Section 5 / Sect5pp.doc / S. W. Tse / P.1 85 Q.22 Which of the following hydrocarbons would most probably be present in petrol? A. C. C2H6 C4H10 B. D. C4H8 C6H14 86 Q.45 glass wool soaked with X heat broken porcelain gas(es) that decolorize(s) acidified KMnO4 heat In the above experiment, X can be (1) crude oil. (2) propan-1-ol. (3) medicinal paraffin. A. C. (1) only (1) and (3) only B. D. (2) only (1), (2) and (3) only 87 Q.18 Liquefied petroleum gas (LPG) consists mainly of A. C. butane. hydrogen. B. D. carbon monoxide. methane. 87 Q.27 The following is a series reactions starting from ethanol: reagent A Na2CO3(aq) ethanol P CO2(g) + Q Which of the following correctly describes the nature of reagent A and the product Q? A. B. C. D. Reagent A dehydrating agent dehydrating agent oxidizing agent oxidizing agent Product Q ethene ethane sodium ethanoate ethanoic acid Section 5 / Sect5pp.doc / S. W. Tse / P.2 87 Q.36 Cracking is an important process in the petroleum industry. 1st statement A. True B. True C. True/False D. False 2nd statement True True False/True False Cracking can separate the light fractions of crude oil from the heavy fractions. 2nd statement is a correct explanation of the 1st one. 2nd statement is NOT a correct explanation of the 1st one. Only ONE of the statements is true, the other is false. ----- 87 Q.44 Which of the following molecular formulae can have isomeric structures? (1) C2H3Cl (2) C3H8O (3) C4H8 A. C. (1) and (2) only (2) and (3) only B. D. (1) and (3) only (1), (2) and (3) 87 Q.46 C3H8(g) + 2Br2(g) → C3H6Br2(l) + 2HBr(g) The above reaction can be classified as (1) an addition reaction. (2) a substitution reaction. (3) a redox reaction. A. C. (1) only (1) and (3) only B. D. (2) only (2) and (3) only 87 Q.47 Which of the following would be present in a higher concentration inside the Cross Harbour Tunnel than in the atmosphere? (1) carbon monoxide (2) carbon dioxide (3) nitrogen dioxide (4) lead compounds A. (1) and (2) only B. (1), (3) and (4) only C. (2), (3) and (4) only D. (1), (2), (3) and (4) 88 Q.21 The number of structural isomers having the same molecular formula C4H9Br is A. C. 2. 4. B. D. 3. 5. Section 5 / Sect5pp.doc / S. W. Tse / P.3 88 Q.50 Which of the following would NOT reduce the amount of pollutants in the atmosphere? A. B. C. D. reducing the lead content of gasoline. using fuels of low sulphur content. building tall chimneys for factories and incinerators. installing filters and electrostatic precipitators in factory and incinerator chimneys. 89 Q.49 Which of the following experimental procedures would NOT be carried out in the laboratory? A. B. C. D. Cutting sodium metal with a knife under paraffin oil. Adding a 1 cm3 piece of potassium metal to a beaker of 2M hydrochloric acid. Adding concentrated sulphuric acid to copper(II) sulphate crystals in a test-tube using a dropper. Mixing bromine water with tetrachloromethane in a boiling tube. 90 Q.6 The boiling points of some hydrocarbons are given in the table below: Hydrocarbon Ethane Ethene Propene o Boiling point ( C) -89 -104 -48 If a mixture of these three hydrocarbons at -110oC is allowed to warm up gradually to -80oC, which of the following will happen? A. B. C. D. Ethene will remain in the liquid state. Propene will remain in the liquid state. Ethane and ethene will remain in the liquid state. Ethane, ethene and propene will exist in the gaseous state. 90 Q.34 What is the total no. of isomers for an alkanol having the chemical formula C4H9OH? A. C. 2 4 B. D. 3 5 90 Q.36 Which of the following tests can be used to distinguish between ethane and ethene? (1) burning the gas in air (2) bubbling the gas through bromine in tetrachloromethane (3) bubbling the gas through acidified potassium permanganate solution A. C. (1) and (2) only (2) and (3) only B. D. (1) and (3) only (1), (2) and (3) Section 5 / Sect5pp.doc / S. W. Tse / P.4 91 Q.24 The IUPAC name for is H H H Br H C C C C H Br H A. C. 3-dibromobut-1-ene. 3,3-dibromobut-1-ene. B. D. 2-dibromobut-4-ene. 2,2-dibromobut-4-ene. 91 Q.25 Which of the following statements about structural isomers is correct? A. B. C. D. They have the same molecular formula but different empirical formulae. They have the same molecular formula but different structural formulae. They have the same empirical formula but different molecular formulae. They have the same empirical formula but different structural formulae. 91 Q.34 The rain-water samples collected in Tsuen Wan District are found to be more acidic than those collected in Central District. Which of the following air pollutants would be responsible for this phenomenon? (1) carbon monoxide (2) sulphur dioxide (3) nitrogen dioxide A. C. (2) only (1) and (2) only B. D. (3) only (1) and (3) only 91 Q.36 Equal moles of chlorine and methane are allowed to react in diffused sunlight. Which of the following statements concerning the reaction is / are correct? (1) The reaction is violent. (2) The final contains CH3Cl and HCl only. (3) The final product contains CH3Cl, CH2Cl2, CHCl3, CCl4 and HCl. A. C. (1) only (1) and (2) only B. D. (2) only (1) and (3) only 92 Q.24 Which of the following statements concerning CH3CH3, CH3CH2CH3 and CH3CH(CH3)CH3 is correct? A. They have different boiling points. B. They belong to different homologous series. C. They burn in excess oxygen to form carbon monoxide and water. D. They readily decolorize bromine in tetrachloromethane. Section 5 / Sect5pp.doc / S. W. Tse / P.5 92 Q.44 Which of the following pollutants are found in the exhaust from cars using petrol as fuel? (1) CO (2) SO2 (3) NO2 A. (1) and (2) only B. (1) and (3) only C. (2) and (3) only D. (1), (2) and (3) 93 Q.29 catalyst C10H22 C6H14 + 2X heat In the above process, which of the following combinations is correct? Process X A. fractional distillation an alkane B. fractional distillation an alkene C. cracking an alkane D. cracking an alkene 93 Q.32 Which of the following substances can react with propene? (1) concentrated sodium hydroxide solution. (2) acidified potassium permanganate solution (3) ethanol A. C. (1) only (1) and (3) only B. D. (2) only (2) and (3) only 93 Q.33 Which of the following statements about fossils fuels is correct? A. B. C. D. They are liquids or gases. They are all formed from plants which died millions of years ago. They can be recycled to help converse energy resources. They cause air pollution when burnt. 93 Q.48 When car exhaust gases are bubbled into citrated blood, the colour of the blood gradually becomes cherry red. A. B. C. D. 1st statement True True True/False False 2nd statement True True False/True False Nitrogen dioxide is present in car exhaust gases. 2nd statement is a correct explanation of the 1st one. 2nd statement is NOT a correct explanation of the 1st one. Only ONE of the statements is true, the other is false. ----- Section 5 / Sect5pp.doc / S. W. Tse / P.6 Directions: Questions 94 Q.22 and 94 Q.23 refer to the following diagram which shows a fractionating column of an oil refinery. fraction P fraction Q fraction R fraction S vapour of crude oil fraction T fraction U 94 Q.22 Which of the following fraction is NOT cracked to produce more useful products? A. C. P S B. D. R T 94 Q.23 Which of the following statements is correct? A. B. C. D. Fraction P has the highest boiling point. Fraction T is used for surfacing roads. Fraction U is the least viscous. Fraction S burns with a more sooty flame than fraction Q. 94 Q.40 Compounds X and Y have the following structures: CH3 H H H H H H C C C H H C C C H H H CH3 X H H H Y Which of the following statements about compounds X and Y are correct? (1) They have the same boiling point. (2) They belong to the same homologous series. (3) They are isomers. A. (1) and (2) only B. (1) and (3)only C. (2) and (3) only D. (1), (2) and (3) Section 5 / Sect5pp.doc / S. W. Tse / P.7 95 Q.15 The structural formula of a certain compound is shown below. H H C H H H H C C C H H H OH The name of this compound is A. C. butan-1-ol. 2-methylpropan-1-ol B. D. butan-2-ol 2-methylpropan-2-ol 95 Q.23 Which of the following substances can cause acid rain? A. B. C. D. lead compounds from the burning of leaded petrol in motor cars carbon dioxide from the complete combustion of town gas carbon soots from the incomplete combustion of coal nitrogen dioxide from the burning of fuels in power stations 95 Q.29 Which of the following compounds have the same empirical formula? (1) ethene (2) ethane (3) propene (4) propane A. (1) and (2) only B. (1) and (3) only C. (2) and (4) only D. (3) and (4) only 95 Q.42 Which of the following products may be formed from the cracking of heavy oil fraction? (1) CO (2) C2H4 (3) C8H18 A. (1) and (2) only B. (1) and (3) only C. (2) and (3) only D. (1), (2) and (3) 95 Q.43 Which of the following are characteristics of a homologous series? (1) Members of the series can be represented by the same general formula. (2) Members of the series have same physical properties. (3) Members of the series have similar chemical properties. A. (1) and (2) only B. (1) and (3) only C. (2) and (3) only D. (1), (2) and (3) Section 5 / Sect5pp.doc / S. W. Tse / P.8 95 Q.48 Huge quantities of carbon dioxide produced by the burning of fossil fuels cause the greenhouse effect. 1st statement A. True B. True C. True/False D. False 2nd statement True True False/True False Carbon dioxide can trap the solar energy which is re-radiated from the earth‘s surface to the atmosphere. 2nd statement is a correct explanation of the 1st one. 2nd statement is NOT a correct explanation of the 1st one. Only ONE of the statements is true, the other is false. ----- 96 Q.20 Which of the following methods can be used to minimize the air pollutant mentioned? A. increasing the air supply to remove nitrogen dioxide produced by burning heavy oil B. using catalytic converters to remove lead compounds produced by burning leaded petrol C. using scrubbers to remove carbon monoxide produced by the incomplete combustion of diesel D. using electrostatic precipitators to remove particulates produced by burning coal 96 Q.48 The cost of town gas goes up when the cost of crude oil rises. 1st statement A. True B. True C. True/False D. False 2nd statement True True False/True False Town gas is manufactured from naphtha. 2nd statement is a correct explanation of the 1st one. 2nd statement is NOT a correct explanation of the 1st one. Only ONE of the statements is true, the other is false. ----- 97 Q.16 Which of the following compounds represents the first member of a homologous series? A. C. ethane ethanol B. D. ethene ethanoic acid Section 5 / Sect5pp.doc / S. W. Tse / P.9 97 Q.18 The model shown below represents a compound containing 6 hydrogen atoms (white spheres) and 3 carbon atoms (black spheres). Which of the following statements concerning the compound is INCORRECT? A. Its structural formula is C3H6. B. It can be prepared by cracking petroleum fractions. C. It can decolourize bromine in 1,1,1-trichloroethane. D. It can undergo polymerization. 97 Q.19 Which of the following compounds CANNOT be produced directly from ethene? A. carbon dioxide B. ethanol C. ethyl ethanoate D. 1,2-dibromoethane Directions: 97 Q.23 and Q.24 refer to the following experiment: broken porcelain delivery tube rocksil soaked with medicinal paraffin heat 97 Q.23 Which of the following set-up should be connected to the delivery tube to collect the gaseous products formed? A. B. C. D. ice Section 5 / Sect5pp.doc / S. W. Tse / P.10 97 Q.24 Which of the following reaction is involved in this experiment? A. C. cracking catalytic hydration B. D. redox destructive distillation 97 Q.33 Which of the following statements concerning the reaction of methane with bromine is / are correct? (1) It is an addition reaction. (2) It is a substitution reaction. (3) A similar reaction will occur if propane is used instead of methane. A. C. (1) only (1) and (3) only B. D. (2) only (2) and (3) only 97 Q.38 Which of the following statements about ethanol as a car fuel is correct? (1) Ethanol is a cleaner fuel than petrol. (2) Using ethanol as a car fuel is economical in agricultural countries with sugar cane as the main crop. (3) A car engine has to be suitably modified when using ethanol as fuel. A. C. (1) and (2) only (2) and (3) only B. D. (1) and (3) only (1), (2) and (3) 97 Q.42 Which of the following measures can reduce the formation of acid rain? (1) installing catalytic oxidizers in cars (2) using unleaded petrol in cars (3) using fuels of low sulphur content in cars A. C. (1) and (2) only (2) and (3) only B. D. (1) and (3) only (1), (2) and (3) 98 Q.3 Which of the following substances is the main constituent of town gas? A. C. hydrogen carbon monoxide B. D. methane gaseous naphtha 98 Q.7 Which of the following environmental problems is NOT caused by excessive burning of fossil fuels? A. C. the corrosion of marble statues a higher incidence of liver diseases B. D. the formation of smog global warming Section 5 / Sect5pp.doc / S. W. Tse / P.11 98 Q.17 Which of the following statements concerning the compounds C2H4, C3H6 and C4H10 is correct? A. C. They belong to the same homologous series. They are gases at room temperature and pressure. B. They are unsaturated hydrocarbons. D. They have the same physical properties. 98 Q.29 X is a compound containing four carbon atoms. It gives negative results with the following tests. The structural formula of X may be A. B. C. D. 98 Q.39 The diagram below shows a catalytic converter fitted to the exhaust system of a car. Which of the following pollutants from the car engine undergo reactions in the catalytic converter to produce less harmful products? (1) carbon monoxide (2) hydrocarbons (3) nitrogen monoxide A. C. (1) and (2) only (2) and (3) only B. D. (1) and (3) only (1), (2) and (3) Section 5 / Sect5pp.doc / S. W. Tse / P.12 98 Q.47 The use of leaded petrol has been banned in Hong Kong. 1st statement A. True B. True C. True/False D. False 2nd statement True True False/True False Lead compounds in car exhaust can cause damage to human brains. 2nd statement is a correct explanation of the 1st one. 2nd statement is NOT a correct explanation of the 1st one. Only ONE of the statements is true, the other is false. ----- 99 Q.30 Which of the following combinations is INCORRECT? A. B. C. D. Pollutant hydrocarbons carbon monoxide lead compounds carbon particles Harmful effect causing liver diseases causing unconsciousness causing brain damage causing respiratory diseases 99 Q.32 Which of the following substances can react with acidified potassium permanganate solution? (1) ethene (2) copper(II) sulphate solution (3) iron(II) sulphate solution A. C. (1) only (1) and (3) only B. D. (2) only (2) and (3) only 99 Q.44 Which of the following statements concerning the reaction of an alkane with bromine are correct? (1) The reaction occurs faster under sunlight than in darkness. (2) The reaction is a substitution reaction. (3) The colour of the reaction mixture fades. A. C. (1) and (2) only (2) and (3) only B. D. (1) and (3) only (1), (2) and (3) 99 Q.49 Water-type fire extinguisher is suitable Water can cut off the supply of oxygen for putting out a fire caused by kerosene. for a fire caused by kerosene. 1st statement 2nd statement A. True True 2nd statement is a correct explanation of the 1st one. B. True True 2nd statement is NOT a correct explanation of the 1st one. C. True/False False/True Only ONE of the statements is true, the other is false. D. False False ----- Section 5 / Sect5pp.doc / S. W. Tse / P.13 00 Q.6 Which of the following pairs of compounds can be distinguished by treating with an acidified potassium dichromate solution? A. C. ethane and ethene sodium carbonate and sodium hydrogencarbonate B. D. ethanol and propan-l-ol sodium sulphite and sodium sulphate 00 Q.8 Which of the following statements concerning members of a homologous series is INCORRECT? A. B. C. D. They contain carbon and hydrogen only. They can be represented by the same general formula. They have similar chemical properties. Their boiling points increase with their relative molecular masses. 00 Q.26 Which of the following combinations is correct? A. B. C. D. Type of fire electrical fire electrical fire kerosene fire kerosene fire Type of fire extinguisher to use water foam water foam 00 Q.27 Which of the following changes occurs in a catalytic converter installed in a motor car? A. B. C. D. Nitrogen monoxide changes to nitrogen dioxide. Carbon monoxide changes to carbon dioxide. Unburnt hydrocarbons change to carbon particles. Sulphur changes to sulphur dioxide. 00 Q.40 Which of the following measures can reduce the emission of pollutants from a coal-fired power station? (1) installation of scrubbers (2) installation of electrostatic precipitators (3) increasing the height of the chimney A. C. (1) and (2) only (2) and (3) only B. D. (1) and (3) only (1), (2) and (3) Section 5 / Sect5pp.doc / S. W. Tse / P.14 01 Q.14 Which of the following pairs is correctly matched? A. B. C. D. Pollutant carbon monoxide sulphur dioxide lead compounds unburnt hydrocarbons Effect global warming darkening of building walls liver disease lung cancer 01 Q.32 The formulae of three straight-chain hydrocarbons are listed below: (1) C2H6 (2) C3H6 (3) C4H8 Which of these hydrocarbons is/are unsaturated? A. C. (1) and (2) only (2) and (3) only B. D. (1) and (3) only (1), (2) and (3) 02 Q.9 Which of the following equations represents a cracking reaction? A. B. C. D. C4H8 +H2 → C4H10 C4H10 → C3H6 + CH4 C6H12O6 → 2C2H5OH + 2CO2 C4H9OH → C4H8 + H2O 02 Q.11 Which of the following petroleum fractions has supply that outweighs the demand in modern society? A. C. fuel gases Petrol B. D. kerosene heavy oil 02 Q.34 Upon complete combustion, gaseous hydrocarbon X gives an equal number of moles of carbon dioxide and water. Which of the following hydrocarbons may X be? (1) ethane (2) ethene (3) propene A. C. (1) only (1) and (3) only B. D. (2) only (2) and (3) only Section 5 / Sect5pp.doc / S. W. Tse / P.15 02 Q.40 Which of the following gasses can cause global warming? (1) (2) (3) A. C. methane carbon dioxide chlorofluorocarbons (1) and (2) only (2) and (3) only B. D. (1) and (3) only (1), (2) and (3) 02 Q.44 Both ethene and ethyne are gaseous hydrocarbons. Their structures are shown below: Which of the following statements concerning ethene and ethyne are correct? (1) (2) (3) A. C. Both are unsaturated hydrocarbons. Both are insoluble in water. Ethyne burns with a more sooty frame than ethene. (1) and (2) only (2) and (3) only B. D. 02 Q.50 A foam extinguisher is suitable for putting out electrical fires. 1st statement A. True B. True C. True/False D. False 2nd statement True True False/True False The foam from a foam extinguisher is an electrical insulator. 2nd statement is a correct explanation of the 1st one. 2nd statement is NOT a correct explanation of the 1st one. Only ONE of the statements is true, the other is false. ----- 03 Q.8 Which of the following combinations is correct? A. B. C. D. Homologous series alkanes alkenes alkanols alkanoic acids (1) and (3) only (1), (2) and (3) General formula CnH2n CnH2n+2 CnH2nOH CnH2n+1CO2H Section 5 / Sect5pp.doc / S. W. Tse / P.16 03 Q.33 Ethane reacts with bromine under suitable conditions. Which of the following statements concerning this reaction is/are correct? (1) (2) (3) A. C. The reaction occurs readily in the dark. The reaction is a substitution. The reaction gives a mixture of organic products. (1) only (1) and (3) only B. D. (2) only (2) and (3) only 03 Q.37 Which of the following statements concerning the manufacture of town gas in Hong Kong is/are correct? (1) (2) (3) A. C. Town gas is produced from coal. Town gas contains hydrogen as the major component. Oxygen is added to enhance the flammability of town gas prior to its delivery to consumers. (1) only (1) and (3) only B. D. (2) only (2) and (3) only Section 5 / Sect5pp.doc / S. W. Tse / P.17 M.C. Answer 85 22 94 22 23 40 03 8 33 37 D A D C 86 45 95 15 23 29 42 43 48 D C D B C B A 87 18 27 36 44 46 47 96 20 48 A C C C D D D A 88 21 50 97 16 18 19 23 24 33 38 42 C C B A C D A D D B 89 49 98 3 7 17 29 39 47 B A C C D D C 90 6 34 36 99 30 32 44 49 B C C 91 24 25 34 36 A C D D 00 6 8 26 27 40 C B A D D A D B A 92 24 44 01 14 32 A B D D 93 29 32 33 48 D B D B 02 9 11 34 40 44 50 B D D D D D
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