SAFETY DATA SHEET according Regulation EC No 1907/2006 and Regulation EU No 830/2015 23.1.2017 Date of issue: Revision: Date of revision: MORDANT INK Page 1 of 13 SECTION 1. 1.1. Identification of the substance/mixture and of the company/undertaking Product identifier Product name: Chemical name: Shadow specification: MORDANT INK - 34584 34583 34582 34586 Buk Dub Dub světlý Dub tmavý English name Beech Oak Oak light Oak dark 34587 Mahagon Mahagony Shadow No. Czech name Shadow No. 34589 34585 34581 34591 34591 Czech name Olše Ořech Smrk Teak Tmavě hnědý English name Alder Walnut Spruce Teak Dark brown Mahagon Mahagony 34580 Třešeň Cherry červený red 34588 Modřín Larch Note: The identification numbers of chemicals or hazardous ingredients mixture see. Section 3. 34590 Registration number: 1.2. 1.3. not registered (mixture) Relevant identified uses of the substance or mixture and uses advised against Identified uses of the substance or mixture: Filling in the production fixes. For repairing wood defects (carpentry work). Uses advised against All other uses different from identified uses. Details of the supplier of the safety data sheet Supplier identification Trade name: Address: VAT number: Phone number: E-mail: KOH-I-NOOR HARDTMUTH a.s. F. A. Gerstnera 21/3, 371 30 České Budějovice, závod 1, 289 03 Městec Králové 26055996 +420 325 870 311/+420 325 643 241 [email protected] Responsible person for the safety data sheet Name: Ing. Jiří Švachula, CSc Trade name: EKONOX, s.r.o. Address: V Ráji 501, 530 02 Pardubice Phone number: +420 466 415 799 E-mail: [email protected] 1.4. Emergency telephone number +420 602 414 051 or Toxicological information centre, Na Bojišti 1, 128 08 Prague 2, Non-stop telephone 224 919 293, 224 915 402, or (only during the day 224 914 575) SAFETY DATA SHEET according Regulation EC No 1907/2006 and Regulation EU No 830/2015 23.1.2017 Date of issue: Revision: Date of revision: MORDANT INK Page 2 of 13 SECTION 2. 2.1. Hazards identification Classification of the substance or mixture 2.1.1 Classification of mixture according Directive 1272/2008/EC (CLP): Hazard Class and Flam. Liq. 2, Skin Sens. 1, Eye Irrit. 2, STOT SE 3, Aquatic Chronic 3 Category Code: H-statements: H225-H317-H319-H336-H412 For the wording of the listed H-statements, refer to section 16. 2.1.2 Other information The most important adverse physicochemical effects: High flammable liquids and vapours. The most important adverse for human health: Inhalation: Not known. Ingestion: Not known. Contact with skin: May cause an allergic skin reaction. Contact with eyes: Causes serious eye irritation. The most important adverse for the environment: Harmful to aquatic life with long lasting effects. 2.2. Label elements Labelling of mixture with classification according Directive 1272/2008/EC (CLP): Hazard pictogram(s): Signal word: H-statements: P-statements: Danger H225-H317-H319-H336-H412 P102-P210-P233-P261-P271-P273-P280- P(304+340) - P(305+351+338)P(333+313)+P(362+364)-P(370+378)-P(403+235)-P501 For the wording of the listed P-statements, refer to section 16. Additional information on the packaging/label: Contains: Ethanol, 1-methoxy-2-propanol, rosin The packaging must be equipped with a tactile warning. 2.3. Other hazard Not known SECTION 3. 3.1. Composition/information on ingredients Mixture Product name: MORDANT INK Description of mixture: Mixture of ethanol, 1-methoxy-2-propanol, appropriate colorants and other additives. SAFETY DATA SHEET Date of issue: Revision: Date of revision: according Regulation EC No 1907/2006 and Regulation EU No 830/2015 23.1.2017 MORDANT INK Page 3 of 13 Other identification data of substances: 1) Index No 2) CAS No 3) EC No 4) Registration No 1) 603-002-00-5 2) 64-17-5 3) 200-578-6 4) 01-2119457610-43-xxxx 1) 603-064-00-3 2) 107-98-2 3) 203-539-1 4) 02-2119752510-47-0000 1) 650-015-00-7 2) 8050-09-7 3) 232-475-7 4) not yet assigned 1) 603-117-00-0 2) 67-63-0 3) 200-661-7 4) 01-2119457558-25-xxxx 1) 606-002-00-3 2) 78-93-3 3) 201-159-0 4) 01-2119457290-43-xxxx 1) not assigned 2) 94276-33-2 3) 304-519-6 4) not yet assigned 1) not assigned 2) 94277-77-7 3) 304-661-9 4) not yet assigned 1) not assigned 2) 84961-40-0 3) 284-628-2 4) not yet assigned 1) not assigned 2) 85029-57-8 3) 285-082-8 4) not yet assigned Chemical name Concentration [% by weight] Classification EC No 1272/2008 ethanol 49,9 – 64,4 Flam Liq. 2 (H225), Eye Irrit. 2 (H319) 1-methoxy-2-propanol 20,4 Flam. Liq. 3 (H226), STOT SE 3 (H336) rosin 2,05 – 3,07 Skin Sens. 1 (H317) propan-2-ol 1,83 – 2,05 Flam. Liq. 2 (H225), Eye Irrit. 2 (H319), STOT SE 3 (H336) butanone 1,83 – 2,05 Flam. Liq. 2 (H225), Eye Irrit. 2 (H319), STOT SE 3 (H336) C.I. Solvent Yellow 81 0,9 – 4,01 Aquatic Chronic 2 (H411) C.I. Solvent Blue 70 0-2 Aquatic Chronic 3 (H412) 0 - 0,83 Acute Tox. 4 (H302) 0 - 0,83 Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410) 0,4 Aquatic Chronic 3 (H412) 0 – 0,1 Aquatic Acute 1 (H400), Aquatic Chronic 1 (H410) Amines, C10-14-branched and linear alkyl, bis[2,4dihydro-4-[(2-hydroxy-5nitrophenyl)azo]-5-methyl-2phenyl-3H-pyrazol-3-onato(2)]chromate(1-) (1:1) Amines, C10-14-branched and linear alkyl, bis[2,4dihydro-4-[(2-hydroxy-4nitrophenyl)azo]-5-methyl-2phenyl-3H-pyrazol-3-onato(2)]chromate(1-) 1) not assigned 2) 84962-27-6 C.I. Solvent Red 160 3) 284-723-9 4) not yet assigned 1) not assigned 2) 85029-58-9 C.I. Solvent Yellow 82 3) 285-083-3 4) not assigned For the wording of the listed H-statements, refer to section 16. SAFETY DATA SHEET according Regulation EC No 1907/2006 and Regulation EU No 830/2015 Date of issue: Revision: Date of revision: 23.1.2017 MORDANT INK Page 4 of 13 SECTION 4. 4.1. First aid measures Description of first aid measures General information: Symptomatic treatment. In case of health problems or in doubt seek medical treatment. On the accident and sickness seek medical help and show this data sheet. When providing first aid affected person must not cold. Inhalation: Transfer the affected person to fresh air and keep it in a position comfortable for breathing. If breathing becomes difficult, give oxygen. Seek medical advice. Skin contact: Take off contaminated clothing. Wash with plenty of water and soap, threat with protective cream. If irritation persists, seek physician. Contact with eyes: Remove contact lenses, hold the affected eyelids open and flush with water for at least 15 minutes. Seek medical advice. Ingestion: If the victim is conscious, let to drink him plenty of water. Do not induce vomiting! Seek physician immediately. Personal protective equipment for first aid responders According to extent of first aid given is necessary to use suitable protective equipment – isolated breathing apparatus or mask with filter and eventually the safeguarding by other worker. Always use protective gloves and resuscitation mask in the case artificial respiration. Wash carefully hands after first aid. Always change clothes if during first aid giving the contamination of clothes occurs. Other data: Other information concerning the delivery of first aid measures, especially in serious cases of health damage, the attending physician can consult the procedure with Toxikologické informační středisko, Praha, Czech Republic, phone (continually): +420 224 919 293, 224 915 402, fax 224 914 570. 4.2. Most important symptoms and effects, both acute and delayed May cause drowsiness or dizziness. Inhalation: Ingestion: Contact with skin: Contact with eyes: 4.3. Not known. Not known. May cause an allergic skin reaction. Causes serious eye damage. Indication of any immediate medical attention and special treatment needed See section 4.1 SECTION 5. 5.1. Firefighting measures Extinguishing media Suitable extinguishing media: Alcohol-resistant foam, dry chemical powder, carbon dioxide SAFETY DATA SHEET according Regulation EC No 1907/2006 and Regulation EU No 830/2015 Date of issue: Revision: Date of revision: 23.1.2017 MORDANT INK Page 5 of 13 Unsuitable extinguishing media: Full water jet, danger of fire spreading. 5.2. Special hazards arising from the substance or mixture Hazardous combustion products: Burning releases carbon oxides and harmful gases containing organic derivatives. Fumes can combine with air to form an explosive mixture. 5.3. Advice for firefighters Fire-resistant clothing and self-contained breathing apparatus (EN 133). Threatened containers move to the safe distance. Prevent firefighting water to escape into drains, soil or water. Residues and contaminated fire extinguishing water must be disposed of as waste in compliance with local regulations. 5.4. Other information Not available. SECTION 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1 For non-emergency personnel Protective measures: Wear appropriate protective equipment. After work Always wash your hands thoroughly with soap and water. Prevent unauthorized access. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take precautions against static discharge. Avoid breathing vapour / aerosol. Emergency measures: Wear appropriate protective equipment to prevent contact with skin and eyes. No smoking. Ensure adequate ventilation of working areas. During a fire, evacuate area. 6.1.2 For emergency responders Use suitable personal protective equipment to avoid contact with product. 6.2. Environmental precaution Avoid leakage of spilled mixture into drains/surface water/ground water. 6.3. Methods and material for containment and cleaning up Methods of containment of leakage: After using the container, have to be tightly closed. Methods for cleaning up: Free liquid pump / move to the appropriate container. Remove the rest from contaminated surfaces with non-combustible sorbent (sand, soil, vermiculite). The contaminated sorbent place in a suitable container and remove waste in accordance with waste regulations. Disposal, see Section 13. Other information: Not available. 6.4. Reference to other section See Section 8 and 13. SAFETY DATA SHEET according Regulation EC No 1907/2006 and Regulation EU No 830/2015 23.1.2017 Date of issue: Revision: Date of revision: MORDANT INK Page 6 of 13 SECTION 7. Handling and storage 7.1. 7.1.1 Precautions for safe handling Protective precautions Fire precaution: When handling the product do not smoke, drink or eat. Wear personal protective equipment to avoid contact with skin and eyes. Use only outdoors or in well-ventilated areas. Avoid breathing vapour / aerosol. Remove contaminated clothing and wash before reuse. Take precautions against static discharge. Precaution for elimination of dust and aerosol formation: Ensure efficient ventilation or exhausting. Environment protection: Avoid leakage of concentrated product into soil/ water sources/ sewer. 7.1.2 Advice on general occupational hygiene Wearing adequate protective equipment, avoid direct eye contact with the substance. Avoid formation and inhalation of vapours and dust. Avoid drying the product and subsequent formation and inhalation of dust. When handling with the product do not smoke, drink or eat. After work, wash hands and face. 7.2. Conditions for safe storage, including any incompatibilities Technical measures and conditions of storage: Keep the packaging well labelled, tightly closed, protect them from damage. Store the product in its original packaging or in containers designed for this purpose in a cool, dry place. Store in a well-ventilated place. Vapours-air may form explosive mixtures. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Do not expose the product to direct sunlight. Take precautions against static discharge. Ground container and receiving equipment. With the rising temperatures, threaten to increase the pressure in the vessel and subsequent damage to the packaging and product leakage. Incompatible materials: Alkali metals, ammonia, oxidizing agents, peroxides. Packaging materials: Container keep well labelled, tightly closed, protect it from damage. Storage requirements: Store in cool, dry place in original closable containers. 7.3. Specific end use(s) See section 1.2. SECTION 8. 8.1. Exposure controls/personal protection Control parameters The mixture contain substances for which the occupational concentration limits are set (Czech Republic NV 361/2007 Coll., as amended) (maximum permissible exposure limit = PEL; maximum permissible concentration = NPK-P). Látka CAS číslo PEL NPK-P mg.m-3 2-Butanon 78-93-3 600 Ethanol 64-17-5 1000 iso-Propanol 67-63-0 500 Rosin – dust, smoke* 8050-09-7 1 1-Methoxy-2-propanol** 107-98-2 270 D - During exposure, absorption through the skin or strong skin irritation S - Substance has a sensitizing effect. 900 3000 1000 550 Poznámka D S D SAFETY DATA SHEET according Regulation EC No 1907/2006 and Regulation EU No 830/2015 23.1.2017 Date of issue: Revision: Date of revision: MORDANT INK Page 7 of 13 8.2. Exposure control 8.2.1 Appropriate engineering controls Do not smoke, drink and eat. Hands always thoroughly wash and treat with a suitable skin cream after manipulation with product. Remove contaminated clothing and wash before reuse. Ensure efficient ventilation / exhaustion at the workplace. 8.2.2 Personal protective equipment In the workplace, keep running water or containers with sufficient drinking water or eye washer. 8.2.2.1 Eye/ face protection Protective goggles. 8.2.2.2 Skin protection Hand protection: Suitable protective gloves, solvent resistant (butyl rubber material - thickness 0.7 mm, breakthrough time> 480 minutes, the material is natural latex - thickness 0.4 mm Breakthrough time> 120 minutes). The glove material has to be impermeable and resistant to the product. Other skin protection: Protective clothing, working shoes. 8.2.2.3 Respiratory protection Insufficient workplace ventilation, use appropriate respiratory protection (respirator or mask with filter the filter A / P2 against vapours of organic compounds). 8.2.2.4 Thermal hazard Not known. 8.2.3 Environmental exposure controls Do not discharge into surface / ground water or sewage system. If the product contaminates surface / ground water or drains inform respective authorities. SECTION 9. 9.1. Physical and chemical properties Information on basic physical and chemical properties Appearance: Colour: Odour: Odour threshold: pH: Melting point/ freezing point: Initial boiling point and boiling range: Flash point: Evaporation rate: Flammability (solid, gas): Upper/lower explosive limits: Vapour pressure: Vapour density: Density: Solubility: Partition coefficient: n-octanol/water: Auto-ignition temperature:; Decomposition temperature: Viscosity: liquid see Section 1.1. (Shadow Specification) alcoholic not determined not determined not determined not determined 19 °C (ČSN 65 6065) not determined highly flammable liquid and vapours not determined not determined not determined not determined not determined not determined not determined not determined not determined SAFETY DATA SHEET according Regulation EC No 1907/2006 and Regulation EU No 830/2015 23.1.2017 Date of issue: Revision: Date of revision: MORDANT INK Page 8 of 13 Explosive properties: Oxidising properties: 9.2. possible formation of explosive mixtures with air not determined Other information Not available. SECTION 10. Stability and reactivity 10.1. Reactivity Product is not reactive under normal conditions of use. 10.2. Chemical stability Product is chemical stable under normal conditions of use. 10.3. Possibility of hazardous reactions Vapours may form explosive mixture with air. 10.4. Conditions to avoid Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Do not expose the product to direct sunlight. Take precautions against static discharge. Higher temperature increase risk of increasing the pressure in the vessel and subsequent damage to the packaging and product leakage. 10.5. Incompatibles materials Alkali metals, ammonia, oxidizing agents, peroxides. 10.6. Hazardous decomposition products Carbon oxides and harmful gases containing organic derivatives are released during burning of product. Fumes can combine with air to form an explosive mixture. SECTION 11. Toxicological information 11.1.Information on toxicological effects Acute toxicity: not determined Acute toxicity determined for hazardous components of mixture: Ethanol: LD50 (rat, oral): LC50 (rat, inhal): LD50 (rabbit, dermal): 1-methoxy-2-propanol LD50 (rat, oral): LC50 (rat, inhal, 4 hrs): LD50 (rabbit, dermal): rosin LD50 (rat, oral): Skin corrosion/irritation: Serious eye damage/irritation: Respiratory or skin sensitisation: Germ cell mutagenicity: Carcinogenicity: not determined Category 2 Category 1, skin not determined not determined 10 470 mg/kg 30 000 mg/m3 15 800 mg/kg 5 200 mg/kg 54,6 mg/m3 14 000 mg/kg 7 600 mg/kg SAFETY DATA SHEET according Regulation EC No 1907/2006 and Regulation EU No 830/2015 23.1.2017 Date of issue: Revision: Date of revision: MORDANT INK Page 9 of 13 Reproductive toxicity: STOT-single exposure: STOT-repeated exposure: Aspiration hazard: Information on likely routes of exposure: not determined Category 3, narcotic effect not determined not determined not known Symptoms related to the physical, chemical and toxicological characteristics: not known Delayed and immediate effects as well as chronic effects from short and long-term exposure: not known SECTION 12. Ecological information 12.1. Toxicity Harmful to aquatic life with long lasting effects. Ethanol: LC50 (fresh water fish) = 11 200 mg/l EC50/LC50 (fresh water - invertebrates) = 5 012 mg/l EC50/LC50 (sea water – inertebrates) = 857 mg/l Long-term toxicity: EC10/LC10 or NOEC (fresh water invertebrates) = 9,6 mg/l EC10/LC10 or NOEC (sea water invertebrates) = 79 mg/l EC50/LC50 (fresh water algae) = 275 mg/l EC50/LC50 (sea water algae) = 1 970 mg/l EC50/LC50 or NOEC (fresh water algae) = 115 mg/l EC50/LC50 or NOEC (sea water algae) = 1 580 mg/l EC50/LC50 (fresh water plants) = 4 432 mg/l EC50/LC50 or NOEC (fresh water plants) = 280 mg/l Short-term toxicity: EC50 or LC50 (terrestrial plants) = 633 mg / kg soil dw EC50/LC50 (water microorganisms) = 5800 mg / l 1-methoxy-2-propanol: LC0 (Leuciscus idus melanotus, 96 hrs) >4600 mg/l EC50 (Daphnia magna, 48 hrs) = 23 300 mg/l EC50 (Pseudokirchneriella subcapitata, 168 hrs) >1000 mg/l EC50 (activated sludge) >1000 mg/l rosin: EC50 (Daphnia magna, 48 hod) >1000 mg/l 12.2. Persistence and degrability Biodegradation: 94% (modified screaning test OECD). 12.3. Bio accumulative potential Data are not available. 12.4. Mobility in soil Data are not available. 12.5. Results of PBT and vPvB assessment SAFETY DATA SHEET according Regulation EC No 1907/2006 and Regulation EU No 830/2015 23.1.2017 Date of issue: Revision: Date of revision: MORDANT INK Page 10 of 13 Product is not PBT or vPvB. 12.6. Other adverse effects Not known SECTION 13. Disposal considerations 13.1. Waste treatment methods 13.1.1 Removing the product / packaging: Substance treatment methods: Product has to be disposed as hazardous waste. Product has to be disposed in accordance with law of wastes in valid version and with connecting on legal directives. Contaminated container treatment methods: Contaminated container has to be disposed as hazardous waste. Contaminated container has to be disposed in accordance with law of wastes in valid version and with connecting on legal directives. 13.1.2 Other information: Waste labelling must correspond with European catalogue of waste. SECTION 14. Transport information 14.1. UN number UN1170 Labelling ADR/RID, IMDG, ITA-DGR: 14.2. UN proper shipping name ETHANOL, SOLUTION (ETHANOL, SOLUTION) 14.3. Transport hazard class(es) 3 14.4. Packing group II 14.5. Environmental hazards YES 14.6. Special precautions for user Not determined 14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code SAFETY DATA SHEET according Regulation EC No 1907/2006 and Regulation EU No 830/2015 23.1.2017 Date of issue: Revision: Date of revision: MORDANT INK Page 11 of 13 Not applicable to product 14.8. Other information Not available SECTION 15. Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture REGULATION (EC) No 1907/2006 of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC REGULATION (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures COMMISSION REGULATION (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) COMMISSION REGULATION (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) CZECH NATIONAL LEGISLATION (Safety, health and environmental regulations): Act no. 350/2011 Coll., on chemical substances and chemical preparations 15.2. Chemical safety assessment Not required – mixture. SECTION 16. Other information 16.1. Changes in MSDS Safety Data Sheet was prepared in compliance with Regulation (EC) 1272/2008 and Regulation (EU) 2015/830. Data for compiling were Safety Data Sheet Mořidlové inkousty, KOH-I-NOOR, January 2017 16.2. Methods used for the purpose of classification of mixture (EC) No 1272/2008 Classification has been worked out according with COMMISION REGULATION (EC) No 1272/2008, information from ECHA website and Safety Data Sheet Mořidlové inkousty, KOH-I-NOOR, January 2017 List of relevant H-statements (Sections 2. and 3.): H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H302 Harmful if swallowed, H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. SAFETY DATA SHEET according Regulation EC No 1907/2006 and Regulation EU No 830/2015 23.1.2017 Date of issue: Revision: Date of revision: MORDANT INK Page 12 of 13 H411 H412 Toxic to aquatic life with long lasting effects. Harmful to aquatic life with long lasting effects. List of relevant P-statements (Sections 2. and 3.): P102 Keep out of reach of children. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P (304+340) IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P (303+361+353) IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P (333+313) If skin irritation or rash occurs: Get medical advice/attention. P (362+364) Take off contaminated clothing and wash before reuse. P (370+378) In case of fire: Use foam for extinction. P (403+235) Store in a well-ventilated place. Keep cool. P501 Dispose of contents/container to an approved waste disposal plant. 16.3. Advices for training Acquaint the workers with this Safety Data Sheet and with general rules of handling with chemical substances/ mixtures. Training carry out once time per year. 16.4. Wellspring of information for elaboration of Safety Data Sheet Safety Data Sheet Mořidlové inkousty, KOH-I-NOOR, January 2017 Database of registered substances ECHA (www.echa.eu), January 2017 16.5. Abbreviations Acute Tox. 4 Aquatic Acute 1 Aquatic Chronic 1 Aquatic Chronic 2 Aquatic Chronic 3 BCF CAS EC10 EC50 Eye Irrit. 2 Flam. Liq. 2 Flam. Liq. 3 LC0 LC50 LD50 NPK-P PBT PEL Skin Sens. 1 STOT SE 3 vPvB Acute Toxicity, Hazard Category 4 Hazardous to the aquatic environment — Acute Hazard, Category 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1 Hazardous to the aquatic environment — Chronic Hazard, Category 2 Hazardous to the aquatic environment — Chronic Hazard, Category 3 Bio concentration factor Chemical Abstracts Service Effective concentration, causes 10% changes in response. Half maximal effective concentration. Serious eye damage/eye irritation, Hazard Category 2 Flammable Liquids, Hazard Category 2 Flammable Liquids. Hazard Category 3 Maximal tolerable concentration Lethal Concentration to 50% of a test population Lethal Dose to 50% of a test population Maximal available concentration Persistent, bioaccumulative and toxic Permissible exposure limit Sensitization – skin, Hazard Category 1 Specific Target Organ Toxicity — Single Exposure, Hazard Category 3 Very persistent and very bioaccumulative SAFETY DATA SHEET according Regulation EC No 1907/2006 and Regulation EU No 830/2015 Date of issue: Revision: Date of revision: 23.1.2017 MORDANT INK Page 13 of 13 16.6. Other information Labelling of mixture with classification according Directive 1272/2008/EC (CLP): label of packaging with a volume less than 125 ml, (Article 26 and 29, Section 1.5.2, Annex 1) Hazard pictogram(s): Signal word: H-statements H317 H336 H412 Danger May cause an allergic skin reaction. May cause drowsiness or dizziness. Harmful to aquatic life with long lasting effects. P-statements P102 P210 Keep out of reach of children. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves. P (303+361+353) IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P (304+340) IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P501 Dispose of contents/container to an approved waste disposal plant. Additional information on the packaging/label: Contains: Ethanol, 1-methoxy-2-propanol, rosin The packaging must be equipped with a tactile warning. The details in this safety data sheet are based on our status of knowledge and experience at the time of date issue. They are not a contractual assurance of quality properties of the product, and they apply only in conjunction with correct and proper handling of the product under normal conditions, and according to the details of specified use on the packing and/or in the technical instructions. The user himself is fully responsible for every other use of the product such as in combination with other products or with other processes.
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