When showing the amounts of each element present in a compound using percentage by mass % mass = grams of element x 100% total grams of compound Part divided by total Multiply by 100 Round till whole. Please Make Rice! Purple Monkeys Rule! Px100 T Percent Composition of CaCl2. Ca = 40.1 g Cl = 35.5 x 2 = 71.0 g Total = 111.1 g Ca = 40.1g/111.1 x 100 = 36% Cl = 71.0g/111.1 x 100 = 64% Exactly 9.63g of Mg combines with 3.48 g of Nitrogen. 9.63 g x 100 = 73% Magnesium 13. 11g 100% – 73% = 27% Nitrogen (Or to check do 3.48/13.11 x 100) Number 2 Exactly 29.0g of Argon combine with 4.30g of Sulfur. Numbers 3-6 on your Percent Composition Practice worksheet. Catalysts: ◦ Molar Mass Practice WS ◦ Moles Practice WS #2 ◦ Moles to Particles WS If you do not fill out the table of contents or staple your work in the correct order, 5 points will be taken off your score. 1/21/14 Empirical Formulas EQ: What is an empirical formula? Calculate the percent composition of each element in Na2O. Na2O = 2(23.0) + 16.0 = 46.0 + 16.0 = 62.0 g/mol The formulas for compounds can be expressed as an empirical formula and as a molecular(true) formula. Empirical CH CH CO2 CH2O Molecular (true) Name C2H2 acetylene C6H6 benzene CO2 carbon dioxide C5H10O5 ribose 9 Write your own one-sentence definition for each of the following: Empirical formula Molecular formula 10 An empirical formula represents the simplest The molecular formula is the true or actual whole number ratio of the atoms in a compound. ratio of the atoms in a compound. 11 A. What is the empirical formula for C4H8? 1) C2H4 2) CH2 3) CH B. What is the empirical formula for C8H14? 1) C4H7 2) C6H12 3) C8H14 C. What is a molecular formula for CH2O? 1) CH2O 2) C2H4O2 3) C3H6O3 12 Pretend that you have a 100 gram sample of the compound. Step 1: That is, change the % to grams. Ex: Suppose a compound whose molecular mass is 695g is analyzed to contain 26.7% phosphorus, 12.1% nitrogen, and 61.2% chlorine. ◦ ◦ ◦ Phosphorus = 26.7g Nitrogen = 12.1g Chlorine = 61.2g Convert the grams to mols for each element. 26.7 g P 1 mol P 31.0 g P 12.1 g N 1 mol N 14.0 g N 61.2 g Cl 1 mol Cl 35.5 g Cl = 0.862 mols P = 0.864 mols N = 1.726 mols Cl Because!! Divide each number by the least number of moles. 0.862 mols P/0.862mols = 1 0.864 mols N/0.862 mols = 1 1.726 mols Cl/0.862/mols = 2 Write the number of mols as a subscript in a chemical formula. Multiply the result to get rid of any fractions. P = 1, N = 1, Cl = 2 Therefore the Empirical formula is PNCl2 Step Step Step Step Empirical Formula: 1: 2: 3: 4: Change the % to grams. Divide by molar mass Divide by the least number answer. Write answer as a subscript. ◦ Change, Divide, Divide, Write Mole Test: Tuesday, Jan. 28 Mini Quiz Friday (one question for each of the following) ◦ Percent composition, empirical formula, molar mass A compound is 43.64 % P and 56.36 % O. What is the empirical formula? 1mol P 43.64 g P 1.4 mole P 31.0 g P 1 mol O 56.36 g O 3.5 mole O 16.0 g O 1.4 mol P 1 mol P 1.4 mol 3.5 mol O 2.5 mol O 1.4 mol The ratio is P1O2.5 Get rid of decimals by multiplying to get a whole number. Multiply by 2. The empirical formula is P2O5. Do problems 2, 3, and 4 on your worksheet. From empirical to molecular formula The empirical is the formula with the lowest whole number ratios between elements. The molecular formula is a multiple of the empirical formula. It represents the actual molecule. Examples: CH3 is an empirical formula, C2H6 is a molecular formula (CH3 x 2 = C2H6) CH2O is an empirical formula, C6H12O6 is a molecular formula (CH2O x 6 = C6H12O6) Since the empirical formula is the lowest ratio, the actual molecule would weigh the same or more. Divide the actual molar mass by the molar mass of the empirical formula to determine the factor. Step 1: Find the molar mass of the empirical formula. Step2: Divide the actual molar mass by the molar mass of the empirical formula. Step 3: Multiply the empirical formula subscripts by your answer from step 2. The empirical formula of a substance is CH5N. The actual molar mass of the substance is 62 g/mol. What is its molecular formula? CH5N = 12.0 + 5(1.0) + 14.0 = 31.0 g/mol 62.0 g/mol 2 31.0 g/mol Multiply the empirical formula x 2. The molecular formula is C2H10N2. For Empirical Formula and molecular practice, work on completing the front side of the worksheet provided today. Quiz tomorrow!!! ◦ Three Questions Percent Composition Empirical Formula Molecular Formula 1/23/14 EQ: What do I know about moles? Pull out your worksheet from yesterday. Your catalyst is to complete #6. You may work it on the worksheet, and we will give your stamp on the catalyst sheet when you are done. #2-10 ◦ You will receive a classwork stamp for this assignment. IT IS DUE TODAY. After you have completed this, work on the study guide for next week’s test and tomorrow’s quiz. 1. 1/24/14 EQ: What do I know about moles? What is the percent composition of KNO3? You will need a calculator and something to write with. A periodic table will be provided. When you finish your quiz, work on your study guide. Catalysts ◦ ◦ ◦ ◦ Percent Composition Empirical Formula Empirical and Molecular Formula Practice AKS Moles Test Review If you do not put the Table of Contents or your name on the front, 5 points will be deducted. Mole Babies NEXT MONDAY ◦ Bring in fabric, ribbon, buttons, thread or any accessory you would like to put on your mole. ◦ If you bring supplies for yourself or for others to share with, you will get EXTRA CREDIT!!! ◦ If you need to finish your test, come in today during your guided study! 1/31/14 Mole Conversions EQ: How can I use balanced equations to convert moles of one substance to another? 6H2O + 6CO2 C6H12O6 + 6O2 Observe the balanced chemical equation above. There are 6 moles of CO2 in this chemical equation. There are also 6 moles of oxygen gas in this chemical equation. How many moles of water are there? Li3PO4 How many mols are there of each element? Li = 3 mols P = 1 mol O = 4 mols Just as you can compare elements to each other within a compound, the same works for chemical equations. Because of this, we can predict the yield of a certain substance within a reaction. 2H2 + O2 2H2O How many moles? How many moles of O2 are needed to react with one mole of C3H8? 5 How many moles of CO2 will be produced from one mole of C3H8? 3 How many moles of H2O will be produced from one mole of C3H8? 4 How many moles of O2 are needed to react with six moles of C3H8? 30 (6 moles x 5 O2) How many moles of CO2 will be produced from six moles of C3H8? 18 (6 moles x 3 CO2) How many moles of H2O will be produced from six moles of C3H8? 24 (6 moles x 4 H2O) 1 How many moles of O2 are needed to react with 16.3 moles of C3H8? 16.3 mol C3H8 5 mol O2 1 mol C3H8 = 81.5 mol O2 How many moles of H2O are produced from 12.9 moles of O2? 12.9 mol O2 4 mol H2O = 10.3 mol 5 mol O2 H2O If 29 moles of H2O was produced, how many moles of C3H8 were burned? 29 mol H2O 1 mol C3H8 4 mol H2O = 7.25 mol C3H8 4 Al + 3 O2 2 Al2O3 4 mol Al: 3 mol O2 4 mol Al: 2 mol Al2O3 3 mol O2: 2 mol Al2O3 1 mol Al2O3 4 mol Al 2 mol Al2O3 = 2 mol Al Complete practice problems 2-4.
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