Application Note AN 1011.00 Measuring the Color of Non-Opaque & Textured Samples Abstract An Ideal Sample is... • opaque or transparent (not translucent) • solid (not liquid) • flat (not curved) • smooth (not textured) • homogenous (all the same color) • non-thermochromic (color does not change with temperature) • non-hygrochromic (color does not change with humidity or moisture) • non-directional (color does not change with sample orientation) A repeatable color measurement is essential to successfully quantify the color of your product. If you have an ideal sample like a color tile or glass filter it is easy to make a repeatable color measurement. Most real world samples are less than ideal, but can be measured with success if good color measurement techniques are used. This application note looks at guidelines for presenting liquids, semi-solids, powders, pellets and loose fibers to achieve repeatable results. Measuring the Color of Non-Opaque & Textured Samples AN 1011.00 2 Challenge: To select the optimal color measurement technique and derive a repeatable color measurement method based on the type of sample and instrument geometry available. For optimal color analysis of samples, the selection of appropriate accessories and proper placement of the sample in the optical path is important. Once a measurement method has been defined, this procedure be followed for all subsequent color measurements. Application #1: Liquids Accessories: Glass transmittance cell or sample cup. Transparent, translucent, and opaque liquids must be placed in a container for measurement. Transparent liquid samples are poured into a glass transmittance cell or vial, and measured in the transmittance compartment (Figure 1). The preferred technique for translucent and opaque liquids is to measure them in reflectance using a sample cup on a directional instrument such as the LabScan XE or ColorFlex EZ 45°/0°. Alternatively, translucent and opaque liquids can be measured at the reflectance port of a diffuse/8° instrument such as the ColorQuest XE, UltraScan PRO, or UltraScan VIS using a 50 mm path length cell. Application #2: Translucent Semi-Solids Accessories: Glass sample cup or transmittance cell. Translucent semi-solids, such as yogurt, baby food, and salad dressings, are normally measured in a glass sample cup using a directional type instrument such as the LabScan XE or ColorFlex EZ 45°/0° (Figure 2), or placed in a glass transmittance cell and measured at the reflectance port of a diffuse/8° sphere instrument (Figure 3). Figure 1. Transparent liquid measured in transmittance using a clear glass vial. Figure 2. Semi-solid yogurt sample measured throught the Figure 3. Translucent liquid can also be read in a 50 mm thick bottom of a sample cup on a directional 45°/0° instrument. cell on a diffuse/8° sphere instrument. Measuring the Color of Non-Opaque & Textured Samples Application #3: Powders Accessories: Powder press, glass sample cup or transmission cell. In measuring powders, the best technique for color analysis is to make them more solid. One technique is to press the powder into a smooth plaque and measured on a directional instrument such as the LabScan XE in the port-down or port-up orientation. An alternate technique is to measure loose powder through the bottom of a sample cup (Figure 4). Powders can also be placed in a 50 mm glass transmission cell and measured at the reflectance port of a diffuse/8° sphere instrument in RSEX (Reflectance Specular Excluded) mode. AN 1011.00 Figure 4. Measuring the color of a loose powder in a sample cup on a directional 45°/0° instrument. Application #4: Pellets or Large Particulates Accessories: Glass Sample Cup. Plastic pellets and similar granular items such as rice and sugar can be measured through the bottom window of a sample cup making the granular sample effectively into a solid. These samples are typically measured using a directional geometry instrument such as the LabScan XE or ColorFlex EZ 45°/0°. As an alternate but less preferred technique, pellets or large particulates can be placed in a 50 mm glass transmission cell and measured at the reflectance port of diffuse/8° sphere instrument in RSEX (Reflectance Specular Excluded) mode. Application #5: Textiles Accessories: Compression Cell & Sample Cup. Like powders, loose textile fibers trap light and are not solid. However, if flattened against the glass window of a sample cup using an air-driven compression plunger, loose fibers effectively become a solid. A compression cell set is available for the ColorQuest XE, LabScan XE, UltraScan PRO, and UltraScan VIS. 3 Figure 5. Dried green peas presented to a ColorFlex 45°/0° through the bottom of a clear plastic dish for color analysis. Figure 6. Loose textile fibers placed in a sample cup, then compressed with air. Measuring the Color of Non-Opaque & Textured Samples AN 1011.00 4 Conclusion The guidelines presented here promote the repeatable and reproducible measurement of color for a variety of non-uniform samples. Once an optimal measurement method has been established, consistent measurements from lot-to-lot and site-to-site can be made. References AATCC Evaluation Procedure 6 - Instrumental Color Measurement. ASTM E179 Standard Guide for Selection of Geometric Conditions for Measurement of Reflection and Transmission Properties of Materials. Hunter, Richard S., and Harold, Richard W., The Measurement of Appearance, 2nd Ed., John Wiley and Sons, Inc. New York, NY USA 1987. More Information about Color Measurement on our HunterLab Blog measuretruecolor.com About Hunterlab HunterLab, the first name in color measurement, provides ruggedly dependable, consistently accurate, and cost effective color measurement solutions. With over 6 decades of experience in more than 65 countries, HunterLab applies leading edge technology to measure and communicate color simply and effectively. The company offers both diffuse/8° and a complete line of true 45º/0º optical geometry instruments in portable, bench-top and production in-line configurations. HunterLab, the world’s true measure of color. © Hunterlab 2014 Hunter Associates Laboratory Inc., 11491 Sunset Hills Road, Reston, VA 20190-5280 USA [email protected] www.hunterlab.com
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