G.10 Science—Chemistry Shaftesbury High School Compounds and Naming Shaftesbury High School 2240 Grant Avenue Winnipeg, Manitoba R3P 0P7 Phone: 204-888-5898 Fax: 204-896-5492 http://www.pembinatrails.ca/shaftesbury/ G.10 Science—Naming and Compounds Shaftesbury High School Compounds There are about ____________________ pure substances that have been identified. Chemical Formulas A chemical formula acts as a recipe for a compound, it tells us... Reading a Chemical Formula: Eg. Consider table salt (Sodium Chloride—NaCl). Count the Atoms Na Atoms = _________ Cl Atoms = _________ Sometimes there are subsctripts present. Eg 2. Consider water (Dihydrogen Oxide—H20) H Atoms = _________ O Atoms = _________ G.10 Science—Naming and Compounds Shaftesbury High School Sometimes there are brackets with a subscript… Eg 3. Calcium Hydroxide—Ca(OH)2 Ca Atoms = _________ O Atoms = _________ H Atoms = _________ Sometimes there are subscripts in the brackets… Eg 4. Calcium Nitrate—Ca(NO3)2 Ca Atoms = _________ O Atoms = _________ N Atoms = _________ G.10 Science—Naming and Compounds Shaftesbury High School Review—Counting Atoms 1. The symbol of an element represents one atom of that element. Eg. Ca 2. A subscript is a number written at the lower right corner behind the symbol of an element. If there is more than one atom of the element in the molecule, then a subscript is used to indicate the number of atoms. Eg 2. N2 3. A subscript outside a bracket multiplies all the elements inside the brackets. Eg 3. Ba3(PO4)2 4. i. A coefficient is a number written in front of a chemical symbol and indicates the number of atoms of that element. Eg 4. 3C OR ii. A coefficient is a number written in front of a chemical formula and indicates the number of molecules of that compound. Note: A coefficient multiplies the number of atoms of each element in the formula. Eg 5. 2H2O Eg 6. 3FeSO4 Eg 7. 4Cu(NO3)2 G.10 Science—Counting Atoms Worksheet Shaftesbury High School Na2CO3 Type of Atom Ca3(PO4)2 # of Atoms Type of Atom Total Total K2CrO4 3BaCl2 Type of Atom # of Atoms Type of Atom # of Atoms # of Atoms Total Total 4Al2(CO3)3 Type of Atom Pb(NO3)2 # of Atoms Type of Atom Total Total NH4C2H3O2 2(NH4)2Cr2O7 Type of Atom Total # of Atoms Type of Atom Total # of Atoms # of Atoms G.10 Science—Subscripts and Coefficients Shaftesbury High School Calculate the number of each type of atom in the following compounds. 1. NaOH Na _____ O ______ H ______ 2. H3PO4 H ______ P ______ O ______ 3. ZnCO3 Zn _____ C ______ O ______ 4. NH4C2H3O2 N ______ H ______ C ______ 5. Ca(ClO3)2 Ca _____ Cl ______ O ______ 6. Zn(NO3)2 Zn _____ N ______ O ______ 7. Al2(SO4)3 Al ______ S ______ O ______ 8. (NH4)2SO4 N ______ H ______ S ______ O ______ O ______ Calculate the number of each type of atom and the total number of atoms. 1. 3Fe2O3 Fe _____ O _____ Total _____ 2. 2NaHSO4 Na _____ H _____ S _____ Total _____ 3. 4Al2(CO3)3 Al ______ C _____ O _____ Total _____ 4. 3K2SO4 K ______ S _____ O _____ Total _____ 5. 4Zn3(PO4)2 Zn _____ P _____ O _____ Total _____ O _____ G.10 Science—Chemical Bonding Shaftesbury High School Chemical Bonding Atoms must gain, lose, or share electrons to obtain full valence shells and become stable. Chemical Bond Compound Molecule Atom Ion Element Chemical Formula Valence (Combining Capacity) G.10 Science—Ionic Bonding Shaftesbury High School Ionic Bonding Examples of Compounds with Ionic Bonds KCl K is a metal and Cl is a non-metal, therefore the bond is ionic. The Chemical formula tells us that 1 K atom will join with 1 Cl. Bohr Lewis AlCl3 Al is a metal and Cl is a non-metal, therefore the bond is ionic. The Chemical formula tells us that 1 Al atom will join with 3 Cl. Bohr Lewis G.10 Science—Covalent Bonding Shaftesbury High School Covalent Bonding Examples of Compounds with Covalent Bonds H2O H is a non-metal and O is a non-metal, therefore the bond is covalent. The Chemical formula tells that 2 atoms of hydrogen will bond with 1 atom of oxygen. Bohr Lewis CH4 C is a non-metal and Cl is a non-metal, therefore the bond is covalent. The Chemical formula tells us that 1 C atom will join with 4 H atoms. Bohr Lewis G.10 Science—HOFBrINCl Clown Shaftesbury High School When two identical atoms link together, the arrangement is called a diatomic molecule. H-O-F-Br-I-N-Cl the clown will help you remember diatomic molecules. Take a close look at his ear (and the number 2), and remember that all of these elements exist in pairs. G.10 Science—Naming and Compounds Assignment Shaftesbury High School Additional Resource Identify whether the bond between atoms is ionic or covalent and then draw the compound using a Lewis Dot diagram. 1. CaCl2 2. H2 3. MgF2 4. NaCl 5. NF3 6. K3N 7. Na2O 8. NH3 9. MgBr2 10. LiF 11. Cl2 12. HBr G.10 Science—Naming Ionic Compounds Shaftesbury High School Writing Formulas An ionic compound consists of a ____________________ and a __________________. Metals ______________ electrons to form ________________ ions called _______________________. Eg. Draw the ionic bond between Magnesium and Fluorine. An easier way to determine the formula of an ionic compound without drawing the bond structure is to make sure that the __________________ charges are equal to the ______________________ charges. G.10 Science—Ionic Compounds Shaftesbury High School Steps for Naming Ionic Compounds 1. Write the element symbol with the charge of the ion, as a superscript (Na-1), next to it. 2. If charges are already equal just write the formula as it is. Eg. Magnesium and Oxygen 3. If the charges are not equal, adjust the quantity of each element so that the charges of the cations and anions are equal. Eg. Magnesium and Fluorine Eg 2. Potassium and Nitrogen Eg 3. Calcium and Nitrogen The Criss-Cross Method Eg. Calcium and Nitrogen G.10 Science—Ionic Compounds Shaftesbury High School Make the formulas for the following ionic compounds. 1. Sodium and Oxygen _________________________________ 2. Magnesium and Bromine _________________________________ 3. Potassium and Chlorine _________________________________ 4. Calcium and Sulfur _________________________________ 5. Aluminum and Iodine _________________________________ 6. Aluminum and Nitrogen _________________________________ Naming Binary Ionic Compounds 1. 2. Eg. LiF _________________________________ Eg 2. CaCl2 _________________________________ Eg 3. Na2O _________________________________ Write the names for the following compounds: 1. Li2O _________________________________ 2. NaI _________________________________ 3. Rb2S _________________________________ 4. AlP _________________________________ 5. CaF2 _________________________________ Write the formulas for the following compounds: 1. Magnesium Oxide _________________________________ 2. Calcium Fluoride _________________________________ 3. Cesium Sulfide _________________________________ 4. Aluminum Oxide _________________________________ 5. Potassium Chloride _________________________________ G.10 Science—Binary Ionic Compounds Puzzle Shaftesbury High School Objectives Discover how metal cations and non-metal anions combine in specific ratios to form neutral compounds. Match puzzle pieces with their respective ion groups on the periodic table Combine puzzle pieces to form neutral binary ionic compounds Write the chemical formulas for neutral binary ionic compounds. Puzzle Piece Picture Charge Number of Pieces One protrusion +1 3 Two protrusions +2 3 Three protrusions +3 2 One indentation –1 3 Two indentations –2 3 Three indentations –3 2 TOTAL = 16 Rules of the Game Each puzzle piece represents a separate ion that is either positively or negatively charged. Consider puzzle pieces with protrusions as male pieces and puzzle pieces with indentations as female pieces. Male puzzle pieces represent positively charged ions because they transfer their electrons to make negatively charged female ions and form ionic compounds. The challenge of the game is to construct as many different combinations of neutrally charged binary ionic compounds as possible. A neutrally charged binary ionic compound is made when as many male pieces of one type are combined with the appropriate number of female puzzle pieces of a second type so that no protrusions or indentations remain. G.10 Science—Binary Ionic Compounds Puzzle Shaftesbury High School Directions Empty the contents of the plastic bag onto you desk and make sure you have the necessary number of puzzle pieces. Arrange the pieces on your desk to make the periodic table of the ions, omitting the transition metals. Check your final product with the instructor before moving on to the next step. (3 marks) Binary Ionic Compound Chemical Formulas (9 marks) Construct as many different combinations of neutrally charged binary ionic compounds as possible. 1. 2. 3. 4. Select a specific ion symbol for each coloured piece. Record the elements chosen for each charge in the box space provided. Record the chemical formula of each of your puzzle compounds in the table below. Finally, sketch an image of the compound created with the puzzle pieces. 1+ & 1– 1+ & 2– 1+ & 3– 2+ & 2– 2+ & 1– 3+ & 1– 3+ & 3– 2+ & 3– 3+ & 2– /12 G.10 Science—Metals With More Than One Cation Shaftesbury High School Some transition metals can have more than one cation. For example, copper can have a +1 or a +2 charge. Eg. Write the formula for copper (I) sulfide. Eg 2. Write the formula for copper (II) sulfide. Write the chemical formula for each of the following compounds. 1. Copper (I) Oxide _________________________________ 2. Lead (IV) Bromide _________________________________ 3. Iron (III) Sulfide _________________________________ 4. Nickel (II) Fluoride _________________________________ 5. Manganese (IV) Sulfide _________________________________ Finding the name of a compound using the stock system (use a reverse criss-cross method). Eg. FeCl3 (Hint: Iron can have a charge of +2 or +3) Eg 2. Cu2S G.10 Science—Metals With More Than One Cation Shaftesbury High School Write the names for the following compounds. 1. Fe2O3 _________________________________ 2. PbO2 _________________________________ 3. NiCl2 _________________________________ 4. CrN _________________________________ 5. HgO _________________________________ Ionic Compounds: Names and Formulas Assignment 1. Write the formulas for the following compounds. a. Magnesium Oxide ________________ k. Copper (I) Bromide ________________ b. Sodium Fluoride ________________ l. Tin (II) Iodide c. Aluminum Nitride ________________ m. Iron (III) Chloride ________________ d. Potassium Sulfide ________________ n. Calcium Phosphide ________________ e. Lithium Iodide ________________ o. Lead (II) Oxide ________________ f. Calcium Bromide ________________ p. Lead (IV) Flouride ________________ g. Beryllium Oxide ________________ q. Tin (IV) Bromide ________________ h. Nickel Chloride ________________ r. Copper (II) Sulfide ________________ i. Magnesium Nitride ________________ s. Iron (II) Oxide ________________ j. Aluminum Sulfide ________________ t. Calcium Nitride ________________ ________________ 2. Write the names for the following compounds. a. Li2O ________________ k. PbS ________________ b. AlCl3 ________________ l. SnO2 ________________ c. MgS ________________ m. Na2S ________________ d. CaO ________________ n. Mg3P2 ________________ e. KBr ________________ o. NiO ________________ f. BeF ________________ p. CuI ________________ g. Na3N ________________ q. PbCl4 ________________ h. Al2O3 ________________ r. FeP ________________ i. CuCl2 ________________ s. CaF2 ________________ j. FeBr3 ________________ t. K3P ________________ G.10 Science—Polyatomic Ions Shaftesbury High School Polyatomc ions are ions that are made of more than _____________ atom. Each Polyatomic ion has its own name. For example… Sulfate Ion ______________ Nitrate Ion ______________ Phosphate Ion ______________ We can still write formulas for compounds which contain polyatomic ions. For example... Sodium Nitrate ______________ Sodium Phosphate ______________ Calcium Nitrate ______________ Copper (II) Nitrate ______________ Make sure you place ______________________________________________________ _____________________________________. When Naming compounds with polyatomic ions _________________________________ ______________________________________________________________________. For Example... NaNO3 ______________ Ca3(PO4)2 ______________ CuSO4 ______________ NH4Cl ______________ G.10 Science—Criss Cross Method Shaftesbury High School Complete the following table, being sure that the total charge on the resulting compound is zero. Ions Hydrogen H1+ Sodium Na1+ Ammonium NH41+ Potassium K1+ Calcium Ca2+ Magnesium Mg2+ Aluminum Al3+ Ferrous Fe2+ Iron (II) Fe2+ Ferric Fe3+ Iron (III) Fe3+ Plumbous Pb2+ Stannic Sn4+ Copper (I) Cu1+ Cupric Cu2+ Chloride Cl1- Hydroxide OH1- Nitrate NO31- Sulfate SO42- Sulfide S2- Carbonate CO32- Phosphate PO43- G.10 Science—Ionic Compounds: Polyatomic Ions Shaftesbury High School Write the name of each of the following compounds. 1. NH4Cl ______________________ 2. HClO2 ______________________ 3. Ca(BrO3)2 ______________________ 4. BeSO4 ______________________ 5. (NH4)3N ______________________ 6. NH4NO3 ______________________ 7. Sr3(PO4)2 ______________________ 8. Zn(ClO3)2 ______________________ 9. AgIO3 ______________________ 10. K2Cr2O7 ______________________ Write the chemical formula for each of the given names. 11. sodium chromate ______________________ 12. barium nitrate ______________________ 13. ammonium sulfate ______________________ 14. aluminum hydroxide ______________________ 15. calcium phosphate ______________________ 16. cesium cyanide ______________________ 17. sodium nitrite ______________________ 18. calcium acetate ______________________ 19. beryllium chlorite ______________________ 20. rubidium sulfite ______________________ G.10 Science—Polyatomic Ions with Multiple Charges Shaftesbury High School Write the name of each of the following compounds. 1. V(ClO3)5 ______________________ 2. Re(SO4)3 ______________________ 3. Os(IO3)3 ______________________ 4. Ir3(PO4)4 ______________________ 5. Pd(SO3)2 ______________________ 6. AuNO3 ______________________ 7. FePO4 ______________________ 8. Ni(BrO3)2 ______________________ 9. Pb(CN)4 ______________________ 10. Mn(Cr2O7)2 ______________________ Write the chemical formula for each of the given names. 11. copper (II) hydroxide ______________________ 12. rhenium nitrate ______________________ 13. niobium (III) sulfate ______________________ 14. platinum (IV) iodate ______________________ 15. molybdenum phosphate ______________________ 16. titanium (II) cyanide ______________________ 17. gold (I) thiosulfate ______________________ 18. iron (III) acetate ______________________ 19. cobalt (II) chlorate ______________________ 20. tin (IV) sulfite ______________________ G.10 Science—Naming Covalent Compounds Shaftesbury High School Covalent compounds have a different naming system since there are no ions involved and no need to balance charges. Eg. CO2 Eg 2. CO Covalent compounds are named using __________________________. 1- 6- 2- 7- 3- 8- 4- 9- 5- 10 - Simply, 1. PCl3 _________________________________ 2. N2O4 _________________________________ 3. H2O _________________________________ 4. CF4 _________________________________ 5. SiO4 _________________________________ G.10 Science—Naming Covalent Compounds Shaftesbury High School Writing Covalent Formulas 1. Disulfur Oxide _________________________________ 2. Nitrogen Trichloride _________________________________ 3. Carbon Monoxide _________________________________ 4. Tetrabromine Nonoxide _________________________________ 5. Arsenic Trihydride _________________________________ Covalent Compound Review 1. What is a covalent compound? What elements are involved? 2. How many electrons are shared in a covalent bond? Provide examples to support your answer. Write the chemical formula for each of the following covalent compounds. a. Carbon Monoxide _________________________________ b. Nitrogen Trifluoride _________________________________ c. Dinitrogen Oxide _________________________________ d. Dihydrogen Oxide _________________________________ e. Sulfur Dioxide _________________________________ f. Silicon Flouride _________________________________ Write the covalent compound name from the following formulas. g. CCl4 _________________________________ h. NO3 _________________________________ i. CS2 _________________________________ j. NO _________________________________ k. CO2 _________________________________ l. PCl3 _________________________________ G.10 Science—Naming Assignment Shaftesbury High School Name the following covalent compounds. 1. HI __________________________________________ 2. CCl4 __________________________________________ 3. Cl2O __________________________________________ 4. HBr __________________________________________ 5. PF3 __________________________________________ 6. ICl __________________________________________ 7. S2O __________________________________________ 8. P4O6 __________________________________________ 9. CO2 __________________________________________ 10. PH3 __________________________________________ 11. SiCl4 __________________________________________ 12. CBr4 __________________________________________ 13. AsH3 __________________________________________ 14. Br4O9 __________________________________________ 15. NO2 __________________________________________ 16. CO __________________________________________ 17. IF7 __________________________________________ 18. S4N4 __________________________________________ 19. NCl3 __________________________________________ 20. H2O __________________________________________ G.10 Science—Naming and Compounds Web Shaftesbury High School G.10 Science—Covalent Binary Compounds Shaftesbury High School Write the name of each of the following compounds. 1. HF ______________________ 2. H2S ______________________ 3. NO ______________________ 4. N2O ______________________ 5. NO2 ______________________ 6. N2O5 ______________________ 7. SO2 ______________________ 8. CBr4 ______________________ 9. C2H6 ______________________ 10. C4H10 ______________________ Write the chemical formula for each of the given names. 11. Nitrogen Triiodide ______________________ 12. Dinitrogen Tetroxide ______________________ 13. Sulfur Trioxide ______________________ 14. Carbon Monoxide ______________________ 15. Dihydrogen Monoxide ______________________ 16. Hydrogen Monobromide ______________________ 17. Phosphorus Trichloride ______________________ 18. Tricarbon Octahydride ______________________ 19. Carbon Tetrahydride ______________________ 20. Dicarbon Tetrahydride ______________________ G.10 Science—Naming and Compounds Shaftesbury High School G.10 Science—Naming and Compounds Shaftesbury High School G.10 Science—Naming and Compounds Shaftesbury High School G.10 Science—Molar Mass Shaftesbury High School The molar mass of a molecule is calculated by Eg. H2O Eg 2. CH4 G.10 Science—Molar Mass Conversions Shaftesbury High School For all calculations, show your work and include units. Calculate the molar mass for each of the following compounds. Include units. Calcium Nitrate Formula: Formula: Molar Mass: Sodium Hydroxide Formula: Molar Mass: Molar Mass: Lead (IV) Oxide Formula: Molar Mass: Molar Mass: Copper (II) Nitrate Lead (II) Iodide Formula: Calcium Cyanide Molar Mass: Formula: G.10 Science—Molar Mass Conversions Shaftesbury High School Dinitrogen Pentoxide Formula: Molar Mass: Nickel (II) Sulfate Molar Mass: Formula: Molar Mass: Formula: Potassium Dichromate Formula: Molar Mass: Molar Mass: Carbon Dioxide Calcium Acetate Formula: Iron (III) Chloride Molar Mass: Formula: G.10 Science—Molar Mass Assignment Shaftesbury High School Calculate the molar mass of the following chemicals. Ensure that you show all your work. 1. Cl2 ANS: ____________ 2. KOH ANS: ____________ 3. BeCl2 ANS: ____________ 4. FeCl3 ANS: ____________ 5. BF3 ANS: ____________ 6. CCl2F2 ANS: ____________ 7. Mg(OH)2 ANS: ____________ 8. UF6 ANS: ____________ 9. SO2 ANS: ____________ 10. H3PO4 ANS: ____________ 11. (NH4)2SO4 ANS: ____________ 12. CH3COOH ANS: ____________ 13. Pb(NO3)2 ANS: ____________ 14. Ga2(SO3)3 ANS: ____________ G.10 Science—Naming and Compounds Shaftesbury High School
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