GHS and have
it operational by 2008. GHS is designed to help workers
identify the intrinsic hazards associated with chemicals
and convey detailed information about hazardous ingredients, first aid measures, and proper storage and handling techniques for chemical substances and mixtures.
The Occupational Safety and Health Administration
(OSHA) announced a proposed rule to align its existing Hazard Communication Standard with the GHS.
Although not finalized, it’s important for businesses to
become familiar with the proposed rule.
BWC’s Division of Safety & Hygiene Safety Talk
Under GHS, safety data sheets (SDSs) will replace
material safety data sheets (MSDSs). The new system
standardizes the format and content of SDSs, and the
revised SDSs will include additional information on
ecology, disposal, transport and other regulatory information.
The United States has not finalized the change to the
GHS. However, companies should begin to educate
their employees about the pending changes.
Discussion
O Ask each participant if they are aware of the efforts
to develop a GHS for hazardous chemicals.
O Ask them what information do they feel would improve communication of chemical hazards in the
workplace.
Group activities
Follow up with an exercise that asks students to describe the benefits of the proposed GHS system. What
are these specific benefits?
The students should mention such things as improving
the efficiency of the regulatory system and reducing
duplication and wasted time. The system should promote international trade and ease compliance issues
between countries. The universal labeling system will
reduce regulatory costs, provide more consistent and
perhaps even more complete information. Overall, the
handling and transport of hazardous chemicals should
be safer and more efficient.
Follow up with an exercise where each member of the
group (or team) develops a list of potential emergencies
or problems that could occur at their facilities and how
GHS would impact that specific emergency situation.
Demonstrate how the GHS should work.
What are some of the specific changes proposed to the
existing HazCom standard?
O Revised criteria for classifying chemical hazards
and how that might look in the future
O Current labeling and how it might change
in the future
O Format and content change of current MSDS
(to GHS-compliant SDSs)
O Current requirements and future changes
that might occur
Follow-up questions
Does your plant or facility use GHS now?
Are the people at your plant or facility aware of GHS?
Was OSHA successful in adopting the new guidelines to
the HazCom standard?
Do you know where to find CURRENT HazCom rules?
References
EHS Today
Article submitted by:
Byron Bombay, BWC Industrial Safety Consultant Specialist
Rich Gaul, BWC Safetry Projects Manager
Discussion
What are the main points making up the GHS?
The GHS addresses three main areas. They are:
1. Classification of substances;
2. Classification of mixtures;
3. A system of hazard communication
internationally understood and recognized.
What are the target groups for this system?
1. Workplaces, including educational institutions
2. Household use
3. Transportation including labels and placards
4. Emergency response
From the 2012 Safety Leader’s Discussion Guide
QUICK
CARD
TM
Hazard Communication
Standard Pictogram
As of June 1, 2015, the Hazard Communication Standard
(HCS) will require pictograms on labels to alert users of
the chemical hazards to which they may be exposed. Each
pictogram consists of a symbol on a white background
framed within a red border and represents a distinct
hazard(s). The pictogram on the label is determined by
the chemical hazard classification.
HCS Pictograms and Hazards
Flame
• Carcinogen
• Mutagenicity
• Reproductive Toxicity
• Respiratory Sensitizer
• Target Organ Toxicity
• Aspiration Toxicity
• Flammables
• Pyrophorics
• Self-Heating
• Emits Flammable Gas
• Self-Reactives
• Organic Peroxides
Gas Cylinder
Corrosion
• Gases Under Pressure
• Skin Corrosion/
Burns
• Eye Damage
• Corrosive to Metals
Flame Over Circle
Environment
Exclamation Mark
• Irritant (skin and eye)
• Skin Sensitizer
• Acute Toxicity (harmful)
• Narcotic Effects
• Respiratory Tract
Irritant
• Hazardous to Ozone
Layer (Non-Mandatory)
(Non-Mandatory)
• Oxidizers
• Aquatic Toxicity
Exploding Bomb
• Explosives
• Self-Reactives
• Organic Peroxides
Skull
and Crossbones
• Acute Toxicity
(fatal or toxic)
For more information:
U.S. Department of Labor
www.osha.gov (800) 321-OSHA (6742)
OSHA 3491-02 2012
Health Hazard
TM
Hazard Communication Standard Labels
}
Product
Identifier
Company Name_______________________
Street Address________________________
City_______________________ State_____
Postal Code______________Country_____
Emergency Phone Number_____________
}
Supplier
Identification
OSHA has updated the requirements for labeling of
hazardous chemicals under its Hazard Communication
Standard (HCS). As of June 1, 2015, all labels will be
required to have pictograms, a signal word, hazard and
precautionary statements, the product identifier, and
supplier identification. A sample revised HCS label,
identifying the required label elements, is shown on the
right. Supplemental information can also be provided
Keep container tightly closed. Store in a cool,
well-ventilated place that is locked.
Keep away from heat/sparks/open flame. No smoking.
Only use non-sparking tools.
Use explosion-proof electrical equipment.
Take precautionary measures against static discharge.
Ground and bond container and receiving equipment.
Do not breathe vapors.
Wear protective gloves.
Do not eat, drink or smoke when using this product.
Wash hands thoroughly after handling.
Dispose of in accordance with local, regional, national,
international regulations as specified.
on the label as needed.
In Case of Fire: use dry chemical (BC) or Carbon Dioxide (CO2)
fire extinguisher to extinguish.
For more information:
(800) 321-OSHA (6742)
www.osha.gov
First Aid
If exposed call Poison Center.
If on skin (or hair): Take off immediately any contaminated
clothing. Rinse skin with water.
}
Hazard Pictograms
Signal Word
Danger
}
Highly flammable liquid and vapor.
May cause liver and kidney damage.
Hazard
Statements
Precautionary
Statements
Supplemental Information
Directions for Use
__________________________________
__________________________________
__________________________________
Fill weight:____________ Lot Number:___________
Gross weight:__________ Fill Date:______________
Expiration Date:________
OSHA 3492-02 2012
QUICK
CARD
SAMPLE LABEL
CODE _______________________________
Product Name________________________
Example 1: This example demonstrates a
simple label.
Precautionary Statements:
Prevention:
• Wash hands and face thoroughly after
handling.
• Do not eat, drink or smoke when using this
product.
The Substance:
HS85
Batch Number: 85L6543
Response:
• If swallowed: Call a doctor if you feel
unwell.2
• Rinse mouth
Step 1: Perform Classification
Class: Acute Oral Toxicity; Category 4
Step 2: Gather Labeling Information
Pictograms:
Storage:
None specified
Disposal:
• Dispose of contents/container in
accordance with local/regional/national/
international regulations.3
Signal Word:
WARNING
Hazard Statements:
Harmful if Swallowed
Step 3: Create the Label
Putting together the above information on HS85, a
label might list the following information:
Example 1: HS85 Label
HS85
Batch number: 85L6543
Warning
Harmful if swallowed
Wash hands and face thoroughly after handling. Do not eat, drink or smoke when using this
product. Dispose of contents/container in accordance with local, state and federal regulations.
First aid:
If swallowed: Call a doctor if you feel unwell. Rinse mouth.
GHS Example Company, 123 Global Circle, Anyville, NY 130XX
Telephone (888) 888-8888
The manufacturer of this chemical determined that
calling a doctor was the most appropriate emergency
medical advice; therefore, it is listed as part of the
first-aid procedures.
3
The downstream users must familiarize themselves
with the proper disposal methods in accordance
with local, regional, state and federal regulations. It
is impractical to expect the label preparer to list all
potential regulations that exist.
2
6
Example 2: This example demonstrates a
more complex label.
Response:
• IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with
water.
• IF ON CLOTHING: Rinse immediately
contaminated clothing and skin with plenty
of water before removing clothes. Wash
contaminated clothing before reuse.
• IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
• IF INHALED: Remove person to fresh air
and keep comfortable for breathing.
• IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
• Immediately call poison center.4
Example 2 is for a substance that is a severe
physical and health hazard. For shipping
packages of chemicals that will be transported
in the United States (i.e., drums, totes, tanks,
etc.), the U.S. DOT requires a DOT label(s)
on the outside container(s) for hazardous
chemicals. Two versions of this label are
presented below to demonstrate the difference
between an OSHA label with pictograms from
the HCS and a DOT label required for transport
of a shipping container.
The Substance:
OXI252 (disodiumflammy)
CAS number: 111-11-11xx
Specific Treatment:
Treat with doctor-prescribed burn cream.5
Step 1: Perform Classification
In case of fire:
Use water spray. In case of major fire and large
quantities: Evacuate area. Fight fire remotely
due to the risk of explosion.
Class: Oxidizing Solid, Category 1
Class: Skin Corrosive, Category 1A
Step 2: Gather Labeling Information
Pictograms:
Storage:
Store locked up.
Disposal:
• Dispose of contents/container in
accordance with local/regional/national/
international regulations.³
Signal Word:
DANGER
Step 3: Create the Label
Putting together the above information on OXI252,
a label might list the following information:
Hazard Statements:
• May cause fire or explosion; strong oxidizer
• Causes severe skin burns and eye damage
Precautionary Statements:
Prevention:
• Keep away from heat.
• Keep away from clothing and other
combustible materials.
• Take any precaution to avoid mixing with
combustibles.
• Wear protective neoprene gloves, safety
goggles and face shield with chin guard.
• Wear fire/flame resistant clothing.
• Do not breathe dust or mists.
• Wash arms, hands and face thoroughly
after handling.
In this example, the manufacturer determined that
calling a poison control center is the most appropriate emergency medical advice.
5
Not all SDSs will have direction for “specific treatment” on the label. This is only if the manufacturer
specifically notes a certain treatment that needs to be
used to treat a worker who has been exposed to this
chemical.
4
7
Example 2A: OXI252 Label inner package label with OSHA pictograms
OXI252
(disodiumflammy)
CAS #: 111-11-11xx
Danger
May cause fire or explosion; strong oxidizer
Causes severe skin burns and eye damage
Keep away from heat. Keep away from clothing and other combustible materials. Take any precaution to avoid
mixing with combustibles. Wear protective neoprene gloves, safety goggles and face shield with chin guard. Wear
fire/flame resistant clothing. Do not breathe dust or mists. Wash arms, hands and face thoroughly after handling.
Store locked up. Dispose of contents and container in accordance with local, state and federal regulations.
First aid:
IF ON SKIN (or hair) or clothing6: Rinse immediately contaminated clothing and skin with plenty of water before
removing clothes. Wash contaminated clothing before reuse.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Immediately call poison center.
Specific Treatment: Treat with doctor-prescribed burn cream.
Fire:
In case of fire: Use water spray. In case of major fire and large quantities: Evacuate area. Fight fire remotely due to
the risk of explosion.
Great Chemical Company, 55 Main Street, Anywhere, CT 064XX
Telephone (888) 777-8888
Example 2B: OXI252 Label meeting DOT requirements for shipping7
OXI252
(disodiumflammy)
CAS #: 111-11-11xx
Danger
May cause fire or explosion; strong oxidizer
Causes severe skin burns and eye damage
Keep away from heat. Keep away from clothing and other combustible materials. Take any precaution to avoid
mixing with combustibles. Wear protective neoprene gloves, safety goggles and face shield with chin guard. Wear
fire/flame resistant clothing. Do not breathe dust or mists. Wash arms, hands and face thoroughly after handling.
Store locked up. Dispose of contents and container in accordance with local, state and federal regulations.
First aid:
IF ON SKIN (or hair) or clothing: Rinse immediately contaminated clothing and skin with plenty of water before
removing clothes. Wash contaminated clothing before reuse.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a doctor.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Immediately call poison center.
Specific Treatment: Treat with doctor-prescribed burn cream.
Fire:
In case of fire: Use water spray. In case of major fire and large quantities: Evacuate area. Fight fire remotely due to
the risk of explosion.
Great Chemical Company, 55 Main Street, Anywhere, CT 064XX
There are occasions where label preparers may
combine statements on the label. In this case the
similar statements were combined and the most
stringent were listed. For example, the first-aid pre-
6
8
Telephone (888) 777-8888
cautionary statements were combined for exposure
to skin, hair and clothing.
7
DOT Labels must comply with the size requirements presented in 49 CFR 172.
GHS SAFETY DATA SHEET
Date Revised: FEB 2010
WELD-ON® 763™ Low VOC Styrene Rubber Cement
Supersedes:
OCT 2009
SECTION I - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME:
WELD-ON® 763™ Low VOC Styrene Rubber Cement
PRODUCT USE:
Low VOC Styrene Rubber Cement
SUPPLIER:
MANUFACTURER:
EMERGENCY: Transportation: Tel. 800.424.9300, 703.527.3887 CHEMTREC (International)
IPS Corporation
17109 South Main Street, Carson, CA 90248-3127
P.O. Box 379, Gardena, CA 90247-0379
Tel. 1-310-898-3300
Medical: Tel. 800.451.8346, 760.602.8703 3E Company (International)
SECTION 2 - HAZARDS IDENTIFICATION
GHS CLASSIFICATION:
Health
Acute Toxicity:
Category 4
Skin Irritation:
Category 3
Skin Sensitization:
NO
Eye:
Category 2B
Acute Toxicity:
Chronic Toxicity:
Environmental
None Known
None Known
GHS LABEL:
Physical
Flammable Liquid
Signal Word:
Danger
OR
WHMIS CLASSIFICATION:
Hazard Statements
Category 2
CLASS B, DIVISION 2
Precautionary Statements
H225: Highly flammable liquid and vapor
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking
H319: Causes serious eye irritation
P261: Avoid breathing dust/fume/gas/mist/vapors/spray
H332: Harmful if inhaled
P280: Wear protective gloves/protective clothing/eye protection/face protection
H335: May cause respiratory irritation
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
H336: May cause drowsiness or dizziness
P403+P233: Store in a well ventilated place. Keep container tightly closed
EUH019: May form explosive peroxides
P501: Dispose of contents/container in accordance with local regulation
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
CAS#
Methyl Ethyl Ketone (MEK)
EINECS #
78-93-3
201-159-0
REACH
Pre-registration Number
CONCENTRATION
% by Weight
05-2116297728-24-0000
54 - 71
All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing.
* Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).
SECTION 4 - FIRST AID MEASURES
Contact with eyes:
Skin contact:
Inhalation:
Ingestion:
Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately.
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice.
Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice.
Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.
SECTION 5 - FIREFIGHTING MEASURES
Suitable Extinguishing Media:
Unsuitable Extinguishing Media:
Exposure Hazards:
Combustion Products:
Protection for Firefighters:
Dry chemical powder, carbon dioxide gas, foam, Halon, water fog.
Water spray or stream.
Health
Inhalation and dermal contact
Flammability
Oxides of carbon, hydrogen chloride and smoke
Reactivity
Self-contained breathing apparatus or full-face positive pressure airline masks.
HMIS
2
3
0
NFPA
2
3
0
0-Minimal
1-Slight
2-Moderate
3-Serious
4-Severe
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personal precautions:
Keep away from heat, sparks and open flame.
Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.
Prevent contact with skin or eyes (see section 8).
Environmental Precautions:
Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course.
Methods for Cleaning up:
Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel.
Materials not to be used for clean up:
Aluminum or plastic containers
SECTION 7 - HANDLING AND STORAGE
Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.
Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.
Do not eat, drink or smoke while handling.
Storage: Store in ventilated room or shade below 44°C (110°F) and away from direct sunlight.
Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.
Follow all precautionary information on container label, product bulletins and solvent cementing literature.
SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTION
EXPOSURE LIMITS:
Component
Methyl Ethyl Ketone (MEK)
ACGIH TLV
ACGIH STEL
200 ppm
300 ppm
OSHA PEL OSHA STEL:
200 ppm
Engineering Controls: Use local exhaust as needed.
Monitoring:
Maintain breathing zone airborne concentrations below exposure limits.
Personal Protective Equipment (PPE):
Eye Protection:
Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,
etc. as may be appropriate for the exposure.
Skin Protection:
Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion.
Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive application
practices and procedures are used for making structural bonds.
Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use local
exhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.
With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.
Filename: W-O763LoVoc_2-10.xls
Page 1 of 2
2/23/2010 3:05 PM
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Milky, medium syrupy liquid
Odor:
Ketone
Odor Threshold:
5.4 ppm (MEK)
pH:
Not Applicable
Melting/Freezing Point:
86°C (187°F) Based on first melting component: MEK
Boiling Range:
80°C (176°F)
Boiling Point:
80°C (176°F) Based on first boiling component: MEK
Evaporation Rate:
> 1.0 (BUAC = 1)
Flash Point:
-9°C (16°F) TCC based on MEK
Flammability:
Category 2
Specific Gravity:
0.880 @23°C ( 73°F)
Flammability Limits:
LEL: 1.4% based on MEK
Solubility:
Solvent portion soluble in water. Resin portion separates out.
UEL: 11.4% based on MEK
Partition Coefficient n-octanol/water:
Not Available
Vapor Pressure:
78 mm Hg @ 20°C (68°F) MEK
Auto-ignition Temperature:
515°C (959°F) based on MEK
Vapor Density:
>2 (Air = 1)
Decomposition Temperature:
Not Applicable
Other Data: Viscosity:
Medium bodied
When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 490 g/l.
VOC Content:
SECTION 10 - STABILITY AND REACTIVITY
Stability:
Hazardous decomposition products:
Conditions to avoid:
Incompatible Materials:
Stable
None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke.
Keep away from heat, sparks, open flame and other ignition sources.
Oxidizers, strong acids and bases, amines, ammonia
SECTION 11 - TOXICOLOGICAL INFORMATION
Likely Routes of Exposure:
Inhalation, Eye and Skin Contact
Acute symptoms and effects:
Inhalation:
Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages.
Eye Contact:
Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid.
Skin Contact:
Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact.
Ingestion:
May cause nausea, vomiting, diarrhea and mental sluggishness.
Chronic (long-term) effects:
None known to humans
LD50
LC50
Toxicity:
Inhalation 8 hrs. 23,500 mg/m3 (rat)
Methyl Ethyl Ketone (MEK)
Oral: 2737 mg/kg (rat), Dermal: 6480 mg/kg (rabbit)
Reproductive Effects
Not Established
Teratogenicity
Not Established
Mutagenicity
Not Established
Embryotoxicity
Not Established
Sensitization to Product
Not Established
Synergistic Products
Not Established
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Mobility:
Degradability:
Bioaccumulation:
None Known
In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 490 g/l.
Biodegradable
Minimal to none.
SECTION 13 - WASTE DISPOSAL CONSIDERATIONS
Follow local and national regulations. Consult disposal expert.
SECTION 14 - TRANSPORT INFORMATION
Proper Shipping Name:
Hazard Class:
Secondary Risk:
Identification Number:
Packing Group:
Label Required:
Marine Pollutant:
Adhesives
3
EXCEPTION for Ground Shipping
None
DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package.
UN 1133
Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" .
PG II
Class 3 Flammable Liquid
TDG INFORMATION
NO
TDG CLASS:
FLAMMABLE LIQUID 3
SHIPPING NAME:
ADHESIVES
UN NUMBER/PACKING GROUP:
UN 1133, PG II
SECTION 15 - REGULATORY INFORMATION
Precautionary Label Information: Highly Flammable, Irritant
Symbols:
F, Xi
Risk Phrases:
R11: Highly flammable.
Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia
AICS, Korea ECL/TCCL, Japan MITI (ENCS)
R20: Harmful by inhalation.
R36/37: Irritating to eyes and respiratory system.
Safety Phrases:
S9: Keep container in a well-ventilated place.
S16: Keep away from sources of ignition - No smoking.
S25: Avoid contact with eyes.
R66: Repeated exposure may cause skin dryness or cracking
R67: Vapors may cause drowsiness and dizziness
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S33: Take precautionary measures against static discharges.
S46: If swallowed, seek medical advise immediately and show this container or label.
SECTION 16 - OTHER INFORMATION
Specification Information:
Department issuing data sheet:
E-mail address:
IPS, Safety Health & Environmental Affairs
<[email protected]>
Training necessary:
Reissue date / reason for reissue:
Intended Use of Product:
Yes, training in practices and procedures contained in product literature.
2/23/2010 / Updated GHS Standard Format
Adhesive for bonding/cementing Styrene plastic piping and fittings
All ingredients are compliant with the requirements of the European
Directive on RoHS (Restriction of Hazardous Substances).
This product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state of
knowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof.
Filename: W-O763LoVoc_2-10.xls
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2/23/2010 3:05 PM
TEST YOUR KNOWLEDGE
Hazard Communication Quiz QUESTIONS
1. SDS is an abbreviation for ___________________ .
2. Some chemicals require you to wear what type of equipment to
guard against exposure?
3. Standard pictograms must have a white background
framed by a ____________________ border.
4. The only two “Signal Words” contained on the product
label and SDS are ______________ and _________________.
Hazard Communication Quiz ANSWERS
1. Safety Data Sheet
2. Personal Protective Equipment (PPE)
3. Red
4. Danger and Warning