Main research areas of the Faculty CHEMICAL STABILIZATION OF METALS/ METALLOIDS IN CONTAMINATED SOILS Team introduction: Chemical stabilization is a soil remediation method based on the application of various inorganic and organic amendments to contaminated soils. These stabilizing agents lower the mobility and bioavailability of risk elements in such soils. Immobilization is achieved through several physico-chemical processes, such as adsorption, complexation, precipitation and co-precipitation. Our research team studies sorption mechanisms on various amendments, mostly iron and manganese (nano-)oxides and biochar. The efficiency of the stabilizing agents is evaluated using batch, column and lysimeter experiments in the laboratory and field and modeled using geochemical and hydropedological transport models. Team members: Dr. Michael Komárek (team leader, environmental geochemistry; contact: [email protected]) Dr. Lukáš Trakal (hydropedology; contact: [email protected]) Dr. Martina Vítková (environmental mineralogy; contact: [email protected]) Contacts Address: Faculty of Environmental Sciences, Czech University of Life Sciences Prague Kamýcká 129 165 21 Prague 6 – Suchdol Tel. +420 224 382 147 e-mail: [email protected] w w w . f z p. c z u . c z / e n Main research areas of the Faculty of Environmental Sciences 5 most significant recent publications by team members: Komárek M., Koretsky C.M., Stephen K.J., Alessi D.S., Chrastný V. 2015. Competitive adsorption of Cd(II), Cr(VI) an Pb(II) onto nano-maghemite: A spectroscopic an modeling approach. Environmental Science & Technology. Vítková M., Komárek M., Tejnecký V., Šillerová H., 2015. Interactions of nano-oxides with low-molecular-weight organic acids in a contaminated soil. Journal of Hazardous Materials 293, 7-14. Trakal L., Bingöl D., Pohořelý M., Hruška M., Komárek M., 2014. Geochemical and spectroscopic investigations of Cd and Pb sorption mechanisms on contrasting biochars: Engineering implications. Bioresource Technology 171, 442-451. Komárek M., Vaněk A., Ettler V., 2013. Chemical stabilization of metals and arsenic in contaminated soils using oxides - A review. Environmental Pollution 172, 9-22. Trakal L., Kodešová R., Komárek M., 2013. Modelling of Cd, Cu, Pb and Zn transport in metal contaminated soil and their uptake by willow (Salix x smithiana) using HYDRUS- 2D program. Plant and Soil 366, 433-451. Applied outcomes of the research and further potential applications of the research: Metal contamination of soils is a serious environmental problem. The development of innovative non-destructive soil remediation methods is currently under intensive research and chemical stabilization represents a gentle approach. Nano-oxides are becoming an interesting stabilizing amendment particularly owing to their high specific surface and reactivity. The development of geochemical and transport models describing contaminant behavior and migration on remediated sites is also crucial for the evaluation of remediation procedure efficiency. Keywords: soil contamination; chemical stabilization; nano-oxides; biochar; metals; metalloids w w w . f z p. c z u . c z / e n
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