SM-613-901 Set Samples High-Purity Standards Chemwatch Hazard Alert Code: 4 Catalogue number: SM-613-901 Set Samples Version No: 2.2 Safety Data Sheet according to OSHA HazCom Standard (2012) requirements Issue Date: 08/19/2015 Print Date: 08/19/2015 Initial Date: 08/19/2015 S.GHS.USA.EN SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name Synonyms Other means of identification SM-613-901 Set Samples SM-613-901 SM-613-901 Set Samples Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use according to manufacturer's directions. Details of the manufacturer/importer Registered company name Address Telephone Fax Website Email High-Purity Standards P.O. Box 41727 Charleston, SC 29423 United States (843) 767-7900 (843) 767-7906 highpuritystandards.com Not Available Emergency telephone number Association / Organisation INFOTRAC Emergency telephone numbers 800-535-5053 Other emergency telephone numbers Not Available SECTION 2 HAZARDS IDENTIFICATION Classification of the substance or mixture GHS Classification STOT - RE Category 2 Label elements GHS label elements SIGNAL WORD WARNING Hazard statement(s) H373 May cause damage to organs through prolonged or repeated exposure Precautionary statement(s) Prevention P260 Do not breathe dust/fume/gas/mist/vapours/spray. Continued... Catalogue number: SM-613-901 Set Samples Page 2 of 7 Version No: 2.2 SM-613-901 Set Samples Issue Date: 08/19/2015 Print Date: 08/19/2015 Precautionary statement(s) Response P314 Get medical advice/attention if you feel unwell. Precautionary statement(s) Storage Precautionary statement(s) Disposal P501 Dispose of contents/container to authorised chemical landfill or if organic to high temperature incineration SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition of Mixtures Mixtures CAS No %[weight] Name 9004-70-0 80-95 nitrocellulose 9004-35-7 0-10 cellulose acetate 1304-56-9 <0.1 beryllium oxide Beryllium is derived from either (Be4O(C2H3O2)6) or BeO. For this reason both sources are listed on the SDS. Refer to the product’s Certificate of Analysis to determine which source was used in the production of the lot number received. 543-81-7 <0.1 beryllium acetate 7732-18-5 balance water SECTION 4 FIRST AID MEASURES Description of first aid measures Eye Contact Skin Contact If this product comes in contact with eyes: Wash out immediately with water. If irritation continues, seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin or hair contact occurs: Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. Inhalation If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor. Ingestion Immediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Most important symptoms and effects, both acute and delayed See Section 11 Indication of any immediate medical attention and special treatment needed The material may induce methaemoglobinaemia following exposure. Initial attention should be directed at oxygen delivery and assisted ventilation if necessary. Hyperbaric oxygen has not demonstrated substantial benefits. Hypotension should respond to Trendelenburg's position and intravenous fluids; otherwise dopamine may be needed. Symptomatic patients with methaemoglobin levels over 30% should receive methylene blue. (Cyanosis, alone, is not an indication for treatment). The usual dose is 1-2 mg/kg of a 1% solution (10 mg/ml) IV over 50 minutes; repeat, using the same dose, if symptoms of hypoxia fail to subside within 1 hour. Thorough cleansing of the entire contaminated area of the body, including the scalp and nails, is of utmost importance. BIOLOGICAL EXPOSURE INDEX - BEI These represent the determinants observed in specimens collected from a healthy worker exposed at the Exposure Standard (ES or TLV): Determinant Index Sampling Time Comment 1. Methaemoglobin in blood 1.5% of haemoglobin During or end of shift B, NS, SQ B: Background levels occur in specimens collected from subjects NOT exposed NS: Non-specific determinant; also observed after exposure to other materials SQ: Semi-quantitative determinant - Interpretation may be ambiguous; should be used as a screening test or confirmatory test. SECTION 5 FIREFIGHTING MEASURES Extinguishing media There is no restriction on the type of extinguisher which may be used. Special hazards arising from the substrate or mixture Fire Incompatibility None known. Continued... Catalogue number: SM-613-901 Set Samples Page 3 of 7 Version No: 2.2 Issue Date: 08/19/2015 SM-613-901 Set Samples Print Date: 08/19/2015 Advice for firefighters Fire Fighting Fire/Explosion Hazard WARNING: EXPLOSIVE MATERIALS / ARTICLES PRESENT! Evacuate all personnel and move upwind. May emit poisonous fumes. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Minor Spills WARNING!: EXPLOSIVE. Major Spills WARNING!: EXPLOSIVE. Personal Protective Equipment advice is contained in Section 8 of the SDS. SECTION 7 HANDLING AND STORAGE Precautions for safe handling Safe handling Other information Handle gently. Store cases in a well ventilated magazine licenced for the appropriate Class, Division and Compatibility Group. Conditions for safe storage, including any incompatibilities Suitable container Storage incompatibility All packaging for Class 1 Goods shall be in accordance with the requirements of the relevant Code for the transport of Dangerous Goods. Store drums on end and invert them regularly (at least monthly) to avoid separation of the desensitising liquid. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Source US OSHA Permissible Exposure Levels (PELs) Table Z3 Ingredient nitrocellulose Material name Inert or Nuisance Dust TWA 5 mg/m3 / 15 mg/m3 / 15 mppcf / 50 mppcf STEL Not Available Peak Notes Not Available Respirable fraction;All inert or nuisance dusts, whether mineral, inorganic, or organic, not listed specifically by substance name are covered by this limit, which is the same as the Particulates Not Otherwise Regulated (PNOR) limit in Table Z-1. / Total dust;All inert or nuisance dusts, whether mineral, inorganic, or organic, not listed specifically by substance name are covered by this limit, which is the same as the Particulates Not Otherwise Regulated (PNOR) limit in Table Z-1. 0.1 mg/m3 Not Available Not Available See Table Z-3;less than 1% crystalline silica(respirable dust) / See Table Z-3;less than 1% crystalline silica, total dust / See Table Z-3;less than 1% crystalline silica, respirable dust / less than 1% crystalline silica;see 29 CFR 1910.1001;See Table Z-3;(containing asbestos); use asbestos limit; (STEL (Excursion limit)(as averaged over a sampling period of 30 minutes)) / less than 1% crystalline silica;See Table Z-3, (containing no asbestos), respirable dust / (as quartz), respirable dust;ess than 1% crystalline silica;see 1910.1001;(STEL (Excursion limit)(as averaged over a sampling period of 30 minutes)) US OSHA Permissible Exposure Levels (PELs) Table Z1 beryllium oxide Silicates - Mica / Silicates - Soapstone / Silicates- Soapstone / Silicates - Talc / Silicates - Tremolite, asbestiform US OSHA Permissible Exposure Levels (PELs) Table Z1 beryllium oxide Beryllium and beryllium compounds / Zirconium compounds 5 mg/m3 Not Available Not Available See Table Z-2;(as Be) / (as Zr) US OSHA Permissible Exposure Levels (PELs) Table Z2 beryllium oxide Beryllium and beryllium compounds 0.002 mg/m3 Not Available 0.005 mg/m3 (Z37.29–1970) US OSHA Permissible Exposure Levels (PELs) Table Z3 beryllium oxide Silicates: Mica / Silicates: Soapstone / Silicates: Talc / Silicates: Tremolite, asbestiforms 0.1 f/cc / 20 mppcf Not Available Not Available (less than 1% crystalline silica) / (containing asbestos) Use asbestos limit;(less than 1% crystalline silica) / (see 29 CFR 1910.1001);(less than 1% crystalline silica) US ACGIH Threshold Limit Values (TLV) beryllium oxide Beryllium and compounds, as Be / Beryllium and compounds, as Be Soluble compounds / Beryllium and compounds, as Be Soluble and insoluble compounds 0.00005 mg/m3 Not Available Not Available TLV® Basis: Beryllium sens; chronic beryllium disease (berylliosis) US OSHA Permissible Exposure Levels (PELs) Table Z1 beryllium acetate Silicates - Mica / Silicates - Soapstone / Silicates- Soapstone / Silicates - Talc / 0.1 mg/m3 Not Available Not Available See Table Z-3;less than 1% crystalline silica(respirable dust) / See Table Z-3;less than 1% crystalline silica, total dust / See Table Z-3;less than 1% crystalline silica, respirable dust / less than 1% crystalline silica;see 29 CFR 1910.1001;See Table Continued... Catalogue number: SM-613-901 Set Samples Page 4 of 7 Version No: 2.2 Issue Date: 08/19/2015 Print Date: 08/19/2015 SM-613-901 Set Samples Z-3;(containing asbestos); use asbestos limit; (STEL (Excursion limit)(as averaged over a sampling period of 30 minutes)) / less than 1% crystalline silica;See Table Z-3, (containing no asbestos), respirable dust / (as quartz), respirable dust;ess than 1% crystalline silica;see 1910.1001;(STEL (Excursion limit)(as averaged over a sampling period of 30 minutes)) Silicates - Tremolite, asbestiform US OSHA Permissible Exposure Levels (PELs) Table Z1 beryllium acetate Beryllium and beryllium compounds / Zirconium compounds 5 mg/m3 Not Available Not Available See Table Z-2;(as Be) / (as Zr) US OSHA Permissible Exposure Levels (PELs) Table Z2 beryllium acetate Beryllium and beryllium compounds 0.002 mg/m3 Not Available 0.005 mg/m3 (Z37.29–1970) US OSHA Permissible Exposure Levels (PELs) Table Z3 beryllium acetate Silicates: Mica / Silicates: Soapstone / Silicates: Talc / Silicates: Tremolite, asbestiforms 0.1 f/cc / 20 mppcf Not Available Not Available (less than 1% crystalline silica) / (containing asbestos) Use asbestos limit;(less than 1% crystalline silica) / (see 29 CFR 1910.1001);(less than 1% crystalline silica) beryllium acetate Beryllium and compounds, as Be / Beryllium and compounds, as Be Soluble compounds / Beryllium and compounds, as Be Soluble and insoluble compounds 0.00005 mg/m3 Not Available Not Available TLV® Basis: Beryllium sens; chronic beryllium disease (berylliosis) US ACGIH Threshold Limit Values (TLV) EMERGENCY LIMITS Ingredient Material name TEEL-1 TEEL-2 TEEL-3 nitrocellulose Pyroxylin; (Cellulose tetranitrate) 15 mg/m3 170 mg/m3 990 mg/m3 beryllium oxide Beryllium oxide 0.0063 mg/m3 0.069 mg/m3 0.28 mg/m3 Ingredient Original IDLH Revised IDLH nitrocellulose Not Available Not Available cellulose acetate Not Available Not Available beryllium oxide 10 mg/m3 4 mg/m3 beryllium acetate 10 mg/m3 4 mg/m3 water Not Available Not Available Exposure controls Appropriate engineering controls Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Personal protection Eye and face protection Skin protection Hands/feet protection Safety glasses with side shields Chemical goggles. See Hand protection below The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Body protection See Other protection below Other protection For handling explosives or explosive compositions: Wear close-fitting flame-protection treated clothing closed at the neck and sleeves. Thermal hazards Not Available Respiratory protection Particulate. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance Physical state white porous solid disks Solid Relative density (Water = 1) Not Available Not Available Not Available Odour Not Available Partition coefficient n-octanol / water Odour threshold Not Available Auto-ignition temperature (°C) Continued... Catalogue number: SM-613-901 Set Samples Page 5 of 7 Version No: 2.2 Issue Date: 08/19/2015 Print Date: 08/19/2015 SM-613-901 Set Samples pH (as supplied) Not Available Decomposition temperature Not Available Melting point / freezing point (°C) Not Available Viscosity (cSt) Not Available Initial boiling point and boiling range (°C) Not Available Molecular weight (g/mol) Not Available Flash point (°C) Not Available Taste Not Available Evaporation rate Not Available Explosive properties Not Available Flammability Not Available Oxidising properties Not Available Upper Explosive Limit (%) Not Available Surface Tension (dyn/cm or mN/m) Not Applicable Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available Vapour pressure (kPa) Not Available Gas group Not Available pH as a solution (1%) Not Available VOC g/L Not Available Solubility in water (g/L) Immiscible Vapour density (Air = 1) Not Available SECTION 10 STABILITY AND REACTIVITY Reactivity Chemical stability See section 7 Unstable in the presence of incompatible materials. Possibility of hazardous reactions See section 7 Conditions to avoid See section 7 Incompatible materials See section 7 Hazardous decomposition products See section 5 SECTION 11 TOXICOLOGICAL INFORMATION Information on toxicological effects Inhaled Ingestion Skin Contact Eye Chronic Inhalation of dusts, generated by the material, during the course of normal handling, may be harmful. The material is not thought to produce adverse health effects following ingestion (as classified by EC Directives using animal models). Skin contact is not thought to produce harmful health effects (as classified under EC Directives using animal models). Although the material is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may cause transient discomfort characterised by tearing or conjunctival redness (as with windburn). Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure. TOXICITY IRRITATION Not Available Not Available SM-613-901 Set Samples nitrocellulose TOXICITY IRRITATION Oral (rat) LD50: >5000 mg/kg [2] Not Available TOXICITY IRRITATION Not Available Not Available cellulose acetate TOXICITY beryllium oxide Oral (rat) LD50: >2000 mg/kg IRRITATION [1] Not Available TOXICITY IRRITATION Not Available Not Available beryllium acetate TOXICITY water Oral (rat) LD50: >90000 mg/kg Legend: BERYLLIUM OXIDE IRRITATION [2] Not Available 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances Chronic pulmonary oedema, respiratory tract tumours, effects on fertility, foetotoxicity, specific developmental abnormalities, multiple enzyme effects recorded. Continued... Catalogue number: SM-613-901 Set Samples Version No: 2.2 Page 6 of 7 Issue Date: 08/19/2015 SM-613-901 Set Samples SM-613-901 Set Samples & NITROCELLULOSE & CELLULOSE ACETATE & WATER BERYLLIUM OXIDE & BERYLLIUM ACETATE Print Date: 08/19/2015 No significant acute toxicological data identified in literature search. The following information refers to contact allergens as a group and may not be specific to this product. Acute Toxicity Carcinogenicity Skin Irritation/Corrosion Reproductivity Serious Eye Damage/Irritation STOT - Single Exposure Respiratory or Skin sensitisation STOT - Repeated Exposure Mutagenicity Aspiration Hazard – Data required to make classification available – Data available but does not fill the criteria for classification – Data Not Available to make classification Legend: SECTION 12 ECOLOGICAL INFORMATION Toxicity Cellulosic products, includingcellulose ethers, generally have a low biodegradation rate and are generally oflow toxicity to fish. Persistence and degradability Ingredient Persistence: Water/Soil Persistence: Air water LOW LOW Bioaccumulative potential Ingredient Bioaccumulation water LOW (LogKOW = -1.38) Mobility in soil Ingredient Mobility water LOW (KOC = 14.3) SECTION 13 DISPOSAL CONSIDERATIONS Waste treatment methods Product / Packaging disposal Explosives which are surplus, deteriorated or considered unsafe for transport, storage or use shall be destroyed and the statutory authorities shall be notified. SECTION 14 TRANSPORT INFORMATION Labels Required Marine Pollutant NO Land transport (DOT): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS SECTION 15 REGULATORY INFORMATION Safety, health and environmental regulations / legislation specific for the substance or mixture NITROCELLULOSE(9004-70-0) IS FOUND ON THE FOLLOWING REGULATORY LISTS International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List Passenger and Cargo Aircraft US - California OEHHA/ARB - Chronic Reference Exposure Levels and Target Organs (CRELs) US - California Permissible Exposure Limits for Chemical Contaminants US - Hawaii Air Contaminant Limits US - Michigan Exposure Limits for Air Contaminants US - Oregon Permissible Exposure Limits (Z-1) US - Tennessee Occupational Exposure Limits - Limits For Air Contaminants US - Washington Permissible exposure limits of air contaminants US - Wyoming Toxic and Hazardous Substances Table Z1 Limits for Air Contaminants US OSHA Permissible Exposure Levels (PELs) - Table Z3 US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory CELLULOSE ACETATE(9004-35-7) IS FOUND ON THE FOLLOWING REGULATORY LISTS US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory Continued... Catalogue number: SM-613-901 Set Samples Version No: 2.2 Page 7 of 7 SM-613-901 Set Samples Issue Date: 08/19/2015 Print Date: 08/19/2015 BERYLLIUM OXIDE(1304-56-9) IS FOUND ON THE FOLLOWING REGULATORY LISTS International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs US - Alaska Limits for Air Contaminants US - California - Proposition 65 - Priority List for the Development of MADLs for Chemicals Causing Reproductive Toxicity US - California OEHHA/ARB - Chronic Reference Exposure Levels and Target Organs (CRELs) US - California Permissible Exposure Limits for Chemical Contaminants US - California Proposition 65 - Carcinogens US - California Proposition 65 - No Significant Risk Levels (NSRLs) for Carcinogens US - Hawaii Air Contaminant Limits US - Idaho - Acceptable Maximum Peak Concentrations US - Idaho - Limits for Air Contaminants US - Michigan Exposure Limits for Air Contaminants US - Minnesota Permissible Exposure Limits (PELs) US - New Jersey Right to Know - Special Health Hazard Substance List (SHHSL): Carcinogens US - Oregon Permissible Exposure Limits (Z-1) US - Oregon Permissible Exposure Limits (Z-2) US - Tennessee Occupational Exposure Limits - Limits For Air Contaminants US - Vermont Permissible Exposure Limits Table Z-1-A Final Rule Limits for Air Contaminants US - Vermont Permissible Exposure Limits Table Z-1-A Transitional Limits for Air Contaminants US - Washington Permissible exposure limits of air contaminants US - Washington Toxic air pollutants and their ASIL, SQER and de minimis emission values US - Wyoming Toxic and Hazardous Substances Table Z1 Limits for Air Contaminants US - Wyoming Toxic and Hazardous Substances Table Z-2 Acceptable ceiling concentration, Acceptable maximum peak above the acceptable ceiling concentration for an 8-hr shift US ACGIH Threshold Limit Values (TLV) US ACGIH Threshold Limit Values (TLV) - Carcinogens US EPA Carcinogens Listing US EPCRA Section 313 Chemical List US National Toxicology Program (NTP) 13th Report Part A Known to be Human Carcinogens US OSHA Permissible Exposure Levels (PELs) - Table Z1 US OSHA Permissible Exposure Levels (PELs) - Table Z2 US OSHA Permissible Exposure Levels (PELs) - Table Z3 US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory BERYLLIUM ACETATE(543-81-7) IS FOUND ON THE FOLLOWING REGULATORY LISTS International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs US - Alaska Limits for Air Contaminants US - California OEHHA/ARB - Chronic Reference Exposure Levels and Target Organs (CRELs) US - California Permissible Exposure Limits for Chemical Contaminants US - Hawaii Air Contaminant Limits US - Idaho - Acceptable Maximum Peak Concentrations US - Idaho - Limits for Air Contaminants US - Michigan Exposure Limits for Air Contaminants US - Minnesota Permissible Exposure Limits (PELs) US - Oregon Permissible Exposure Limits (Z-1) US - Oregon Permissible Exposure Limits (Z-2) US - Tennessee Occupational Exposure Limits - Limits For Air Contaminants US - Vermont Permissible Exposure Limits Table Z-1-A Final Rule Limits for Air Contaminants US - Vermont Permissible Exposure Limits Table Z-1-A Transitional Limits for Air Contaminants US - Washington Permissible exposure limits of air contaminants US - Washington Toxic air pollutants and their ASIL, SQER and de minimis emission values US - Wyoming Toxic and Hazardous Substances Table Z1 Limits for Air Contaminants US - Wyoming Toxic and Hazardous Substances Table Z-2 Acceptable ceiling concentration, Acceptable maximum peak above the acceptable ceiling concentration for an 8-hr shift US ACGIH Threshold Limit Values (TLV) US ACGIH Threshold Limit Values (TLV) - Carcinogens US EPA Carcinogens Listing US EPCRA Section 313 Chemical List US National Toxicology Program (NTP) 13th Report Part A Known to be Human Carcinogens US OSHA Permissible Exposure Levels (PELs) - Table Z1 US OSHA Permissible Exposure Levels (PELs) - Table Z2 US OSHA Permissible Exposure Levels (PELs) - Table Z3 WATER(7732-18-5) IS FOUND ON THE FOLLOWING REGULATORY LISTS US Toxic Substances Control Act (TSCA) - Chemical Substance Inventory National Inventory Status Australia - AICS N (beryllium acetate) Canada - DSL N (beryllium oxide; beryllium acetate) Canada - NDSL N (nitrocellulose; water; beryllium acetate) China - IECSC N (beryllium acetate) Europe - EINEC / ELINCS / NLP N (cellulose acetate; nitrocellulose) Japan - ENCS N (water; beryllium acetate) Korea - KECI N (beryllium acetate) New Zealand - NZIoC N (beryllium acetate) Philippines - PICCS N (beryllium oxide; beryllium acetate) USA - TSCA N (beryllium acetate) Legend: Y = All ingredients are on the inventory N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets) SECTION 16 OTHER INFORMATION Other information Ingredients with multiple cas numbers Name CAS No cellulose acetate 9004-35-7, 9035-69-2 Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. This document is copyright. end of SDS
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