S1 TITAN 600-800
Restricted Materials Calibration (P/N: 730.0091)
Al
LDPlastics
LOD in mg/Kg In Low Density Plastics (PE/ABS)
Min LOD (ppm) 2929.9
Average LOD (ppm) 3700.9
Cl
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
Br
Cd
Sn
Sb
Ba
29.3
19.8
5.3
0.3
1.8
10.1
6.2
2.5
3.0
2.0
0.1
0.3
0.4
8.3
13.6
10.9
135.5
41.1
24.8
9.2
0.5
2.3
18.4
9.9
4.4
5.7
3.1
0.8
1.3
0.9
9.8
21.3
17.6
254.8
Ca
Ti
Cr
Fe
Cu
Zn
As
Se
Br
Cd
Sb
Ba
Hg
Pb
Hg
LDPlastics (Continued)
LOD in mg/Kg In Low Density Plastics (PE/ABS)
Min LOD (ppm) 0.7
Pb
Average LOD (ppm) 1.7
2.3
HDPlastics
LOD in mg/Kg In High Density Plastics (PVC)
Al
Cl
Min LOD (ppm)
3897.7
47.3
4.7
7.5
3.2
12.3
5.0
2.6
1.6
1.0
1.1
6.5
1.2
72.1
3.5
4.0
Average LOD (ppm)
4960.1
74.5
22.2
18.1
11.7
25.8
11.2 5.9
3.1
2.2
2.6
11.8
1.9
109.3
8.0
9.9
Al
MidDensity
LOD in mg/Kg In Mid Density(Soil, Powders, Al, Glass,
Ceramics)
Si
Cl
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Br
Sr
Zr
Nb
611.8
204.3
39.0
14.1
13.6
9.9
11.4
33.8
20.3
10.8
8.2
5.8
2.8
1.8
2.0
1.0
1.8
1.6
2761.7
398.4
70.2
32.8
28.1
19.5
22.1
76.2
47.1
31.1
25.2
19.1
19.6
12.8
15.8
5.7
9.7
6.8
Pd
Ag
Cd
Sn
Sb
Ba
Hf
Ta
W
Pt
Au
Hg
Pb
Bi
Min LOD (ppm) 2.3
17.3
30.5
8.9
11.2
14.5
58.4
20.4
13.8
28.3
7.6
39.7
5.0
4.5
4.9
Average LOD (ppm) 8.1
71.5
79.1
28.9
37.8
43.6
144.3
89.3
59.8
124.6
35.4
278.1
28.3
30.8
31.0
Si
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Br
Zr
Nb
Mo
Rh
Pd
821.3
2393.7
37.8
72.6
43.2
79.3
25.4
50.0
55.2
185.8
63.2
174.0
45.4
103.2
12.0
89.6
7.0
66.6
9.0
57.8
1.0
60.2
6.5
24.3
4.7
37.2
4.0
14.1
4.6
15.4
5.8
17.6
13.6
33.3
16.5
38.5
Cd
Sn
Sb
Ta
W
Pt
Au
Hg
Pb
Bi
1.1
33.1
32.1
100.7
36.9
103.3
49.8
172.1
53.1
165.7
41.7
112.1
193.5
1030.2
18.4
67.8
1.0
64.4
10.6
44.1
Min LOD (ppm) 2174.2
Average LOD (ppm) 11326.9
Mo
MidDensity (Continued)
LOD in mg/Kg In Mid Density(Soil, Powders, Al, Glass,
Ceramics)
RAlloys
LOD in mg/Kg In Alloys
Al
Min LOD (ppm) 1307.9
Average LOD (ppm) 6683.2
RAlloys (Continued)
LOD in mg/Kg In Alloys
1.2
Ag
Min LOD (ppm) 12.4
Average LOD (ppm) 32.6
*NOTE: Not a true LOD. It is an artificial threshold designed to prevent false positives, below which the calibration won't report a value.
Limit of Detection (LOD) is the smallest concentration which can be detected.
In this document LOD is specified for various matrices in three sigma 99.7% confidence level and 180 second analysis time per phase (dual phase calibration). Individual elemental LOD's improve as a
function of the square root of the analysis time.
Detection limits are specified for real samples in close to ideal conditions where only few elements are present in a sample. For samples which contain significant amount of other overlapping elements,
LOD for specific element can be significantly higher than reported.
Limit of Detection is dependent on several factors, such as: Matrix Interferences, Overlapping elements, Level of statistical confidence and Testing time.
Bruker Elemental - April 24, 2014
S1 TITAN 600-800 Restricted Materials Calibration
P/N: 730.0091
H
He
Li Be
Na Mg
B C N O
Al Si P
F Ne
S Cl Ar
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Fr Ra Ac
Phase 1: 50 kV
Phase 2: 15 kV
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
Th Pa U N p Pu Am Cm Bk Cf Es Fm Md No Lr