11/18/2013 ES 10 Other sources of oil / Unconventional Nonrenewable Energy Resources Oil Shale and Oil Sand (aka “Heavy Oils”) 11/19/13 Oil and Natural Gas Past to Present (31 slides) What are fossil fuels Why use Oil / Natural Gas Drawbacks Where does oil come from? Oil Traps; Source, Reservoir & Cap Rocks Abiotic Oil? Who has the oil & how much is there? How long will it last? Where does US get it’s oil? Unconventional sources of oil and gas: Oil Shale & Sand (aka Tar Sand) Methane Clathrates, aka Gas Hydrates Oil still in Source Rock Oil Shale: Sedimentary rock containing organic kerogen (altered org matter in Sed Rk) – never buried deep enough to raise temperature required to convert Kerogen to liquid oil – Massive deposits underlie US (estimate 2-5 trillion barrels) Oil Sand/ aka Tar Sand: mixture of sand, clay, water and Bitumen (a viscous, heavy oil, too thick to flow out of rock, the soluble portion of Kerogen). – Alberta Canada extensive deposits-few in US Green areas are parks, etc Monterey Shale areas Shown in loops http://graphics8.nytimes.com/packages/images/newsgraphics/2013/0204‐shale/0204‐nat‐webshale.jpg 1 11/18/2013 Oil Shale Booming • Hydraulic Fracturing (Fracking) is a drilling process designed to increase the yield of oil and/or gas out of rock; the method involves fracturing surrounding rock (increasing permeability) and pumping fluids into the fractures under extremely high pressures to force the desired gas or liquids out. • Web Link: Horizontal Wells and Fracking http://www.northernoil.com/drilling http://www.youtube.com/watch?v=VY34PQUiwOQ (6.5min) Oklahoma Earthquakes: between 1978 and 2008 ~2- 6/yr. In 2010 there were 1,047 earthquakes Some Fracking Practices http://www.propublica.org/special/hydraulic‐fracturing‐national electrical gunshots perforate steel casing & cement, then slickwater pressure + propping agents fracture the shale How Fracking Can Impact The Environment • water consumption • Horizontal drilling • diesel pumps, compressors, drills, etc. • methane escape & flaring • Steel casing, cement sleeve – protect aquifers • truck traffic, emissions, habitat impacts, pipelines • Perforation • wastewater disposal • Water + sand + slickening agents + salt • aquifer contamination – underground – untreated in streams – burden on sewage treatment plants • unaesthetic views 2 11/18/2013 Making Fracking Greener Resources for the Future different state fracking rules • Run equipment with cleaner natural gas rather than diesel pumps, compressors, drills • Replace water trucks & traffic with temporary water pipelines • fresh water withdrawals • underground injection wells for wastewater • “Kitchen counter” frack fluids as safe as what’s under your kitchen sink • cementing of well • Recycle fracking fluids – commonly done now • all other state regulations • Use gas as a fracking medium rather than water – CO2 or propane ‐ produces 30% more natural gas 9 The Athabasca Tar Sands of Alberta, Canada How much oil shale and oil sand? • Global supplies are estimated to be 200X larger than conventional oil. • More oil is trapped in Canadian tar sands than Saudi Arabia has in all it’s reserves. • It is estimated that oil sand in Alberta & Orinico Oil Belt in Venezuela contain nearly 3.4 trillion barrels of oil. At end of 2010, world proven crude oil reserves stood at over >1.4 trillion Barrels 3 11/18/2013 Athabasca Oil Sands • Suncore, Syncrude and Shell Canada combined oil production in 2006 was 1,126,000 bpd (barrels per day). • By 2020, Canadian oil production may reach 3 million bpd & ~5 million bpd by 2030 4 11/18/2013 Why not use these resources? • Oil shale and sand extraction requires surface mining – ecosystem disruption; forests, wetlands, grasslands – huge volumes of waste rock-- only ~3 barrels of shale oil for 1 ton of rock processed. – 3 barrels of H2O/1 barrel of shale oil produced – tailing ponds created: hold leftover water, sand, clay, bitumen, salts, metals (Ni, V, Hg, As, Pb), – pollution floats downstream. – land reclamation issues – lower useful energy yield than conventional oil and gas Web Link: http://www.nature.com/news/2010/100831/full/news.2010.439.html Web Link: Garth Lenz: The True Cost of Oil – http://www.ted.com/talks/garth_lenz_images_of_beauty_and_devastation.html ES 10 Methane Clathrates Nonrenewable Energy Resources aka Methane Hydrates or Gas Hydrates another source of “unconventional” fossil fuels 11/19/13 Oil and Natural Gas Past to Present (31 slides) What are fossil fuels Why use Oil / Natural Gas Drawbacks Where does oil come from? Oil Traps; Source, Reservoir & Cap Rocks Abiotic Oil? Who has the oil & how much is there? How long will it last? Where does US get it’s oil? Unconventional sources of oil and gas: Oil Shale, Tar Sands, Methane Clathrates, aka Methane Hydrates, Gas Hydrates 5 11/18/2013 Newer Estimates: (2013) ~500 – 2,500 Still approx 2 – 10 X the amount of conventional natural gas Stored mostly in broad, shallow layers beneath the seafloor, methane hydrate is, by some estimates, twice as abundant as all other fossil fuels combined. The yellow squares show where methane hydrate has already been recovered; the blue dots, where it is thought to exist. 6 11/18/2013 ~1,300 trillion cubic ft off N and S Carolina, >60X amount US uses each year (~20 trillion cubic ft/yr) Total US gas Hydrate deposits ~320,222 trillion cubic ft, at 10% recovery, enough to last 1600 years Seismic Reflection Profile data on Blake Ridge showing BSR (meters below sea level on left, meters below ocean floor on right) P-Wave rates in hydrates can be as fast as 3.0 – 3.6Km/s 7 11/18/2013 Methane Hydrate recovered from Blake Ridge Review Questions/Key Concepts – Where do most reserves exist? Who is OPEC? Which member has the most oil? Which countries (top 3) are producing the most oil? – From what material does petroleum form? How does it form? How long does it take? What are the necessary conditions required? – Daily production of crude oil ~ 84 m bpd. Global conventional oil reserves ~ 1.4 trillion barrels. Who uses the most? Primary use? – Why are most petroleum deposits younger than 200 million years? – – List pros and cons of using fossil fuels. – When will global conventional oil supplies be economically depleted? – What is a Source Rock, Reservoir Rock, Cap Rock & “Oil Trap”? – What are the drawbacks of mining tar sands? – What geologic structures do petroleum geologists look for as high potential areas of oil/gas? – What are oil shale and tar sand? Who is mining these and where? – What is Hydraulic Fracturing, aka Fracking? Drawbacks? – What are Methane or Gas Hydrates and why are scientists interested in them? – Can petroleum be produced abiotically? If so, how? – How do scientists locate Methane Hydrates? What does BSR stand for? – What is Thermal Conversion and Thermal Depolymerization? – What are some concerns about mining methane hydrates? 8
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