Chemistry Chapter 5 – Electrons in Atoms Notes Name ________________________ Date _________________________ ATOMIC MODEL See Atomic Model Timeline worksheet for specifics. ELECTRONS Quantum Mechanical (QM) Model- This is the currently accepted model of the atom. o Erwin Schrödinger wrote an equation which describes _______________________________ __________________________________________________________________________. These locations are not definite because of the Heisenberg Uncertainty Principle. Each of the following terms gives a more specific description of where an electron probably is. In Chemistry… In CB South, for example… o Energy level, n o Sublevel, l o Orbital, ml o Spin, s Energy Levels, no An electron may NOT be found _____ _______________________________. o Higher n = higher energy (typically) o n is called the ______________ _____________________________. o To determine how many electrons fit into a given energy level, use this formula: _____ o The maximum number of electrons is 32. o Electrons will occupy ________________________________ first. Sublevels (subshells), l- s Sublevel Shape Appears # of Orbitals Capacity p Sublevel d Sublevel f Sublevel ELECTRON CONFIGURATIONS Electron Configurations- Electron Configuration PRACTICE o Sulfur (S) o Chromium (Cr) o Cobalt (Co) o Zinc (Zn) o Strontium (Sr) o Selenium (Se) o Molybdenum (Mo) o Mercury (Hg) o Antimony (Sb) o 1s22s22p63s23p4 o Chlorine (Cl) o 1s22s22p63s23p64s23d10 o Calcium (Ca) o 1s22s22p63s23p64s23d104p1 Shorthand notation- To write in shorthand electron configuration notation: o 1st – Find the _________________ that is in the row above the element you want o 2nd – Write that noble gas's __________ in [brackets] o 3rd – Then continue with the e– configuration starting with the next element Ex- Scandium: 1s22s22p63s23p64s23d1 Ex- Chlorine: 1s22s22p63s23p5 ELECTRON EXCEPTIONS Write the configuration for the following: o Cr: o Cu: What they actually are: o Cr: o Cu: Reason – _________________ sublevels are the most _________________. ____________________ sublevels are not as stable as filled, but more stable than others. ORBITAL NOTATIONS & THE RULES Orbital Notations o Use a ________________ to represent each _____________________. s orbitals have _________ line p orbitals have _________ lines d orbitals have _________ lines f orbitals have _________ lines o Use up/down arrows to represent _________________________. o Each line can hold a maximum of _____________ electrons. o Example Titanium: ___ 1s ___ 2s ___ ___ ___ 2p ___ 3s ___ ___ ___ 3p ___ 4s FILLING RULES Aufbau Principle- o This is the order we get from “reading” the Periodic Table. Pauli Exclusion Principle- o This is the electron “spin.” Either +½ or –½ Hund’s Rule – o They’d rather spread out. ___ ___ ___ ___ ___ 3d ELECTRON IN ATOMS Electron Demonstration – try to identify key concepts for electrons moving within an atom… Flame Tests o Elements give off characteristic _________________ which can be used to identify them. o Electrons ____________ energy from the flame (or other heat source). o When a certain amount of energy is reached, which is called a __________________, electrons jump to a higher energy level called the _______________________________. o When the electrons ___________ energy in the form of ______________, this is also called a photon or unit of light, they fall back to the lowest, most ________________ energy level called the ____________________________. VISIBLE LIGHT & THE EM SPECTRUM Visible light exists as a narrow band of ____________________ that our eyes can detect. o The colors of the rainbow ________________________. o Red light has a wavelength of about _____________ nanometers and represents _________________ frequencies. o Violet light has a wavelength of about _____________ nanometers and represents _________________ frequencies. Wave Statistics o Amplitude – the __________________ of the wave from zero to crest. o Wavelength – the distance between ________________________ points in phase. Unit: Symbol: o Frequency – the number of cycles (wave peaks) that occur in a unit of time. Unit: Symbol: o Wavelength & frequency are ______________________ related, meaning that ____________ wavelengths go with ____________ frequencies and ____________ wavelengths go with ____________ frequencies. Wave Equation o Formula: o Speed of light is always: o Example 1 - If the frequency of radiation for yellow light is 5.10 x 1014 Hz, what is the wavelength? o Example 2 - What is the frequency of radiation with a wavelength of 5.00 x 10-8 m? Electromagnetic Spectrum – a grouping of all waves that travel at the speed of light. ATOMIC EMISSION SPECTRA Electrons returning from an _________________ energy level emit ______________ of specific ______________________ (specific bands of color). Each element has a ___________________ emission spectra and therefore is a good way to _______________ an element! Additional transitions exist, but we can’t see them because our eyes only detect visible light. These series of transitions are called Lyman, Balmer and Paschen. Energy – as an _____________ falls from excited states they release a ________________ of energy that can be calculated using Plank’s constant and the frequency of the transition. o Formula: o Example 1 - The energy given off when an electron transfers from energy level 6 to 5 is 2.66 x 10-20 J. What is the frequency? What is the wavelength? o Example 2 - If the frequency associated with a transition from energy level 2 to 1 is 2.48 x 1015, how much energy is released?
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