BCAS Vol.25 No.1 2011 Green Plate-making Technology Based on Nanomaterials SONG Yanlin Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China Email: [email protected] M ovable type printing technology is one of the four great inventions of ancient China which played a significant role in passing down the history and civilization of human society. Today, with economic development and people’s diverse needs for presswork, printing has penetrated into all spheres of life, and the printing industry has become one of the industries that have important impacts on China’s national economy. Since China is now the third largest printing market in the world, the rapid development of this huge market calls for digital plate-making technologies for the sake of environmental protection. The major plate-making technologies used nowadays, namely the laser typesetting plate-making technology and the computer to plate technology (CTP), involve multiple processes including photo-sensing, developing, washing, etc., and are complicated, timeconsuming and costly, leading to environment pollution due to the use of chemicals. In light of the notion of sustainable development, the environment-friendly “green printing” has become a trend in the printing industry. Based on innovative research on nanomaterials, we have developed a new type of green plate-making technology which abandoned the idea of photo-sensing and effectively avoided the environment pollution induced by current plate-making technologies. This new technology is non-photosensitive, non-polluting and Figure 1. Technical route of making printing plates via laser typesetting technology Figure 2. Technical route of making printing plates via CTP technology low-cost with simple operation processes, which is bound to bear positive influences on the sustainable development of Song Yanlin is a research professor and chief of the New Material Laboratory of the CAS Institute of Chemistry. His research Interest lies in environmentally-friendly printing materials and technology, high density information storage medium, and photonic crystal material. 52 Bulletin of the Chinese Academy of Sciences Vol.25 No.1 2011 green printing process and the printing industry. I. Current status and problems of plate-making technologies in China About 30 years ago, China’s printing industry was dominated by the movable type printing technology, and the exhausting word-picking process and heavy use of lead resulted in low productivity and serious pollution. In the 1980’s, Prof. WANG Xuan, a computer science expert and Member of the Chinese Academy of Sciences, successfully developed a computerized laser photocomposition system for the typesetting of Chinese characters, lifting China’s printing industry "out of lead and fire to enter an era of light and electricity”. Wang’s innovation not only marks a milestone in the history of Chinese character typesetting, but is still the mainstream printing-plate technology in China today. Meanwhile, CTP has become a representative of advanced plate-making technologies in recent years. The technical routes of laser typesetting and CTP are respectively shown in Figure 1 and Figure 2. The laser typesetting technology involves two steps of photographic imaging and the corresponding chemical developing processes, while the CTP involves only one step of photographic process. However, although the latter has omitted one step of photo-sensitive chemical imaging and been optimized to protect environment, the existing platewashing process still inevitably releases chemical waste and exerts a negative impact on the environment. Therefore, developing a non-polluting plate-making technology is urgent for environmental conservation and the sustainable development of the industry. II. Research and development of green plate-making technology based on nanomaterials Different from the above photo-sensitization imaging technologies, we have developed a “green” technology for making printing plates based on nanomaterials. Thanks to long-time accumulation in the field of nanomaterials research, we have invented the new technology after achieving the modulation of surface wettability and the development of printing materials. It starts from the innovative application of nanomaterials to meet the specific Chemistry Benefits Us requirements of the printing industry via a new platemaking technology route (Figure 3). The new technology makes use of the superhydrophilic or superoleophilic properties of nanomaterials to print specific transfer materials precisely onto the superhydrophilic plate with micron-nano composite structures. Through the control of transfer materials and the interface properties between transfer-printing materials and the plate with nano-scale roughness, the nmacrozone (graphic and non-graphic zones) with the opposite wettability (superhydrophobic/ superhydrophilic) will be formed on the inkjet printing plate, which can be directly used as a printing plate. As the new technology abandons the idea of sensitization imaging, it differs radically from the current plate-making technologies in concept, material and technical process to be non-photosensing, non-polluting and of low cost. It provides an opportunity for Chinese printing enterprises to achieve a technological breakthrough and contribute to environmental protection. III. Industrialization of the green plate-making technology With support from the Chinese Academy of Sciences and the Ministry of Science and Technology, our team has applied more than 30 patents in China, seven of which are already granted together with 5 PCT (Patent Cooperation Treaty) patents. By far, we have pooled together all the necessary technologies for direct plate-making and printing, including the technologies for making nano-composite transfer printing materials, superhydrophilic plates with micro- or nano-structures as well as relevant equipment and software, and established a pilot line with an annual output up to millions of square meters of printing plates and tens of thousands of liters of nano-composite transfer printing materials. To promote the demonstration applications of the technology, we are keeping close cooperation with many printing companies. Through these collaborations, we have accumulated much experience for further application of the new technology. It can be expected that the industrialization of the nanomaterial-based green plate-making technology would reduce the environmental pollution of printing plants and play an active role in the greening of the printing industry in China. Figure 3. A “green” process of making plates using nanomaterials Bulletin of the Chinese Academy of Sciences 53
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