C:\ DATA\B9907009\ARO002.RAW
V3/9/99
Software Version:
Sample Name:
Instrument:
Raw Data File:
Sequence File:
Aromatics GC
Component
Name
1-MENAPTHALENE
2-MENAPTHALENE
2,6+2,7-DIMETHYLNAPT
1,3+1,7-DIMETHYLNAPT
1,6-DIMETHYLNAPTHALE
1,5+1,5+2,3-DIMETHYL
1,2-DIMETHYLNAPTHALE
4.1<OG07>
9907SED009S002 34/11-4 3924m
SAC_GC
C:\_DATA\B9907009\AR0002.RAW
C:\_DATA\B9907008\ARO.SEQ
Time
[min]
9.3
9.522
10.918
11.093
3-ME PHENANTHRENE
2-ME PHENANTHRENE
9-ME PHENANTHRENE
1-ME PHENANTHRENE
Area
Area
[uV-s]
[%1
29146
27702.5
29032.3
28736.49
24634.98
2943.87
27581.4
11.14
11.15
11.377
11.57
12.26
12.474
12.543
12.612
9251.8
10192.43
17332.65
20522.92
24720.25
13259.8
28803.15
10199.51
15721.09
6205.91
8122.23
13202.36
18262.6
12415.12
12977.48
0
23230.03
21259.77
0
24297.8
6320.5
9922.6
6211.8
8719.7
92.72
5.94
5.64
5.91
5.85
5.02
0.6
5.62
0
1.88
2.08
3.53
4.18
5.03
2.7
5.87
2.08
3.2
1.26
1.65
2.69
3.72
2.53
2.64
0
4.73
4.33
0
4.95
1.29
2.02
1.27
1.78
0.02
491021.8
100
0
12.803
PHENANTHRENE
9907SED009S002
12.857
13.028
13.182
13.303
14.554
14.612
14.691
15.498
16.808
16.86
16.91
17.058
17.112
17.168
18.281
18.343
19.649
22.143
23.169
33.784
Page 1
GC-MS PEAK HEIGHT DATA
PEAK HEIGHTS
MPDMIO0085302 1 .US
34/1 1-4 3924m
$9907SED009S002$
PRISTANE
PHYTANE
C19 TRICYCLIC TERPANE(19/3
C20 TRICYCLIC TERPANE(20/3
C21 TRICYCLIC TERPANE(21/3
C22 TRICYCLIC TERPANE(22/3
C23 TRICYC TERPANE(T5:23/3
C24 TRICYC TERPANE (24/3)
C25 TRICYC TERPANE (25/3)
C24 TETRACYC TERP ($:24/4)
C26 TRICYCLIC TERPANE(26/3
C26 TRICYCLIC TERP 2 (26/3)
C28 TRICYCLIC TERPANE(28/3
C28 TRICYCLIC TERP 2 (28/3)
C29 TRICYCLIC TERPANE(29/3
C29 TRICYCLIC TERP 2 (29/3)
C2718AHOPANE (Ts:27Ts)
C2717AHOPANE (Tm:27Tm)
C30 TRICYCLIC TERPANE(30/3
C30 TRICYCLIC TERP 2 (30/3)
25-TRISNORm/zl 77(25nor28ab)
C28 BISNORHOPANE (X:28ab
25-NOR m/z!77 (Y:25nor30ab)
25-NORHOPANE (Y:25nor30ab)
C29 HOPANE
(D:29ab)
C29 18A NORHOPANE (D2:29T
C30 C30 DIAHOPANE (PI:30d)
C29 NORMORETANE (A:29ba
C30 18A OLEANANE (B:30O)
C30 HOPANE
(G:30ab)
NOR-GAMMACERANE?
(G
C30 MORETANE
(K:30ba)
C3122S HOPANE (N:31abS)
C3122R HOPANE (O:31abR)
C3122SM/Z205
(N205)
C3122RM/Z205
(O205)
C30 GAMACERANE (S:30G)
C30 1 7B 2 1 B HOPANE (P)
C3222S HOPANE (U:32abS)
C3222R HOPANE (V:32abR)
C33 22S HOPANE(Alpha:33abS)
C33 22R HOPANE (Beta:33abR)
C34 22S HOPANE(Gamma:34abS
C34 22R HOPANE(Delta:34abR)
C35 22S HOP (Epsilon:35abS)
C35 22R HOPANE (Zeta:35abR)
C21 STERANE
C27 20S DIASTER (10:27dbS)
C27 20R DIASTER (1 1 :27dbR)
C27 20S AAA STER (20:27aaS)
C29 20S DIASTER (21 A:29dbS)
C27 20R ISOST218(21B:27bbR)
C27 20S ISOST218 (22:27bbS)
C27 20R ISOSTER 217 (27bbR)
C27 20S ISOSTER 217 (27bbS)
C27 20R AAA STER (25:27aaR)
C29 20R DIASTER (27:29dbR)
C28 20R ISOST218(33A:28bbR)
C28 20S ISOST218 (34:28bbS)
C28 20R ISOSTER 217 (28bbR)
C28 20S ISOSTER 217 (28bbS)
C28 20R AAA STER (36:28aaR)
C29 20S AAA STER (39:29aaS)
C29 20R ISOST218 (40:29bbR)
C29 20S ISOST218 (41:29bbS)
C2920RISOSTER217 (29bbR)
C2920SISOSTER217 (29bbS)
C29 20R AAA STER (42:29aaR)
C3020RISOSTER218 (30bbR)
C3020SISOSTER218 (30bbS)
C30 4-METHYL STERANE (46)
19564600
20323600
1569050
862106
1252200
208962
1604730
1473390
746312
1340290
895869
620571
854797
880817
1386540
1009990
9559550
4322190
0
0
0
1116850
0
0
2777310
5862200
6928410
708615
0
10253000
0
1049530
4496440
3234250
1608030
1362040
0
1212300
3920060
2746150
2451730
2043190
1637930
1169950
1260110
894573
4124150
7553170
5047430
1656300
4825950
2364620
1765420
4825950
1508400
1076470
3693290
2003150
1888530
2785880
1652490
357095
1394190
1875480
1963280
1705080
1635550
662809
799118
805053
389311
GC-MS PEAK HEIGHT DATA
MPDMI000853021.LIS
PEAK HEIGHTS
2-ME NAPHTHALENE
1-ME NAPHTHALENE
2-ME BIPHENYL
3-ME BIPHENYL
4-ME BIPHENYL
PHENANTHRENE
3-ME PHENANTHRENE
2-ME PHENANTHRENE
9-ME PHENANTHRENE
1-ME PHENANTHRENE
DIBENZOTHIOPHENE
4-MEDIBENZOTHIOPHENE
3+2-ME DIBENZOTHIOPHENE
1 -ME DIBENZOTHIOPHENE
C21 MA STERANE (F22:A1)
C22 MA STERANE (F23:B1)
C27 20S 5B DM MA-ST(F2:C1)
C27 20S 10B DM MA-DIA (Cl)
C2720R5BDMMA-ST(F3:D1)
C27 20S 5A DM MA-ST(F4:D1)
C28 20S 5B DM MA-ST(F5:E1)
C27 20S 5A DM MA-DS( :F1)
C27 20R 5A DM MA-ST(F6:G1)+
C28 20S 5A DM MA-ST(F7:G1)
C28 20R 5B DM MA-ST(F8:G1)
C2920S5BDMMA-ST(F9:G1)
C29 20S 5A DM MA-ST(F10:H1)
C28 20R 5A DM MA-ST(F11 :H1
C29 20R 5B DM MA-ST(F12:H1
C2920R5ADMMA-ST(F13:I1)
C20META-STER(F14:al)
C21 ME TA-STER(F15:b 1)
C26 20S ME TA-STER(F16:cl)
C2620RMETA-STER(F17:dl)+
C2720SMETA-STER(F18:dl)
C28 20S ME TA-STERCF19:el)
C27 20R ME TA-STER(F20:fl)
C28 20R ME TA-STER(F21 :gl)
7C2120SDIASTER
7C2I20RDIASTER
?C21 AAA+ABB
?C22 DIASTER
7C22AAA+ABB
34/11-4 3924m
S9907SED009S002$
336088992
345264000
21849000
70137800
22628000
77817504
34024100
27701500
146150000
62336600
1945960
22529000
1637450
1496850
3912570
2888940
152611
1430420
1096260
547470
1554960
460088
592316
592316
1150210
1430150
331962
752012
0
391513
20445300
19262400
1530110
3435010
3435010
2043730
1545780
1914030
3753900
1801070
4124150
0
1562890
GC-MS BIOMARKER PARAMETERS
HSRUN
Hl C32 HOPANES 22S/(22S+22R)
H2 C3 1 HOPANES 22S/(22S+22R) M/Z205
H3 C30: HOPANE/(HOPANE+MORETANE)
H4 C30: BB HOPANE / C30 HOPANE AS %
H5_0 C29 HOPANE AS %C30
H5_l HOPANE DISTRIBUTION RELATIVE TO C30
H5_2 C3 1 HOPANES AS % OF C30 (205 CORRECTED)
H5_3 C32 HOPANES
H5_4 C33 HOPANES
H5_5 C34 HOPANES
H5_6 C35 HOPANES
H6 C27 HOPANES TS/(TS+TM)
H7 C33 HOPANES 22S/(22S+22R)
HI 1 C23 TRICYCLIC/C30 HOPANE AS %
H 1 2 C24 TETRAC YCLIC/C30 HOPANE AS %
HI3 28 30 BISNORHOPANE/HOPANE AS %
HI 4 C30DIAHOPANEPI/HOPANEAS%
HI 5 OLEANANE/HOPANE AS %
H16 GAMMACERANE/HOPANE AS % (205 BACK CALCULATE
H17 HOPANE INDEX C35/(C35+C34) %
HI 8 25-NORHOPANE(Y)/HOPANE AS % G
HI9 C29 18A-NORHOPANE D2/C30 HOPANE AS %
51 C29 STERANES 20S/(20S+20R)
52 C29 STERANES m/z218 ABB/(ABB+AAA)
S3_l STERANE DISTRIBUTION AAA C27 %
S3_2
C28%
S3_3
C29%
S4J STERANE DISTRIBUTION ABB C27 %
S4_2
C28 %
S4_3
C29 %
S5 BA DIASTERANES/(BA DIASTERANES+AAA+ABB STERAN
57 STERANE INDEX C27/(C27+C29) % FROM S3
58 C30 4-ME STERANE AS % OF C2920R AAA
M4 SUM C27 TO C35 HOPANES/(SAME-K:27 TO C29 STERANE
PR/PH PRISTANE/PHYTANE RATIO ESTIMATE
M2 PHENANTHRENES (3ME+2ME)/(9ME+1ME)
M3 MPI1 PHENANTHRENES (3ME+2ME) / (9ME+1ME+PHEN) *
A1 ARO STERANES: C28 20R TRI/(SAME+C29 20R 5A&B MON
A2 ARO STERANES: SUM TRI/(SAME+SUM MONOXF9&F12spl
A3 TRI ARO STERANES: C20/(C20+C28 20R)
A4 TRI ARO STERANES: (C20+C21 V(SAME+SUM C26 TO C28)
A5 TRI ARO STERANES: C2620S/C2820S
A6 TRI ARO STERANES: C27 20R / C28 20R
MDR 4-ME DIBENZOTHIOPHENE / 1 -ME DIBENZOTFflOPHENE
MBP 3-METHYLBIPHENYL/2-METHYLBIPHENYL
MNR 2-ME NAPTHALENE/1 -ME NAPHTHALENE
SMN (2-ME NAPTH+1 -ME NAPTH)/C23 TRICYCLIC
DBTP DIBENZOTHOIOPHENE(MZ184)/PHENANTHRENE(MZ178
T19 C19TRICYCLIC/C23TRICYCLIC%
T20 C20 TRICYCLIC/C23 TRICYCLIC %
T21 C21TRICYCLIC/C23TRICYCLIC%
T22 C22 TR1CYCLIC/C23 TRICYCLIC %
T23 C23 TRICYCLIC/C23 TRICYCLIC %
T24 C24 TRICYCLIC/C23 TRICYCLIC %
T25 C25 TRICYCLIC/C23 TRICYCLIC %
T26 C26 TRICYCLICS/C23 TRICYCLIC %
T28 C28 TRICYCLICS/C23 TRICYCLIC %
T29 C29 TRICYCLICS/C23 TRICYCLIC %
T30 C30 TRICYCLICS/C23 TRICYCLIC %
19/23 C19 TRICYCLIC/C23 TRICYCLIC AS %
20/21 C20 TRIGYCLIC/C21 TRICYCLIC AS %
22/21 C22 TRICYCLIC/C21 TRICYCLIC AS %
24/23 C24 TRICYCLIC/C23 TRICYCLIC AS %
26/25 C26 TRICYCLICS/C25 TRICYCLIC AS %
244_24 C24 TETRACYCLIC/C24 TRICYCLIC AS %
TET_23 C24 TETRACYCLIC/C23 TRICYCLIC AS %
34/1 1-4 3924m
MPDMI000853021
0.59
0.54
0.91
27.09
100
81
65.02
43.84
27.39
21.02
0.69
0.55
15.65
13.07
67.57
43.42
57.18
0.68
0.65
51.35
17.03
31.62
34.82
32.81
32.37
56.82
61.89
47.74
1.44
0.33
0.4
0.7
0.76
0.91
0.79
0.75
0.81
15.05
3.21
0.97
0.03
97.78
53.72
78.03
13.02
100
91.82
46.51
94.5
108.16
149.34
97.78
68.85
16.69
91.82
203.19
90.97
83.52
CARBON ISOTOPE DATA
34/11-4 Cuttings Extracts
SAMPLE CODE
DEPTH
SATURATES
9907SED009S002
3924.00
-31.1
del 13 C PBD
AROMATICS RESIDUE ASPHALTENES WHOLE OIL KEROGEN
.
Std NBS22 -29.8
-30.2.
-29.9
-29.1
-30.4
-29.5
BULK COMPOSITION OF EXTRACTS
34/11-4T2 Cuttings Extracts
Sample code
Depth
(m)
WtExt
(g)
EOM
(mg)
TSE
%wt
Saturates
%wt
Aromatics
%wt
Residue
%wt
Asph
%wt
HC
%wt
NonHC
%wt
9907SED008S001
9907SED008S004
9907SED008S006
9907SED008S008
9907SED008S010
9907SED008S012
9907SED008S014
3960
3996
4017
4041
4065
4089
4119
0.36465
0.28906
0.25596
0.32628
0.26611
0.22418
0.23778
364.65
289.06
255.96
326.28
266.11
224.18
237.78
7.182
5.758
4.791
5.316
5.277
4.439
4.670
91.6
91.6
88.5
88.8
84.0
88.84
90.7
0.0
0.4
1.6
0.0
0.0
0
0.31
6.4
7.2
9.5
8.0
13.1
6.63
8.07
1.98
0.88
0.38
3.18
2.96
4.53
0.92
91.6
92.0
90.1
88.8
84.0
88.8
91.0
6.4
7.2
9.5
8.0
13.1
6.6
8.1
EXTRACTION DATA 1
34/11-4T2 Cuttings Extracts
Sample code
9907SED008S001
9907SED008S004
9907SED008S006
9907SED008S008
9907SED008S010
9907SED008S012
9907SED008S014
Depth
(m)
3960
3996
4017
4041
4065
4089
4119
Rock
(g)
5.077
5.02
5.342
6.138
5.043
5.05
5.092
EOM
(mg)
364.65
289.06
255.96
326.28
266.11
224.18
237.78
EOM
Sat/EOM Aro/EOM Pol/EOM Asph/EOM HC/EOM NON HC/EOM
%
(mg/Kg rock)
%
%
%
%
%
71824
91.6
6.4
0.0
91.6
6.4
1.98
91.6
57582
0.4
7.2
0.88
92.0
7.2
47915
88.5
1.6
9.5
0.38
90.1
9.5
88.8
53157
0.0
8.0
3.18
88.8
8.0
84.0
52768
0.0
13.1
2.96
84.0
13.1
44392
88.84
0
6.63
88.8
6.6
4.53
46697
90.7
0.31
8.07
0.92
91.0
8.1
EXTRACTION DATA 2
34/11-4T2 Cuttings Extracts
Sample code
9907SED008S001
9907SED008S004
9907SED008S006
9907SED008S008
9907SED008S010
9907SED008S012
9907SED008S014
Depth
(m)
3960
3996
4017
4041
4065
4089
4119
Rock
(g)
5.077
5.02
5.342
6.138
5.043
5.05
5.092
TOC
i70
5.84
5.96
7.39
3.10
2.06
2 .18
3.35
EOM/TOC
Sat
Aro
Pol
(mg/gTOC) (mg/gTOC) (mg/gTOC) (mg/gTOC)
12.30
3.09
0.22
0.00
9.66
3.06
0.01
0.24
6.48
2.24
0.04
0.24
17.15
4.67
0.00
0.42
25.62
8.08
0.00
1.26
20.36
8.07
0.00
0.60
13.94
5.32
0.02
0.47
Asph
(mg/gTOC)
0.07
0.03
0.01
0.17
0.28
0.41
0.05
100*Sat/Aro
%
0
24754
5396
0
0
0
29258
100*HC/NON HC
%
1432
1283
950
1113
644
1340
1128
SATURATE GC
34/11-4T2 Cuttings Extracts
Depth (m)
Saturates Fraction GC Analysis
Component
9907SED008S001 9907SED008S004
3996m
3960m
Area
Area
[uV-s]
[uV-s]
9907SED008S006
4017m
Area
[uV-s]
N-C12
N-C13
N-C14
N-C15
N-C16
N-C17
PRISTANE
N-C18
PHYTANE
N-C19
N-C20
N-C21
N-C22
N-C23
N-C24
N-C25
N-C26
N-C27
N-C28
N-C29
N-C30
N-C31
N-C32
N-C33
N-C34
N-C35
N-C36
9913
114076.28
2462810.36
1705981.8
2349391.71
1073882.87
223043.53
753764.5
200759
408086.6
262036.2
173181.35
101063.1
54092.2
26325.8
11881.2
5198.45
3258.4
2544.96
2823.2
1358.86
1298.47
1097.85
1285.4
351.3
345.43
358.99
28016.2
153364.09
2040252.19
1276269.73
1469472.83
991765.72
410466.58
622276.07
210095.45
339628.6
219769.19
135215.9
82830.9
45747.2
23006.2
11303.4
5890.8
4035
3034.2
3620.51
1685.62
1708.76
1357
1601.7
351.44
602.41
376.02
51575.2
265288.62
3406794.66
1909101.6
2135019.09
1371317.83
575727.52
782166.17
209721.55
464664.42
277592.4
182021.14
105394.2
58409.8
27940.2
13243.8
6013.25
4444.2
3375.7
4127.59
1754.6
1677.9
1170.8
2234.72
261.21
352.2
409.29
TOTAL
9950210.8
8083743.72
11861799.64
Batch Code
CPI (24 to 32)
Pr/Ph Ratio
Pr/n-C17
Ph/n-C18
Alkane Index (C17/(C17+C27)%
R22 Index 2*C22/(C21+C23)
(Pr/n-C17)/(Ph/n-C18)
Note: -1 denotes not calculated
9907SED008S001 9907SED008S004
1.17
1.22
1.95
1.11
0.41
0.21
0.34
0.27
99.59
99.70
0.92
0.89
0.779818204
1.225843828
9907SED008S006
1.25
2.75
0.42
0.27
99.68
0.88
1.565794745
SATURATE GC
34/11-4T2 Cuttings Extracts
Depth (m)
Saturates Fraction GC Analysis
Component
9907SED008S008 9907SED008S010 9907SED008S012 9907SED008S014
4065m
4041m
4089m
4119m
Area
Area
Area
Area
[uV-s]
[uV-s]
[uV-s]
[uV-s]
N-C12
N-C13
N-C14
N-C15
N-C16
N-C17
PRISTANE
N-C18
PHYTANE
N-C19
N-C20
N-C21
N-C22
N-C23
N-C24
N-C25
N-C26
N-C27
N-C28
N-C29
N-C30
N-C31
N-C32
N-C33
N-C34
N-C35
N-C36
5982.53
56590.8
1018942.68
666525.16
784552.6
604672.45
251887.39
379253.06
154003.24
194380.2
121657.8
74364.8
46777.2
24490
11791.6
5344
2022.35
1221.87
1074.6
962.52
519.55
371.64
0
0
0
0
0
13632.4
67527.34
886121.24
488387.73
612141.8
326091.01
73541.79
217590.3
64393.51
130291.14
72452.4
45973.6
27801.9
15338.9
7333
2774.35
1467.13
1061.46
570.45
954.93
286.5
372.09
257.35
449.8
0
0
0
19916.3
99545
1027096.95
568385.08
789691.96
412212.11
95152.69
272743.79
100797.21
164051.3
92491
58667.2
36118.8
19945.8
9522.9
4361.8
1876.08
1129.91
724.02
1014.4
376.31
646.8
0
0
0
0
0
16909.6
64520.62
733055.27
366508.34
409601.8
230771.8
62382.96
173644.7
57384.55
101432.9
57687
36098.6
22804.2
12057.8
5900.6
2233.87
1253.29
780.41
396.6
616.84
204.03
213.03
0
0
0
0
0
TOTAL
4407388.04
3056812.13
3776467.42
2356458.81
Batch Code
CPI (24 to 32)
Pr/Ph Ratio
Pr/n-C17
Ph/n-C18
Alkane Index (C17/(C17+C27)%
R22 Index 2*C22/(C21+C23)
(Pr/n-C17)/(Ph/n-C18)
Note: -1 denotes not calculated
9907SED008S008 9907SED008S010 9907SED008S012 9907SED008S014
1.27
1.35
1.49
1.28
1.14
1.64
0.94
1.09
0.23
0.42
0.23
0.27
0.41
0.30
0.37
0.33
99.80
99.68
99.73
99.66
0.91
0.95
0.92
0.95
0.762066393
1.025853849
0.817993412
0.624606723
C:\ DATA\B9907008\ARO001.RAW
V3/9/99
Software Version:
Sample Name:
Instrument:
Raw Data File:
Sequence File:
4.1<OG07>
9907SED008S001 34/11-4T2 3960m
SAC_GC
C:\_DATA\B9907008\ARO001 .RAW
C:\_DATA\B9907008\ARO.SEQ
Aromatics GC
Component
Name
Time
[min]
1-MENAPTHALENE
2-MENAPTHALENE
2,6+2,7-DIMETHYLNAPT
1,3+1,7-DIMETHYLNAPT
1,6-DIMETHYLNAPTHALE
1,5+1,5+2,3-DIMETHYL
1,2-DIMETHYLNAPTHALE
9907SED008S001
Area
[uV-s]
8.46
9.303
9.54
9.726
10.237
10.471
10.578
10.647
10.747
10.913
11.022
11.15
11.155
11.193
11.312
11.477
11.559
11.626
11.771
11.82
11.951
12.025
12.116
12.223
12.434
12.498
12.632
12.796
12.878
12.981
13.131
13.244
13.315
13.405
13.552
13.648
13.767
13.893
14.05
14.203
14.322
14.402
14.471
14.535
14.623
14.842
14.959
15.074
15.236
15.372
15.469
221144.9
7637.2
0
16445.2
4962
8077.2
28128.64
43610.04
23603.11
53129.45
461516.6
39131.6
59167.8
0
25402.1
22317.46
19671.94
13323.8
35514.47
41030.64
88980.28
66669.91
44968.7
8186.8
45074.54
143145.1
37789.93
13350.8
20637
16891.2
99959.03
90700.73
74996.64
39608.2
15842.8
310307.2
125521.1
12565.61
6483.6
17731.6
62919.34
68067.9
35210.13
49041.61
43451.22
25533.1
98666.27
20536.93
20217.7
9895.12
55289.37
Pagel
Area
[%]
6.09
0.21
0
0.45
0.14
0.22
0.77
1.2
0.65
1.46
12.7
1.08
1.63
0
0.7
0.61
0.54
0.37
0.98
1.13
2.45
1.83
1.24
0.23
1.24
3.94
1.04
0.37
0.57
0.46
2.75
2.5
2.06
1.09
0.44
8.54
3.45
0.35
0.18
0.49
1.73
1.87
0.97
1.35
1.2
0.7
2.72
0.57
0.56
0.27
1.52
C:\ DATA\B9907008\ARO001.RAW
V3/9/99
PHENANTHRENE
3-ME PHENANTHRENE
2-ME PHENANTHRENE
9-ME PHENANTHRENE
1-ME PHENANTHRENE
15.547
15.63
15.69
15.777
15.832
16.095
16.168
16.569
16.731
16.783
16.854
16.875
16.91
17.114
17.176
17.364
17.729
17.837
17.973
18.207
18.868
19.095
19.195
19.332
19.558
19.661
20.142
20.863
21.206
24.077
25.228
27.701
28.188
28.929
33.787
Page 2
9907SED008S001
0
52799.52
24055.62
15362.5
8462.77
56976.8
5733.8
27208.62
20219.7
23496.62
0
16908.86
0
0
38055.8
7998.1
17433.88
15832.12
30734.7
19283.9
11353.4
12244.1
11586.4
16875.8
8918.06
11340.04
5851
6035.9
37129.2
25762.1
61139.3
20584.4
44359.3
87665.4
174.16
0
1.45
0.66
0.42
0.23
1.57
0.16
0.75
0.56
0.65
0
0.47
0
0
1.05
0.22
0.48
0.44
0.85
0.53
0.31
0.34
0.32
0.46
0.25
0.31
0.16
0.17
1.02
0.71
1.68
0.57
1.22
2.41
0
3633635
100
GC-MS PEAK HEIGHT DATA
MPDMIO0085303 1 USMPDMIO0085304 1 US MPDMIO0085305 1 IJS MPDMIO0085306 1 .LIS
34/1 1-4T2 3960m
34/1 1-4T2 3996m
34/11 -4124017m
34/ll-4T24041m
$9907SED008S001$ S9907SED008S004S $9907SED008S006$ $9907SED008S008$
PEAK HEIGHTS
PRISTANE
PHYTANE
C19 TRICYCLIC TERPANE(19/3)
C20 TRICYCLIC TERPANE(20/3)
C21 TRICYCLIC TERPANE{2 1/3)
C22 TRICYCLIC TERPANE(22/3)
C23 TRICYC TERPANE(T5:23/3)
C24TRICYCTERPANE (24/3)
C25 TRICYC TERPANE (25/3)
C24 TETRACYC TERP ($:24/4)
C26 TRICYCLIC TERPANE(26/3)
C26 TRICYCLIC TERP 2 (26/3)
C28 TRICYCLIC TERPANE(28/3)
C28 TRICYCLIC TERP 2 (28/3)
C29 TRICYCLIC TERPANE(29/3)
C29 TRICYCLIC TERP 2 (29/3)
C2718AHOPANE (Ts:27Ts)
C2717AHOPANE (Tm:27Tm)
C30 TRICYCLIC TERPANE(30/3)
C30 TRICYCLIC TERP 2 (30/3)
25-TRISNORm/zl 77(25nor28ab)
C28 BISNORHOPANE (X:28ab)
25-NOR m/z!77 (Y:25nor30ab)
25-NORHOPANE (Y:25nor30ab)
C29 HOPANE
(D:29ab)
C29 ISA NORHOPANE (D2:29Ts)
C30 C30 DIAHOPANE (PI:30d)
C29NORMORETANE (A:29ba)
C30 18A OLEANANE (B:30O)
C30 HOPANE
(G:30ab)
NOR-GAMMACERANE?
(G2)
C30 MORETANE
(K:30ba)
C3122S HOPANE (N:31abS)
C3122R HOPANE. (O:31abR)
C3122SM/Z205
(N205)
C3122RM/Z205
(O205)
C30 GAMACERANE (S:30G)
C30 1 7B 2 1 B HOPANE (P)
C3222S HOPANE (U:32abS)
C32 22R HOPANE (V:32abR)
C33 22S HOPANE(Alpha:33abS)
C33 22R HOPANE (Beto:33abR)
C34 22S HOPANE(Gamma:34abS)
C34 22R HOPANE(Dclta:34abR)
C35 22S HOP (Epsilon:35abS)
C35 22R HOPANE (Zcta:35abR)
C21 STERANE
C27 20S DIASTER (10:27dbS)
C27 20R DIASTER (1 1 :27dbR)
C27 20S AAA STER (20:27aaS)
C29 20S DIASTER (21A:29dbS)
C27 20R ISOST218(21B:27bbR)
C27 20S ISOST218 (22:27bbS)
C27 20R ISOSTER 217 (27bbR)
C27 20S ISOSTER.217 (27bbS)
C27 20R AAA STER (25:27aaR)
C29 20R DIASTER (27:29dbR)
C28 20R ISOST218(33A:28bbR)
C28 20S ISOST218 (34:28bbS)
C28 20R ISOSTER 217 (28bbR)
C28 20S ISOSTER 217 (28bbS)
C28 20R AAA STER (36:28aaR)
C29 20S AAA STER (39:29aaS)
C29 20R ISOST218 (40:29bbR)
C29 20S ISOST218 (41:29bbS)
C2920RISOSTER217 (29bbR)
C2920SISOSTER217 (29bbS)
C29 20R AAA STER (42:29aaR)
C3020RISOSTER218 (30bbR)
C30 20S ISOSTER218 (30bbS)
C30 4-METHYL STERANE (46)
0
0
0
0
0
0
292117
1237330
1806860
580360
1932590
705147
298988
690146
231827
214163
0
0
0
0
446580
1977500
552543
1029410
1560170
429980
1560610
533180
257142
569939
221810
173937
0
0
0
0
702919
1892510
0
0
0
0
0
0
5208380
0
429493
846102
0
8609110
0
2227090
1655290
2280520
563975
1154750
2200710
2494170
632561
2237180
809887
462202
1084940
0
0
0
0
0
0
875927
3938780
0
0
0
0
0
0
11927100
0
511702
1922490
0
18565500
0
459689
0
943463
0
1402770
1751090
1077920
821114
647890
375360
462051
268678
199416
0
0
0
0
0
0
6245960
0
264609
995315
0
9986030
0
2690800
1895500
2650100
639931
560629
0
474963
1120500
688660
536432
460989
943320
621696
484779
428999
390695
267665
291778
201830
241479
215849
220868
126115
409815
689724
438720
612839
593863
322931
263161
593863
253740
1060490
346882
441542
389607
576085
150821
309783
547892
377829
646292
413061
343472
235957
413061
236889
1039860
307133
486019
423804
609515
404345
1193730
386367
1097150
607199
412267
399650
373027
377641
972596
105848
0
103695
605885
376559
355128
419572
358500
939680
60075
73037
77072
4972740
3291950
5571040
1139090
472840
662697
459742
694659
408001
393880
294603
408001
164103
1166220
349201
564783
547962
730932
489400
1742970
907893
483573
528107
472370
470143
1446890
117093
0
172488
0
0
320683
2403580
2792310
644480
2532370
917376
418960
1142240
0
0
0
0
0
0
464341
4287540
0
0
0
0
0
0
14449900
0
0
1805110
0
22747300
0
5909690
3758780
6417720
1308530
1079560
0
761906
1853770
1292570
945299
739069
419561
443125
303213
224137
349132
499447
331663
647623
379563
339219
258489
379563
240944
1206880
284400
637930
546239
765325
488557
1860930
934673
505984
538265
481203
493729
1564650
76687
0
172442
GC-MS PEAK HEIGHT DATA
MPDMIO008S3031JLISMPDMIO008S3041.LISMPDM1O00853051USMPDMIO008S3061.LIS
PEAK HEIGHTS
2-ME NAPHTHALENE
1 -ME NAPHTHALENE
2-MEBBPHENYL
3-MEBIPHENYL
4-MEBIPHENYL
PHENANTHRENE
3-ME PHENANTHRENE
2-ME PHENANTHRENE
9-ME PHENANTHRENE
1-ME PHENANTHRENE
DIBENZOTHIOPHENE
4-ME DIBENZOTHIOPHENE
3+2-ME DIBENZOTHIOPHENE
1-ME DIBENZOTHIOPHENE
C21 MA STERANE(F22:A1)
C22 MA STERANE (F23:B1)
C27 20S SB DM MA-ST(F2:C1)
C27 20S 10B DM MA-DIA (Cl)
C27 20R SB DM MA-ST(F3:D1)
C27 20S 5A DM MA-ST(F4:D1)
C28 20S SB DM MA-ST(F5:E1)
C27 20S 5 A DM MA-DS( :F1)
C27 20R 5A DM MA-ST(F6:G1)+
C28 20S 5 A DM MA-ST(F7:G1)
C28 20R SB DM MA-ST(F8:G1)
C29 20S SB DM MA-ST(F9:G1)
C29 20S 5A DM MA-ST(F10:H1)
C28 20R 5A DM MA-ST(F1 1 :H1)
C29 20R SB DM MA-ST(F12:H1)
C29 20R 5A DM MA-ST(F13:I1)
C20 ME TA-STER(F14:al)
C21 META-STER(F15:bl)
C26 20S ME TA-STER(F16:cl)
C26 20R ME TA-STER(F17:dl)+
C27 20S ME TA-STER(F18:dl)
C28 20S ME TA-STER(F19:el)
C27 20R ME TA-STER(F20:fl)
C28 20R ME TA-STER(F21:gl)
7C2120SDIASTER
?C21 20RDIASTER
?C21 AAA+ABB
?C22 DIASTER
?C22 AAA+ABB
34/11 -4123960m
34/11 -4123996m
34/ll-4T24017m
34/ll-4T24041m
$9907SED008S001$
$9907SED008S004$
$9907SED008S006$
$9907SED008S008$
2805130
2909080
885663
1257190
501311
1687460
474075
421332
1815490
773832
154622
367259
90354
130297
203435
150788
82458
278879
286605
4876480
5723400
687085
2452420
836306
23587900
23132100
1528260
8282060
2800290
12111000
5935030
5016360
24373500
10728300
740167
3437350
629761
604396
309984
193399
69935
289749
380895
89235
529516
80S80
198853
5459930
5349610
60567
446835
52844
137303
137303
412036
0
91424
105496
205383
91987
511802
466374
114011
526580
526580
290739
263746
287008
543038
175138
309783
0
196650
3367720
1361660
1299730
6698020
2564490
241979
933882
157612
165321
279104
169093
61142
258864
292758
0
429309
47925
153701
153701
307250
391740
129223
163614
261701
88053
1248770
979246
165557
527061
527061
363456
283061
343372
507737
171203
409815
0
173537
198853
4I7I31
492497
161008
157533
575770
1755290
716331
2680950
1020080
889230
3553020
1488390
217863
515779
121692
148333
138497
128062
84800
315842
316967
74095
508054
64157
180438
180438
263084
170692
2221630
1620210
217492
956478
394298
496055
96388
119799
232430
134674
434713
352702
121999
527599
956478
527599
645238
388452
282940
347484
517905
577182
623132
199185
472840
0
273392
541858
187244
349132
0
240295
GC-MS PEAK HEIGHT DATA
PEAK HEIGHTS
MPDMIO00853071.USMPDMICX)0853081JJSMPDM1O00853091.LIS
34/11 -4124065m
34/1 1-4T2 4089m
34/ll-4T24119m
$9907SED008S010$ $9907SED008S012$ $9907SED008S014$
PRISTANE
PHYTANE
C19 TRICYCLIC TERPANE(19/3)
C20 TRICYCLIC TERPANE(20/3)
C21 TRICYCLIC TERPANE(21/3)
C22 TRICYCLIC TERPANE(22/3)
C23 TRICYC TERPANE(T5:23/3)
C24 TRICYC TERPANE (24/3)
C25 TRICYC TERPANE (25/3)
C24 TETRACYC TERP ($:24/4)
C26 TRICYCLIC TERPANE(26/3)
C26 TRICYCLIC TERP 2 (26/3)
C28 TRICYCLIC TERPANE(28/3)
C28 TRICYCLIC TERP 2 (28/3)
C29 TRICYCLIC TERPANE(29/3)
C29 TRICYCLIC TERP 2 (29/3)
C2718AHOPANE (Ts:27Ts)
C2717AHOPANE (Tm:27Tm)
C30 TRICYCLIC TERPANE(30/3)
C30 TRICYCLIC TERP 2 (30/3)
25-TRISNORm/zl 77(25nor28ab)
C28 BISNORHOPANE (X:28ab)
25-NORm/zl77 (Y:25nor30ab)
25-NORHOPANE (Y:25nor30ab)
C29 HOPANE
(D:29ab)
C29 18ANORHOPANE(D2:29Ts)
C30 C30 DIAHOPANE (PI:30d)
C29 NORMORETANE (A:29ba)
C3018AOLEANANE (B:30O)
C30 HOPANE
(G:30ab)
NOR-GAMMACERANE?
(G2)
C30 MORETANE
(K:30ba)
C3 1 22S HOPANE (N:3 1 abS)
C3122RHQPANE (0:31abR)
C3122SM/Z205
(N205)
C3122RM/Z205
(O205)
C30 GAMACERANE (S:30G)
C30 17B 21B HOPANE (P)
C3222S HOPANE (U:32abS)
C32 22R HOPANE (V:32abR)
C33 22S HOPANE(Alpha:33abS)
C33 22R HOPANE (Beta:33abR)
C34 22S HOPANE(Gamma:34abS)
C34 22R HOPANE(Delta:34abR)
C35 22S HOP (Epsilon:35abS)
C35 22R HOPANE (Zeta:35abR)
C21 STERANE
C27 20S DIASTER (10:27dbS)
C27 20R DIASTER (1 l:27dbR)
C27 20S AAA STER (20:27aaS)
C29 20S DIASTER (21A:29dbS)
C27 20R ISOST218(21B:27bbR)
C27 20S ISOST218 (22:27bbS)
C27 20R ISOSTER 217 (27bbR)
C27 20S ISOSTER 217 (27bbS)
C27 20R AAA STER (25:27aaR)
C29 20R DIASTER (27:29dbR)
C28 20R ISOST218(33A:28bbR)
C28 20S ISOST218 (34:28bbS)
C28 20R ISOSTER 217 (28bbR)
C28 20S ISOSTER 217 (28bbS)
C28 20R AAA STER (36:28aaR)
C29 20S AAA STER (39:29aaS)
C29 20R ISOST218 (40:29bbR)
C29 20S ISOST218 (41:29bbS)
C2920RISOSTER217 (29bbR)
C2920SISOSTER217 (29bbS)
C29 20R AAA STER (42:29aaR)
C3020RISOSTER218 (30bbR)
C30 20S ISOSTER218 (30bbS)
C30 4-METHYL STERANE (46)
0
0
0
0
0
0
1560710
3289900
3646390
850432
3178420
1128070
603492
1553560
0
0
0
0
0
0
748008
6422980
0
0
0
0
0
0
21061200
0
0
2737690
0
34894000
0
9404870
6148180
10310700
2096460
1656240
0
1912730
29881 10
2003510
1485450
1139010
694245
736128
414518
335543
433628
584486
362663
844990
463685
387652
333859
463685
298643
1471620
394294
864323
776284
1044130
695482
2769910
1399640
710763
756731
671166
730440
2294800
97536
0
266763
870561
1980070
2132580
430137
1799210
674910
305164
868442
0
0
0
0
0
0
303543
3176760
0
0
0
0
0
0
10384300
0
0
1316440
0
16273700
0
4640230
2913070
4858260
1011650
830037
0
692485
1360090
945717
760797
605452
326283
335049
203615
136995
248193
297971
203660
416283
245643
213846
166111
245643
141432
790098
178348
439415
377416
518956
338722
1201010
664778
362388
351037
356510
321406
1058210
35564
0
123318
1286530
3046010
3611830
670563
3144050
1125630
630338
1464390
0
0
0
0
0
0
594319
5975410
0
0
0
0
0
0
19161200
0
0
2559000
0
28426200
0
8110140
4907420
8478470
1716870
1349180
0
1525740
2442620
1646160
1439200
1031020
606878
624100
359662
220891
419837
557659
353677
737237
400780
419986
318860
400780
254668
1384300
321462
740868
653638
921297
592401
2463430
1235210
619317
651607
595736
628800
2143000
101040
0
219299
GC-MS PEAK HEIGHT DATA
PEAK HEIGHTS
2-ME NAPHTHALENE
1 -ME NAPHTHALENE
2-MEBBPHENYL
3-MEBIPHENYL
4-MEBEPHENYL
PHENANTHRENE
3-ME PHENANTHRENE
2-ME PHENANTHRENE
9-ME PHENANTHRENE
1 -ME PHENANTHRENE
DIBENZOTfflOPHENE
4-ME DffiENZOTfflOPHENE
3+2-ME DIBENZOTHIOPHENE
1-ME DIBENZOTHIOPHENE
C21 MA STERANE(F22:A1)
C22 MA STERANE (F23:B1)
C27 20S 5B DM MA-ST(F2:C1)
C27 20S 10B DM MA-DIA (Cl)
C27 20R SB DM MA-ST(F3:D1)
C27 20S 5 A DM MA-ST(F4:D1)
C28 20S 5B DM MA-ST(F5:E1)
C2720S5ADMMA-DS( :F1)
C27 20R 5A DM MA-ST(F6:G1)+
C28 20S 5 A DM MA-ST(F7:G1)
C28 20R 5B DM MA-ST(F8:G1)
C29 20S 5B DM MA-ST(F9:G1)
C29 20S 5A DM MA-ST(F10:H1)
C28 20R 5A DM MA-ST(F1 1:H1)
C29 20R 5B DM MA-ST(F12:H1)
C29 20R 5A DM MA-ST(F13:I1)
C20 ME TA-STER(F14:al)
C21 META-STER(F15:bl)
C26 20S ME TA-STER(F16:cl)
C26 20R ME TA-STER(F17:dl)+
C27 20S ME TA-STER(F18:dl)
C28 20S ME TA-STER(F19:el)
C27 20R ME TA-STER(F20:fl)
C28 20R ME TA-STER(F21:gl)
?C21 20S DIASTER
?C21 20R DIASTER
?C21 AAA+ABB
?C22 DIASTER
?C22 AAA+'ABB
MPDMIO00853071.LISMPDMIO00853081.L1SMPDMIO00853091.LIS
34/1 1-4T2 4065m
34/11 -4124089m
34/ll-4T24119m
$9907SED008S010$ $9907SED008S012$ S9907SED008S014S
4309670
4186130
540285
2140270
702027
2215690
864095
750869
3244360
1502290
286203
464906
139567
151987
208597
171515
83419
374472
407150
101830
547195
85755
261289
261289
449407
607759
155518
218898
300815
166718
600544
548587
188394
848374
848374
642259
468558
573348
583383
155288
433628
0
276357
3691130
3535400
415049
1435550
455089
1897120
674755
618986
2406300
1096990
145505
390993
83805
99888
58294
77499
52338
184197
198946
52628
308533
44634
118107
118107
252222
268014
82458
97168
136901
68928
249834
212114
59995
322677
.322677
255069
166550
215381
300524
99332
248193
0
171091
14936000
12405600
535969
5410420
1653330
9190220
3872730
3321620
10537000
4566830
525772
1126220
296717
244192
187591
148370
101554
312040
403042
94369
537814
80718
203591
203591
553023
0
142737
145633
266863
148187
815774
615967
183994
838837
838837
614277
460633
543961
614553
196352
419837
0
260469
GC-MS BIOMARKER PARAMETERS
HSRUN
34/1 1-4T2 3960m 34/1 1-4T2 3996m 34/ll-4T24017m 34/1 1 -4T2 404 1 m
MPDMIO0085303 MPDMIO0085304 MPDMIO0085305 MPDMIO0085306 1
Hl C32 HOPANES 22S/(22S+22R)
H2 C3 1 HOPANES 22S/(22S+22R) M/Z205
H3 C30: HOPANE/(HOPANE+MORETANE)
H4 C30: BB HOPANE / C30 HOPANE AS %
H5_0 C29 HOPANE AS % C30
H5_l HOPANE DISTRIBUTION RELATIVE TO C30
H5_2 C31 HOPANES AS % OF C30 (205 CORRECTED)
H5_3 C32 HOPANES
H5_4 C33 HOPANES
H5_5 C34 HOPANES
H5_6 C35 HOPANES
H6 C27 HOPANES TS/(TS+TM)
H7 C33 HOPANES 22S/(22S+22R)
H 1 1 C23 TRICYCLIC/C30 HOPANE AS %
HI 2 C24 TETRACYCLIC/C30 HOPANE AS %
HI 3 28 30 BISNORHOPANE/HOPANE AS %
H14 C30 DIAHOPANE PI/HOPANE AS %
HI 5 OLEANANE/HOPANE AS %
H 1 6 GAMMACERANE/HOPANE AS % (205 BACK CALCULATE
H 1 7 HOPANE INDEX C35/(C35+C34) %
HI 8 25-NORHOPANE(Y)/HOPANE AS % G
H 1 9 C29 1 8A-NORHOPANE D2/C30 HOPANE AS %
S 1 C29 STERANES 20S/(20S+20R)
S2 C29 STERANES m/z2 1 8 ABB/( ABB+AAA)
S3_l STERANE DISTRIBUTION AAA C27 %
S3_2
C28 %
S3_3
C29 %
S4 1 STERANE DISTRIBUTION ABB C27 %
S4_2
C28 %
S4_3
C29 %
S5 BA DIASTERANES/(BA DIASTERANES+AAA+ABB STERAN
S7 STERANE INDEX C27/(C27+C29) % FROM S3
S8 C30 4-ME STERANE AS % OF C2920R AAA
M4 SUM C27 TO C35 HOPANES/(SAME+C27 TO C29 STERANE
PR/PH PRISTANE/PHYTANE RATIO ESTIMATE
M2 PHENANTHRENES (3ME+2ME)/(9ME+1ME)
M3 MPI 1 PHENANTHRENES (3ME+2ME) / (9ME+1 ME+PHEN) *
A 1 ARO STERANES: C28 20R TRI/(SAME+C29 20R 5A&B MON
A2 ARO STERANES: SUM TRI/(SAME+SUM MONOKF9&F1 2spl
A3 TRI ARO STERANES: C20/(C20+C28 20R)
A4 TRI ARO STERANES: (C20+C2 1 )/(SAME+SUM C26 TO C28)
A5 TRI ARO STERANES: C26' 20S / C28 20S
A6 TRI ARO STERANES: C27 20R / C28 20R
MDR 4-ME DIBENZOTHIOPHENE / 1 -ME DIBENZOTHIOPHENE
MBP 3-METHYLBIPHENYL / 2-METHYLBIPHENYL
MNR 2-MENAPTHALENE/l-ME NAPHTHALENE
SMN (2-ME N APTH+ 1 -ME NAPTH)/C23 TRICYCLIC
DBTP DIBENZOTHOIOPHENE(MZ 1 84)/PHENANTHRENE(MZ 1 78
Tl 9 C 1 9 TRICYCLIC/C23 TRICYCLIC %
T20 C20 TRICYCLIC/C23 TRICYCLIC %
T2 1 C2 1 TRIG YCLIC/C23 TRICYCLIC %
T22 C22 TRICYCLIC/C23 TRICYCLIC %
T23 C23 TRICYCLIC/C23 TRICYCLIC %
T24 C24 TR1CYCLIC/C23 TRICYCLIC %
T25 C25 TRICYCLIC/C23 TRICYCLIC %
T26 C26 TRICYCL1CS/C23 TRICYCLIC %
T28 C28 TRICYCLICS/C23 TRICYCLIC %
T29 C29 TRICYCLICS/C23 TRICYCLIC %
T30 C30 TRICYCLICS/C23 TRICYCLIC %
19/23 C19 TRICYCLIC/C23 TRICYCLIC AS %
20/21 C20 TR1CYCL1C/C21 TRICYCLIC AS %
22/21 C22 TRICYCLIC/C21 TRICYCLIC AS %
24/23 C24 TRJCYCL1C/C23 TRICYCLIC AS %
26/25 C26 TRICYCLICS/C25 TRICYCLIC AS %
244_24 C24 TETRACYCLIC/C24 TRICYCLIC AS %
TET_23 C24 TETRACYCLIC/C23 TRICYCLIC AS %
0.62
0.53
0.79
4.76
62.55
100
35.61
18.12
9.67
5.6
3.53
0.18
0.56
19.35
6.91
0.6
0.55
0.79
5.35
60.5
100
34.9
18.18
10.17
5.31
4.03
0.27
0.55
18.13
6.62
0.62
0.55
0.79
7.56
64.24
100
32.42
15.24
7.91
4.51
2.52
0.18
0.56
12.05
5.84
2.65
4.99
2.76
9.91
38.66
10.82
43.14
15.32
35.86
14.58
37.94
0.38
0.34
32.43
37.23
30.33
25.18
39.54
35.28
26.58
51.67
10.66
69.58
0.39
0.32
34.24
35.42
30.34
27.27
38.68
34.05
30.51
53.02
8.2
55.73
0.39
0.3
26.77
40.01
33.22
24.48
39.56
35.97
29.26
44.63
11.92
78.98
0.37
0.29
26.05
40.17
33.78
21.15
41.9
36.95
23.32
43.55
11.02
80.49
0.39
0.4
0.47
0.49
0.64
0.4
0.39
0.92
2.82
1.42
0.96
0.32
0.39
0.44
0.57
0.78
0.57
0.46
0.82
5.65
3.57
0.85
0.35
0.43
0.57
0.64
0.79
0.57
0.34
0.9
5.69
5.42
1.02
0.43
0.47
0.48
0.43
0.56
0.32
0.31
0.81
3.48
3.05
1.02
0.09
15.12
64.02
93.49
30.03
100
36.49
15.47
23.08
0.07
35.41
65.%
99.97
27.55
100
34.16
16.48
25.36
0.06
51.62
98.37
111.49
28.27
100
36.2
20.66
0.08
12.66
94.91
110.26
25.45
100
36.23
16.54
15.12
68.48
32.12
36.49
149.17
97.87
35.71
35.41
65.98
27.56
34.16
153.9
106.89
36.52
51.62
88.23
25.36
36.2
12.66
86.08
23.08
36.23
133.96
48.5
124.51
45.11
0.59
0.55
0.79
3.35
63.52
100
30.16
13.83
7.4
3.79
2.32
0.1
0.56
11.13
5.02
GC-MS BIOMARKER PARAMETERS
HSRUN
34/1 1-4T2 4065m 34/1 1-4T2 4089m 34/ll-4T24119m
1MPDMIO00853071MPDMIO00853081MPDMIO00853091
Hl C32 HOPANES 22S/(22S+22R)
H2 C3 1 HOPANES 22S/(22S+22R) M/Z205
H3 C30: HOPANE/(HOPANE+MORETANE)
H4 C30: BB HOPANE / C30 HOPANE AS %
H5 0 C29 HOPANE AS % C30 .
H5_l HOPANE DISTRIBUTION RELATIVE TO C30
H5_2 C3 1 HOPANES AS % OF C30 (205 CORRECTED)
H5_3 C32 HOPANES
H5_4 C33 HOPANES
H5_5 C34 HOPANES
H5_6 C35 HOPANES
H6 C27 HOPANES TS/(TS+TM)
H7 C33 HOPANES 22S/(22S+22R)
H 1 1 C23 TRIG YCLIC/C30 HOPANE AS %
HI 2 C24 TETRACYCLIC/C30 HOPANE AS %
HI 3 28 30 BISNORHOPANE/HOPANE AS %
H 1 4 C30 DI AHOPANE PI/HOPANE AS %
H 1 5 CLEAN ANE/HOPANE AS %
H 1 6 GAMMACERANE/HOPANE AS % (205 BACK CALCULATE
H 1 7 HOPANE INDEX C35/(C35+C34) %
HI 8 25-NORHOPANE(Y)/HOPANE AS % G
H 1 9 C29 1 8 A-NORHOPANE D2/C30 HOPANE AS %
S 1 C29 STERANES 20S/(20S+20R)
S2 C29 STERANES m/z2 1 8 ABB/( ABB+AAA)
S3_l STERANE DISTRIBUTION AAA C27 %
S3 2
C28%
S3 3
C29%
S4_l STERANE DISTRIBUTION ABB C27 %
S4 2
C28 %
S4_3
C29 %
S5 BA DIASTERANES/(BA DIASTERANES+AAA+ABB STERAN
S7 STERANE INDEX C27/(C27+C29) % FROM S3
S8 C30 4-ME STERANE AS % OF C29 20R AAA
M4 SUM C27 TO C35 HOPANES/(SAME+C27 TO C29 STERANE
PR/PH PRISTANE/PHYTANE RATIO ESTIMATE
M2 PHENANTHRENES (3ME+2ME)/(9ME-HME)
M3 MPI 1 PHENANTHRENES (3ME+2ME) / (9ME+1 ME+PHEN) *
A 1 ARO STERANES: C28 20R TRI/(SAME+C29 20R 5A&B MON
A2 ARO STERANES: SUM TRI/(SAME-t-SUM MONOXF9&F12spl
A3 TRI ARO STERANES : C20/(C20+C28 20R)
A4 TRI ARO STERANES: (C20+C2 1 )/(SAME+SUM C26 TO C28)
A5 TRI ARO STERANES: C26 20S / C28 20S
A6 TRI ARO STERANES: C2720R/C2820R
MDR 4-ME DIBENZOTHIOPHENE / 1 -ME DIBENZOTHIOPHENE
MBP 3-METHYLBIPHENYL/2-METHYLBIPHENYL
MNR 2-MENAPTHALENE/l -ME NAPHTHALENE
SMN (2-ME N APTH+ 1-ME N APTH)/C23 TRIG YCLIC
DBTP DIBENZOTHOIOPHENE(MZ 1 84)/PHENANTHRENE(MZ 1 78
T 1 9 C 1 9 TRIG YCLIC/C23 TRIG YCLIC %
T20 C20 TRICYCLIC/C23 TRICYCLIC %
T2 1 C2 1 TRICYCLIC/C23 TRICYCLIC %
T22 C22 TRICYCLIC/C23 TRICYCLIC %
T23 C23 TRICYCLIC/C23 TRICYCLIC %
T24 C24 TRICYCLIC/C23 TRICYCLIC %
T25 C25 TRICYCLIC/C23 TRICYCLIC %
T26 C26 TRICYCLICS/C23 TRICYCLIC %
T28 C28 TRICYCLICS/C23 TRICYCLIC %
T29 C29 TRICYCLICS/C23 TRICYCLIC %
T30 C30 TRICYCLICS/C23 TRICYCLIC %
1 9/23 C 1 9 TRICYCLIC/C23 TRICYCLIC AS %
20/21 C20 TRICYCLIC/C21 TRICYCLIC AS %
22/21 C22TRICYCLIC/C21 TRICYCLIC AS %
24/23 C24 TRICYCLIC/C23 TRICYCLIC AS %
26/25 C26 TRICYCLICS/C25 TRICYCLIC AS %
244_24 C24 TETRACYCLIC/C24 TRICYCLIC AS %
TET_23 C24 TETRACYCLIC/C23 TRICYCLIC AS %
0.6
0.56
0.79
5.48
60.36
100
31.54
14.31
7.52
4.1
2.15
0.1
0.57
9.11
4.45
0.59
0.55
0.78
4.26
63.81
100
32.59
14.17
8.4
4.06
2.09
0.09
0.56
11.06
5.34
0.6
0.56
0.78
5.37
67.41
100
30.83
14.38
8.69
4.33
2.04
0.09
0.58
11.06
5.15
15.63
34.4
15.17
33.99
16.26
32.05
0.38
0.28
22.51
42.38
35.11
18.84
42.84
38.32
22.25
39.07
11.62
82.56
0.39
0.29
25.91
39.39
34.7
19.89
42.76
37.35
21.62
42.75
11.65
82.29
0.37
0.27
23.11
41.12
35.77
21.7
40.96
37.33
23.28
39.25
10.23
81.84
0.38
0.44
0.51
0.49
0.51
0.3
0.29
0.82
3.06
3.%
1.03
0.42
0.45
0.46
0.43
0.54
0.31
0.24
0.77
3.91
3.46
1.04
0.54
0.57
0.56
0.56
0.6
0.35
0.3
0.85
4.61
10.09
1.2
0.13
49.1
103.51
114.72
26.76
100
35.49
18.99
0.08
48.39
110.05
118.53
23.91
100
37.51
16.96
0.06
40.92
96.88
114.88
21.33
100
35.8
20.05
49.1
90.22
23.32
35.49
48.39
92.85
20.17
37.51
40.92
84.33
18.57
35.8
137.72
48.88
128.68
48.27
130.1
46.58
APPENDIX - C
CORE EXTRACTS DATA
BULK COMPOSITION OF EXTRACTS
34/11-4T2 Cores Extracts
Sample code
9906SED008S002
9906SED008S004
9906SED008S007
9906SED008S011
9906SED008S016
9906SED008S017
9906SED008S019
Depth (m)
4152.7
4157.95
4165.85
4176.85
4195.15
4196.15
4198.2
Rock(g)
4.608
5.469
6.567
9.422
6.116
6.498
7.442
WtExt(g) EOM (mg)
0.16187
0.16816
0.08006
0.16804
0.17079
0.18503
0.19315
161.87
168.16
80.06
168.04
170.79
185.03
193.15
%TSE
Saturates
Aromatics
Residue
Asph
HC
NonHC
3.513
3.075
1.219
1.783
2.793
2.847
2.595
98.1
98.7
98.2
94.8
94.8
97.85
98.97
0.3
0.3
0.5
1.7
2.9
0.8
0.29
1.4
0.8
1.3
2.6
1.8
1.01
0.5
0.19
0.19
0.01
0.88
0.45
0.34
0.24
98.4
99.0
98.7
96.6
97.8
98.7
99.3
1.4
0.8
1.3
2.6
1.8
1.0
0.5
EXTRACTION DATA 1
34/11-4T2 Core Extracts
Sample code
9906SED008S002
9906SED008S004
9906SED008S007
9906SED008S011
9906SED008S016
9906SED008S017
9906SED008S019
Depth
(m)
4152.7
4157.95
4165.85
4176.85
4195.15
4196.15
4198.2
Rock
(g)
4.608
5.469
6.567
9.422
6.116
6.498
7.442
EOM
(mg)
161.87
168.16
80.06
168.04
170.79
185.03
193.15
Sat/EOM Aro/EOM Pol/EOM Asph/EOM HC/EOM NON HC/EOM
EOM
%
(mg/Kg rock)
%
%
%
%
%
98.1
35128
0.3
1.4
0.19
98.4
1.4
98.7
30748
0.3
0.8
0.19
99.0
0.8
98.2
12191
0.5
0.01
98.7
1.3
1.3
17835
94.8
96.6
2.6
0.88
2.6
1.7
27925
94.8
0.45
97.8
2.9
1.8
1.8
97.85
0.34
98.7
28475
0.8
1.01
1.0
25954
98.97
0.24
99.3
0.29
0.5
0.5
EXTRACTION DATA 2
34/11-4T2 Core Extracts
nd= not determined
Sample code
9906SED008S002
9906SED008S004
9906SED008S007
9906SED008S011
9906SED008S016
9906SED008S017
9906SED008S019
Depth
(m)
4152.7
4157.95
4165.85
4176.85
4195.15
4196.15
4198.2
TOC
%
nd
nd
nd
nd
nd
nd
nd
EOM/TOC
(mg/gTOC)
nd
nd
nd
nd
nd
nd
nd
Sat
(mg/g TOC)
. nd
nd
nd
nd
nd
nd
nd
Aro
(mg/g TOC)
nd
nd
nd
nd
nd
nd
nd
Pol
Asph
(mg/gTOC) (mg/gTOC)
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
nd
100*Sat/Aro
%
32700
32900
19640
5576
3269
12231
34128
100*HC/NONHC
%
7029
12375
7592
3715
5433
9870
19860
SATURATE GC
9906SED008S002
4152.7m
Area
[uV-s]
9906SED008S004
4157.95m
Area
[uV-s]
9906SED008S007
4165.85m
Area
[uV-s]
N-C12
N-C13
N-C14
N-C15
N-C16
N-C17
PRISTANE
N-C18
PHYTANE
N-C19
N-C20
N-C21
N-C22
N-C23
N-C24
N-C25
N-C26
N-C27
N-C28
N-C29
N-C30
N-C31
N-C32
N-C33
N-C34
N-C35
N-C36
52197.8
191988.27
1631639.52
1111935.06
1221341.46
824384.09
318146.05
512818.16
173247.55
298905
193334.1
125478.2
82524.6
52637.8
34550.2
21817.1
16055.2
12231.7
9902.4
9225.6
6272.2
5040.4
3646.6
4501.16
1697.54
1639.56
1086.56
26255
114179.84
1163805.11
804681.41
1009447.21
586868.71
135147.29
387076.35
121728.66
248980.56
143273.2
94967.6
63066
36908.6
21757.7
12594.2
6967.06
6555
4378.89
4751.2
2520.06
2493.3
1695.65
2410.4
919.49
669.44
583
72793.2
222950.87
1652875.58
1063889.09
1249687.54
718012.24
167719.96
512404.43
163417.79
299757.9
207451.2
133855.8
108960.7
66278.6
47616
35046
28092
21519.2
17319.5
15971.8
10432.2
9901.1
7618.4
7236.9
3161.98
2698
2424.85
TOTAL
6918243.88
5004680.93
6849092.83
9906SED008S002
1.04
1.84
0.39
0.34
98.54
0.93
1.14
9906SED008S004
1.22
1.11
0.23
0.31
98.90
0.96
0.73
9906SED008S007
1.05
1.03
0.23
0.32
97.09
1.09
0.73
34/11-4T2 Core Extracts
Depth (m)
Saturates Fraction GC Analysis
Component
Batch Code
CPI (24 to 32)
Pr/Ph Ratio
Pr/n-C17
Ph/n-C18
Alkane Index (C17/(C17+C27)%
R22 Index 2*C22/(C21+C23)
(Pr/n-C17)/(Ph/n-C18)
Note: -1 denotes not calculated
SATURATE GC
9906SED008S011
4176.85m
Area
[uV-s]
9906SED008S016
4195.15m
Area
[uV-s]
9906SED008S017
4196.15m
Area
[uV-s]
9906SED008S019
4198.2m
Area
[uV-s]
N-C24
N-C25
N-C26
N-C27
N-C28
N-C29
N-C30
N-C31
N-C32
N-C33
N-C34
N-C35
N-C36
20758.6
89381.29
1061541.43
589898.04
755977.37
442095.57
101417.73
333380.82
129489.91
175086.8
103863
66555.6
40486.9
22425.6
10944.5
5233.4
2139.86
1387.16
1060.61
1323.6
535.46
0
0
0
0
0
0
11238.4
85235.45
1112797.8
903557.24
892288.7
642604.6
141836.2
455195.41
149276.52
253407.9
164384.43
102594.5
66328
39499.6
24323.5
14452
9906.8
7450.6
5707.62
5969.8
3224.47
3273.55
2550.66
3043.26
1296.5
991.95
807.51
22231.6
85605.94
928226.14
538877.07
534579.4
354321.3
77920.7
221012.9
27196.3
145300.56
81681.2
52268.6
33029.8
18536.6
9498.3
5163.5
2250.08
1795.58
1398.52
1552.6
696.14
717.86
485.2
828.01
236.42
288.6
165.76
22706.8
112784.57
1183230.96
901775.12
1162312.82
723340.83
156299.17
522038.47
175664.03
297448.6
193538.51
122109.6
82632.3
52618.8
33564.7
21182
14542.1
11416.8
9071.9
8586.5
5290.6
4941.4
3406.6
3934.18
1765.19
1206.9
1138.8
TOTAL
3512887.67
5103242.96
3145864.7
5828548.25
9906SED008S011
1.33
0.78
0.23
0.39
99.69
0.91
0.59
9906SED008S016
1.09
0.95
0.22
0.33
98.85
0.93
0.67
9906SED008S017
1.29
2.87
0.22
0.12
99.50
0.93
1.79
9906SED008S019
1.08
0.89
0.22
0.34
98.45
0.95
0.64
34/11-4T2 Core Extracts
Depth (m)
Saturates Fraction GC Analysis
Component
N-C12
N-C13
N-C14
N-C15
N-C16
N-C17
PRISTANE
N-C18
PHYTANE
N-C19
N-C20
»N-C21
- N-C22
N-C23
r
Batch Code
CPI (24 to 32)
Pr/Ph Ratio
Pr/n-C17
Ph/n-C18
Alkane Index (C17/(C17+C27)%
R22 Index 2*C22/(C21+C23)
(Pr/n-C17)/(Ph/n-C18)
Note: -1 denotes not calculated
C:\ DATA\B9906008\ARO002.RAW
V3/9/99
9906SED008S002
Software Version:
Sample Name:
Instrument:
Raw Data File:
Sequence File:
4.1<OG07>
9906SED008S002 34/11-4T2 4152.7m
SAC_GC
C:\_DATA\B9906008\AR0002.RAW
C:\_DATA\B9906008\ARO_GC.SEQ
Aromatics GC
Component
Name
Time
[min]
1-MENAPTHALENE
2-ME NAPTHALENE
2,6+2,7-DIMETHYLNAPT
1,3+1,7-DIMETHYLNAPT
1,6-DIMETHYLNAPTHALE
1,5+1,5+2,3-DIMETHYL
1,2-DIMETHYLNAPTHALE
PHENANTHRENE
3-ME PHENANTHRENE
Area
[uV-s]
41621.8
6843.4
54968.1
27752.8
17397.2
36288.29
19414.01
25702.7
16332.8
102145.3
345752.9
41773.71
73051.28
16468.65
24460.25
5983.8
21563.73
14715.22
52258.65
31414.2
14580
50941.13
19877.32
29260.15
16862.82
16292.98
21620.28
44598.45
55359.37
60249.82
30821.57
89566.1
195434.9
65148.41
20481.75
25604.05
23435
29623.66
30189.94
31893.27
50130.43
35406.69
7526.91
62030.2
12842.29
9162.31
12150.03
15532.66
49882.6
58912.1
34832.25
8.421
8.906
9.281
9.504
9.705
10.455
10.559
10.625
10.724
10.894
10.999
11.082
11.131
11.295
11.364
11.542
11.806
11.858
11.927
12.004
12.252
12.473
12.535
12.606
12.791
12.852
13.022
13.112
13.17
13.296
13.432
13.513
13.624
13.744
14.305
14.384
14.463
14.612
14.691
14.819
14.941
15.055
15.358
15.498
15.615
15.762
15.821
15.978
16.08
16.387
16.804
Pagel
Area
[%]
1.41
0.23
1.87
0.94
0.59
1.23
0.66
0.87
0.56
3.47
11.75
1.42
2.48
0.56
0.83
0.2
0.73
0.5
1.78
1.07
0.5
1.73
0.68
0.99
0.57
0.55
0.73
1.52
1.88
2.05
1.05
3.04
6.64
2.21
0.7
0.87
0.8
1.01
1.03
1.08
1.7
1.2
0.26
2.11
0.44
0.31
0.41
0.53
1.7
2
1.18
C:\ DATA\B9906008\ARO002.RAW
V3/9/99
2-ME PHENANTHRENE
9-ME PHENANTHRENE
1-ME PHENANTHRENE
16.859
16.981
17.056
17.108
17.168
17.372
17.56
17.724
17.968
18.092
18.205
18.28
18.7
18.797
18.863
19
19.091
19.19
19.487
19.655
19.933
20.137
20.494
20.844
20.955
21.051
21.676
21.919
22.847
23.162
24.077
25.228
28.178
28.911
33.84
Page 2
9906SED008S002
29980.95
11689.5
17254.15
11911.05
18008.7
89172.2
13177
14812.2
39175.4
11977.6
19630.33
17799.67
13484.1
15468.72
14917.08
30014.05
21660.24
13162
4574.9
14582.5
16481.6
12424.4
13850.5
17736.33
13408.27
11385.8
6303.6
5705.1
36855.8
10757.6
42161.4
85612
17258
33611
46.7
1.02
0.4
0.59
0.4
0.61
3.03
0.45
0.5
1.33
0.41
0.67
0.6
0.46
0.53
0.51
1.02
0.74
0.45
0.16
0.5
0.56
0.42
0.47
0.6
0.46
0.39
0.21
0.19
1.25
0.37
1.43
2.91
0.59
1.14
0
2942209
100
C:\ DATA\B9906008\ARO004.RAW
V3/9/99
9906SED008S004
Software Version:
4.1<OG07>
Sample Name:
Instrument:
Raw Data File:
Sequence File:
9906SED008S004 34/1MT2 4157.95m
SAC_GC
C:\_DATA\B9906008\ARO004.RAW
C:\_DATA\B9906008\ARO_GC.SEQ
Aromatics GC
Component
Name
Time
[min]
1-MENAPTHALENE
2-MENAPTHALENE
2,6+2,7-DIMETHYLNAPT
1,3+1,7-DIMETHYLNAPT
1,6-DIMETHYLNAPTHALE
1,5+1,5+2,3-DIMETHYL
1 >DIMETHYLNAPTHALE
PHENANTHRENE
3-ME
2-ME
9-ME
1-ME
PHENANTHRENE
PHENANTHRENE
PHENANTHRENE
PHENANTHRENE
Area
[nV-s]
8.435
9.291
9.516
9.714
10.465
10.635
10.893
10.996
11.086
11.136
11.299
11.369
11.538
11.804
11.86
11.931
12.006
12.259
12.413
12.481
12.543
12.609
12.792
12,861
12.967
13.111
13.297
13.463
13.619
13.741
14.303
14.381
14.459
14.609
14.687
14.942
15.014
15.317
15.493
15.973
16.076
16.799
16.853
17.052
17.103
17.357
17.962
18.197
19.182
20.489
22.674
22.837
24.067
28.897
33.824
25587.8
25609
13515.7
7449.6
21655.4
7444.6
33353.68
215881.6
22482.39
51721.61
9780.22
13734.28
5411.2
13592.5
8243.48
30064.36
17513.66
19925.61
11426.14
55192.06
61589.97
15308.82
9381
106692.4
10532
15107.4
10502.2
9097.9
1.88
1.88
0.99
0.55
1.59
0.55
2.45
15.83
1.65
3.79
0.72
1.01
0.4
1
0.6
2.2
1.28
1.46
0.84
4.05
4.52
13149.8
99.97
1.12
0.69
7.82
0.77
1.11
0.77
0.67
8.47
2.44
0.87
0.92
0.49
0.9
1.1
3.12
1.23
1.99
1.97
0.57
2.09
0.94
0.93
0.57
0.41
1.64
1.36
0.52
0.32
0.46
0.44
2.28
0.83
0.96
0.01
1363911
100
115578.1
33238.67
11931.89
12563.11
6742.2
12271.8
14978.8
42508.1
16722.8
27156.8
26819.6
7823
28564.8
12824.92
12643.28
7795.6
5592.4
22400.6
18566.2
7076
4327.6
6316
6064.1
31077.4
11280.8
Pagel
Area
[%]
C:\ DATA\B9906008\ARO007.RAW
V3/9/99
Software Version:
Sample Name:
Instrument:
Raw Data File:
Sequence File:
Aromatics GC
Component
Name
1-MENAPTHALENE
2-MENAPTHALENE
2,6+2,7-DIMETHYLNAPT
1,3+1,7-DIMETHYLNAPT
1,6-DIMETHYLNAPTHALE
1,5+1,5+2,3-DIMETHYL
1,2-DIMETHYLNAPTHALE
9906SED008S007
4.1<OG07>
9906SED008S007 34/11-4T2 4165.85m
SAC_GC
C:\_DATA\B9906008\ARO007.RAW
C:\_DATA\B9906008\ARO_GC.SEQ
Time
[min]
Area
[uV-s]
7.599
7.784
8.437
8.922
9.299
9.52
9.756
10.113
10.23
10.294
10.469
10.572
10.739
10.918
11.011
11.098
11.144
11.304
11.371
11.548
11.7
11.823
11.941
12.053
12.264
12.421
12.49
12.554
12.618
12.804
12.87
12.977
13.033
13.12
13.185
13.234
13.31
14693.6
10070.5
44365.6
12795.2
108874
49758.1
24432.8
17028.6
5722.07
9912.73
59249.34
9760.06
42205.4
116267.5
387127.7
83374.4
127734.8
22581.7
41163.3
6534.4
14106.8
19028.04
112858.4
51270.76
24698.5
16795.62
82774.91
112697.7
49911.32
36029.22
148525.3
23592.63
25610.1
35025.42
37838.9
28170.18
72263.07
33596.6
175140.3
46958.2
18406.8
18519.6
27217.23
30876.96
43187.93
58950.79
16765
70779.85
50382.45
13388.01
36279.39
13.447
13.631
13.75
13.864
14.313
14.471
14.543
14.624
14.702
14.823
14.951
15.027
15.224
15.327
Page 1
Area
[%]
0.38
0.26
1.15
0.33
2.82
1.29
0.63
0.44
0.15
0.26
1.54
0.25
1.09
3.01
10.03
2.16
3.31
0.59
1.07
0.17
0.37
0.49
2.93
1.33
0.64
0.44
2.15
2.92
1.29
0.93
3.85
0.61
0.66
0.91
0.98
0.73
1.87
0.87
4.54
1.22
0.48
0.48
0.71
0.8
1.12
1.53
0.43
1.83
1.31
0.35
0.94
C:\ DATA\B9906008\ARO007.RAW
V3/9/99
PHENANTHRENE
3-ME PHENANTHRENE
2-ME PHENANTHRENE
9-ME PHENANTHRENE
1-MEPHENANTHRENE
15.507
15.986
16.082
16.125
16.272
16.388
16.814
16.869
17.064
17.116
17.169
17.371
17.565
17.726
17.97
18.097
18.207
18.286
18.347
18.472
18.702
18.798
19
19.092
19.189
19.403
19.491
19.655
19.881
20.133
20.495
20.837
20.952
21.066
21.675
22.139
22.679
22.841
23.161
24.072
24.282
25.215
28.171
28.903
33.843
9906SED008S007
80545.8
29454.78
54524.06
36226.84
16098.38
50664.33
51857.53
49174.27
37189.39
27737.7
17869.91
74977.6
48130.85
41612
19741.2
19507.4
15602
14731.26
19788.14
11887.2
14605.37
12300.03
13816.6
4979.8
12105
12031.4
18448.39
12270.21
10337
9482.3
13202.3
9934.2
26709.2
21347.2
24206.4
5977.4
10976
13468.4
24904.1
12.2
0.96
0.72
0.46
1.94
0.63
0.46
1.23
0.78
0.64
1.25
1.08
0.51
0.51
0.4
0.38
0.51
0.31
0.38
0.32
0.36
0.13
0.31
0.31
0.48
0.32
0.27
0.25
0.34
0.26
0.69
0.55
0.63
0.15
0.28
0.35
0.65
3.00E-04
3858019
100
24466.88
17693.92
47432
30073.73
24620.82
Page 2
2.09
0.76
1.41
0.94
0.42
1.31
1.34
1.27
C:\ DATA\B9906008\ARO011.RAW
V3/9/99
9906SED008S011
Software Version:
Sample Name:
Instrument:
Raw Data File:
Sequence File:
4.1<OG07>
9906SED008S011 34/11-4T2 4176.85m
SAC_GC
C:\_DATA\B9906008\ARO011.RAW
C:\_DATA\B9906008\ARO_GC.SEQ
Aromatics GC
Component
Name
Time
[min]
Area
[uV-s]
Area
[%]
9.299
9.52
10.891
10.98
11.085
11.131
11.394
11.539
11.927
12.851
13.171
13.61
13.738
14.384
14.458
14.61
14.685
14.815
14.935
15.5
15.614
16.074
16.34
16.801
16.854
17.049
17.101
17.358
17.554
17.963
18.199
18.274
18.491
18.702
18.797
18.94
19.001
19.083
19.719
19.939
20.116
20.191
1727
834.66
2886.24
13889.2
2674.35
2130.45
1894.2
803.2
8935.2
8216.2
15513.6
43555.66
12838.94
5615.76
5679.44
17121.39
13136.21
9182.8
12749
109745.4
17868.6
16773.8
15591.4
28506.75
31071.25
15791.16
18888.64
23047.1
28830.6
20851
7261.87
14944.33
36642.26
15985.87
19090.87
1 1257.84
75379.72
10485.24
9618.8
27824.3
11707.5
12840
15701.09
18177.21
6711.2
5368.8
15346.48
21323.32
13120.6
15108.4
16015
14385.4
28830.39
15260.61
8215.8
12113.8
14094.2
74.67
0.18
0.09
0.29
1.42
0.27
0.22
0.19
0.08
0.91
0.84
1.58
4.45
1.31
0.57
0.58
1.75
1.34
0.94
1.3
11.21
1.82
1.71
1.59
2.91
3.17
1.61
1.93
2.35
2.94
2.13
0.74
1.53
3.74
1.63
1.95
1.15
7.7
1.07
0.98
2.84
1.2
1.31
1.6
1.86
0.69
0.55
1.57
2.18
1.34
1.54
1.64
1.47
2.94
1.56
0.84
1.24
1.44
0.01
979234.8
100
1-MENAPTHALENE
2-MENAPTHALENE
2,6+2,7-DIMETHYLNAPT
1,3+1,7-DIMETHYLNAPT
1,6-DIMETHYLNAPTHALE
1,5+1,5+2,3-DIMETHYL
1,2-DIMETHYLNAPTHALE
PHENANTHRENE
3-ME PHENANTHRENE
2-ME PHENANTHRENE
9-ME PHENANTHRENE
1 -ME PHENANTHRENE
20.411
20.479
20.835
21.544
22.062
22.135
22.834
23.155
24.068
24.637
25.179
25.277
27.557
28.034
28.897
33.764
Pagel
C:\ DATA\B9906008\ARO016.RAW
V3/9/99
9906SED008S016
Software Version:
Sample Name:
Instrument:
Raw Data File:
Sequence File:
4.1<OG07>
9906SED008S016 34/11-4T2 4195.15m
SAC_GC
C:\_DATA\B9906008\AR0016.RAW
C:\_DATA\B9906008\ARO_GC.SEQ
Aromatics GC
Component
Name
Time
[min]
1-MENAPTHALENE
2-MENAPTHALENE
2,6+2,7-DIMETHYLNAPT
1,3+1,7-DIMETHYLNAPT
1,6-DIMETHYLNAPTHALE
1,5+1,5+2,3-DIMETHYL
1,2-DIMETHYLNAPTHALE
PHENANTHRENE
3-ME PHENANTHRENE
2-ME PHENANTHRENE
9-ME PHENANTHRENE
1 -ME PHENANTHRENE
Area
[uV-s]
9.294
9.518
10.893
10.981
11.084
11.132
11.401
11.543
13.17
13.605
15.488
16.794
16.847
17.044
17.097
18.483
18.987
33.77
Pagel
Area
6116.07
4502.86
3636.85
15279
2497.42
1846.08
657.2
806.1
5537.1
13194.5
28314
6135.3
6775.73
2422.5
3610.6
10412.4
25185.2
17.13
4.47
3.29
2.66
11.16
1.82
1.35
0.48
0.59
4.04
9.63
20.68
4.48
4.95
136946.1
100
1.77
2.64
7.6
18.39
0.01
C:\ DATA\B9906008\ARO017.RAW
V3/9/99
4.1«X307>
Software Version:
Sample Name:
Instrument:
Raw Data File:
Sequence File:
C:\_DATA\B9906008\ARO017.RAW
C:\_DATA\B9906008\ARO_GC.SEQ
AromaticsGC
Component
Name
Time
[min]
1-ME NAPTHALENE
2-MENAFTHALENE
2,6+2,7-DIMETHYLNAPT
1,3+1,7-DIMETHYLNAPT
1,6-DIMETHYLNAPTHALE
1,5+1,5+2,3-DZMETHYL
1,2-DIMETHYLNAPTHALE
PHENANTHRENE
3-ME
2-ME
9-ME
1-ME
PHENANTHRENE
PHENANTHRENE
PHENANTHRENE
PHENANTHRENE
9906SED008S017
9906SED008S017 34/11-4T2 4196.15nTime:
SAC_GC
Channel:
Area
17876
42369.3
31552.4
34520
17818.7
26969.4
111922.1
11903.35
7.594
9.293
9.517
10.465
10.731
10.894
10.99
11.085
1U34
11.4
11.543
11.929
12.044
12.471
12.608
13.174
13.295
13.612
13.739
14.302
14.381
14.608
14.685
14.816
14.935
15.501
15.613
16.074
16.34
16.8
16.852
17.048
17.101
17.354
17.553
17.963
18.196
18.491
18.707
18.796
19.002
19.081
19.72
19.94
20.115
20.191
20.409
20.478
21.543
22.062
22.134
22.839
23.156
24.065
24.634
25.18
25.277
27.556
28.034
28.895
33.767
10233.86
4944.2
4644.8
31006.8
12939.4
20141.81
5822.79
29493.6
8768.4
58020.4
13769
6191.49
6957.91
16857.36
12030.44
9475
13981
1.35
3.19
2.38
2.6
1.34
2.03
8.43
0.9
0.77
0.37
0.35
2.34
0.97
1.52
0.44
2.22
0.66
14157.2
13460.2
10.17
4.37
1.04
0.47
0.52
1.27
0.91
0.71
1.05
8.7
1.5
1.11
0.64
1.93
1.95
1.07
1.18
0.66
2.04
1.24
0.51
3.11
1.18
1.27
6.88
0.99
0.67
1.91
0.87
0.88
1.1
1.26
0.42
1.18
1.52
3.53
0.65
1.04
1.07
1.79
1.2
0.72
1.07
1.01
8.00E-04
1327797.8
100
115467.8
19939.2
14723.9
8463.6
25613.52
25903.98
14256.16
15665.64
8742.4
27066.6
16418.4
6757.3
41266
15625.13
16807.27
91383.3
13121.1
8885.2
25421.2
11519.7
11688.2
14627.33
16726.47
5616.6
15608.56
20118.24
46837
8595.2
13772.6
14153
23753.27
15879.13
9537.7
Pagel
Area
C:\ DATA\89906008\ARO019.RAW
V3/9/99
9906SED008S019
Software Version:
Sample Name:
Instrument:
Raw Data File:
Sequence File:
9906SED008S019 34/11-4T2 4198.2m
SAC_GC
C:\_DATA\B9906008\AR0019.RAW
C:\_DATA\B9906008\ARO_GC.SEQ
Aromatics GC
Component
Name
Time
[min]
1-MENAPTHALENE
2-ME NAPTHALENE
2,6+2,7-DIMETHYLNAPT
1,3+1,7-DIMETHYLNAPT
1,6-DIMETHYLNAPTHALE
1,5+1,5+2,3-DIMETHYL
1,2-DIMETHYLNAPTHALE
4.1<OG07>
7.596
8.436
8.921
9.295
9.519
9.717
10.291
10.467
10.569
10.635
10.734
10.902
11.007
11.093
11.14
11.303
11.37
11.467
11.551
11.769
11.864
11.934
12.011
12.1
12.259
12.477
12.542
12.612
12.798
12.857
13.025
13.114
13.179
13.3
13.434
13.533
13.626
13.746
14.307
PHENANTHRENE
14.386
14.463
14.522
14.613
14.693
14.818
14.942
15.047
15.501
15.618
15.763
15.821
Area
[jiV-s]
21451.4
38845.2
11404.6
82534.4
42546.2
4211.4
16883.7
44562.79
20415.59
24232.63
30551.9
112504.6
326878.7
50863.39
89751.8
28061.34
28605.66
7796.58
7101.4
4919.4
10819.19
45048.71
8618.8
8653.4
17859.9
46792.53
19803.98
26727.29
15193.8
15809.6
20457.9
35342.83
54512.54
50835.81
37601.75
25385.36
162911.9
55887.78
18275.29
19589.31
10626.75
17471.45
30095.92
30095.68
26088.6
30070.8
13201.2
79724.5
13908.6
8645.83
7150.37
Area
[%]
0.8
1.45
0.43
3.08
1.59
0.16
0.63
1.67
0.76
0.91
1.14
4.2
12.22
1.9
3.35
1.05
1.07
0.29
0.27
0.18
0.4
1.68
0.32
0.32
0.67
1.75
0.74
1
0.57
0.59
0.76
1.32
2.04
1.9
1.41
0.95
6.09
2.09
0.68
0.73
0.4
0.65
1.12
1.12
0.97
1.12
0.49
2.98
0.52
0.32
0.27
C:\ DATA\B9906008\ARO019.RAW
V3/9/99
3-ME PHENANTHRENE
2-ME PHENANTHRENE
9-ME PHENANTHRENE
1-ME PHENANTHRENE
15.977
16.079
16.804
16.859
17.055
17.107
9906SED008S019
15803.6
0.59
29243.4
1.09
36916
1.38
35053.9
1.31
16353.2
0.61
15410.6
0.58
11439.2
0.43
23910.6
0.89
21054.28
0.79
13879.12
0.52
34850.2
1.3
15635.1
0.58
16444.81
0.61
16301.19
0.61
19671.8
0.74
15428.89
0.58
9242.91
0.35
0.5
13459.67
39052.56
1.46
21324.68
0.8
8894.3
0.33
14994
0.56
8008.85
0.3
15398.95
0.58
8223
0.31
10142.2
0.38
16306.2
0.61
10602.2
0.4
11552.8
0.43
10190.5
0.38
14191.5
0.53
12517.6
0.47
42617.8
1.59
8753.2
0.33
66694
2.49
12856.6
0.48
26042
0.97
20.83 8.00E-04
17.164
17.359
17.558
17.721
17.965
18.09
18.204
18.276
18.492
18.791
18.861
18.942
18.998
19.088
19.186
19.652
19.717
19.939
20.196
20.412
20.486
20.855
22.134
22.677
22.836
23.157
24.07
24.276
25.218
28.168
28.899
33.811
2675812
Page 2
100
GC-MS PEAK HEIGHT DATA
PEAK HEIGHTS
MPDMIO00854021.LIS PDMIO00854031.LIS PDMIO008S4041XIS PDMIO00854051US
34/1 1-4T2 4 152.7m 34/1 1-4T2 4 157.95m 34/1 1-4T2 4165.85m 34/1 1-4T2 4 176.85m
$9906SED008S002$ $9906SED008S004$ $9906SED008S007$ $9906SED008S011$
PRISTANE
PHYTANE
C19 TRICYCLIC TERPANE(19/3)
C20 TRICYCLIC TERPANE(20/3)
C21 TRICYCLIC TERPANE(21/3)
C22 TRICYCLIC TERPANE(22/3)
C23 TRICYC TERPANE(T5:23/3)
C24 TRICYC TERPANE (24/3)
C25 TRICYC TERPANE (25/3)
C24 TETRACYC TERP ($:24/4)
C26 TRICYCLIC TERPANE(26/3)
C26 TRICYCLIC TERP 2 (26/3)
C28 TRICYCLIC TERPANE(28/3)
C28 TRICYCLIC TERP 2 (28/3)
C29 TRICYCLIC TERPANE(29/3)
C29 TRICYCLIC TERP 2 (29/3)
C2718AHOPANE (Ts:27Ts)
C2717AHOPANE (Tm:27Tm)
C30 TRICYCLIC TERPANE(30/3)
C30 TRICYCLIC TERP 2 (30/3)
25-TRISNORm/zl 77(25nor28ab)
C28 BISNORHOPANE (X:28ab)
25-NOR m/z!77 (Y:25nor30ab)
25-NORHOPANE (Y:25nor30ab)
C29 HOPANE
(D:29ab)
C29 18A NORHOPANE (D2:29Ts)
C30 C30 DIAHOPANE (PI:30d)
C29NORMORETANE (A:29ba)
C3018AOLEANANE (B:30O)
C30 HOPANE
(G/.30ab)
NOR-GAMMACERANE?
(G2)
C30 MORETANE
(K:30ba)
C3 1 22S HOPANE (N:3 labS)
C3122R HOPANE (O:31abR)
C3122SM/Z205
(N205)
C3122RM/Z205
(O205)
C30 GAMACERANE (S:30G)
C30 17B 21B HOPANE (P)
C3222S HOPANE (U:32abS)
C3222R HOPANE (V:32abR)
C33 22S HOPANE(Alpha:33abS)
C33 22R HOPANE (Beta:33abR)
C34 22S HOPANE(Gamma:34abS)
C34 22R HOPANE(DcIta:34abR)
C35 22S HOP (Epsilon:35abS)
C35 22R HOPANE (Zeta:35abR)
C21 STERANE
C27 20S DIASTER (10:27dbS)
C27 20R DIASTER (1 l:27dbR)
C27 20S AAA STER (20:27aaS)
C29 20S DIASTER (21A:29dbS)
C27 20R ISOST218(21B:27bbR)
C27 20S ISOST218 (22:27bbS)
C27 20R ISOSTER 217 (27bbR)
C27 20S ISOSTER 217 (27bbS)
C27 20R AAA STER (25:27aaR)
C29 20R DIASTER (27:29dbR)
C28 20R ISOST2 1 8(33 A:28bbR)
C28 20S ISOST218 (34:28bbS)
C28 20R ISOSTER 217 (28bbR)
C28 20S ISOSTER 217 (28bbS)
C28 20R AAA STER (36:28aaR)
C29 20S AAA STER (39:29aaS)
C29 20R ISOST218 (40:29bbR)
C29 20S ISOST218 (41:29bbS)
C2920RISOSTER217 (29bbR)
C2920SISOSTER217 (29bbS)
C29 20R AAA STER (42:29aaR)
C3020RISOSTER218 (30bbR)
C3020SISOSTER218 (30bbS)
C30 4-METHYL STERANE (46)
0
0
0
0
968293
3692970
4636710
973979
4613860
1779420
1239010
2019940
977898
956691
994005
850196
1153010
5736970
1242520
7841620
0
0
0
976042
0
0
26658100
0
0
3420880
0
39181900
0
0
2730910
6453580
1430410
4893180
1950760
1048960
2565210
1023250
1183810
0
0
0
0
1390090
11828700
0
0
0
0
0
0
42159900
0
0
10570700
7702820
11068400
2656900
2213110
0
1279480
3857200
2707880
2191910
1807750
1144980
774568
898082
666785
1188220
1446150
1075700
1428660
1236110
1119160
968766
1236110
895257
2236430
1094090
1647600
1559510
1908730
1428930
3703590
2048170
1395120
1554150
1413730
1489490
3163920
242831
245833
377677
5243410
0
65510100
0
17383700
11918200
19167700
4233330
3540160
0
2306110
6195240
4190130
3246600
2718400
1709030
1377160
1141820
733184
1253860
1809390
1256870
2037550
1552220
1280150
0
0
0
2805500
6670810
1404630
5191200
2160100
1431130
2630010
1019050
1185370
917673
781048
0
0
1623430
12379300
0
0
0
0
0
0
41052900
0
0
5369520
0
66644900
0
18414900
1 1922600
18609500
4105450
3448310
0
2560780
5907360
3988530
3011680
2688560
1498600
1070050
970790
602932
2243620
2570780
1745340
2303340
2242210
0
0
1289500
3056810
3505640
762956
3192140
1116300
575717
1509470
600357
551205
0
0
0
0
608446
5607070
0
0
0
0
0
0
18483700
0
0
2412060
0
27880500
0
7254540
4877970
7682430
1714440
1364030
0
731011
2348470
1627340
1212790
1029660
580364
547913
443712
271672
549970
729560
487496
848855
550130
1711480
1373020
2242210
492251
1030560
3362080
1257190
2178100
2007190
1361090
3650800
1907450
333491
1472950
422651
2615180
848540
2626580
802128
2630490
1892570
3059390
2373210
6311620
3475020
1039430
691387
1152530
1552220
5939920
3154600
1884500
1994980
1971480
2033240
4929000
275775
347763
530751
2389830
2403240
2464630
2312390
5306810
477673
0
557544
407407
550130
2465620
1262490
721275
730998
686470
678372
2090440
108681
0
252182
GC-MS PEAK HEIGHT DATA
PEAK HEIGHTS
MPDMIO0085402 1 US PDMIO00854031JJS PDM1O00854041.LIS PDMIO00854051.L1S
34/1 1-4T2 4152.7m 34/1 1-4T2 4157.95m 34/ll-4T24165.85m 34/1 1-4T2 4 176.85m
$9906SED008S002$ $9906SED008S004S $9906SED008S007$ S9906SED008S011S
2-ME NAPHTHALENE
1 -ME NAPHTHALENE
2-MEBIPHENYL
3-MEBIPHENYL
4-MEBIPHENYL
PHENANTHRENE
3-ME PHENANTHRENE
2-ME PHENANTHRENE
9-ME PHENANTHRENE
1-ME PHENANTHRENE
DffiENZOTfflOPHENE
4-ME DEBENZOTfflOPHENE
3+2-ME DIBENZOTHIOPHENE
1-ME DffiENZOTfflOPHENE
C21 MA STERANE (F22:A1)
C22 MA STERANE (F23:B1)
C2720S5BDMMA-ST(F2:C1)
C27 20S 10B DM MA-DIA (Cl)
C27 20R 5B DM MA-ST(F3:D1)
C27 20S 5A DM MA-ST(F4:D1)
C28 20S 5B DM MA-ST(F5:E1)
C2720S5ADMMA-DS( :F1)
C27 20R 5A DM MA-ST(F6:G1)+
C28 20S 5A DM MA-ST(F7:G1)
C28 20R 5B DM MA-ST(F8:G1)
C29 20S 5B DM MA-ST(F9:G1)
C29 20S 5A DM MA-ST(F10:H1)
C28 20R 5A DM MA-ST(F1 1:H1)
C29 20R 5B DM MA-ST(F12:H1)
C29 20R 5A DM MA-ST(F13:I1)
C20 ME TA-STER(F14:al)
C21 META-STER(F15:bl)
C26 20S ME TA-STER(F16:cl)
C26 20R ME TA-STER(F17:dl)+
C27 20S ME TA-STER(F18:dl)
C28 20S ME TA-STER(F19:el)
C27 20R ME TA-STER(F20:fl)
C28 20R ME TA-STER(F21:gl)
7C2120SDIASTER
7C2120RDIASTER
?C21 AAA+ABB
?C22 DIASTER
?C22 AAA+ABB
.
138820000
82587200
2268660
57294300
18549000
36155700
14645800
1 1978000
18077400
8972000
1601830
2937820
990019
408023
424651
285029
166649
537926
734920
218149
969140
128887
543405
543405
954682
1027420
268160
411082
536676
290438
811332
494832
206805
858309
858309
622751
465910
540148
1261900
448944
1188220
0
542680
133435000
77222600
2065680
49301900
16322700
29687000
12764500
10519300
17105500
8858690
1735190
2965180
1042340
436450
206348
432279
172333
673997
1011420
261892
1432550
221602
567777
567777
1212040
1548960
389547
533557
838814
417130
916742
598173
322048
1436800
1436800
1118350
758407
939563
1479090
538827
1253860
0
576589
266059008
136801008
3161790
107476000
33052200
45261300
23107500
19320900
33720600
14919400
2599900
6079940
1871830
533558
266320
533223
134882
766762
1038800
313320
1376840
201501
634010
634010
1243210
1512320
383587
509572
759779
386272
2345860
1452910
379665
1395840
1395840
1037680
693294
989384
2408080
1028090
2243620
0
713790
312440000
271120992
8812430
85047104
37254800
320250016
53263600
39041700
54606000
43906800
9113960
2189970
1638410
1183620
231500
156543
107026
381361
436103
93502
623815
103811
258021
258021
530941
628633
148029
179422
297616
129568
341436
298895
120810
550790
550790
372024
280138
379664
678132
259832
549970
0
283627
GC-MS PEAK HEIGHT DATA
MPDMIO00854061.LIS PDMIO00854071.LIS PDMIO00854081US
34/1 1-4T2 4195.15m 34/ll-4T24196.15m 34/1 1-4T2 4198.2m
$9906SED008S016$ $9906SED008S017$ $9906SED008S019$
PEAK HEIGHTS
PRISTANE
PHYTANE
C19 TRICYCLIC TERPANE(19/3)
C20 TRICYCLIC TERPANE(20/3)
C21 TRICYCLIC TERPANE(21/3)
C22 TRICYCLIC TERPANE(22/3)
C23 TRICYC TERPANE(T5:23/3)
C24TRICYCTERPANE (24/3)
C25 TRICYC TERPANE (25/3)
C24 TETRACYC TERP ($:24/4)
C26 TRICYCLIC TERPANE(26/3)
C26 TRICYCLIC TERP 2 (26/3)
C28 TRICYCLIC TERPANE(28/3)
C28 TRICYCLIC TERP 2 (28/3)
C29 TRICYCLIC TERPANE(29/3)
C29 TRICYCLIC TERP 2 (29/3)
C2718AHOPANE (Ts:27Ts)
C2717AHOPANE (Tm:27Tm)
C30 TRICYCLIC TERPANE(30/3)
C30 TRICYCLIC TERP 2 (30/3)
25-TRISNORm/zl 77(25nor28ab)
C28 BISNORHOPANE (X:28ab)
25-NOR m/z!77 (Y:25nor30ab)
25-NORHOPANE (Y:25nor30ab)
C29 HOPANE
(D:29ab)
C29 ISA NORHOPANE (D2:29Ts)
C30C30DIAHOPANE (PI:30d)
C29 NORMORETANE (A:29ba)
C3018AOLEANANE (B:30O)
C30 HOPANE
(G:30ab)
NOR-GAMMACERANE?
(G2)
C30 MORETANE
(K:30ba)
C3 1 22S HOPANE (N:3 1 abS)
C3122R HOPANE (O:31abR)
0
0
1718650
3282430
3327450
686165
3033820
1154450
627451
1451840
658005
629103
0
0
0
0
658782
6261450
0
0
0
0
0
0
19060300
0
0
2600930
0
28853100
0
7825950
5502520
8382260
0
0
2132430
1871980
4264990
908576
3598120
1293750
774814
1610760
646429
595166
0
0
0
0
682972
6350610
0
0
0
0
0
0
21659300
0
0
2874620
0
33809200
0
8638540
5713230
0
0
6697400
4048440
9040570
1560070
5870030
2264000
1463720
2771100
1414900
1123750
0
0
0
0
1544490
16046900
0
0
0
0
0
0
58160400
0
0
7521910
0
93063000
0
25108300
9354220
16944300
26851800
C3122SM/Z205
(N205)
1993530
2030240
6133440
C3122RM/Z205
(O205)
1640670
0
1000990
2753470
1859150
1468260
1214200
710913
647345
528461
329728
849893
864769
568661
1025890
724667
639476
498473
724667
482411
1619150
550873
1073320
1751970
0
5051880
0
3295560
8471880
5927480
5456000
4463120
2543340
1924420
1610370
1134260
C30 GAMACERANE
C30 1 7B 2 1 B HOPANE
(S:30G)
(P)
C3222S HOPANE (U:32abS)
C32 22R HOPANE (V:32abR)
C33 22S HOPANE(Alpha:33abS)
C33 22R HOPANE (Beta:33abR)
C34 22S HOPANE(Gamma:34abS)
C34 22R HOPANE(Delta:34abR)
C35 22S HOP (Epsilon:35abS)
C35 22R HOPANE (Zcta:35abR)
C21STERANE
C27 20S DIASTER (10:27dbS)
C27 20R DIASTER (1 1 :27dbR)
C27 20S AAA STER (20:27aaS)
C29 20S DIASTER (21 A:29dbS)
C27 20R ISOST218(21B:27bbR)
C27 20S 1SOST218 (22:27bbS)
C27 20R ISOSTER 217 (27bbR)
C27 20S ISOSTER 217 (27bbS)
C27 20R AAA STER (25:27aaR)
C29 20R DIASTER (27:29dbR)
C28 20R ISOST218(33A:28bbR)
C28 20S ISOST218 (34:28bbS)
C28 20R ISOSTER 217 (28bbR)
C28 20S ISOSTER 2 1 7 (28bbS)
C28 20R AAA STER (36:28aaR)
C29 20S AAA STER (39:29aaS)
C29 20R ISOST218 (40:29bbR)
C29 20S ISOST218 (41 :29bbS)
C2920RISOSTER217 (29bbR)
C2920SISOSTER217 (29bbS)
C29 20R AAA STER (42:29aaR)
C3020RISOSTER218 (30bbR)
C30 20S ISOSTER218 (30bbS)
C30 4-METHYL STERANE (46)
920619
1313280
849511
2747010
1424980
876637
895558
904880
868503
2388230
153990
0
254143
1039230
2841260
1886160
1470310
1219990
743253
642096
511468
373764
677551
2054970
799325
564803
1050930
2380990
1476200
2935880
622984
1989840
594808
476007
1759410
1488830
622984
460234
1772960
1989840
1315350
544147
1109650
973680
1328260
912990
3062990
1554610
926222
912356
929828
876583
2460210
140706
0
277101
4697100
1611920
3255800
2839980
3584450
2409300
8679610
4507470
2792400
2678360
2635970
2589430
7379250
446101
0
718973
GC-MS PEAK HEIGHT DATA
PEAK HEIGHTS
2-ME NAPHTHALENE
1-ME NAPHTHALENE
2-MEBIPHENYL
3-MEBIPHENYL
4-MEBIPHENYL
PHENANTHRENE
3-ME PHENANTHRENE
2-ME PHENANTHRENE
9-ME PHENANTHRENE
1 -ME PHENANTHRENE
DIBENZOTHIOPHENE
4-ME DIBENZOTHIOPHENE
3+2-ME DIBENZOTHIOPHENE
1-ME DIBENZOTHIOPHENE
C21 MA STERANE(F22:A1)
C22 MA STERANE (F23:B1)
C27 20S 5B DM MA-ST(F2:C1)
C27 20S JOB DM MA-DIA (Cl)
C27 20R 5B DM MA-ST(F3:D1)
C27 20S 5 A DM MA-ST(F4:D1)
C28 20S 5B DM MA-ST(F5:E1 )
C27 20S 5A DM MA-DS( :F1)
C27 20R 5A DM MA-ST(F6:G1H
C28 20S 5A DM MA-ST(F7:G1)
C28 20R 5B DM MA-ST(F8:G1)
C29 20S 5B DM MA-ST(F9:G1)
C29 20S 5A DM MA-ST(F10:H1)
C28 20R 5A DM MA-ST(F1 1:H1)
C29 20R 5B DM MA-ST(F12:H1)
C29 20R 5A DM MA-ST(F13:I1)
C20 ME TA-STER(F14:al)
C21 META-STER(F15:bl)
C26 20S ME TA-STER(F16:cl)
C26 20R ME TA-STER(F17:dl>+
C27 20S ME TA-STER(F18:dl)
C28 20S ME TA-STER(F19:el)
C27 20R ME TA-STER(F20:n)
C28 20R ME TA-STER(F21:gl)
?C21 20S DIASTER
7C2120R DIASTER
?C21 AAA+ABB
?C22 DIASTER
?C22 AAA+ABB
MPDMIO00854061.LIS PDNOO00854071US PDMIO008S4081JJS
34/H-4T2 4195.15m 34/ll-4T24196.15m 34/1 1-4T2 4 198.2m
$9906SED008S016$ $9906SED008S017$ $9906SED008S019$
313944000
269918016
11509800
113992000
47834600
668832000
102120000
82362104
112344000
86063800
18709600
5418620
3545070
2214030
241743
211227
166443
376512
527671
124277
672620
137876
305095
305095
680952
0
168508
252188
400766
189822
675337
539663
155038
790358
790358
379064992
315134016
9787800
78912304
32863700
340683008
50024800
39228900
54854900
43859500
10351700
2728780
1882830
1229900
188288
186787
117754
440560
568830
146193
786786
104987
344479
215344000
126855000
2697640
51151400
17351700
57243200
16936200
226220
396266
13465400
17760500
10722900
2621800
3360610
1256280
429317
0
379977
334284
965604
1206330
244855
1748770
212368
838379
838379
1543590
1889890
517632
611107
1025250
180771
465525
1137210
344479
727858
0
194169
361875
156322
722839
1065450
464578
2047040
451597
363195
488481
958505
456273
869912
303665
2047040
1460960
1204110
1456930
412563
979044
677551
0
359982
2054970
0
628849
526699
307165
849893
0
366348
722839
474388
539379
GC-MS BIOMARKER PARAMETERS
34/1 1-4T2 41 52.7m 34/1 1-4T2 4157.95m 34/1 1-4T2 4165.85m 34/1 1-4T2 4176.85m
MPDMIO00854021 MPDMIO00854031 MPDMIO00854041 MPDMIO00854051
HSRUN
Hl
C32 HOPANES 22S/(22S+22R)
H2 C3 1 HOPANES 22S/(22S+22R) M/Z205
H3 C30: HOPANE/(HOPANE+MORETANE)
H4 C30:BBHOPANE/C30HOPANEAS%
H5 0 C29 HOPANE AS % C30
H5 1 HOPANE DISTRIBUTION RELATIVE TO C30
H5_2 C3 1 HOPANES AS % OF C30 (205 CORRECTED)
H5 3 C32 HOPANES
H5 4 C33 HOPANES
H5 5 C34 HOPANES
H5_6 C35 HOPANES
H6 C27 HOPANES TS/(TS+TM)
H7 C33 HOPANES 22S/(22S+22R)
Hil C23 TRICYCLIC/C30 HOPANE AS %
H12 C24 TETRACYCLIC/C30 HOPANE AS %
H13 28 30 BISNORHOPANE/HOPANE AS %
H14 C30 DIAHOPANE PI/HOPANE AS %
H15 OLEANANE/HOPANEAS%
HI 6 GAMMACERANE/HOPANE AS % (205 BACK CALCULATED)
HI 7 HOPANE INDEX C35/(C35+C34) %
HIS 25-NORHOPANEOO/HOPANE AS % G
H19 C29 18A-NORHOPANE D2/C30 HOPANE AS %
SI C29 STERANES 20S/(20S+20R)
S2 C29 STERANES m/z2 1 8 ABB/( ABB+AAA)
S3 1 STERANE DISTRIBUTION AAA C27 %
S3 2
C28%
S3_3
C29 %
S4 1 STERANE DISTRIBUTION ABB C27 %
S4_2
C28 %
S4_3
S5
S7
S8
C29 %
BA DIASTERANES/(BA DIASTERANES+AAA+ABB STERANES) %
STERANE INDEX C27/(C27+C29) % FROM S3
C30 4-ME STERANE AS % OF C29 20R AAA
M4 SUM C27 TO C35 HOPANES/(SAME+C27 TO C29 STERANES)
PR/PH PRISTANE/PHYTANE RATIO ESTIMATE
M2
PHENANTHRENES (3ME+2ME)/(9ME+1ME)
M3
MPI1 PHENANTHRENES (3ME+2ME) / (9ME+1ME+PHEN) * 1.5
Al
A2
ARO STERANES: C28 20R TRI/(SAME+C29 20R 5A&B MONO 12
ARO STERANES: SUM TRI/(SAME+SUM MONOXF9&F1 2split)
A3
TRI ARO STERANES: C20/(C20+C28 20R)
A4
TRI ARO STERANES: (C20+C2 1 V(SAME+SUM C26 TO C28)
A5
TRI ARO STERANES: C26 20S / C28 20S
A6
TRI ARO STERANES: C27 20R / C28 20R
MDR 4-ME DBBENZOTfflOPHENE / 1-ME DIBENZOTfflOPHENE
MBP 3-METHYLBIPHENYL/2-METHYLBIPHENYL
MNR 2-ME N APTHALENE/1 -ME NAPHTHALENE
SMN (2-ME NAPTH+1-ME NAPTH)/C23 TRICYCLIC
DBTP DffiENZOTHOIOPHENE(MZ184VPHENANTHRENE(MZ178)
Tl 9 Cl 9 TRICYCLIOC23 TRICYCLIC %
T20 C20 TRICYCLIC/C23 TRICYCLIC %
T21 C2 1 TRICYCLIC/C23 TRICYCLIC %
T22
C22 TRICYCLIC/C23 TRICYCLIC %
T23 C23 TRICYCLIC/C23 TRICYCLIC %
T24 C24 TRICYCLIC/C23 TRICYCLIC %
T25 C25 TRICYCLIC/C23 TRICYCLIC %
T26 C26 TRICYCLICS/C23 TRICYCLIC %
T28 C28 TRICYCLICS/C23 TRICYCLIC %
T29 C29 TRICYCLICS/C23 TRICYCLIC %
T30 C30 TRICYCLICS/C23 TRICYCLIC %
19/23 C19TRICYCLIC/C23 TRICYCLIC AS %
20/21 C20 TRICYCLIC/C21 TRICYCLIC AS %
0.79
3.27
68.04
100
36.03
16.76
10.21
4.9
3.99
0.14
0.55
11.78
5.16
0.6
0.54
0.79
3.52
64.36
100
33.41
15.85
9.11
4.71
2.86
0.11
0.54
7.47
3.92
100
32.92
14.85
8.55
3.85
2.36
0.12
0.53
7.79
3.95
0.79
2.62
66.3
100
31.42
14.26
8.04
4.05
2.57
0.1
0.54
11.45
5.41
11.87
44.91
14.05
37.79
12.9
37.99
13.63
38.8
0.39
0.36
24.57
40.68
34.75
25.33
38.9
35.77
30.42
41.41
11.94
75.31
0.39
0.32
23.63
41.74
34.64
23.17
39.87
36.96
27.31
0.4
0.35
23.91
41.34
34.75
23.51
0.38
0.3
24.43
40.9
34.67
22.48
41.24
40.55
10.77
79.01
40.76
10.51
76
36.28
26.44
41.34
12.06
79.3
1.11
0.87
0.35
1.01
0.85
0.39
0.98
0.9
0.49
0.35
0.6
0.33
0.33
0.86
7.2
0.39
0.49
0.25
0.29
0.81
6.79
0.42
0.46
0.7
0.46
0.37
0.7
11.4
25.25
23.87
1.73
33.99
1.94
0.06
0.06
55.81
131.89
29.23
54.04
128.5
27.06
100
41.61
27.57
42.46
32.72
0.59
0.55
1.68
0.04
20.99
80.04
100.5
21.11
100
38.57
26.85
41.93
39.97
20.99
79.65
21.01
22/21 C22 TRICYCLIC/C21 TRICYCLIC AS %
24/23 C24 TRICYCLIC/C23 TRICYCLIC AS %
26/25 C26 TRICYCLICS/C25 TRICYCLIC AS %
38.57
156.14
244_24 C24 TETRACYCLIC/C24 TRICYCLIC AS %
TET_23 C24 TETRACYCLIC/C23 TRICYCLIC AS %
113.52
43.78
too
39.87
21.44
45.1
0.6
0.54
0.78
3.84
61.6
39.95
36.53
31.61
0.59
0.56
1.06
0.43
0.36
0.47
0.27
0.32
0.74
1.85
9.65
1.15
0.03
40.4
95.76
109.82
23.9
100
34.97
18.04
36.07
42.32
22.16
42.06
21.06
40.4
87.2
21.76
39.87
210.4
131.5
41.61
154.03
34.97
200.02
121.75
50.66
135.22
47.29
52.42