lubricants Article The Reduction of Static Friction of Rubber Contact under Sea Water Droplet Lubrication Yong-Jie Zhou 1 , De-Guo Wang 1,2, * and Yan-Bao Guo 1,2, * 1 2 * College of Mechanical and Transportation Engineering, China University of Petroleum, Beijing 102249, China; [email protected] Laboratory of Tribology and Surface Engineering, China University of Petroleum, Beijing 102249, China Correspondence: [email protected] (D.-G.W.); [email protected] (Y.-B.G.); Tel.: +86-10-8973-3727 Academic Editor: James E. Krzanowski Received: 29 March 2017; Accepted: 7 May 2017; Published: 12 May 2017 Abstract: In this work, a series of experimental tests is carried out in laboratory conditions which set the rubber compound (soft and stiff), the normal load, and the direction of propagation of sea water droplets into the interface of rubber–steel pipe contact as variables. The results show that the maximum static frictions (F) of rubber–pipe contacts increase as the normal load increases in both dry and lubricating conditions, and the values of F for the softer rubber are higher than that for the stiffer rubber. However, significant reduction in static friction is found due to the lubrication of sea water droplets. The influence of lubrication is stronger when the droplets propagate into the contact interfaces at the tail edge than that at the front edge. Capture sequences of the contact region facilitate the lubrication of seawater droplets by accelerating the progress of separation in the contact interfaces, thus reducing the static friction force. This investigation improves our understanding of the lubrication of sea water droplets during pipe-laying operation, and it will help us to conduct further research on the accuracy and safety of offshore engineering. Keywords: rubber; sea water droplet; lubrication; static friction 1. Introduction Rubber-like materials are widely applied in many engineering fields such as sealing, tire and offshore installation due to their strong mechanical properties, wear resistance and anti-corrosion [1–4]. Tribological behaviors of rubber-like materials in soft contact have been investigated both experimentally and theoretically in the last several decades. It is well known that the friction force of rubber is derived as the product of the total area of the real contact. The friction forces of rubbers on steel increase with normal load, because of the increase in real contact area resulting from the deformation of rubber asperities [5]. Persson [6] presented a discussion on how the resulting friction force depends on the nature of the real contact. The adhesion effect plays a very important role in affecting rubber friction on certain contact conditions. According to Schallamach [7] and Barquins [8], the friction force is velocity dependent and takes a maximum value around a few centimeters per second. Johnson and Greenwood [9] revealed an adhesion map for choosing appropriate mechanical models as a solution of the adhesion between elastic spheres. Schwarz [10] gave a generalized analytical model for the elastic deformation of adhesive contact between a sphere and a flat surface. In addition, static frictional contacts between rubber and rigid materials have been widely studied and the adhesion effect and viscoelastic properties of rubber cannot be neglected. Galligan et al. [11] discussed the nature of static friction and creep. Roberts and Thomas [12] tested the static friction of smooth clean vulcanized rubber. Loeve et al. [13] investigated the static friction of stainless steel wire rope–rubber contacts. Deladi et al. [14] modeled the static friction for contact between rough Lubricants 2017, 5, 12; doi:10.3390/lubricants5020012 www.mdpi.com/journal/lubricants Lubricants 2017, 5, 12; doi: 10.3390/lubricants5020012 2 of 13 rough rubber and Lubricants 2017, 5, 12 metal surfaces. As described in several works by Barquins et al [15,16], Savkoor 2 of 13 [17,18] or more recently by Scheibert et al [19] or Audry and co-workers [20], the static friction of rubber contacts involves complex peeling and micro-slip phenomena which deserve a fracture rubber and description. metal surfaces. As described in several works by Barquins et al [15,16], Savkoor [17,18] or mechanics more Moreover, recently byrubber-like Scheibert etmaterials al [19] or sliding Audry and co-workers [20], the static friction of rubber contacts against rigid metals under wet conditions is a common involves complex and micro-slip phenomena which deservebehaviors a fractureofmechanics description. process for manypeeling engineering applications [21–24]. The frictional rubber-like materials Moreover, rubber-like materials sliding against rigid metals under wet conditions is a common with liquid lubricant are of great importance for steady performance and safety of the equipment. process for many many authors engineering [21–24]. The frictional of rubber-like materials Therefore, have applications focused on water lubricating rubberbehaviors contacts. The well-known Stribeck with liquid lubricant are of great importance for steady performance and safety of the equipment. curve helped us to identify the lubrication regime for each specific contact condition [25]. J. K. Therefore, authors focused on water lubricating of rubber contacts. The on well-known Stribeck Lancaster many reviewed the have friction and wear performances polymers sliding metal with water curve helped he us tosuggested identify the lubrication regime specific contact [25]. J. K. Lancaster lubrication; complicated trends for of each friction forces due condition to the interaction between reviewed wear performances of also polymers sliding onthe metal with water lubrication; he adhesion the andfriction surfaceand properties [26]. Roberts explained that mechanical properties of the suggested complicated trends of friction forces due to the interaction between adhesion and surface vulcanized rubber were modified by liquid absorption [27]. Persson et al. took the phenomenon of properties [26]. Roberts alsocontext explained thatrubber-road the mechanical properties the vulcanized rubberseveral were water entrapment into the of tire contact [28]. A. of Koenen et al. revealed modified by liquid absorption [27]. Persson et al. took the phenomenon of water entrapment into influencers on the friction properties of wiper blade and windscreen contact [29]. Moreover, the the context tire rubber-road contact [28].water A. Koenen et al. revealed several influencers on observed the friction special of contribution to friction by thin film under high contact pressure has been in properties of wiper blade and windscreen contact [29]. Moreover, the special contribution to friction several studies at nanoscale [30]. by thin water film underthis highprogress, contact pressure has of been observed in several studies at nanoscale [30]. However, despite the project static frictional behaviors of soft-rigid contact However, despite this progress, the project ofhas static frictional behaviors of soft-rigid contact during during the deep-water pipe-laying operations rarely been discussed. Deep-water pipe-laying is the deep-water pipe-laying operations has rarely been discussed. Deep-water pipe-laying is known known as a standard industrial process for the installation or maintenance of offshore equipment as a standard the installation or splash maintenance offshore equipment [31–34]. [31–34]. It is industrial inevitable process that seafor water droplets will on theofpipe surface during pipeline Itinstallation. is inevitable that sea water droplets splash on the pipe surface during pipeline installation. The frictional behaviors ofwill the soft contact between the rubber block and pipe with sea The frictional behaviors of the soft contact between the rubber block and pipe with sea water droplets water droplets are of importance for the accuracy and safety of the pipe-laying operation. Three main are of importance for the accuracy andrubber safety of thepipe pipe-laying Three main kinds of contact kinds of contact situations between and with theoperation. lubrication of sea water droplets are situations between rubber and pipe with the lubrication of sea water droplets are schematically shown schematically shown in Figure 1. Sea water droplets can splash at the central, front and tail parts of in FigureIn 1. this Sea study, water droplets can splash at the front and tail parts of contact. In lubrication this study, contact. a series of experiments forcentral, soft rubber–rigid pipe contact with the aofseries of experiments soft rubber–rigid pipe friction contact with the lubrication of sea carried out sea water is carriedfor out with a home-built instrument based on the water three is fundamental with a home-built friction instrument based on the three fundamental lubricating conditions, the lubricating conditions, with the aim of investigating the static friction behaviors under with different aim of investigating the static friction behaviors under different lubricating processes. The evolution lubricating processes. The evolution of the contact area caused by increasing the tangential load has of the contact areaincaused increasing thecomparison tangential load has effect been discussed in detail. Furthermore, been discussed detail.byFurthermore, of the of sea water droplets for each comparison of the effect of sea water droplets for each condition has been discussed. condition has been discussed. Figure 1. 1. Schematic diagram of the lubricating conditions in pipe-laying operation. (a) The Figure Schematic diagram of major the major lubricating conditions in pipe-laying operation. central part of part lubrication; (b) The(b) front ofpart lubrication; (c) The(c) tailThe part ofpart lubrication. (a) The central of lubrication; Thepart front of lubrication; tail of lubrication. 2. Experimental Experimental 2. 2.1. Samples Samples 2.1. Figure2 2illustrates illustrates shapes of rubber and pipe samples. special mould is used to Figure the the shapes of rubber and pipe samples. A special A mould is used to manufacture manufacture vulcanized rubber samples in athe shape of a half oblique frustum cone, the to simulate the vulcanized rubber samples in the shape of half oblique frustum cone, to simulate contacting contacting of conditions of rubber blockswith in tension with pipe the wallpipe-laying during the process. pipe-laying process. conditions rubber blocks in tension the pipe wallthe during Meanwhile, Meanwhile, mould to is polished unify the surface roughness of the rubberUniaxial sample. the surface ofthe thesurface mouldofisthe polished unify thetosurface roughness of the rubber sample. Uniaxial tensile tests are using a test universal test(model machine (model Lina™ WDTII-20, tensile tests are carried outcarried using out a universal machine Lina™ WDTII-20, Shenzhen Shenzhen Lina Instrument Ltd., Shenzhen, China) according to the standard ISO Lina Instrument TechnologyTechnology CO., Ltd., CO., Shenzhen, China) according to the standard ISO 37:1994. The crosshead displacement rate is set at 500 mm/min, and the initial separation distance between Lubricants 2017, 5, 12; doi: 10.3390/lubricants5020012 3 of 13 Lubricants 2017, 5, 12 3 of 13 37:1994. The crosshead displacement rate is set at 500 mm/min, and the initial separation distance between two clamp holders is 36 mm. The hardness of samples is tested by a LX-A tester according two clamp holders 36 mm. The hardness of samplesparameters is tested byofa rubber LX-A tester according to the to the standard ISOis7619:2004. Specific corresponding and pipe samples are standard ISO 7619:2004. Specific corresponding parameters of rubber and pipe samples are listed in listed in Table 1. TableSix 1. black lines are drawn on the surface of the rubber with a marker pen to identify the Six black differences lines are drawn on the surface of the rubber with aand marker pen to identify deformation deformation in the contact area. When normal tangential load arethe applied to the differences in the contact area. When normal and tangential load are applied to the rubber–pipe rubber–pipe contact system, each black line will bend due to the shearing deformation of the contact rubber system, black line will bend the line shearing deformation rubber surface. extentThe of surface. each The extent of the bend ofdue the to black indicates the levelof ofthe shear stress at that The location. the bend of the black line indicates the level of shear stress at that location. The higher the shear stress higher the shear stress level, the greater the extent of bend of the black line. Therefore, the distribution level, thestress greater of of bend the black line. Therefore, the distribution of shear stress on the of shear onthe theextent surface theof rubber can be deduced qualitatively by identifying the different surface of the rubber can be deduced qualitatively by identifying the different extents of bend of test the extents of bend of the black lines. Even though the marker pen ink contributes negligibly to the black lines. Even though the marker pen ink contributes negligibly to the test records, the relative records, the relative displacement of the contact surfaces can be noticed when the ink moves away displacement the contact surfaces can be noticed when the ink moves away from the black line. from the blackofline. Figure 2. The shapes of rubber and pipe samples. Two types of rubber samples: rubber A and B; Two Figure 2. The shapes of rubber and pipe samples. Two types of rubber samples: rubber A and B; types of pipe samples: steel pipe and polymethyl methacrylate (PMMA) pipe. Two types of pipe samples: steel pipe and polymethyl methacrylate (PMMA) pipe. Table 1. Mechanical properties of the unfilled nitrile butadiene rubber (NBR) samples and pipe Table 1. Mechanical properties of the unfilled nitrile butadiene rubber (NBR) samples and pipe samples. samples. Rubber Type Rubber Type AA B B Pipe Type Pipe Type Steel Steel PMMA PMMA MechanicalProperties Properties Mechanical Elastic Modulus [MPa] Tensile Tensile Strength Strength [MPa] [Ra] Elastic Modulus [MPa] [MPa] Shore ShoreHardness Hardness Roughness Roughness [Ra] 2.26 13.2 2.26 13.2 3737 3.13.1 12.79 5151 3.23.2 3.73.7 12.79 MechanicalProperties Properties Mechanical Elastic Modulus [MPa] HRCHRC Roughness [Ra] Elastic Modulus [MPa] Roughness [Ra] 5 2.12.1 × 10 80 80 1.71.7 × 105 × 3103 3 ×3 10 99 99 1.61.6 It is is necessary necessary to to note note that that the the major major difference difference between between rubber rubber A A and and B B is is the the elastic elastic modulus modulus It which is is resulted resulted from from the the different different densities densities of of the the crosslink crosslink [35]. [35]. Therefore, Therefore, the the two two rubber rubber samples samples which behave remarkably differently in the viscoelastic aspect. Moreover, the surfaces of both kinds of pipe pipe behave remarkably differently in the viscoelastic aspect. Moreover, the surfaces of both kinds of samples are arepolished polisheddesignedly designedly to unify roughness of them. Therefore, the influence of the samples to unify the the roughness of them. Therefore, the influence of the surface surface roughness difference is not discussed in this study. roughness difference is not discussed in this study. The sea seawater watersolution solution study is prepared according the standard ASTM1141-98 as The in in thisthis study is prepared according to thetostandard ASTM1141-98 as shown shown 2. This solution is used widely by researchers as a substitute of sea[36]. water [36]. in Tablein2.Table This solution is widely byused researchers as a substitute of sea water Lubricants 2017, 5, 12 4 of 13 Lubricants 2017, 5, 12; doi: 10.3390/lubricants5020012 4 of 13 Table 2. Chemical composition of sea water solution. Table 2. Chemical composition of sea water solution. Compound Compound Concentration (g/L) (g/L) Concentration NaCl Na Na22SO SO44 MgCl 2 2 CaCl 2 2 SrCl 2 2 MgCl CaCl SrCl NaCl 24.53 4.09 5.20 1.16 24.53 4.09 5.20 1.16 0.025 0.025 KCl KCl 0.695 0.695 NaHCO 3 3 KBrKBr H3 BO NaHCO H33BO3 NaFNaF 0.201 0.201 0.101 0.101 0.027 0.027 0.003 0.003 2.2.Tribological TribologicalInstrument Instrument 2.2. schematicdiagram diagramof ofthe thetribological tribologicalinstrument instrumentisisshown shownin inFigure Figure3.3.The Theinstrument instrumentmainly mainly AAschematic consists of of three threecomponents: components: normal normal loading loading module; module; rubber-pipe rubber-pipe contact contact testing testing module; module; and and consists tangential loading module. Normal load is applied to the rubber samples via the lever arm. The pipe tangential loading module. Normal load is applied to the rubber samples via the lever arm. The pipe sampleisismounted mountedatatthe thetop topofofthe thelinear linearslide sliderail railsoso that can slide Y-direction smoothly. sample that it it can slide in in thethe Y-direction smoothly. It isIt is necessary to note that coefficient of friction (COF) of the linear slide without normal loading necessary to note that thethe coefficient of friction (COF) of the linear slide railrail without normal loading is is nearly 0.12, and it will increase much (5%) whenthe therange rangeofofthe thenormal normalload loadisisfrom from00N Nto to nearly 0.12, and it will notnot increase soso much (5%) when 100N. N.The Thetangential tangentialload loadisisdriven drivenby byaamotor motorand andreducer reducerthrough throughwire wirerope ropewhich whichconnects connectsthe the 100 sidesof ofthe thepipe pipeand andreducer. reducer.AAspring springisisused usedto toeliminate eliminaterigid rigidmotional motionaltendency tendencyand andvibration vibration sides whichare arecaused causedby bythe therunning runningof ofthe themotor motorand andreducer. reducer.The Thenormal normalload loadand andtangential tangentialload loadare are which detectedby byforce forcesensors. sensors.The Thedisplacement displacement of ofpipe pipeisistested testedby byaalaser laserdisplacement displacementsensor sensor(model (model detected Panasonic™HG-C1030L; HG-C1030L;Panasonic Panasonic industrial devices SUNX Suzhou CO., Suzhou, Ltd., Suzhou, Panasonic™ industrial devices SUNX Suzhou CO., Ltd., China) China) which is mounted on the of the instrument. All data testing data is recorded in a computer. iswhich mounted on the base of base the instrument. All testing is recorded in a computer. Figure3.3.Schematic Schematicdiagram diagramof ofthe thetribological tribologicalinstrument. instrument.The Theinstrument instrumentmainly mainlyconsists consistsof ofthree three Figure components: normal normal loading loading module; module; rubber-pipe rubber-pipe contact contact testing testing module; module; and and tangential tangentialloading loading components: module. A portable video camera is positioned perpendicular to the contacting surface across the module. A portable video camera is positioned perpendicular to the contacting surface across the PMMA pipe to provide a macroscopic recording of the contact. PMMA pipe to provide a macroscopic recording of the contact. In order to observe the frictional behaviors of the contact area between rubber and polymethyl In order to observe the frictional behaviors of the contact area between rubber and polymethyl methacrylate (PMMA), the portable video camera (model Supereys™ A005; Shenzhen Deyufu methacrylate (PMMA), the portable video camera (model Supereys™ A005; Shenzhen Deyufu Instrument Technology CO., Ltd., Shenzhen, China) is positioned perpendicular to the contact Instrument Technology CO., Ltd., Shenzhen, China) is positioned perpendicular to the contact surface surface across the PMMA pipe. This digital camera provides a macroscopic recording in a whole test across the PMMA pipe. This digital camera provides a macroscopic recording in a whole test run. run. 2.3. Experimental Procedures 2.3. Experimental Procedures A contact area is formed between rubber and pipe samples when normal load is applied to A contact area is formed between rubber andload pipestarts samples when normal load is applied to the the rubber-pipe contact system. Then, tangential to be imposed with a pre-set constant rubber-pipe contact system.load Then, tangential load starts to be imposed a pre-set constant increasing rate. As tangential is continuously increasing, macroscopic slipwith between the surface of increasing rate. As tangential load is continuously increasing, macroscopic slip between the surface the rubber and pipe takes place. The increasing rate of tangential load can be controlled by altering the of the rubber and pipeoftakes place. and The reducer. increasing rate of tangential load can be controlled by altering output rotation speed the motor the output of the out motor and reducer. A seriesrotation of tests speed was carried to investigate the effect of the lubrication of sea water droplets in A series of tests was carried out to investigateofthe effect of the of sea the rubber-steel contact system. The combinations parameters are lubrication given in Table 3. water droplets in the rubber-steel contact system. The combinations of parameters are given in Table 3. Lubricants 2017, 5, 12 5 of 13 Table 3. Parameters of friction tests. Rubber Pipe Normal Load [N] Increasing Rate of Tangential Load [N/s] A B Steel, PMMA Steel, PMMA 10, 20, 30, 40 0.062, 1.5 Specifically, procedures of injecting sea water into the contact system for the three fundamental lubricating conditions are slightly different. In order to lubricate the central part of contact, sea water is sprinkled onto the surface of the pipe before rubber is squeezed on the pipe in normal direction. The amount of sea water should be sufficient to ensure that a steady water film region is spread on the surface of the pipe to cover the contact area completely. On the contrary, for lubricating conditions which are at the front part and tail part of the contact system, sea water is applied to the front edge and the tail edge of contact respectively after the contact area is stably formed. Simultaneously, other groups of tests with the same independent variables between rubber and PMMA pipe were carried out to uncover the similarities between rubbers in contact with steel and PMMA. Moreover, digital recordings were exploited to investigate the behaviors of the contact areas between rubber and PMMA samples. At the beginning of a test, only normal load was applied, and maintained for 180 s without changing any other parameter of the test. The procedure was operated before tangential load was applied to ensure the same normal loading condition. During this time, the radius of the contact area increases gradually to the maximum value and becomes unchanged; the principle of the changing contact radius is revealed by Lee and Radok who took the creep property of the rubbery material into account in studying soft-rigid contact [37]. Furthermore, maintaining the unloading time above three minutes between each test run considerably minimizes the repetition effects during tests including viscoelastic rubber samples [38]. After finishing the first test run, we needed to unload the samples and move the pipe to the initial position for the second test run. The residual sea water on the counter surfaces was removed artificially. It is necessary to note that tangential force data tend to be stable after seven successive test runs. As a consequence, 10 runs for each variable combination were carried out and the last three groups of data are regarded as test values to eliminate the deviation of data at the initial stage of the test [39]. The temperature and relative humidity of the laboratory remained at 25 ◦ C (StDev 0.1–0.5) and 40% (StDev 3–5%) respectively throughout the tests via central air-conditioning. 2.4. Confirmation of the Maximum Static Friction Figure 4a illustrates a combination of test records of the rubber A-steel contact system for the central part lubricating condition. These tests are carried out at 10 N normal load with increasing rates of tangential load at 0.062 N/s and 1.5 N/s, respectively. The results are reproducible for each combination of normal load and increasing rate of tangential load which are tested. A local enlargement of a single testing curve is shown in Figure 4b to demonstrate how the maximum static friction and maximum partial displacement are confirmed. At the beginning of the test, the tangential load curve starts to increase with a constant increasing rate. The entire curve does not show any significant fluctuation until a sudden drop emerges from the top of the curve. The displacement curve also shows a surprising increase at the same time. This time point is chosen as the instant of macroscopical slip, and the values of tangential load and displacement at that time point are treated as the maximum static friction and the maximum partial displacement, respectively. Lubricants 2017, 5, 12; doi: 10.3390/lubricants5020012 Lubricants 2017, 5, 12 Lubricants 2017, 5, 12; doi: 10.3390/lubricants5020012 6 of 13 6 of 13 6 of 13 Figure 4. Confirmation of the maximum static friction. (a) Combination of two test records under 10 Figure 4. Confirmation of the maximum static friction. (a) Combination of two test records under 10 N Figure 4. Confirmation of the static friction.rate (a) Combination of two(b) test records under 10 N normal load with a 0.062 N/smaximum and 1.5 N/s increasing of tangential load; Local enlargement normal load with a 0.062 N/s and 1.5 N/s increasing rate of tangential load; (b) Local enlargement of a N normal load with a 0.062 N/s and 1.5 N/s increasing rate of tangential load; (b) Local enlargement of a single testing curve. single testing curve. of a single testing curve. 3. Results 3.3.Results Results 3.1. The The Maximum Maximum Static Static Friction Friction 3.1. 3.1. The Maximum Static Friction All the the test test results results are areshown shown with with the the maximum maximum static static frictions frictions in in respect respect to to rubber rubber types; types; dry dry All All the test results are shown with the maximum static frictions in respect to rubber types; dry and lubricating lubricatingconditions; conditions;normal normalloads; loads;and andincreasing increasingrates ratesof oftangential tangentialload. load. and and A lubricating conditions; normal loads; and increasing rates of tangential load. series of of maximum maximum static static frictions frictions (F) (F) of of rubber rubber A A and and BB in in contact contact with with steel steel for for dry dry and and A series A series of maximum static frictions (F)respectively. of rubber A In and B in contact with steel for dry and lubricating conditions is plotted in Figure 5a,b, general, the trends of F for each testing lubricating conditions is plotted in Figure 5a,b, respectively. In general, the trends of F for each testing lubricating conditions is plotted in Figure 5a,b, respectively. In general, the trends of F for each testing conditionare arethe thesame; same;values valuesof ofFFincrease increasewith withincreasing increasingnormal normalload. load.ItItis is obvious obviousthat that the the friction friction condition condition are the same; values ofwater F increase withinto increasing normal load. It is obvious that the friction of each test decreases when sea is added the central part of rubber-steel contact systems. of each test decreases when sea water is added into the central part of rubber-steel contact systems. of each test decreases when sea water is added intofriction the central part of rubber-steel contact systems. Sea water shows levels with quite a high proportion. The Sea water shows strong stronglubrication lubricationability abilitytotoreduce reduce friction levels with quite a high proportion. Sea water shows strong lubrication ability to reduce friction levels with quite a high proportion. The lubrication of seawater is more active for rubber A than that for rubber B. When compared with dry The lubrication of seawater is more active for rubber A than that for rubber B. When compared with lubrication of seawater is more active for rubber A than that for rubber B. When compared with dry conditions, the proportion for rubber A ranges fromfrom 30%30% to 45%, while for rubber B, the is 5%– dry conditions, the proportion for rubber A ranges to 45%, while for rubber B, range the range is conditions, theexception proportion for rubber A ranges fromB30% to 45%, is while for10 rubber B, theload range is 5%– 30%. The only takes place for the rubber test which below N normal with an 5–30%. The only exception takes place for the rubber B test which is below 10 N normal load with an 30%. The only exception takes the rubber B test which is below 10 N normal load with an increasing rateof of tangential loadplace at1.5 1.5for N/s. increasing rate tangential load at N/s. increasing rate of tangential load at 1.5 N/s. Figure 5. A series of maximum static frictions (F) of rubber in contact with steel for dry and lubricating Figure 5. A series of maximum static frictions (F) of rubber in contact with steel for dry and lubricating conditions. Results of rubberstatic A tests; (b) Results rubber tests. Figure 5. A(a) series of maximum frictions (F) of of rubber in B contact conditions. (a) Results of rubber A tests; (b) Results of rubber B tests.with steel for dry and lubricating conditions. (a) Results of rubber A tests; (b) Results of rubber B tests. Another Another comparison comparison can can be be easily easily seen seen for for rubber rubber A A tests tests for for which which friction friction levels, levels, with with an an Another comparison can be easily seen for rubber A tests for which friction levels, with an increasing rate of tangential load at 1.5 N/s, are always higher than that with an increasing rate of increasing rate of tangential load at 1.5 N/s, always higher than that with an increasing rate of increasing rate of tangential load at 1.5 N/s, are always higher than that with an increasing rate of tangential tangentialload loadat at0.062 0.062N/s. N/s. Difference of friction levels between the two different different tangential tangential loading loading tangential load at 0.062 N/s. Difference of friction levels between the two different tangential loading conditions conditions is is not not quite quite apparent apparent at at 10 10 N Nand and20 20N Nnormal normalload loadconditions. conditions. However, However, the the difference difference conditions is not quite apparent at 10 N and 20 N normal load conditions. However, the difference increases as normal load increases. increases as normal load increases. increases as normal load increases. Lubricants 2017, 2017, 5, 5, 12 12; doi: 10.3390/lubricants5020012 Lubricants of 13 13 77 of Even though almost the same tendency is shown in tests of rubber B, the difference of friction though the same tendency is shown ofproportion rubber B, the difference of friction levelsEven between twoalmost tangential loading conditions staysinattests a low range. Moreover, when levels between two tangential loading conditions stays at a low proportion range. Moreover, when normal load is 40 N, the lubricated friction for the 1.5 N/s increasing rate of tangential load is lower normal load 400.062 N, the lubricated friction for the 1.5 N/s increasing rate of tangential load is lower than that for is the N/s rate. than that for the 0.062 N/s rate. 3.2. Efficiency of Lubrication 3.2. Efficiency of Lubrication In order to investigate the different lubricating conditions in the central, the front and the tail In to investigate the of different lubricating in the central, the front the tail contact order part, we set α as a ratio the efficiency of theconditions three lubricating conditions. The αand is denoted contact part, we set α as a ratio of the efficiency of the three lubricating conditions. The α is denoted as as a simple function that a simple function that (1) ⁄ lc α= = Flx /F (1) Flt; these threethree factors represent the maximum static friction of rubberwhere FFlxlx includes includesFlcF,lcF,lf Fand Flt ; these factors represent the maximum static friction of lf and seen as the steel contact contact under each the of three conditions, respectively. Flc can Fbe rubber-steel underofeach the lubricating three lubricating conditions, respectively. can be seen lc reference value tovalue examine the lubrication efficiencyefficiency for the other typicaltwo lubricating conditions. as the reference to examine the lubrication for two the other typical lubricating Therefore, the values ofthe α for the of central of the lubricated constantly 1. Theequal higher conditions. Therefore, values α for part the central part of thetests lubricated testsequal constantly 1. value of α reveals friction; the lubrication efficiencyefficiency is not asisgood asgood that for the The higher value ofhigher α reveals highertherefore, friction; therefore, the lubrication not as as that central part lubricating condition. Values Values of α forofthe other typical lubricating conditions which for the central part lubricating condition. α for thetwo other two typical lubricating conditions are under different loading processes are shown in Figure 6. which are under different loading processes are shown in Figure 6. Figure 6a represents a combination of values of αα for for rubber rubber A A tests. tests. Apparently, most of the for the the tail tail part part lubricating lubricating conditions are lower than that for the front part conditions, values of αα for except for for only only one one test test which which is is under under 10 10 N N normal normal load load with with aa 0.062 0.062 N/s N/s increasing except increasing rate of tangential load. This This phenomenon phenomenonmeans meansthat thatlubrication lubrication at the tail part of contact is commonly at the tail part of contact is commonly moremore activeactive than thanatthat the part frontofpart of contact. The values in the most tests 1,exceed 1, it indicates that the that theat front contact. The values of α in of theαmost tests exceed it indicates that the levels of levels of lubrication the two lower at the central part. lubrication at the twoatside partsside are parts lowerare than that than at thethat central part. In Figure 6b, some similar trends are observed, observed, for example, lubrication lubrication at at the tail part of contact behaves more morevigorously vigorouslythan thanthat thatatatthe thefront front part rubber B contact system. Lubrication at behaves part forfor thethe rubber B contact system. Lubrication at the the central part is also more active than that at the other side parts. central part is also more active than that at the other side parts. Figure 6. 6. Lubrication Lubricationefficiency efficiencyat at parts of contact. (a) Results of rubber (b) Figure thethe twotwo sideside parts of contact. (a) Results of rubber A tests;A(b)tests; Results Results of rubber B tests. of rubber B tests. 3.3. Deformation of Contact 3.3. Deformation of Contact The pictures of contact are extracted frame by frame from testing video files (video format: 1600 The pictures of contact are extracted frame by frame from testing video files (video format: × 1200 pixels, 24 bit, 60 frames per second). We select the image which represents the typical shape 1600 × 1200 pixels, 24 bit, 60 frames per second). We select the image which represents the typical of the contact region for each deformation phase of the rubber sample. In order to highlight the shape of the contact region for each deformation phase of the rubber sample. In order to highlight deformation of the contact region, we keep the image of contact at the center of the picture and crop the deformation of the contact region, we keep the image of contact at the center of the picture and the picture to 200 × 200 pixels. Therefore, a series of pictures is demonstrated in Figures 7–9 to identify crop the picture to 200 × 200 pixels. Therefore, a series of pictures is demonstrated in Figures 7–9 to the evolution of the contact region throughout the tests of three typical lubricating conditions. identify the evolution of the contact region throughout the tests of three typical lubricating conditions. Firstly, the evolution of contact for the central part lubricating condition is shown in Figure 7. Sea water has spread onto the pipe surface and has formed a stationary lubricating film before rubber surface of rubber due to the continuously increasing tangential load. Relative displacement of the counter counter surfaces surfaces is is observed observed within within the the yellow yellow dotted dotted ovals, ovals, as as shown shown by by partial partial traces traces of of ink ink which which are are separated separated from from the the black black marker marker pen pen lines. lines. As As long long as as the the tangential tangential load load is is increasing, increasing, more more and and more more separations separations of of partial partial traces traces of of ink ink appear appear within within the the apparent apparent contact contact area area (Figure (Figure 7e). 7e). The The bend at the rear edge of contact is more distinct than that at the front edge. Finally, as soon as bend at the rear edge of contact is more distinct than that at the front edge. Finally, as soon as the the Lubricantsseparations 2017, 5, 12 8 of 13 contact contact separations occupy occupy most most of of the the contact contact region, region, macroscopic macroscopic slip slip emerges emerges (Figure (Figure 7f). 7f). Figure 7. Evolution of the apparent contact area in the rubber A-PMMA test, for the central part Figure 7. 7. Evolution rubber A-PMMA A-PMMA test, the central central part part Figure Evolution of of the the apparent apparent contact contact area area in in the the rubber test, for for the lubricating condition. The test is under 20 N normal load with a 0.062 N/s increasing rate of tangential lubricating condition. The test is under 20 N normal load with a 0.062 N/s increasing rate of tangential lubricating condition. The test is under 20 N normal load with a 0.062 N/s increasing rate of tangential load. The black lines on the surface of the rubber are marked as 1–6. (a) Steady contact between rubber load. The onon thethe surface of the rubber are marked as 1–6. Steady contactcontact between rubber load. Theblack blacklines lines surface of the rubber are marked as (a) 1–6. (a) Steady between and pipe without tangential load; (b) Deformation of the contact at the beginning of tangential load; and pipe without tangential load; (b) Deformation of the contact at the beginning of tangential load; rubber and pipe without tangential load; (b) Deformation of the contact at the beginning of tangential (c) Rubber surface which, at the rear edge of contact, is moving towards with pipe; (d) Partial traces (c) Rubber surface which,which, at the at rear contact, is moving towards with pipe; Partial traces load; (c) Rubber surface theedge rear of edge of contact, is moving towards with(d) pipe; (d) Partial of ink which are separated from the black marker pen lines; (e) More and more separations of partial of ink which separated from thefrom black marker lines; (e) lines; More (e) andMore moreand separations of partial traces of ink are which are separated the black pen marker pen more separations traces of ink appear within the apparent contact area; (f) Macroscopic slip is emerging. The white traces of ink appear within thewithin apparent area; (f) Macroscopic slip is emerging. white of partial traces of ink appear thecontact apparent contact area; (f) Macroscopic slip is The emerging. arrows indicate the direction of expansion of the contact region; The red arrows indicate the arrows indicate the direction of expansion of the contact region; The red arrows indicate the The white arrows indicate the direction of expansion of the contact region; The red arrows indicate deformation of the rubber surface; The yellow dotted circles indicate the relative displacement of deformation of the rubber surface; The yellow dotted the deformation of the rubber surface; The yellow dottedcircles circlesindicate indicatethe therelative relative displacement displacement of interfaces (the interpretation also applies to figures 8 and 9). to Figures figures 8 and 9). interfaces (the interpretation also applies to Figure 8. Evolution of the apparent contact area in the rubber A-PMMA test, for the front part Figure 8. Evolution of the apparent contact area in the rubber A-PMMA test, for the front part Figure 8. Evolution the apparent area load in the rubber A-PMMA test, for the part lubricating condition. of The test is under contact 20 N normal with a 0.062 N/s increasing rate of front tangential lubricating condition. The test is under 20 N normal load with a 0.062 N/s increasing rate of tangential lubricating condition. The test is under 20 N normal load with a 0.062 N/s increasing rate of tangential load. (a) Steady contact between the rubber and pipe without tangential load; (b) Deformation of the load. (a) Steady contact between the rubber and pipe without tangential load; (b) Deformation of the load. (a)atSteady contact between the rubber pipe without tangential (b) Deformation of the contact the beginning of tangential load; and (c) Rubber surface which, atload; the rear edge of contact, is contact at the beginning of tangential load; (c) Rubber surface which, at the rear edge of contact, is contact at the beginning of tangential load; (c) Rubber surface which, at the rear edge of contact, is moving towards with pipe; (d) Partial traces of ink which are separated from the black marker pen moving towards with pipe; (d) Partial traces of ink which are separated from the black marker pen moving towards with pipe; (d) Partial traces of ink which are separated from the black marker pen lines; (e) More and more separations of partial traces of ink appear within the apparent contact area; lines; (e) 5, More and10.3390/lubricants5020012 more separations of partial traces of ink appear within the apparent contact area;9 of 13 Lubricants 2017, 12; doi: lines; (e) More and separations of partial traces of ink appear within the apparent contact area; (f) Macroscopic slipmore is emerging. (f) Macroscopic slip is emerging. (f) Macroscopic slip is emerging. Figure thethe apparent contact area in thein rubber A-PMMA test, for the part lubricating Figure 9.9.Evolution Evolutionofof apparent contact area the rubber A-PMMA test,tailfor the tail part condition. The test is under 20 N normal load with a 0.062 N/s increasing rate of tangential load. lubricating condition. The test is under 20 N normal load with a 0.062 N/s increasing rate of tangential (a) Steady contact between the the rubber andand pipe without tangential load; load. (a) Steady contact between rubber pipe without tangential load;(b) (b)Deformation Deformation of of the the contact at the beginning of tangential load; (c) Rubber surface which, at the rear edge of contact, contact at the beginning of tangential load; (c) Rubber surface which, at the rear edge of contact, is is moving towards with with pipe; pipe; (d) (d) Partial traces of of ink moving towards Partial traces ink which which are are separated separated from from the the black black marker marker pen pen lines; of partial partial traces traces of of ink ink appear appear within within the the apparent apparent contact contact area; area; lines; (e) (e) More More and and more more separations separations of (f) Macroscopic slip is emerging. (f) Macroscopic slip is emerging. Even though the contact areas are deformed in different scales, Figures 8 and 9 show a similar evolution of contact for the front part and the tail part lubricating conditions to the central part lubrication tests. 4. Discussion There are two major factors that influence friction levels not only in the sliding condition but Lubricants 2017, 5, 12 9 of 13 Firstly, the evolution of contact for the central part lubricating condition is shown in Figure 7. Sea water has spread onto the pipe surface and has formed a stationary lubricating film before rubber is normal loaded against to the pipe. Figure 7a illustrates steady contact between the rubber and pipe with seawater lubrication after a certain time which is mentioned in the experimental procedures section. As soon as the tangential load is imposed, the shape of the contact area starts deforming. At the beginning of tangential loading, as shown in Figure 7b, the white arrows indicate that the front edge of contact shrinks backward slightly, while the rear edge expands smoothly. The red arrow is pointing in the opposite shearing direction to the rear edge of the contact region. It is obvious that the scale of deformation at the front edge is slightly lower than that at the rear edge. This phenomenon of contact can be regarded as a consequence of integral elastic deformation of the rubber sample. The bend of line 2 which is shown in Figure 7c indicates that the rubber surface, at the rear edge of contact, is moving towards with pipe and no relative displacement of counter surfaces takes place during this status. The increasing bend of line 2 in Figure 7d reveals remarkable shear of the surface of rubber due to the continuously increasing tangential load. Relative displacement of the counter surfaces is observed within the yellow dotted ovals, as shown by partial traces of ink which are separated from the black marker pen lines. As long as the tangential load is increasing, more and more separations of partial traces of ink appear within the apparent contact area (Figure 7e). The bend at the rear edge of contact is more distinct than that at the front edge. Finally, as soon as the contact separations occupy most of the contact region, macroscopic slip emerges (Figure 7f). Even though the contact areas are deformed in different scales, Figures 8 and 9 show a similar evolution of contact for the front part and the tail part lubricating conditions to the central part lubrication tests. 4. Discussion There are two major factors that influence friction levels not only in the sliding condition but also in the static contact system [40]. The principal factor is the adhesion force between the counter surfaces, which primarily influences the level of friction. The second factor is the viscoelastic property of rubber, which can be seen as an inherent response to external environmental conditions. In this study, adhesion force is still playing a very important role which affects the levels of static friction within the real contact area. In most of the tests, values of F at the 1.5 N/s increasing rate of tangential load are higher than that at 0.062 N/s. This phenomenon may be caused by the viscoelastic property of rubber. The explanation is based on previous research by Schallamach [7] and Barquins [8]. Adhesion load increases as relative displacement velocity increases, however, the end of the adhesion phase decreases. Therefore, it is deduced that there is a critical speed for which the friction takes the maximum value. The relative displacement velocities in our tests are apparently lower than the critical speed; therefore, the friction increases with a higher increasing rate of tangential load. This phenomenon can also indicate that the viscoelastic property of rubber still works at the level of static friction for lubricating conditions. The lubrication of water has complicated influences on the static friction level of rubber. The water film can be entrapped within the apparent contact area due to the convenient elastic deformation of rubber [27]. The sealing effect of the water film is introduced when the rubber is normal against the rough surface of the substrate [28]. The entrapment of water and the sealing effect belong to the essential principle that the water film, within the apparent contact area, supports the normal load and smoothens the counter surfaces, consequently leading to a reduction of adhesion force in the contact system, thus reducing the rubber friction [41]. However, the thin water film and the tacky condition may generate the influence of the capillary effect. The capillary effect establishes capillary bridges among the surface asperities of rubber and the water film, resulting in the enhancement of adhesion and resistance to shear [42]. Therefore, the lubrication of water has two opposite effects on rubber friction based on the certain investigating condition. It is known that a sufficient amount of water Lubricants 2017, 5, 12 10 of 13 leads to the large thickness of the lubricating film and the complete wetting condition. The capillary effect cannot be highlighted during such a testing situation in our study. 4.1. The Central Part Lubrication The Stribeck curve provides guidance to identify the lubricating regime in the central part wetting tests. Even though the tests aim to investigate the static frictional behaviors of rubber, and no macroscopical displacement takes place during most tests, the relative partial displacement emerges as soon as the tangential load is imposed. Therefore, the contact system can be seen as an assemblage of the real contact area surrounded by a circle of the partial sliding zone. We can deduce the relative sliding velocity at the level of a few centimeters per second due to the displacement–time curves. We can clearly conclude that the central part lubrication is belong to the scope of boundary lubrication. In the boundary regime, water lubrication follows the principle of reducing the static friction. Therefore, the maximum static friction for the central part lubricating condition is universally lower than that in the dry condition for both rubber A and B tests. The different extent of bend between line 2 and 5 (Figure 7) reflects the strong difference of the shear stress between the rear edge and the front edge of the contact zone. This phenomenon is well established with previous results obtained in the dry condition [15,38]. Lubrication in the central part of contact can be seen as a function that weakens the adhesion effect within the entire contact zone rather than changing the deformation principle of the rubber surface. Under this assumption, the difference of the maximum static friction between the two rubber types can be understood with the same explanation as for dry condition tests: the lower the elastic moduli, the stronger the contact deformation; therefore, the static friction increases as the real contact area increases. Furthermore, the maximum static friction decreases due to the creep of the rubber surface when sheared for a certain period of time [15]. The improvement of static friction which is achieved at a higher increasing rate of tangential load is also good evidence to prove the assumption. 4.2. Comparison of the Two Side Parts of Lubrication The effect of lubrication on the contact of the two side parts is quite different from that on the central part lubricating condition; this is because sea water solution is applied to each part of the contact zone until the contact is stably formed. Therefore, there is no entrapment of water or sealing water before the tangential load is imposed. If the counter surfaces are smooth enough, then the lubricating film would be propagated along with the boundary of the central contact area and partial slip zone. The counter surfaces in this study are not as smooth as the ideal assumption, and the water film can propagate into the contact zone through gaps between asperities in contact due to seepage flow mechanics. Therefore, the lubricating film can reduce the adhesion force around the crack line of the interfaces. However, the effect of lubricating water within the apparent contact zone is smaller than that at the central part lubricating condition. Figure 10 provides evidence to compare the extent of deformation at the rear edge of the apparent contact zone for the three lubricating conditions. The largest shear stress is shown in Figure 10b and sea water is concentrated at the front part of contact. There is no lubrication at the tail part of contact; the distance to the initiate position at the rear edge of contact is 2.08 mm, so the maximum static friction stays at a high level. The deformation which is shown in Figure 10c is evidently smaller than that in Figure 10b; it indicates that lubrication acts more efficiently and results in lower static friction for the tail part lubricating conditions. However, its deformation (1.51 mm) is still larger than that for the central part lubricating tests (1.25 mm). Furthermore, the contact displacement for each lubricating condition is shown in Figure 10d; we can observe the variation tendency of the maximum displacements in the three tests, and the tendency is similar with the variation of the deformations at the rear edge of the contact. This phenomenon can also prove the different effects of lubrication for the three lubricating conditions. Therefore, values of α are always greater than 1. It is necessary to note that the maximum contact displacement is apparently higher than the deformation distance at the rear edge, because there are two major deformation Lubricants 2017, 5, 12 11 of 13 styles—elastic deformation of the whole rubber sample and tangential deformation which is located at the rear edge—which contribute to the contact displacement from the initiate position. An obvious exception for5,the of α is obtained in rubber A tests; the value is under 10 N normal load and at13a Lubricants 2017, 12; value doi: 10.3390/lubricants5020012 11 of 1.5 N/s increasing rate of tangential load. This is possibly because the static contact system undergoes an unstable status which under relatively low loading a high increasing rate. high increasing shear rate. is The unusual value of thenormal maximum staticwith friction which is shownshear in Figure Themay unusual value of evidence; the maximum static friction which is shown in Figure 5b may be than convincing 5b be convincing the friction of the lubricating condition is slightly higher that in evidence; the friction the lubricating slightly than thatrate in the dry condition the dry condition testof which is under 10condition N normalis load withhigher an increasing of tangential loadtest at which 1.5 N/s.is under 10 N normal load with an increasing rate of tangential load at 1.5 N/s. Figure 10. Comparison of deformations at the rear edge of contact for the different lubricating Figure 10. Comparison of deformations at the rear edge of contact for the different lubricating conditions. (a) Deformation of the rear edge for the central part lubricating condition; (b) Deformation conditions. (a) Deformation of the rear edge for the central part lubricating condition; (b) Deformation of the rear edge for the front part lubricating condition; (c) Deformation of the rear edge for the tail of the rear edge for the front part lubricating condition; (c) Deformation of the rear edge for the tail part lubricating condition. (d) Comparison of the maximum displacements of contact for the three part lubricating condition. (d) Comparison of the maximum displacements of contact for the three lubricating N normal normal load, load, with with aa 1.5 1.5 N/s N/s increasing lubricating conditions; conditions; the the tests tests were were conducted conducted under under 20 20 N increasing rate of tangential load. rate of tangential load. The above discussions may not completely explain the accurate lubricating effects among all of The above discussions may not completely explain the accurate lubricating effects among all of the experimental results. However, the results of this study suggest that the static friction behaviors the experimental results. However, the results of this study suggest that the static friction behaviors of of rubber are affected by different lubricating conditions. The maximum static friction decreases with rubber are affected by different lubricating conditions. The maximum static friction decreases with the lubrication of sea water. These results may provide experimental support for further systematic the lubrication of sea water. These results may provide experimental support for further systematic studies on tensioner design and more accurate investigation of the tribological behavior of static studies on tensioner design and more accurate investigation of the tribological behavior of static rubber contact. rubber contact. 5. Conclusions 5. Conclusions A series of experimental tests was carried out using a home-built friction instrument to A series of experimental tests was carried out using a home-built friction instrument to investigate investigate the static friction behaviors of contact between rubber and pipe. The maximum static the static friction behaviors of contact between rubber and pipe. The maximum static friction decreases friction decreases due to the lubrication of sea water; the extent of the decline ranges from 30% to due to the lubrication of sea water; the extent of the decline ranges from 30% to 45% for the relative 45% for the relative soft rubber compound; the range is not greater than 30% for the relative stiff soft rubber compound; the range is not greater than 30% for the relative stiff rubber compound. All rubber compound. All tests in this study are believed to be in the boundary lubrication condition. tests in this study are believed to be in the boundary lubrication condition. The water film can be seen The water film can be seen to weaken the adhesion effect of the contact system rather than changing to weaken the adhesion effect of the contact system rather than changing the deformation principle of the deformation principle of the rubber surface. The differences of frictions between 0.062 N/s and 1.5 N/s and the increasing rate of tangential load indicate that the effect of rubber’s viscoelastic property still works at the level of static friction for the lubricating conditions. Lubrication at the two side parts of contact shows lower efficiency than that in the central part of contact due to the different extent of lubricating film. Lubricants 2017, 5, 12 12 of 13 the rubber surface. The differences of frictions between 0.062 N/s and 1.5 N/s and the increasing rate of tangential load indicate that the effect of rubber’s viscoelastic property still works at the level of static friction for the lubricating conditions. Lubrication at the two side parts of contact shows lower efficiency than that in the central part of contact due to the different extent of lubricating film. Acknowledgments: This research is sponsored by the National Natural Science Foundation of China (No. 51375495), the Tribology Science Fund of State Key Laboratory of Tribology (No. SKLTKF14A08) and the Science Foundation of China University of Petroleum, Beijing (No. 2462017BJB06, C201602). Author Contributions: Yong-Jie Zhou set up the test devices, performed tribology, and wrote the manuscript; Yan-Bao Guo performed mechanical testing, analysis, and contributed in writing the manuscript; and De-Guo Wang conceived research, analyzed results. Conflicts of Interest: The authors declare no conflict of interest. References 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. Persson, B.N.; Albohr, O.; Tartaglino, U.; Volokitin, A.I.; Tosatti, E. On the nature of surface roughness with application to contact mechanics, sealing, rubber friction and adhesion. J. Phys. Condens. Matter 2004, 17, R1. [CrossRef] [PubMed] Cao, W. 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