South Pasadena • Honors Chemistry Name 4 · Salts and Solutions Period 4.4 Date QUICK CHECK Check off each item if you can do the question. Write down a question to ask if you cannot do the question. Strong Acid/Base, and Soluble Salt Solutions 1. Given a 0.0010 M solution of barium hydroxide. Find the pH and pOH. Ba(OH)2 (aq) Ba2+ (aq) + 2 OH− (aq) Initial 0.0010 M 0M 0M Change −0.0010 M +0.0010 M +0.0020 M Final 0M 0.0010 M 0.0020 M [Ba(OH)2] = 0 M pOH = − log(0.0020) = 2.70 [Ba2+] = 0.0010 M pH = 14.00 – 2.70 = 11.30 [OH−] = 0.0020 M [H+] = 10−11.30 = 5.0 × 10−12 M 2. Given a 0.0010 M solution of aluminum acetate. Find the concentration of all ions. Al(C2H3O2)3 (s) Al3+ (aq) + 3 C2H3O2− (aq) Initial 0.0010 M 0M 0M Change −0.100 M +0.0010 M +0.0030 M Final 0M 0.0010 M 0.0030 M [Al(C2H3O2)3] = 0 M [Al3+] = 0.0010 M [C2H3O2−] = 0.0030 M Weak Acid/Base 3. Given a 0.0010 M solution of hypobromous acid. Find the pH and % dissociation. Ka = 2 × 10−9. HOBr (aq) H+ (aq) + OBr− (aq) Initial 0.0010 M 0M 0M Change −x +x +x Equil. 0.0010 – x x x [H+][OBr−] (x)(x) x2 Ka = = = = 2 × 10−9 [HOBr] (0.0010 − x) 0.0010 Because this is a weak acid, we can assume that x is very small compared to 0.0010, so (0.0010 – x) ≈ 0.0010. x = 1.4 × 10−6 [HOBr] = 0.0010 – x = 0.0010 – (1.4 × 10−6) = 0.0010 M [H+] = x = 1.4 × 10−6 M [OBr−] = x = 1.4 × 10−6 M −6 pH = − log (1.4 × 10 ) = 5.85 x 1.4 × 10−6 M % dissociation = × 100% = × 100% = 0.14% i 0.0010 M Insoluble Salt 4. Given a saturated solution of silver chromate. Find its solubility and the concentration of dissolved ions. Ksp = 9.0 × 10−12. Scratch Paper/Notes:
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