In Situ Charging Potential Monitoring for a High Current Ribbon Beam Svetlana Radovanov, Reuel Liebert, Phil Corey, James Cummings, Gordon Angel and James Buff Varian Semiconductor Equipment 35 Dory Road Gloucester, MA 01930-2297 USA Abstract - We discuss measurements and modeling associated with the high current ion beam space charge neutralization. We show the importance of the electron temperature in maintaining low beam potential and induced voltage on implanted wafers. configurations (Configuration A and Configuration B) to optimize the electron energy and net electron emission current. A twelve channel multi-pixel scanning Faraday system was used to measure the width (X), height (Y), and current density (Z) of the beam. This system incorporates a high speed X-scan actuator for the multi-pixel Faraday that traverses the ion beam at constant velocity. In a production machine the collected data are processed by the control system for automated ion beam profile optimization. For this paper, the scanning Faraday system was used to obtain both ion beam and plasma flood gun net flux distributions. For measuring the plasma flood gun ion energy distribution (IED) an electrostatic retarding field energy analyzer (REA) was mounted in the process chamber along the diffusion axis of the PFG plasma emerging from an aperture. The analyzer consisted of three parallel grids and a collector. The first grid facing the plasma was grounded, the second was used to repel electrons and the third was swept from zero or some slightly negative value to 20 V. The collector was maintained at constant potential of –30 V. The ions were decelerated by the positive potential; the collector current was measured as a function of the retarding voltage. I. INTRODUCTION Neutralization of the ion beam space charge in a high current ion implanter is necessary both to optimize beam transport and to control the positive charge build up on the surface of the implanted wafer. Electrons formed by ionizing collisions between the beam and the background gas are insufficient to achieve this. In order to fully compensate, further electrons must be introduced into the beam. This is most efficiently accomplished by a plasma flood gun in which low energy electrons produced in a controlled discharge are transported to the positively charged ion beam via a plasma plume bridge [1-4]. The low energy electrons formed in the discharge are captured by the potential well of the beam and their accumulation reduces its magnitude until a stationary degree of space charge compensation is reached. The net flux and energy of electrons emerging from the plasma flood gun aperture, and the ion beam potential and charge distribution are of fundamental importance in determining the efficiency of the charge neutralization. This paper presents the results of measurements of ion beam parameters, surface charging potentials, net beam flux distributions, electron temperatures, and electron and ion energy distributions, introduced into the beam from a plasma flood gun (PFG) developed here at Varian. Particle–in-cell simulations with the addition of Monte Carlo collisions (2D XOOPIC-MCC) were used to model charging effects during ion implantation [5,6]. A 2D model of plasma interaction with a high current ion beam was developed. The simulated results include beam potential distributions, accumulated charge densities and induced electric fields at the wafer plane. Beam potential distributions were compared with experimental surface charging potential measurements. II. EXPERIMENTAL The design and configuration of the VIISta 80 Ion Implanter has been described extensively in previous publications [7,8]. The physical arrangement of the flood gun system is shown schematically in Fig.1. A plasma flood gun uses a magnetic field to confine the discharge and in these experiments we investigated the efficiency of two field Fig. 1 PFG Physical arrangement on VIISta 80 1 An axially moveable cylindrical Langmuir probe was used to estimate the temperature and energy distribution function (EEDF) of the plasma flood gun electrons The electron number density could then be estimated using the thick sheath approximation. The second derivative of the I-V characteristic was related to the EEDF as defined by the Druyvesteyn distribution [9]. All measurements reported here used a 60 keV, 10 mA, As+ beam and a suppression voltage of -1 kV to keep R from escaping the wafer region. electrons Lang II. MODELING Fig. 2b. Phase space diagram for electrons as obtained by the 2D particle in cell code XOOPIC The two-dimensional particle-in-cell (PIC) code XOOPIC-MCC was used to solve for the ions and electrons and fields in a self-consistent manner. A Monte Carlo approach was used to model electron-neutral collisions. A 60 keV, 10 mA arsenic beam was assumed to be directed to a insulating wafer with floating potential. The process chamber wall and the plasma flood gun were grounded. The suppression electrode was set to –1 kV. Plasma densities and temperatures were initialized in accordance with experimental data. An ambient gas of 10-5 Torr was assumed. Electrons and Xenon ions were injected at the PFG location. III. In order to evaluate the PFG net current density distribution, the net flux of the plasma flood gun with and without a 60 keV, 10 mA, As+ beam was measured using the multi-pixel Scanning Faraday, as shown on Fig. 3a and 3b. As can be seen, much higher current densities were measured with the beam then with the PFG only. The apparent net flux non-uniformity exists because there is a gradient of current density inside the beam. Separate regions of higher current density are visible on the right hand side of the beam. Figure 4a shows the spatial variation of the wafer surface potential measurement taken during beam scanning (PFG configuration A), using the test monitor wafer [10]. A higher potential is seen at the left side of the wafer (corresponding to the right side of the beam profile shown in Fig. 3a) agreeing well with the net flux distribution (See Fig. 3). As the current density increases a potential barrier (sheath) forms. This barrier inhibits the flow of electrons to the wafer, thus building the wafer surface charge. A higher flux of low energy electrons would significantly reduce this effect. Extremely low surface charging potentials were measured (See Fig. 4b) using the same beam with the PFG in configuration (B) which produced significantly higher flux of low energy electrons. RESULTS AND DISCUSSION The calculated potential distribution after the code had run long enough for initial transients to decay is shown in Fig. 2a. The spatial distribution of electrons is shown in Fig. 2b. There is a region of no electrons near the suppression electrode. There is some variation about the mean value due to the statistical nature of the PIC approach. 50 40 30 20 10 0 -10 -20 -30 -40 -50 -200 -150 -100 -50 0 50 100 150 200 Beam Width - mm a . 50 40 30 20 10 0 -10 -20 -30 -40 -50 -200 500 -150 450 400 -100 350 300 -50 250 0 200 150 50 100 100 50 -1 150 200 Beam Width - mm b . 0.0 -15.0 -30.0 -45.0 -60.0 -75.0 -90.0 Fig. 3. Net flux distribution (µA/cm2) -As+, 60 keV, 10 mA (a) with the beam (b) PFG Only Fig. 2a. Calculated beam potential distribution-As+, 60 keV, 10 mA obtained by the 2D particle in cell code XOOPIC 2 0.08 20 4.00E-05 dI/dV (Volts/cm2/Ampers) 0.07 Wafer Floating Potential (V) 15 Left Side of the wafer 10 Right Side of the wafer 5 0 3.50E-05 0.06 0.05 3.00E-05 0.04 2.50E-05 0.03 0.02 2.00E-05 0.01 -5 5.00 0.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 1.50E-05 -10 10.00 -8 -6 -4 Scan Position (cm) Scan is in the wafer center 15 dI/dV(Volts/cm 2/Ampers) Wafer Surface Potential (V) 2 4 6 8 10 Fig. 5a. Measured ion energy distribution (IED) for the PFG configuration A. 20 10 Left Side of the Wafer 0 Ion Energy (eV) Fig.4a. Wafer surface potential- As+, 60keV, 10 mA single scan (PFG configuration A). Right Side of the Wafer 5 -2 0.08 5.00E-05 0.07 4.50E-05 0.06 4.00E-05 0.05 3.50E-05 0.04 3.00E-05 0.03 2.50E-05 0.02 2.00E-05 0.01 1.50E-05 0 0.00 -5 0 0.02 0.04 0.06 0.08 0.1 Time (s) 0.12 0.14 0.16 1.00E-05 -10 0.18 -8 -6 -4 -2 0 2 4 6 8 10 Ion Energy (eV) Fig.4b. Wafer surface potential- As+, 60keV, 10 mA stationary scan (PFG configuration B). Fig 5b. Measured ion energy distribution (IED) for the PFG configuration B. Retarding potential measurements were used to determine the PFG ion energy distribution. Fig. 5 shows that plasma flood gun IED has a Maxwellian-like distribution and a very low average energy. Examples of the IEDs for PFG configurations (A) and (B) are given in Fig.5a and 5b. Both distributions have a similar shape and confirm the existence of low energy ions along the diffusion axis of the PFG plume. The EEDF of the plasma flood gun electrons, as measured by the cylindrical Langmuir probe in PFG configurations (A) and (B), are shown in Fig. 6. PFG configuration (A) produced an EEDF with an extended tail and very broad bulk electron distribution. The energy loss caused by wall recombination is very low in configuration (A). In this configuration, it is possible for primary electrons from the plasma flood to reach the wafer surface with the possibility of causing negative charging damage. 1 F(e) (a.u.) 10-1 10-2 -3 10 0 5 10 Electron Energy (eV) 15 20 Fig. 6a. Measured electron energy distribution (EEDF) for the PFG in a configuration A. 3 in VIISta 80. The simulations are in good agreement with experiment. . New real time charge monitoring devices are necessary to optimize the charge control systems for the high current ribbon beam technology. We have recently developed a test wafer prepared with 2D array of probes. Each probe can monitor floating potential, electron energy and current density associated with spatially large ion beams and plasmas. This test wafer requires no hard wiring and can be loaded using the standard wafer handling subsystem of the VIISta 80. Local charge non-uniformity can be evaluated in situ using the test wafer, without impacting the throughput of the single wafer high current implanter. 1 F(e) (a.u.) 10-1 10-2 10-3 0 5 10 Electron Energy (eV) 15 20 ACKNOWLEDGMENT Fig. 6b. Measured electron energy distribution (EEDF) for the PFG in a configuration B. We would like to thank G. Unger for constructing the equipment and for his help in acquiring the data. REFERENCES 1.4 Electron Temperature (eV) 1.2 [1] M.F. Mack, M. Pharand, M.S. Ameen, M. Graf, W. Sawyer, P. Lustiber, D. Fish, B.G. Moser, M. Kabasawa, K. Okada, H. Kawaguchi, P. Mason, E. Persson and R. Santiesteban, “Optimized Charge Control for High Current ion Implantation”, IIT’98, June 1998. [2] M.I. Current, M.C. Vella and W. Lukaszek, “ Beamplasma Concepts for Wafer Charging Control During Ion Implantation, IIT’96, June 1996. [3] H. Ito, H. Asechi, Y. Matsunaga, M. Niwayama, K. Yoneda, M. Vella, M. Reilly and W. Hacker,” High Density Plasma Flood System for Wafer Charge Neutralisation”, IIT’98, June 1998. [4] I.A. Soloshenko, “ Space Charge Compensation of Technological Ion Beams”, IEEE Transactions on Plasma Science, Vol. 27, No.4, pp. 1097 (1999). [5] J.P.Verboncoeur, A.B. Langdon and N.T. Gladd, Comp.Phys.Comm 87, May 1995. [6] C.K. Birdsall, “Particle-in-Cell Charged-Particle Simulations, Plus Monte Carlo Collisions With Neutral Atoms, PIC-MCC”, IEEE Transactions on Plasma Science, Vol. 19, N0.2,, pp. 65 (1991). [7] G.Angel, E.Bell, D.Brown, J.Buff, J.Cummings, W.Edwards, C.McKenna, S.Radovanov and N.White, “A Novel beam Line for Sub-keV Implants with reduced Energy Contamination”, IIT’98, June 1998. [8] G.Angel, E.Bell, D.Brown, J.Buff, M. Collins, J.Cummings, W.Edwards, S.Radovanov and N.White “ Enhanced Low Energy Drift-mode Beam Currents in a High Current Ion Implanter, IIT’98, June 1998. [9] F.F. Chen, Plasma diagnostic Techniques (Academic, New York, 1965, pp105. [10] S.B. Radovanov, P. Corey, G. Angel and D. Brown, “Wafer Floating Potential for a High Current serial ion Implantation System”, IIT’98, June, 1998. 1 U-shaped filament 0.8 Xe @0.6 sccm 0.6 0.4 0.2 Hair-pin filament 0 0 1 2 3 4 5 6 7 Arc Current (A) Fig 7. Electron temperatures measured using Langmuir Probe for different arc currents (PFG configuration B) In configuration B however, the EEDF is Maxwellian and is peaked below 1eV, as shown in Fig 6b. This low temperature is maintained for the full range of arc currents, as shown in Fig 7. Fig. 4b also shows that this field configuration produces sufficient electron flux to maintain low surface potentials on implanted wafers. Clearly this is the configuration that would be chosen to eliminate the danger of device damage from either positive or negative wafer charging. IV. CONCLUDING REMARKS In critical applications, such as charge control with very thin gate oxide and inter-poly thicknesses, the plasma flood gun system must meet new requirements to achieve uniform charge distribution and avoid local charging at the wafer surface. 2D XOOPIC-MCC simulation has provided a powerful tool in the optimization of the plasma flood gun systems used 4
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