Name: _________________________________________________________ date: __________ hr: ____________ 2016-2017 CHEMISTRY LAB- Periodic Trends- CH 05 Introduction: The structure of the periodic table is such that elements with similar properties are aligned vertically in columns called “groups or families”. This leads to smoothly varying trends in properties such as ionization energy, electronegativity, and atomic radii as one moves both down a specific group and horizontally along a given period. The reactivity of the elements also follows well-defined trends both within groups and across periods. In this miniexperiment, you will explore a few trends in reactivity. Elements in the periodic table are organized by increasing atomic number. As atomic numbers increase, so does the number the electrons. Electrons, and specifically valence electrons, are important in determining how an atom interacts with other atoms. The elements in a group have similar properties because they have the same number of valence electrons, which are found in similar electron configurations. Part 1: Trends in the Properties within Groups Watch the video on the “Alkali Metals in Water, Accurate!”(2:21 min) http://www.youtube.com/watch?v=uixxJtJPVXk 1. Name all the elements that are Alkali Metals:__________________________________________________________________ 2. How many valence electrons do the Alkali metals have?_________________________________________________________ 3. State the trend in reactivity for the alkali metals as you go down the group._________________________________________ 4. What energy level are the valence electrons found on in the element Lithium?______________________________________ 5. What energy level are the valence electrons found on in Potassium?_______________________________________________ 6. What energy level are the valence electrons found on in Cesium?_________________________________________________ 7. Using the information from #4-#6, EXPLAIN the group trend in reactivity of the Alkali Metals. ________________________________________________________________________________________________________ Group II, Alkaline Earth Metals (4:57 min) https://www.youtube.com/watch?v=T7K4Qi5PiFg 1. Which elements are considered to be Alkaline Earth Metals? ____________________________________________________ 2. How many valence electrons do these elements have?__________________________________________________________ 3. Name 2 physical properties of these elements ________________________________________________________________ 4. Name 1 chemical property of these elements._________________________________________________________________ 5. What do they mean when they say these elements are very “electro-positive”?_____________________________________ 6. How do they compare to the Alkali Metals in hardness, strength, and density?_____________________________________ 7. Access this website and explain the general period and group trend for reactivity in metals and non-metals: http://edtech2.boisestate.edu/lindabennett1/502/periodic%20table%20e%20config/PTable_trends%20aroun d%20table.html Part 2: Complete the chart below, then continue on to the procedure portion of the lab. Metals Long hand electron configuration for the neutral atom of the element Lewis Dot diagram Write the symbol of the ion. Long-hand electron configuration for the ION of the element What element is it isoelectronic to? Mg Al Cu Zn Part 3 (day 1) Materials Goggles Electronic balance 10 mL graduated cylinder Triangular file two 50-150 mL beakers forceps plastic pipette paper towel one post and one pre 1982 penny 1.0 M Hydrochloric Acid weighing paper 1. Copper and Zinc are both key components in the composition of pennies made after 1982. Pennies that were made before 1982 are composed primarily of copper. Pennies made after 1982 are composed primarily of Zinc. 2. Obtain two 50 mL, 100 mL, or 150 mL beakers. Place your name and your partners name on each beaker using a pencil. If you need a sticky label to write you name on let your instructor know. Label on beaker PRE and the other POST. 3. Obtain two pennies; one pre 1982 and one post 1982. 4. Record two physical properties of each penny in the table below. 5. Doing this step over a paper towel: file a notch in four sides of each penny. 6. Mass out each penny and record the mass in the table below. 7. Place each penny in the proper beaker. 8. Using a plastic pipette and graduated cylinder place 10.0 mL of hydrochloric acid into each beaker. 9. Place the beakers on the tray in the chemical hood to be saved overnight. Pennies Observations- before placing in HCL Mass before placing in HCl(g) Mass after placing in HCl (g) Observations after placing in Hydrochloric Acid-immediate and over night Pre 1982 Post 1982 10. What sign of a chemical change did you witness when you placed the pennies in each beaker of HCl? Which penny produced the larger reaction? (you may need to wait 2-3 minutes) Part 4 (Day 2) Materials Goggles Electronic balance weighing paper one 50-150 mL beaker forceps paper towel 11. Using a pair of forceps, place each penny in a beaker of tap water to rinse them off. Now, place each penny on a piece of paper towel. With a different paper towel pat dry each penny (be sure to wash your hands!) 12. Make 1-2 observations for each penny and record in the table found in Part 3. 13. Using a piece of weighing paper mass out each penny and record in the data table found in Part 3. 12. After seeing these results, is copper or zinc more reactive with Hydrochloric Acid? __________________________________ 13. Page 161: Define electronegativity: 14. Hydrochloric Acid is a molecule consisting of Hydrogen and Chlorine. Which element is the most electronegative?(pg 161) 15. Draw Lewis dot diagram for Hydrogen. __________________Draw Lewis dot diagram for Chlorine. ________________ Part 5 Materials: Goggles Four medium sized test tubes Test tube rack 1. 2. 3. 4. 5. Metals: Mg, Al, Cu, Zn 1.0M Hydrochloric Acid Plastic pipette Forceps Sand paper Obtain, all materials except the hydrochloric acid. Now obtain ONE piece of each metal in the data table below. Record two physical properties of each metal and place in the first column of the chart. Sand down each piece of metal, the best you are able. Do this over a piece of paper towel. Place each metal in a large test tube separate from one another. NOW pick up the HCl. Using a plastic pipette add just enough Hydrochloric Acid (HCl) to cover the piece of metal. Let sit for approximately 3-5 minutes then record your observations, be sure to feel the bottom each test tube. Metals Observations before adding HCl Immediate observations and after 3-5 minutes in HCl Rank from most to least reactive in HCl( 1 being least, 4 being most) Mg Al Cu Zn 8. Comparing the elements in period three, Aluminum and Magnesium. Which was most reactive with the HCl? WHY do you think one was more reactive than the other? Explain. 9. Comparing the elements in period four, Copper and Zinc. Which was most reactive with the HCl? 10. Do your results in #9 correspond to your results in PART 3 of the experiment? 11. Circle the atom with the larger atomic radius: Magnesium/Aluminum 12. Circle the atom with the smaller atomic radius: Copper/Zinc 13. What is the effective nuclear charge felt on the last energy level of a Magnesium atom? 14. What is the effective nuclear charge felt on the last energy level of an Aluminum atom? http://www.xtremepapers.com/revision/gcse/chemistry/metals.php Use this website to help answer the questions below. 15. Reactivity of a metal is determined by what? 16. According to the “activity series” is copper or zinc more reactive? 17. Scroll down and look at the chart of data from the same reactions that you and your partner observed. Are your results the same as the data listed on this chart? 18. How many valence electrons does Zinc have? How many valence electrons does Copper have? Where is Zinc on the activity series verses copper? 19. Search the internet…………….. please include the website you use! If Zinc has more valence electrons than Copper, then why is Zinc more reactive than copper in hydrochloric acid?
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