Chemistry 111 Sect. 2 Exam #1 February 28, 2002 Name: ________________________________________________ Student #: ______________________________________________ Please put your name and student number on all pages in case they become separated. The last page of the exam has some useful information. The exam lasts 60 minutes. There are a total of 100 points. MULTIPLE CHOICE QUESTIONS Place an X in the box corresponding to the correct answer. 1. (5 pts) The formula for cobalt (III) nitrate is: Co(NO2)3 Co3(NO2)2 CoNO3 Co(NO3)3 Co3(NO3)2 2. (5 pts) An ion with the symbol 23592U3+ is correctly described by which of the following? (protons, neutrons, electrons) 92, 235, 92 92, 143, 89 92, 143, 95 143, 92, 235 235, 65, 143 3. (5 pts) A series of measured lengths is added together as shown. The correct value to report is: 10.11111 cm + 1.02 cm + 100.00001 cm + 0.04000 cm = 111.17112 cm 111.17112 cm 111.1711 cm 111.171 cm 111.17 cm 111.2 cm Page 1 Chemistry 111 Sect. 2 Exam #1 February 28, 2002 Name: ________________________________________________ Student #: ______________________________________________ 4. (5 pts) A photon of light strikes a hydrogen atom and causes the electron in the atom to transition from level n=2 to level n=4. What is the energy of the photon? -4.1×10-19 J -1.4×10-19 J 1.4×10-19 J 4.1×10-19 J 2.2×10-18 J 5. (5 pts) A compound of boron and hydrogen is 81.1% boron by weight. What is the empirical formula of the compound? BH3 BH5 BH10 B2H5 B2H10 6. (5 pts) A reaction between nitrogen and water produces two products. The balanced chemical equation for the reaction is shown below with one of the products left blank. What is the missing product? 2 N2 + 6 H2O → 4 _____ + 3 O2 H2 NO NH6 NH3 N2H4 Page 2 Chemistry 111 Sect. 2 Exam #1 February 28, 2002 Name: ________________________________________________ Student #: ______________________________________________ 7. (5 pts) Which has the longer wavelength, an electron moving with a speed of 2 × 106 m/sec or a neutron moving at the same speed? Note: me = 9.1 × 10-28 g, mn = 1.7 × 10-24 g. the electron has longer wavelength the neutron has longer wavelength they have the same wavelength neither has a wavelength can’t tell from the information given 8. (5 pts) The element in group 5A, period 3 is: indium nitrogen phosphorus potassium scandium MULTIPLE MULTIPLE CHOICE QUESTIONS Place an X in the boxes corresponding to the correct answers. Any number of answers may be correct, including none of them. 9. (10 pts) Consider the properties of electromagnetic radiation: energy (E), frequency (ν) and wavelength (λ). Which of the following ways to plot will give a linear graph? λ vs. ν E vs. ν E vs. λ λ vs. 1/ν E vs. 1/ν Page 3 Chemistry 111 Sect. 2 Exam #1 February 28, 2002 Name: ________________________________________________ Student #: ______________________________________________ 10. (10 pts) Which of the following is not a metal? argon chlorine silicon sodium sulfur 11. (10 pts) Which of the following are TRUE? 1/2 mole of Cl2 contains 3.0 × 1023 atoms of chlorine the density of hydrogen gas at room temperature and atmospheric pressure is less than that of air cations always carry negative net electric charge 50 °C is a lower temperature than 50 K the radius of the lowest energy Bohr orbital in hydrogen is 2.3 nm SHORT ANSWER QUESTIONS Answer in the spaces indicated. 12. (10 pts) What is the name of the alkali metal that is in period 7? __________________________ What is the name of the halogen that is in period 4? _____________________________ What is the name of the alkaline earth metal that is in period 4? ___________________ What is the name of the noble gas that is in period 1? ___________________________ What is the name of the anion ClO-? _________________________________________ Page 4 Chemistry 111 Sect. 2 Name: ________________________________________________ Exam #1 Student #: ______________________________________________ February 28, 2002 13. (10 pts) As we saw in class, aluminum reacts with bromine to produce solid aluminum bromide. If 2.7 g of Al foil is placed in an excess volume of Br2, how many grams of aluminum bromide will be formed? 2 Al(s) + 3 Br2(l) → Al2Br6(s) 14. (10 pts) You weigh a lump of metal and find its mass to be 340.00 grams. The metal lump, when dropped in a beaker completely full of water, displaces 1.7 mL of water. What is the density of the metal? (Report your answer to the correct number of significant figures and include units.) Page 5 Chemistry 111 Sect. 2 Exam #1 February 28, 2002 Name: ________________________________________________ Student #: ______________________________________________ Useful information NA = 6.02 × 1023 molecules/mol d = m/V c = 3.0 × 108 m/sec E = -Rhc/n2 h = 6.6 × 10-34 J sec Rhc = 2.2 × 10-18 J me = 9.1 × 10-28 g a0 = 0.0529 nm E = hν c = λν λ = h/(m v) PERIODIC TABLE OF THE ELEMENTS IA IIA IIIB IVB VB VIB VIIB VIIIB IB IIB IIIA IVA VA VIA VIIA VIIIA 1 2 H He 1.008 4.003 3 4 5 Li Be B C N O F Ne 6.939 9.012 10.81 12.01 14.01 16.00 19.00 20.18 11 12 13 14 15 16 17 18 Na Mg Al Si P S Cl Ar 22.99 24.31 26.98 28.09 30.97 32.07 35.45 39.95 19 20 21 22 K Ca Sc Ti 39.10 40.08 44.96 37 38 39 Rb Sr 85.47 55 23 6 7 8 9 10 24 25 26 27 28 29 30 31 32 33 34 35 36 V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 47.90 50.94 52.00 54.94 55.85 58.93 58.71 63.55 65.39 69.72 72.61 74.92 78.96 79.90 83.80 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te 87.62 88.91 91.22 92.91 95.94 (99) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn 132.9 137.3 138.9 178.5 181.0 183.8 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0 (209) (210) (222) 87 88 89 Fr Ra Ac (223) 226.0 227.0 Page 6 I Xe
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