Name
bp °C/mm (mp)
MW
D420
TITANIUM
element and common binary componds)
Titanium
*α-phase
Titanium dioxide
Anatase
Rutile
Atomic number:
22
Atomic/molecular weight:
47.867
79.90
79.90
CAS #:
7440-32-6
1317-70-0
1317-80-2
Melting point:
1,668˚C
Converts to rutile
1,830-1,850˚C
Enthalpy of melting:
18.8 kJ/mole
Thermal Properties
Boiling point:
3,287˚C
Enthalpy of vaporization:
425 kJ/mole
Thermal conductivity, 27˚C:
21.9 W/(m K)
Heat capacity, 20˚:
0.52 J/kg˚
600˚/10-4 sub
5-10.4 W/(m K)
Electrical Properties
Resistivity, 20˚:
1 x 1010-14 μΩ·cm
42.0 μΩ·cm
100˚:
Electrode potential
0.86 V (+4)
(st'd hydrogen scale):
Dielectric constant:
425
85-170
2.54
2.75
3.89
4.24
Optical Properties
54%
Reflectivity:
Refractive index; α
β
γ
Acoustical Properties
Velocity of sound:
4,140 m/s
Bulk Properties
Specific gravity, 20˚:
4.507
Molar volume:
10.64 cm3
Young's modulus:
120,000 MPa
Tensile strength:
230-460 MPa
Hardness, Mohs:
6.0
Hardness, Vickers:
970 MN/m2
Crystal form:
Space group:
Cell parameters, a:
1.1-1.5 MPa
5.5-6
7-7.5
Hexagonal close packed
P63/mmc
Tetragonal
141/amd
Tetragonal
295.11 pm
378.45 pm
459.37 pm
468.43 pm
951.43 pm
295.87 pm
P42/mnm
b:
c:
Chemical Properties
Oxidation states:
0, 2, 3, 4
Electronegativity, Pauling:
1.54
Ionization potential, spectral:
6.82 eV
13.58 eV
* at temperatures >882.5˚ titanium
converts to a β-phase
nD20
Name
MW
nD20
D420
bp °C/mm (mp)
COMPOUNDS
AKT841
O-ALLYLOXY(POLYETHYLENEOXY)TRIISOPROPOXYTITANATE, 95%
OiC H
660-780
1.08
OiC3H 7
H 2C
CHCH 2(OCH 2CH 2)10O
Ti
3
OiC3H 7
7
TITANIUM (ALLYLOXYPOLYETHYLENEOXIDE)TRIISOPROPOXIDE
C32H66O14Ti (approx)
Average of 10 -(OCH2CH2)- units
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
HMIS: 2-3-1-X
25g ¥8,500
100g ¥16,800
（既） 1-1118
INTI004
AMMONIUM HEXAFLUOROTITANATE
197.97
H8F6N2Ti
TOXICITY: ivn mus, LD50: 56 mg/kg
Color: white
Reagent for micropatterned SrTiO3 films.1
In combination with H3BO3 forms titania coatings on glass fibers.2
Intermediate for TiNxOyFz photocatalyst.3
1. Gao, Y. et al. Chem. Mater. 2002, 14 , 5006.
2. Razgon, A. et al. J. Mater. Res . 2005, 20 , 2544.
3. Maeda, K. et al. Chem. Mater. 2009, 21 , 2286.
(NH 4)2TiF 6
HYDROLYTIC SENSITIVITY: 0: forms stable aqueous solutions
[16962-40-6]
TSCA
EC 241-036-9
HMIS: 3-0-0-X
25g ¥16,800
OMTI008
BIS(t-BUTYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE
C18H26Cl2Ti
Color: red
C(CH 3)3
Cl
Ti Cl
C(CH 3)3
361.19
(195)
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
HMIS: 2-1-0-X
[79269-71-9]
2.5g ¥38,500
10g ¥115,000
OMTI010
BIS(CYCLOPENTADIENYL)TITANIUM(III) CHLORIDE
213.55
NUGENT'S REAGENT; TITANOCENE MONOCHLORIDE
C10H10ClTi
Dimeric in solid state, monomeric in solution
Color: green
Soluble: THF
Reagent for one-electron reduction of epoxides.1
Reagent for rapid preparation of protected glycals.2
1. Gold, H. Synlett 1999, 159.
2. Schwartz, J. et al. J. Org. Chem. 1999, 64 , 3987.
Ti Cl
HYDROLYTIC SENSITIVITY: 9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric glove box or sealed system required
HMIS: 3-2-1-X
[60955-54-6]
store <5°C
5g ¥61,000
BIS(CYCLOPENTADIENYL)TITANIUM DICHLORIDE see OMTI085 TITANOCENE DICHLORIDE
OMTI012
BIS(CYCLOPENTADIENYL)TITANIUM DIFLUORIDE
216.05
C10H10F2Ti
Color: yellow
Soluble: chloroform, THF, toluene
Catalyst for conversion of lactones to lactols.1
1. Depré, D. et al. Org. Process Res. Dev. 2008, 12 , 96.
F
Ti
F
120 / 0.01 sub
(238-280 dec)
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
HMIS: 3-2-0-X
[309-89-7]
2.5g ¥39,500
（既） 5-6507
BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)534.39
(160-170)
PHENYL)TITANOCENE
C30H22F4N2Ti
TOXICITY: oral rat, LD50: >2,000 mg/kg
Color: orange-yellow
Soluble: acetone, methylethylketone, > hexanediol diacrylate, toluene
Visible (blue-green) light and UV photoinitiator
Long wavelength photoinitiator with Al- (488nm) and FD Nd/YAG- (532nm) lasers
OMTI014
F
F
Ti
N
F
F
N
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[125051-32-3]
TSCA
HMIS: 3-2-1-X
store <5°C
10g ¥32,000
25
Name
nD20
OMTI016
CH 3
H 3C
CH 3
H 3C
Cl
H 3C
D420
bp °C/mm (mp)
MW
CH 3
Ti Cl
CH 3
H 3C
CH 3
BIS(PENTAMETHYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE
C20H30Cl2Ti
Color: red-brown
(190 dec)
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[11136-36-0]
CH 3
389.23
HMIS: 3-2-1-X
5g ¥64,500
OMTI018
Cl
CYCLOPENTADIENYLTITANIUM TRICHLORIDE
C5H5Cl3Ti
Color: yellow
Ti
Cl
219.35
(198-9)
(>210 dec)
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
Cl
HMIS: 3-2-1-X
[1270-98-0]
5g ¥24,500
25g ¥84,500
OMTI020
CO Ti
DICYCLOPENTADIENYLDICARBONYL TITANIUM(II)
234.09
C12H10O2Ti
Color: red
Catalyst for conversion of enynes to cyclopentenones.1
1. Hicks, F. et al. J. Am. Chem. Soc. 1996, 118 , 9450.
CO
HYDROLYTIC SENSITIVITY: 9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric glove box or sealed system required
[12129-51-0]
（既） 1-319
HEXAFLUOROTITANIC ACID, 60% in water
H2F6Ti
H 2TiF 6
5g ¥84,500
HMIS: 3-2-1-X
INTI021
163.91
1.675
HYDROLYTIC SENSITIVITY: 0: forms stable aqueous solutions
[17439-11-1]
TSCA
EC 241-460-4
1.5kg ¥16,000
HMIS: 3-0-0-X
PBL6465
劇物
LEAD TITANATE
303.09
O3PbTi
TOXICITY: ipr rat, LD50: 2,000 mg/kg
Crystallization temperature: ≥705°
Mixed lead zirconate titanates (PZT) possess piezoelectric properties
[12060-00-3]
TSCA
EC 235-038-9 HMIS: 2-0-0-X
100g ¥10,800
PbTiO3
劇物
PBL6459
LEAD TITANIUM OXOACETOXYETHOXIDE
1386.86
C16H38O10PbTi2
Dimeric
Soluble: hexane, toluene
[PbTi 2O(OOCCH 3)(OC 2H 5)7]2
In combination with Ti(OR)4, an intermediate for PbTiO3 by sol-gel
Employed in solution deposition of PZT ferroelectric thin films
films.1
1. Tuttle, B. et al. Mater. Res. Soc. Bull . 1996 21(6) , 49.
HMIS: 3-2-1-X
7.52
2.66
(130-144)
50g ¥30,500
OMTI046
OiC3H 7
H 3C
Ti OiC3H 7
OiC3H 7
METHYLTITANIUM TRIISOPROPOXIDE, 1M in tetrahydrofuran
C10H24O3Ti
Color: yellow
Selective methylation reagent
240.18
50-2 / 0.02
(10)
0.895
HYDROLYTIC SENSITIVITY: 8: reacts rapidly with moisture, water, protic solvents
[18006-13-8]
CH 3
H 3C
CH 3
H 3C
Cl
Ti
Cl
HMIS: 3-4-1-X
store <5°C
25g ¥49,500
OMTI050
CH 3
Cl
H 3C
CH 3
Ti
CH 3O
OCH 3
OCH 3
289.47
(225)
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[12129-06-5]
HMIS: 3-2-1-X
5g ¥53,500
OMTI052
CH 3
H 3C
PENTAMETHYLCYCLOPENTADIENYLTITANIUM TRICHLORIDE
C10H15Cl3Ti
CH 3
PENTAMETHYLCYCLOPENTADIENYLTITANIUM TRIMETHOXIDE
C13H24O3Ti
Yellow liquid
276.21
285
Flashpoint: 61°C (142°F)
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[123927-75-3]
HMIS: 2-2-1-X
5g ¥67,500
1.081
1.5540
Name
D420
bp °C/mm (mp)
MW
nD20
OMTI054
OiC3H 7
PHENYLTITANIUM TRIISOPROPOXIDE, 1M in tetrahydrofuran
302.27
(80-2)
(>100 dec)
Ti OiC3H 7 PHENYLTRIS(2-PROPOXO)TITANIUM
C15H26O3Ti
OiC3H 7
Color: pale yellow
Reagent for substitution of alkenyl sulfones to form allyl arenes.1
1. Yoshida, K. et al. J. Am. Chem. Soc. 2003, 125 , 2872.
HYDROLYTIC SENSITIVITY: 8: reacts rapidly with moisture, water, protic solvents
[111452-11-0]
HMIS: 3-4-1-X
store <5°C
25g ¥47,000
OMTI057
N
N
N
Ti
N
N
PHTHALOCYANINE TITANIUM OXIDE
576.44
C32H16N8OTi
γ modification
UV max: 717 nm
Color: deep blue
E1/2: 1.4 erg/cm2
Charge generator for laser printers; sensitizer for reprographics.1
1. Haisch, P. et al. Adv. Mater . 1997, 9 , 316.
N
O
N
N
(547)
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[26201-32-1]
1.0g ¥25,500
HMIS: 2-1-0-X
5g ¥88,500
TITANIUM ACETOACETATE - see AKT855 TITANIUM DIISOPROPOXIDE(BIS-2,4-PENTANEDIONATE)
H 2C
AKT843
CHCH 2O
C
O
C
O
Ti
HC
H 3C
(OiC3H 7)3
TITANIUM ALLYLACETOACETATETRIISOPROPOXIDE
C16H30O6Ti
358.25
(55-60)
1.056
1.508
Slowly crystallizes after melting
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
25g ¥9,800
HMIS: 2-3-1-X
100g ¥20,500
AKT844
(CH 3)3C
C
O
Cl
C
O
Ti
2 Cl
HC
(CH 3)3C
TITANIUM BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE DICHLORIDE
C22H38Cl2O4Ti
Color: orange
485.33
215 dec
(127-9)
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
HMIS: 3-1-1-X
[53293-32-6]
(HOCH 2CH 2)2NCH 2CH 2O
OiC3H 7
Ti
(HOCH 2CH 2)2NCH 2CH 2O
+
OiC3H 7
mixed chelates
5g ¥24,500
（既） 2-2167
AKT845
TITANIUM BIS(TRIETHANOLAMINE)DIISOPROPOXIDE, 80% in isopropanol
C18H42N2O8Ti
Metal content: 8.0-8.4% Ti
Equilibrium mixture of monomers, oligomers
Soluble: water, isopropanol
Adhesion promoter for aqueous laminating inks
462.42
Flashpoint: 12°C (54°F)
TOXICITY: oral rat, LD50: 13,525 mg/kg
Viscosity, 25˚: 90 cSt
1.065
1.488
HYDROLYTIC SENSITIVITY: 6: forms irreversible hydrate
[36673-16-2]
TSCA
EC 253-153-2
TiB2
HMIS: 3-4-1-X
25g ¥10,500
100g ¥24,000
（既） 1-1164
INTI027
TITANIUM BORIDE, powder
B2Ti
Particle size: ~10 μ
Thermal conductivity, 25˚: 20-60 W/m˚C
Coefficient of thermal expansion: 8.1 x 10-6
Employed in ceramic armor plate
69.52
(2,850-2,900)
4.52
Color: gray
Electrical conductivity: 10-30 micro ohm-cm
HYDROLYTIC SENSITIVITY: 1: no significant reaction with aqueous systems
[12045-63-5]
TSCA
EC 234-961-4
50g ¥13,300
HMIS: 1-0-0-X
TITANIUM iso-BUTOXIDE - see AKT870 TITANIUM ISOBUTOXIDE
（既） 2-2150
AKT850
TITANIUM n-BUTOXIDE
340.36
154 / 1
(-50)
Flashpoint: 76°C (169°F)
TOXICITY: oral rat, LD50: 3,122 mg/kg
ΔHform: -399 kcal/mole
ΔHvap: 9.8 kcal/mole
Dielectric constant: 3.0
Dipole moment: 1.68
TETRABUTYLTITANATE
OCH 2CH 2CH 2CH 3
Ti
CH 3CH 2CH 2CH 2O
OCH 2CH 2CH 2CH 3
1.493
C16H36O4Ti
Metal content: 14.0-14.2% Ti
Viscosity, 25˚: 67 cSt
Vapor pressure, 140˚: 0.5 mm
Vapor pressure, 200˚: 19 mm
Surface tension: 28.0 dynes/cm
Transesterification catalyst
Forms KTP (potassium titanylphosphates) with KOEt and phosphate esters.1
Improves adhesion of polyethylene extruded onto aluminum.2
1. Barbé, C. et al. J. Sol.-Gel Sci. Technol . 1997, 9 , 183.
2. Brill, H. C. U.S. Patent 3,002,854, 1962.
COMMERCIAL
CH 3CH 2CH 2CH 2O
0.998
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[5593-70-4]
TSCA
EC 227-006-8
HMIS: 2-2-1-X
100g ¥7,000
2kg ¥25,500
18kg inquire
Name
bp °C/mm (mp)
MW
D420
nD20
TITANIUM n-BUTOXIDE POLYMER - see PTI-023 POLY(BUTYLTITANATE)
AKT850.1
H3C CH2
HC O Ti
H3C
4
TITANIUM s-BUTOXIDE
C16H36O4Ti
340.33
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[873376-17-1]
HMIS: 3-4-1-X
100g ¥18,000
AKT850.2
tC4H 9O
OtC4H 9
Ti
OtC4H 9
tC4H 9O
TITANIUM t-BUTOXIDE
340.36
60 / 0.3
0.881
C16H36O4Ti
Vapor pressure, 27˚C: 0.05 mm
ΔHform (l): -349 kcal/mole
Vapor pressure, 50˚C: 0.30 mm
ΔHform(g): -325 kcal/mole
Vapor pressure, 75˚C: 1.6 mm
Molecular complexity: 1.0
Vapor pressure, 125˚C: 20.15 mm
Average bond dissociation energy (Ti-O): 101 kcal/mole
Improves adhesion of polyethylene extruded onto aluminum.1
1. Brill, H. C. U.S. Patent 3,002,854, 1962.
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[3087-39-6]
EC 221-412-9
25g ¥37,500
HMIS: 2-2-1-X
INTI079
Cl3Ti•(THF)3
TITANIUM(III) CHLORIDE, tetrahydrofuran complex
370.56
C12H24Cl3O3Ti
1:3 complex
Color: pale blue
Forms bimetallic complexes.1
1. Grillo, V. et al. J. Chem. Soc., Chem. Commun. 1997, 1561.
(>250 dec)
HYDROLYTIC SENSITIVITY: 8: reacts rapidly with moisture, water, protic solvents
[18039-90-2]
HMIS: 3-2-1-X
OCH 2CH 2CH 2CH 3
Cl
Ti OCH 2CH 2CH 2CH 3
OCH 2CH 2CH 2CH 3
25g ¥69,500
（既） 2-2202
AKT850.5
TITANIUM CHLORIDE TRI-n-BUTOXIDE
C12H27ClO3Ti
Catalyst component for olefin polymerization.1
Highly active catalyst for alcoholysis of silane esters.2
1. Morini, G. et al. PCT Int'l WO 2004085495.
2. Khonina, T. et al. Russ. J. Chem . 1997, 67 , 79.
302.68
154 / 0.2
1.099
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[4200-76-4]
EC 224-100-0
25g ¥12,500
HMIS: 3-2-1-X
AKT851
Cl
OiC3H 7
Ti
iC3H 7O
OiC3H 7
Cl
OiC3H 7
Ti
OiC3H 7
iC3H 7O
TITANIUM CHLORIDE TRIISOPROPOXIDE, 95%
260.62
63-6 / 0.1
(34-6)
1.091
C9H21ClO3Ti
Flashpoint: 22°C (72°F)
Reagent for conversion of carbanions and enolates to titanates with stereoselectivity.1,2
1 S
1.
Seigel,
i l C
C. and
d Th
Thornton,
t
E
E. R
R. Tetrahedron
T t h d
Lett
L tt . 1986,
1986 27 , 457
457.
2. Nerz-Stonies, M.; Thornton, E. R. Tetrahedron Lett . 1986, 27 , 897.
F&F: Vol. 11, p 375; Vol. 14, p 87.
HMIS: 3-3-1-X
100g ¥10,000
500g ¥26,500
TSCA
[20717-86-6]
AKT851.1
TITANIUM CHLORIDE TRIISOPROPOXIDE, 2M in hexane
(58 wgt%)
C9H21ClO3Ti
260.62
0.898
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[20717-86-6]
TSCA
HMIS: 3-4-1-X
25g ¥8,500
750g ¥21,500
AKT851.2
Cl
OiC3H 7
Ti
OiC3H 7
iC3H 7O
TITANIUM CHLORIDE TRIISOPROPOXIDE, 1.25M in tetrahydrofuran (34.6 wgt%)
C9H21ClO3Ti
260.62
Flashpoint: 22°C (72°F)
0.941
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[20717-86-6]
TSCA
HMIS: 3-4-1-X
25g ¥9,300
750g ¥25,500
25g ¥9,300
750g ¥25,500
AKT851.3
Cl
OiC3H 7
Ti
iC3H 7O
OiC3H 7
TITANIUM CHLORIDE TRIISOPROPOXIDE, 2M in heptane
C9H21ClO3Ti
260.62
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[20717-86-6]
TSCA
HMIS: 3-4-1-X
TITANIUM CRESYLATE - see AKT881 TITANIUM METHYLPHENOXIDE
1.5169
Name
O
CH 3CH 2CH 2CH 2O
CHC4H 9
OC
CHC4H 9
O
bp °C/mm (mp)
D420
C2H 5
TITANIUM DI-n-BUTOXIDE BIS(2-ETHYLHEXANOATE)
C24H48O6Ti
Low temperature pyrolysis yields TiO2 films
480.52
1.017
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
25g ¥13,500
HMIS: 2-2-1-X
AKT852.5
C2 H 5
H 3C
CHO
H 3C CH 2
O
Ti
O
2
C2 H 5
2
TITANIUM DI-s-BUTOXIDE BIS(3,5-HEPTANEDIONATE)
C22H40O8Ti
Color: orange-red
Precursor for CVD of TiO2
456.39
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
HMIS: 2-2-1-X
C
CH 3
170 / 0.5
10g ¥35,500
AKT853
CH 3
HC
C
OnC 4H 9
Ti
O 2 OnC 4H 9
O
TITANIUM DI-n-BUTOXIDE BIS(2,4-PENTANEDIONATE) 392.32
C18H32O6Ti
Flashpoint: >110°C (>230°F)
Viscosity: 35-45 cSt
TSCA
[16902-59-3]
EC 240-947-9 HMIS: 2-2-1-X
100g ¥12,000
1.085
500g ¥34,500
AKT854
Cl
OCH 2CH 3
Ti
Cl
OCH 2CH 3
TITANIUM DICHLORIDE DIETHOXIDE, 95%
208.91
C4H10Cl2O2Ti
Forms TiO2 coatings with water of hydrolysis from ambient humidity
TSCA-L EC 222-704-9 HMIS: 3-3-1-X
[3582-00-1]
142 / 18
25g ¥13,000
AKT854.5
CH 3CH 2
TITANIUM DIETHYLDITHIOCARBAMATE
C20H40N4S8Ti
Ti
C
Color: red
S 4
Soluble: CH2Cl2, toluene
640.97
198-200 dec
S
N
CH 3CH 2
nD20
AKT852
C2H 5
OC
Ti
CH 3CH 2CH 2CH 2O
MW
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[12367-51-0]
HMIS: 2-1-0-X
10g ¥22,500
(40-50)
100g ¥32,000
1.4910
OiC3H 7
Ti
O 2 OiC3H 7
C
O
HC
CH3
C
MW
（既） 2-2161
AKT855
TITANIUM DIISOPROPOXIDE BIS(2,4-PENTANEDIONATE), 75% in isopropanol
364.26
20
nD20
0.992
1.4935
D4
bp °C/mm (mp)
COMMERCIAL
CH3
Name
Flashpoint: 12°C (54°F)
C16H28O6Ti
TOXICITY: oral rat, LD50: 2,870 mg/kg
Viscosity, 25˚: 8-11 cSt
Miscible: aqueous acetone, most organics
Employed in formation of mixed and pure TiO2 by sol-gel.1
1. LaCourse, W. In Sol-Gel Technology, Klein, L. Ed. Noyes 1988, p. 184.
TSCA
EC 241-866-1 HMIS: 2-3-1-X
100g ¥7,500
2kg ¥25,500
[17927-72-9]
TIACA
AKT857
(CH 3)3C
C
O
OiC3H 7
C
O
Ti
2 OiC3H 7
HC
(CH 3)3C
150 / 0.1
(170-7)
5g ¥25,000
（既） 2-2139
TITANIUM DIISOPROPOXIDE BIS(ETHYLACETO424.33
1.05
Flashpoint: 27°C (81°F)
ACETATE), 95%
Metal content: 11.0-11.2% Ti
C18H32O8Ti
TOXICITY: oral rat, LD50: 23,020 mg/kg
Viscosity, 25˚: 45-55 cSt
[27858-32-8]
TSCA
EC 248-697-2 HMIS: 2-3-1-X
100g ¥8,500
500g ¥20,500
AKT865
CH 3CH 2O
C
O
C
O
Ti
HC
H 3C
TITANIUM DIISOPROPOXIDE BIS(2,2,6,6-TETRA532.60
METHYL-3,5-HEPTANEDIONATE)
C28H52O6Ti
Decomposition temperature: >200˚
HMIS: 2-2-1-X
[144665-26-9]
OiC3H 7
OiC3H 7
2
1.522
CXTI038
TITANIUM 3,6-DIOXAHEPTANOATE
530.38
C20H36O16Ti
O
Yellow liquid
OCCH 2OCH 2CH 2OCH 3
Ti
Soluble: water, propanol, THF
OCCH 2OCH 2CH 2OCH 3
Employed in spin-on high K BST dielectric films.1
O
1. Dougherty, T. et al. U.S. Patent 6,316,651, 2001.
HMIS: 3-2-1-X
O
CH 3OCH 2CH 2OCH 2CO
CH 3OCH 2CH 2OCH 2CO
O
OCH 2CH 3
Ti
OCH 2CH 3
CH 3CH 2O
CH 3CH 2O
OCH 2CH 3
Ti
OCH 2CH 3
CH 3CH 2O
TITANIUM ETHOXIDE, tech-95
228.14
122 / 1
(20-5)
1.088
C8H20O4Ti
Metal content: 20-1% Ti
Flashpoint: 28°C (82°F)
Contains 15-20% (EtO)3TiOiPr to maintain liquid behavior
Viscosity, 25˚: 40 cSt
ΔHform: -349 kcal/mole
Surface tension, 25˚: 23.1 dynes/cm
ΔHvap: 21.6 kcal/mole
Vapor pressure, 100˚: 0.75 mm
Dipole moment: 1.50
Vapor pressure, 200˚: 125 mm
Molecular complexity: 2.4
Hydrolysis yields narrow distribution TiO2 particles suitable for sintering.1,2
1 JJean, JJ. ett al.l L
1.
Langmuir
i 1986,
1986 2 , 251
251.
2. Ring, T. MRS Bull . 1990, 15 , 34.
TSCA
[3087-36-3]
EC 221-410-8 HMIS: 2-3-1-X
100g ¥9,300
500g ¥23,500
（既） 2-2150
AKT861
TITANIUM ETHOXIDE, 99%
228.14
C8H20O4Ti
White, gelatinous solid - returns to liquid on warming
Soluble: warm heptane
TSCA
EC 221-410-8 HMIS: 2-3-1-X
[3087-36-3]
TITANIUM 2-ETHYLHEXOXIDE
C4H 9CHCH 2O
OCH 2CHC4H 9
Ti
C4H 9CHCH 2O
OCH 2CHC4H 9
C2H 5
C2H 5
1.107
1.509
0.937
1.482
25g ¥23,500
C32H68O4Ti
Metal content: 8.4-8.6% Ti
Viscosity, 25˚: 120-130 cSt
Catalyst for silicone condensation RTVs
Controls TiO2 structure for low loss optical fibers.1
1. Yoshida, M. et al. Chem. Mater. 1996, 8 , 235.
564.79
194 / 0.25
(-55)
Flashpoint: 71°C (160°F)
TOXICITY: oral rat, LD50: 7,500 mg/kg
COMMERCIAL
TETRAOCTYLTITANATE
C2H 5
(50-54)
（既） 2-2150
AKT867
C2H 5
122 / 1
1.5043
COMMERCIAL
CH 3CH 2O
25g ¥25,500
（既） 2-2150
AKT860
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[1070-10-6]
TSCA
EC 213-969-1
HMIS: 2-2-1-X
100g ¥7,500
2kg ¥25,500
TITANIUM(lV) IODIDE - see INTI070 TITANIUM TETRAIODIDE
AKT868.2
I
OiC3H 7
Ti
iC3H 7O
OiC3H 7
TITANIUM IODIDE TRIISOPROPOXIDE, 352.07
1.25M in tetrahydrofuran
Flashpoint: 22°C (72°F)
C9H21IO3Ti
HMIS: 3-4-1-X
[28427-46-5]
25g ¥15,000
1.04
17kg inquire
Name
MW
bp °C/mm (mp)
D4
20
nD20
1.02
1.495
AKT870
iC4H 9O
TITANIUM ISOBUTOXIDE
C16H36O4Ti
Vapor pressure, 140˚: 0.5 mm
Vapor pressure, 200˚: 68 mm
OiC4H 9
Ti
OiC4H 9
iC4H 9O
340.36
141 / 1
(30-1)
ΔHform: -403 kcal/mole,
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
EC 211-658-5
[681-98-1]
iC3H7O
TITANIUM ISOPROPOXIDE
C12H28O4Ti
Metal content: 16.6-16.9% Ti
OiC3H7
Ti
100g ¥9,500
500g ¥24,500
284.25
58 / 1
(15-19)
Flashpoint: 25°C (77°F)
TOXICITY: ihl rat, 4 hour LD50: 7.78 mg/l
Molecular complexity: 1.4
ΔHform: -377 kcal/mole
ΔHvap: 14.7 kcal/mole
0.937
1.4654
Soluble: heptane, isopropanol
Viscosity: 2 cSt
Vapor pressure, 50˚: 0.9 mm
Vapor pressure, 100˚: 19 mm
Vapor phase pyrolysis gives oxide.1
Yields coatings of barium titanate in combination with Ba(OR)2.2
Utilized in spray pyrolysis synthesis of BaTiO3 and SrTiO3.3
OiC3H7
iC3H7O
HMIS: 2-2-1-X
（既） 2-2150
AKT872
Courtesy Vidromecanica
COMMERCIAL
Titanium isopropoxide provides
scratch resistance for glass bottles
by pyrolytic coating at 500˚
Catalyst for rearrangement4 and cleavage5 of epoxy alcohols.
6
Catalyst for cyclization of ω-amino acids to lactams.
In combination with lead alkyls yields PZT films by MOCVD.7
Review of reactions in combination with Grignard reagents and various organic substrates.8
In combination with triethylamine and trimethylchlorosilane extends aldehydes to two carbons to enals.9
1. Nandi, M. et al. Inorg. Chem. 1990, 29 , 3065.
2. Scuhoff, L. U.S. Patent 3,002,861, 1961.
3. Nonaka, S. et al. J. Mater. Res. 1991, 6 , 1750.
4. Morgans, D. et al. J. Am. Chem. Soc. 1981, 103 , 462.
5. Caron, M. et al. J. Org. Chem . 1985, 50 , 1557.
6. Mader, M. et al. Tetrahedron Lett. 1988, 29 , 3049.
7. Kwak, B. S. et al. Appl. Phys. Lett. 1988, 53 , 1702.
8. Wolan, A.; Six, Y. Tetrahedron 2010, 66 , 15.
9. Kagana, N. et al. Tetrahedron Lett. 2010, 51 , 482.
F&F: Vol. 6, p. 11; Vol. 10, p. 404; Vol. 11, p. 3724 Vol. 12, p. 19, 504; Vol. 13, p. 13; Vol. 14, p. 247, 311;
Vol. 16, p. 339; Vol. 17, p. 347.
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[546-68-9]
TSCA
EC 208-909-6
HMIS: 2-3-1-X
（既） 2-2132
TITANIUM LACTATE, AMMONIUM SALT, 50% in water
100g ¥7,000
2kg ¥19,500
17 kg inquire
AKT875
294.09
1.22
1.4380
BIS(2-HYDROXYPROPANATO)DIHYDROXYTITANATE, DIAMMONIUM SALT; TiBALDH
C6H18N2O8Ti
+-
NH 4 O
O
OH O
CH3
Ti
H3C
O
-
+
O NH 4
OH O
Metal content: 7.5-8.5% Ti
Flashpoint: >65°C (>150°F)
Forms protective coatings on ink
ink-jet
jet printer heads
heads.1
Intermediate for nanostructured titanium phosphate.2
3
Forms titania structures by biologically mediated assembly.
1. Jpn. Kokai Tokkyo Koho 58 134,164, 1983
2. Cole, K. et al. Chem. Mater. 2006, 18 , 4592.
3. Fang, Y. et al. Chem. Mater. 2009, 21 , 5704.
HYDROLYTIC SENSITIVITY: 0: forms stable aqueous solutions
[65104-06-5]
H 2C
O
C C OTi(OiC 3H 7)3
CH 3
TSCA
EC 265-409-0
TITANIUM METHACRYLATE TRIISOPROPOXIDE
C13H26O5Ti
25g ¥9,300
100g ¥20,000
25g ¥9,800
100g ¥20,500
302.18
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
HMIS: 2-3-1-X
[18327-72-5]
H 2C
HMIS: 2-1-0-X
AKT877
CH 3
C
O
C
O
Ti
HC
H 3C
store <5°C
AKT878
O
C C OCH 2CH 2O
(OiC3H 7)3
TITANIUM METHACRYLOXYETHYLACETOACETATE TRIISOPROPOXIDE, 88% in isopropanol
C19H34O8Ti
Inhibited with MEHQ
438.38
1.044
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
HMIS: 2-3-1-X
store <5°C
25g ¥11,500
100g ¥27,300
AKT880
CH 3O
OCH 3
Ti
CH 3O
OCH 3
TITANIUM METHOXIDE, 95%
172.04
70 / .01 sub
C4H12O4Ti
Metal content: 27.7-28.0% Ti
Flashpoint: 48°C (118°F)
Contains methanol
Photocatalytic TiO2 films prepared by ALD in combination with H2O.1
1. Pore, V. et al. Chem. Vap. Dep. 2004, 10 , 143.
(210)
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[992-92-7]
TSCA
EC 213-596-4
HMIS: 2-3-1-X
25g ¥9,000
100g ¥19,300
1.485
Name
CH 3
CH 3
CH 3OCH 2CHO
OCHCH 2OCH 3
Ti
OCHCH 2OCH 3
CH 3OCH 2CHO
CH 3
CH 3
MW
bp °C/mm (mp)
404.35
136-7 / 0.12
1.10
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
HMIS: 2-2-1-X
TITANIUM METHYLPHENOXIDE, tech-90
CH 3
Ti
25g ¥16,500
100g ¥41,500
（既） 3-498
476.40
230-40 / 0.01
Flashpoint: 66°C (151°F)
CRESYLTITANATE
4
nD20
AKT880.5
TITANIUM METHOXYPROPOXIDE
C16H36O8Ti
AKT881
O
20
D4
1.055
C28H28O4Ti
Mixed methylphenyl isomers
1
Employed in preparation of SrTiO3, BaTiO3, CaTiO3 by sol-gel.
2
Adhesion promoter for wire enamels.
Forms homogeneous catalysts with Et3Al2Cl3 for oligomerization of α-olefins.3
1. Ali, N. et al. In Better Ceramics Through Chemistry III , Brinker, Ed. 269, 1988.
2. Cynkovska, G. PCT Int'l WO9203831, 1992; Chem. Abstr. 117, 50898d.
3. Tenbe, G. et al. Ind. Eng. Chem. Res . 1991, 30 , 2247.
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[28503-70-0]
TSCA
EC 249-057-5
HMIS: 3-2-1-X
25g ¥10,000
250g ¥43,000
AKT882
nC9H 19O
OnC9H 19
Ti
OnC 9H 19
nC9H 19O
TITANIUM n-NONYLOXIDE, 95%
C36H76O4Ti
Metal content: 7.7-7.8% Ti
Dipole moment: 1.68
620.85
226 / 1
Flashpoint: 60°C (140°F)
0.93
1.486
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[83897-87-4]
HMIS: 2-2-1-X
（既） 2-2994
TITANIUM OXIDE BIS(2,4-PENTANEDIONATE)
CH 3
C
O
Ti(O)
HC
CH 3
EC 281-195-1
25g ¥16,500
AKT883
C
O 2
262.12
(184 dec)
TITANYL ACETOACETATE
C10H14O5Ti
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[14024-64-7]
TSCA
EC 237-861-9
HMIS: 3-1-0-X
25g ¥19,500
100g ¥53,300
AKT884
(CH 3)3C
C
O
HC
(CH 3)3C
O
C
Ti(O)
2
TITANIUM OXIDE BIS(2,2,6,6-TETRAMETHYL-3,5HEPTANEDIONATE)
C22H38O5Ti
HMIS: 2-1-0-X
OCH 2CH 2CH3
CH 3CH 2CH 2O
OCH 2CH2CH 3
2.5g ¥21,500
（既） 2-228
AKT885
Ti
(120)
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[152248-67-4]
CH 3CH 2CH 2O
430.42
TITANIUM n-PROPOXIDE
C12H28O4Ti
Vapor pressure, 120˚: 1.2 mm
Vapor pressure, 200˚: 65 mm
284.25
137 / 5
Flashpoint: 45°C (113°F)
Viscosity, 25˚: 150-165 cSt
Surface tension, 25.4 dynes/cm
0.955
HYDROLYTIC SENSITIVITY
SENSITIVITY: 7
7: reacts
t slowly
l l with
ith moisture/water
i t / t
[3087-37-4]
TSCA
EC 221-411-3
HMIS: 2-3-1-X
25g ¥8,500
100g ¥17,500
SIT8005.0
TiSi 2
TITANIUM SILICIDE, 95%, powder
112.03
(1540°)
Si2Ti
Contains 3-5% iron
Particle size, average: 4-8 microns
ΔHform: -80 kcal/mole
Resistivity: 123 μΏ•cm
Low and high resitivity phases present.1
1. Clevenger, L. A. et al. J. Appl. Phys. 1992, 72 , 4978.
4.39
HYDROLYTIC SENSITIVITY: 1: no significant reaction with aqueous systems
[12039-83-7]
TSCA
EC 234-904-3
HMIS: 2-1-0-X
シリコンカタログ参照
INTI060
TITANIUM TETRABROMIDE (99.9% on metals basis)
Br4Ti
Soluble: CCl4
Orange crystals
1
Forms titanium silicide on Si substrates.
1. Lee, C. J. Mater.Synth. Process . 1998, 6 , 55.
367.54
230
(39)
ΔHform: -147.7 kcal/mole
HYDROLYTIC SENSITIVITY: 8: reacts rapidly with moisture, water, protic solvents
[7789-68-6]
EC 232-185-0
HMIS: 3-0-1-X
25g ¥16,500
2.6
1.4986
Name
MW
bp °C/mm (mp)
20
D4
nD20
（既） 1-262
INTI065
TITANIUM TETRACHLORIDE, 99%
Cl4Ti
ΔHform: -198.4 kcal/mole
189.71
136.4
(-24)
TOXICITY: oral rat, LD50: 464 mg/kg
1.730
HYDROLYTIC SENSITIVITY: 8: reacts rapidly with moisture, water, protic solvents
F&F: Vol. 1, p 1169; Vol. 2, p 414; Vol. 3, p 291; Vol. 4, p 507; Vol. 5, p 671; Vol. 6, p 590.
TSCA
EC 231-441-9 HMIS: 3-0-2-X
25g inquire
[7550-45-0]
2.5kg inquire
* includes zCYL-L-2400 liquid dispensing cylinder
（既） 1-262
INTI065.5
TITANIUM TETRACHLORIDE, 1M in toluene (19.7 wgt%)
Cl4Ti
189.71
Flashpoint: 8°C (46°F)
0.964
HYDROLYTIC SENSITIVITY: 8: reacts rapidly with moisture, water, protic solvents
[7550-45-0]
TSCA
EC 231-441-9
HMIS: 3-4-1-X
400g ¥20,000
2kg ¥47,000
INTI068
Cl
Cl
TITANIUM TETRACHLORIDE - BIS(TETRAHYDROFURAN) COMPLEX
Cl4Ti·2C 4 H 8 O
Color: yellow crystal
Cl
O
Ti
O
Cl
189.68/333.91
(126-8)
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[31011-57-1]
HMIS: 3-3-2-X
25g ¥25,500
AKT886
TITANIUM TETRAHYDROFURFURYLOXIDE,
50% in isopropanol, tetrahydrofuran
O Ti
O
4
452.87
Flashpoint: 71°C (160°F)
1.14
TETRA(TETRAHYDROFURFURYLOXY)TITANIUM
C20H36O8Ti
Precursor for sol-gel chemistry
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
HMIS: 3-4-1-X
[22290-53-5]
25g ¥18,000
（既） 1-747
TITANIUM TETRAIODIDE (99.9% on metals basis)
555.52
377
I4Ti
Contains ~ 3% free Iodine
Vapor pressure, 275˚: 100 mm
ΔHform: -89.8 kcal/mole
Undergoes thermal transition at 126-9°
ΔHsub: 23.4 kcal/mole
Cocatalyst with Al(iBu)3 for high cis-butadiene polymers
INTI070
(150-1)
4.3
HYDROLYTIC SENSITIVITY: 8: reacts rapidly with moisture, water, protic solvents
[7720-83-4]
TSCA
EC 231-754-0
HMIS: 3-2-1-X
100g ¥26,000
1kg ¥165,000
CVD Ti-Si-N film showing
conformality at 130nm wide,
10:1 aspect ratio
Courtesy E. Eisenbraun, SUNY, Albany
INTI071
TITANIUM TETRAIODIDE (99+%)
555.52
I4Ti
99.99% on metals basis
Employed in CVD of Ti and TiN films for microelectronics.1,2
3
In combination with SiI4 forms Ti-Si-N diffusion barriers.
1. Faltermeier, C. et al. J. Electrochem. Soc. 1997, 144 , 1002.
2. Kaloyeros, A. et al. U.S. Patent 6,090,709, 2000.
3. Eisenbraun, E. et al. J. Vac. Sci. Technol., B 2000, 18(4) , 2011.
377
(150-1)
4.3
HYDROLYTIC SENSITIVITY: 8: reacts rapidly with moisture, water, protic solvents
[7720-83-4]
CH 2OCH 2CH
Ti OCH 2 C CH 2CH 3
CH 2OCH 2CH
CH 2
CH 2 4
TSCA
EC 231-754-0
HMIS: 3-2-1-X
50g ¥32,500
AKT887
TITANIUM TETRAKIS(BIS 2,2-(ALLYLOXYMETHYL)901.06
BUTOXIDE)
C48H84O12Ti
EC 270-524-4 HMIS: 2-2-1-X
[68443-46-9]
1.08
25g ¥11,800
100g ¥28,000
1.4993
Name
MW
bp °C/mm (mp)
20
nD20
0.938
1.5360
D4
OMTI075
TITANIUM TETRAKIS(DIETHYLAMIDE), 99+%
TDEAT
N(CH 2CH 3)2
(CH 3CH 2)2N
Ti N(CH 2CH 3)2
N(CH 2CH 3)2
336.40
133 / 1.2
Flashpoint: 165°C (329°F)
C16H40N4Ti
Vapor pressure, 40˚: 0.035 mm
In combination with ammonia produces TiN by CVD.1
1. Yun, J. et al. Thin Solid Films 1998, 312 , 14.
HYDROLYTIC SENSITIVITY: 8: reacts rapidly with moisture, water, protic solvents
[4419-47-0]
TSCA
HMIS: 3-3-1-X
5g ¥19,500
25g ¥64,500
OMTI080
(CH 3)2N
N(CH 3)2
TITANIUM TETRAKIS(DIMETHYLAMIDE), 99+%
Ti N(CH 3)2
TDMAT
224.20
50 / .05
Flashpoint: 87°C (189°F)
0.947
C8H24N4Ti
N(CH 3)2
HYDROLYTIC SENSITIVITY: 8: reacts rapidly with moisture, water, protic solvents
[3275-24-9]
TSCA
EC 221-904-3
HMIS: 4-3-1-X
5g ¥19,500
25g ¥64,500
OMTI083
CH 3CH 2
CH 3
N
H 3C
CH 2CH 3
N Ti N
CH 3CH 2
H 3C
280.32
80 / 0.1
0.923
Precursor to TiN by CVD.1
1. Shin, H. et al. Chem. Mater. 1997, 9 , 76.
CH 3
N
TITANIUM TETRAKIS(ETHYLMETHYLAMIDE), 99+%
C12H32N4Ti
CH 2CH 3
HYDROLYTIC SENSITIVITY: 8: reacts rapidly with moisture, water, protic solvents
HMIS: 3-3-1-X
[308103-54-0]
5g ¥24,500
25g ¥84,500
AKT887.2
O
(H 2C CH C O) 3TiO(CH 2CH2O) 2OCH 3
TITANIUM TRIACRYLATE METHOXYETHOXYETHOXIDE, tech-90
C14H20O9Ti
Dark red-brown liquid
Viscosity: 15-20 cSt
380.19
1.14
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
HMIS: 3-2-1-X
[99749-57-2]
（既） 2-3099
TITANIUM TRIISOSTEAROYLISOPROPOXIDE, tech-90
store <5°C
100g ¥11,500
AKT887.5
OiC18H 37
iC3H 7O
Ti
OC18H 37
OC18H 37
TRIS(ISOOCTADECANOATO)PROPANOLATOTITANIUM
C57H118O4Ti
8.3-9.1% TiO2
Dark amber liquid
Soluble: isopropanol, toluene
[61417-49-0]
TSCA
EC 262-774-8
957.37
Flashpoint: 93°C (199°F)
0.95
1.481
Viscosity: 160-200 cSt
HMIS: 2-1-0-X
100g ¥9,300
500g ¥23,500
AKT888
O
(H2C C C O)3Ti(OCH2CH2)2OCH3
CH3
TITANIUM TRIMETHACRYLATE METHOXYETHOXY422.28
ETHOXIDE, 70% in methoxydiethyleneglycol/isopropanol
Flashpoint: 60°C (140°F)
C17H26O9Ti
Miscible: toluene, isopropanol
Color: amber-red
EC 262-788-4 HMIS: 3-3-1-X
100g ¥9,800
[61436-48-4]
1.11
500g ¥24,000
SIT7305.0
TITANIUM TRIMETHYLSILOXIDE
404.66
110 / 10
Flashpoint: 51°C (124°F)
TETRAKIS(TRIMETHYLSILOXY)TITANIUM
(CH3)3SiO
OSi(CH 3)3
Ti
OSi(CH 3)3
(CH 3)3SiO
0.900
C12H36O4Si4Ti
Partial hydrolysis gives soluble polymer.1
Catalyst for condensation cure silicones.2
1. Bradley, D. et al. Can. J. Chem. 1963, 41 , 629.
2. Buehler, F. A. U.S. Patent 3,235,495.
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[15990-66-6]
HMIS: 2-2-1-X
シリコンカタログ参照
AKT889.1
C8H 17O O
C8H 17O
P
O
Ti
3
TITANIUM TRIS(DIOCTYLPYROPHOSPHATO)ISO1191.33
PROPOXIDE, tech-90
Flashpoint: 63°C (145°F)
C51H109O13P3Ti
Amber liquid
OiC3H 7 Dispersion agent for conductive fillers in capacitance discs.1
1. Labib, M. U.S. Patent 4,532,074, 1985.
1.04
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[68585-79-5]
EC 271-588-6
HMIS: 2-2-1-X
25g ¥11,500
100g ¥27,300
1.4278
Name
MW
20
D4
bp °C/mm (mp)
nD20
AKT889.3
C12H 23
SO 3
Ti
OiC3H 7
3
TITANIUM TRIS(DODECYLBENZENESULFONATE)1077.4
ISOPROPOXIDE, tech-90
Contains isopropanol
C57H88O10S3Ti
Color: dark amber
Viscosity: 8,000 cSt
TSCA
EC 262-777-4 HMIS: 2-3-0-X
[61417-55-8]
1.08
25g ¥8,000
100g ¥16,000
AKT889.4
C(CH 3) 3
O
Ti
O
C(CH 3) 3 3
TITANIUM(III) TRIS(2,2,6,6-TETRAMETHYL-3,5HEPTANEDIONATE)
C33H57O6Ti
Color: purple
597.66
(75 / 0.1 sub)
HYDROLYTIC SENSITIVITY: 8: reacts rapidly with moisture, water, protic solvents
[171418-64-4]
HMIS: 3-2-1-X
1.0g ¥22,500
（既） 3-4343
OMTI085
TITANOCENE DICHLORIDE
249.00
(288-9)
1.600
BIS(CYCLOPENTADIENYL)TITANIUM DICHLORIDE
Cl
C10H10Cl2Ti
TOXICITY: ipr rat, LD50: 25 mg/kg
Color: red
F&F: Vol. 6, p 48; Vol. 10, p 130; Vol. 13, p 102; Vol. 14, p 120.
Ti Cl
HYDROLYTIC SENSITIVITY: 4: no reaction with water under neutral conditions
[1271-19-8]
nC4H 9
nC4H 9
Sn
OiC3H 7
O Ti
nC4H 9
OiC3H 7
OiC3H 7
TSCA
EC 215-035-9
HMIS: 2-1-0-X
100g ¥28,000
500g ¥98,500
SNT8380
(TRIISOPROPOXYTITANOXY)TRI-n-BUTYLTIN, tech-95
C21H48O4SnTi
531.18
70-5 / 0.05, 110-2 / 4
1.08
HYDROLYTIC SENSITIVITY: 7: reacts slowly with moisture/water
[32124-32-6]
HMIS: 3-2-1-X
10g ¥12,000
50g ¥34,500
DOUBLE METAL AND POLYMERIC ALKOXIDES
nBuO
OnBu
Ti O
nBu
OnBu
4-10
Name
PTI-023
Empirical Formula
Metal Content
Density
POLY(DIBUTYLTITANATE)
Stabilized with ~5% ethylene glycol
Viscosity: 3,200-3,500 cSt
TSCA
[9022-96-2]
[(C4H9O)2TiO]4-10
Unit M.W.: 210.10
22.0-23.0% Ti
1.07-1.10
HMIS: 2-3-1-X
シリコンカタログ参照
PTI-008
Et
Et
OCH 2CHCH 2CH 2CH 2CH 2OH
OCH 2CHCH 2CH 2CH 2CH 2TiO
n
OCH 2CHCH 2CH 2CH 2CH 2OH
Et
[OCH2CHEt(CH2)4OTi(CH2CHEt(CH2)4OH)2]n
Unit M.W.: 482.54
C t i ~25%
Contains
25% free
f
2-ethyl-1,3-hexanediol,
2 th l 1 3 h
di l oligomeric
li
i
7.5-7.6%
7 5 7 6% Ti
Flashpoint: 50°C (122°F)
Viscosity: 1,700 cSt
TSCA
[5575-43-9]
EC 226-949-2 HMIS: 2-3-1-X
シリコンカタログ参照
POLY(OCTYLENEGLYCOLTITANATE)
PSITI-019
DIETHOXYSILOXANE - ETHYLTITANATE COPOLYMER
19.1-19.6% Si
2.1-2.3% TI
[(C2H5O)2SiO][(C2H5O)2TiO]
Viscosity: 10-25 cSt
Employed in formation of titania-silica aerogels.1
Forms micro- and mesopores through titanosilicates.2
1. Miller, J. et al. J. Mater. Chem. 1995, 5 , 1759.
2. D'Amore, M. B. and Schwartz, S. J. Chem. Soc., Chem. Commun . 1999, 92 , 121.
HMIS: 2-3-1-X
シリコンカタログ参照
1.035