Calderglen High Higher Chemistry Homework Chemical Changes & Structure - Bonding in Compounds 1. (a) Which type of bonding exists in (i) silicon dioxide (ii) sulphur dioxide (b) (i) Use the data booklet to find the boiling points of these two compounds. silicon dioxide and sulfur dioxide (ii) Explain why the boiling points are so different. 2. Copy and complete the table below: Note:- Under type of bonding mention both intermolecular and intramolecular, where appropriate. Compound Type of bonding Structure SiO2 CCl4 LiCl 3. 4. Which type of bonding is never found in elements? A Metallic B London dispersion forces C Polar covalent Which of the following chlorides is likely to have least ionic character? A BeCl2 5. B CaCl2 C LiCl D CsCl Atoms of nitrogen and element X form a bond in which the electrons are shared equally. Element X could be A carbon 6. D Non-polar covalent B oxygen C chlorine D phosphorus. Which of the following structures is never found in compounds? A Ionic B Monatomic C Covalent network D Covalent molecular Calderglen High Higher Chemistry Homework Chemical Changes & Structure - Bonding in Compounds 7. Liquid hydrogen sulphide has a boiling point of −60 ºC. Explain clearly why hydrogen sulphide is a gas at room temperature. In your answer, you should name the intermolecular forces involved and indicate how they arise. 8. Which line in the table represents the solid in which only van der Waals’ forces are overcome when the substance melts? 9. Hydrogen will form a non-polar covalent bond with an element which has an electronegativity value of A 0·9 10. B 1·5 C 2·2 Which property of a chloride would prove that it contained ionic bonding? A It conducts electricity when molten. C It is a solid at room temperature. 11. D 2·5. B It is soluble in a polar solvent. D It has a high boiling point. A student writes the following two statements. Both are incorrect. In each case explain the mistake in the student’s reasoning. (a) All ionic compounds are solids at room temperature. Many covalent compounds are gases at room temperature. This proves that ionic bonds are stronger than covalent bonds. (b) The formula for magnesium chloride is MgCl2 because, in solid magnesium chloride, each magnesium ion is bonded to two chloride ions. Calderglen High Higher Chemistry Homework Chemical Changes & Structure - Bonding in Compounds 12. Triethanol amine and triisopropyl amine are bases used to neutralise acidic compounds in the hairspray to prevent damage to the hair. molecular mass 149 boiling point 335 °C molecular mass 143 boiling point 47 °C In terms of the intermolecular bonding present, explain clearly why triethanol amine has a much higher boiling point than triisopropyl amine. 13. When two atoms form a non-polar covalent bond, the two atoms must have A the same atomic size C the same ionisation energy 14. B the same electronegativity D the same number of outer electrons Which line in the table shows the correct entries for tetrafluoroethene? Calderglen High Higher Chemistry Homework Chemical Changes & Structure - Bonding in Compounds 15. In which of the following compounds would hydrogen bonding not occur? 16. Which of the following shows the types of bonding in decreasing order of strength? A B C D 17. Covalent : hydrogen : London dispersion forces Covalent : London dispersion forces: hydrogen Hydrogen : covalent : London dispersion forces London dispersion forces: hydrogen : covalent Some covalent compounds are made up of molecules that contain polar bonds but the molecules are overall non-polar. Which of the following covalent compounds is made up of non-polar molecules? A Ammonia 18. D Hydrogen fluoride B Caesium chloride C Calcium chloride D Phosphorus chloride Which of the following compounds exists as discrete molecules? A Sulfur dioxide 20. C Carbon tetrachloride Which of the following chlorides is most likely to be soluble in tetrachloromethane, CCl4? A Barium chloride 19. B Water B Silicon dioxide C Aluminium oxide D Iron(II) oxide Which of the following chlorides is likely to have least ionic character? A BeCl2 B CaCl2 C LiCl D CsCl
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