Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013 1. IDENTIFICATION Product Name Lead Oxide Grey Other Names Mixture - All components listed on AICS Uses Use of lead metal in lead oxide production under industrial conditions Use of lead oxides in lead stabiliser production under industrial conditions Use of lead oxides in lead acid battery production Use of lead oxides in crystal glass production Use of lead oxides in production of ceramic ware Use of lead oxides in rubber production Use of lead oxides in explosive manufacture Professional use of adsorbents Professional use of paints and pigments Professional use of lead oxides as laboratory agents and in chemical analysis Chemical Family No Data Available Chemical Formula PbO + Pb Chemical Name Lead Oxide Grey Product Description Lead monoxide with high content in lead metal. Contact Details of the Supplier of this Safety Data Sheet Organisation Location Telephone Redox Pty Ltd 2 Swettenham Road Minto NSW 2566 Australia +61-2-97333000 Redox Pty Ltd 11 Mayo Road Wiri Auckland 2104 New Zealand +64-9-2506222 Redox Inc. 2132A E. Dominguez Street Carson CA 90810 USA +1-424-675-3200 Redox Chemicals Sdn Bhd Level 2, No. 8, Jalan Sapir 33/7 Seksyen 33, Shah Alam Premier Industrial Park 40400 Shah Alam Sengalor, Malaysia +60-3-5614-2111 Emergency Contact Details For emergencies only; DO NOT contact these companies for general product advice. Organisation Location Telephone Poisons Information Centre Westmead NSW 1800-251525 131126 Chemcall Australia 1800-127406 +64-4-9179888 Chemcall Malaysia +64-4-9179888 Chemcall New Zealand 0800-243622 +64-4-9179888 National Poisons Centre New Zealand 0800-764766 CHEMTREC USA & Canada 1-800-424-9300 CN723420 +1-703-527-3887 2. HAZARD IDENTIFICATION Redox Pty Ltd Corporate Office Sydney Locked Bag 15 Minto NSW 2566 Australia 2 Swettenham Road Minto NSW 2566 Australia All Deliveries: 4 Holmes Road Minto NSW 2566 Australia Form 21047, Revision 3, Page 1 of 11, 15-Jun-2017 02:12:17 Phone Fax E-mail Web ABN +61 2 9733 3000 +61 2 9733 3111 [email protected] www.redox.com 92 000 762 345 Australia Adelaide Brisbane Melbourne Perth Sydney New Zealand Auckland Christchurch Hawke’s Bay Malaysia Kuala Lumpur USA Los Angeles Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013 Poisons Schedule (Aust) 6 Globally Harmonised System Hazard Classification Hazardous according to the criteria of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS) Hazard Categories Carcinogenicity - Category 2 Germ Cell Mutagenicity - Category 2 Specific Target Organ Toxicity (Repeated Exposure) - Category 2 Toxic To Reproduction - Category 1A Pictograms Signal Word Danger Hazard Statements H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H360fD May damage the unborn child. Suspected of damaging fertility. H373 May cause damage to organs through prolonged or repeated exposure. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe fume/gas/mist/vapours/spray. P281 Use personal protective equipment as required. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P314 Get medical advice/attention if you feel unwell. Storage P405 Store locked up. Disposal P501 Dispose of contents/container in accordance with local / regional / national / international regulations. Precautionary Statements Prevention Response National Transport Commission (Australia) Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code) Dangerous Goods Classification Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code) Environmental Protection Authority (New Zealand) Hazardous Substances and New Organisms Amendment Act 2015 HSNO Classifications Health Hazards Form 21047, Revision 3, Page 2 of 11, 15-Jun-2017 02:12:17 6.1C Substances that are acutely toxic- Toxic 6.6B Substances that are suspected human mutagens 6.7B Substances that are suspected human carcinogens 6.8A Substances that are known or presumed human reproductive or developmental toxicants 6.8C Substances that produce toxic human reproductive or developmental effects on or via lactation 6.9A Substances that are toxic to human target organs or systems 6.9B Substances that are harmful to human target organs or systems Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013 Environmental Hazards 9.1A Substances that are very ecotoxic in the aquatic environment 9.3B Substances that are ecotoxic to terrestrial vertebrates 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients Chemical Entity Formula CAS Number Proportion Lead monoxide (PbO) No Data Available 1317-36-8 72.00 - 82.00 % Metal Lead Powdered (Pb) No Data Available 7439-92-1 18.00 - 28.00 % 4. FIRST AID MEASURES Description of necessary measures according to routes of exposure Swallowed Rinse mouth with water. Seek medical attention. Eye Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. Take care not to rinse contaminated water into the non-affected eye. Seek medical attention. Skin Remove contaminated clothing. Wash affected area with plenty of Soap and water for at least 15 minutes. Seek medical attention if irritation develops or persists. Wash clothing before reuse. Inhaled Remove victim from exposure to fresh air. Wash lips and nose. In case of irritation of respiratory ways, mucous membrane or indisposition, consult a physician. Advice to Doctor Treat symptomatically based on judgement of doctor and individual reactions of patient. Medical Conditions Aggravated by Exposure Toxic for Reproduction Category 1: May cause harm to the unborn child. 5. FIRE FIGHTING MEASURES General Measures Clear fire area of all non-emergency personnel. Stay upwind. Keep out of low areas. Eliminate ignition sources. Move fire exposed containers from fire area if it can be done without risk. Avoid the inhalation of toxic fumes. Flammability Conditions Product is a non-flammable solid. Extinguishing Media In case of fire, use appropriate extinguishing media most suitable for surrounding fire conditions. Do NOT use halogen products and water spurt. Hazardous Products of Combustion No Data Available Special Fire Fighting Instructions HAZCHEM: 2Z Do NOT allow fire fighting water to reach waterways, drains or sewers. Store fire fighting water for treatment. Personal Protective Equipment Fire fighters should wear a positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots and gloves) or chemical splash suit. Flash Point No Data Available Lower Explosion Limit No Data Available Upper Explosion Limit No Data Available Auto Ignition Temperature No Data Available Hazchem Code 2Z 6. ACCIDENTAL RELEASE MEASURES Form 21047, Revision 3, Page 3 of 11, 15-Jun-2017 02:12:17 Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013 General Response Procedure Eliminate all sources of ignition. Increase ventilation. Avoid generating dust. Stop leak if safe to do so. Isolate the danger area. Use clean, non-sparking tools and equipment. Clean Up Procedures Contain and sweep/shovel up spills with dust binding material. Transfer to a suitable, labelled container and dispose of promptly as hazardous waste. Containment Stop leak if safe to do so. Environmental Precautionary Measures Do not allow product to reach drains, sewers or waterways. If product does enter a waterway, advise the Environmental Protection Authority or your local Waste Authority. Evacuation Criteria Evacuate all unnecessary personnel. Personal Precautionary Measures Personnel involved in the clean up should wear full protective clothing as listed in section 8. 7. HANDLING AND STORAGE Handling Ensure an eye bath and safety shower are available and ready for use. Observe good personal hygiene practices and recommended procedures. Wash thoroughly after handling. Take precautionary measures against static discharges by bonding and grounding equipment. Avoid contact with eyes, skin and clothing. Do not inhale product vapours. Avoid prolonged or repeated exposure. Apply adequate filter equipment, ventilation and personal protection to avoid the inhalation. Storage Store in a cool, dry, well-ventilated area. Keep containers tightly closed when not in use. Inspect regularly for deficiencies such as damage or leaks. Protect against physical damage. Store away from incompatible materials as listed in section 10. Keep away from food or drinks. Storage in original closed containers, or in other suitable ones, isolated from wet and chemical products. This product has a UN classification of 2291 and a Dangerous Goods Class 6.1 Toxic according to The Australian Code for the Transport of Dangerous Goods By Road and Rail. Container Store in original packaging as approved by manufacturer. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION General The following exposure standard has been established by The Australian Safety and Compensation Council (ASCC); Lead, inorganic dusts & fumes (as Pb). CAS: 7439-92-1 TWA = 0.15mg/m3 OELs - Lead and inorganic compounds (as Pb): Limit values - 8 hours mg/m3 Limit values - short term mg/m3 Austria 0.1 inhalable aerosol 0.4 inhalable aerosol Belgium 0.15 Denmark 0.05 inhalable aerosol 0.10 inhalable aerosol European Union 0.15 inhalable aerosol France 0.1 inhalable aerosol Germany (AGS) 0.1 inhalable aerosol Hungary 0.15 inhalable aerosol 0.60 inhalable aerosol 0.05 respirable aerosol 0.2 respirable aerosol Italy 0.15 inhalable aerosol Poland 0.05 Spain 0.15 inhalable aerosol Sweden 0.1 inhalable aerosol 0.15 respirable aerosol Switzerland 0.1 inhalable aerosol 0.8 inhalable aerosol United Kingdom 0.15 DN(M)ELs for workers: Exposure pattern Route DNEL/DMEL Most sensitive (appropriate unit) endpoint Acute - systemic Dermal (mg/kg bw /day) NA NA NA effects Inhalation (mg/m3) NA NA NA Acute - local effects Dermal (mg/cm2) NA NA NA Inhalation (mg/m3) NA NA NA Long-term - systemic Systemic (ug lead /dL NOAEL = 40 ug/dL 40 ug/dL Adult neurological effects blood) function NOAEL = 10 ?g/dL 10 ug/dL Developmental effect on foetus of pregnant women Long-term - local Dermal (mg/cm2) NA NA NA effects Inhalation (mg/m3) NA NA NA Form 21047, Revision 3, Page 4 of 11, 15-Jun-2017 02:12:17 Descriptors Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013 Organisational measures: Blood lead monitoring: Set in place a certified monitoring regime which covers all site activities; Define a policy for submitting workers to regular blood lead monitoring, including increased frequency for workers undertaking high-risk jobs and workers with elevated blood lead levels; Ensure all workers have a blood test prior to working on site. Set an "action level" that is typically 5 ug/dL below the exposure limit deemed to be safe. If the action level is exceeded, appropriate measures are to be taken, to prevent further increases in blood lead. If the safe threshold is exceeded, continue or begin ban on overtime, ensure strict hygiene procedures are followed, undertake detailed inspections to ensure correct use of personal protective equipment, undertake detailed inspections to ensure recommended workplace procedures are followed, move employee to workplace where exposure is expected to be lower or remove from lead environment altogether, further increase blood lead sampling frequency, and continue frequent sampling until results are below the first action level. Exposure Limits No Data Available Biological Limits Biological action levels, inorganic lead EU 70 ug/dL Spain 70 ug/dL Germany 40 ug/dL 30 ug/dL (for woman, age below 45 years) UK 60 ug/dL 30 ug/dL (for woman of reproductive capacity) France 40 ug/dL 30 ug/dL (for woman of reproductive capacity) Engineering Measures A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Adequate ventilation should be provided so that exposure limits are not exceeded. Personal Protection Equipment RESPIRATOR: Wear an approved air-purifying respirator with filter Type P2 if engineering controls are inadequate (AS1715/1716). EYES: Safety glasses with side shields (AS1336/1337). HANDS: Protective gloves, Neoprene or Leather (AS2161). CLOTHING: Long-sleeved protective coveralls and safety footwear. For workers in areas of significant exposure, provide sufficient working clothes to enable daily change into clean clothes. In such cases all work clothing should be cleaned by the employer on a daily basis and is not permitted to leave the work site. (AS3765/2210). Work Hygienic Practices Personal Hygiene: Ensure workers follow simple hygiene rules (e.g. do not bite nails and keep them cut short, avoid touching or scratching face with dirty hands or gloves); Ensure workers do not wipe away sweat with hands or arms; Ensure workers use disposable tissues rather than a handkerchief; Prohibit drinking, eating and smoking in production areas, or access to eating and non-production areas in working clothes; Ensure workers wash hands, arms, faces and mouths (but preferably shower) and change into clean clothing before entering eating areas; For high exposure workplaces, separate rooms for cleaning hands, removal of clothes, showers and clean clothes may be necessary; Ensure workers handle dirty working clothes with care; Allow no personal belongings to be taken into production areas, or items that have been used in production areas to be taken home. Ensure general shop cleanliness is maintained by frequent washing/vacuuming. Clean every workplace at the end of every shift. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Solid Appearance Powder Odour N/A Colour Brown / grey pH 9.9 - 10.0 Vapour Pressure No Data Available Relative Vapour Density No Data Available Boiling Point 1472 °C Melting Point 886 °C Freezing Point No Data Available Solubility Practically Insoluble 20°C Specific Gravity No Data Available Flash Point No Data Available Auto Ignition Temp No Data Available Evaporation Rate No Data Available Bulk Density No Data Available Form 21047, Revision 3, Page 5 of 11, 15-Jun-2017 02:12:17 Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013 Corrosion Rate No Data Available Decomposition Temperature No Data Available Density 9.5 g/cm3 UNE-EN ISO 787-10 Specific Heat No Data Available Molecular Weight No Data Available Net Propellant Weight No Data Available Octanol Water Coefficient No Data Available Particle Size No Data Available Partition Coefficient No Data Available Saturated Vapour Concentration No Data Available Vapour Temperature No Data Available Viscosity No Data Available Volatile Percent No Data Available VOC Volume No Data Available Additional Characteristics Solubility in 0.07 mol/l HCl: 100 % ISO 6713 Potential for Dust Explosion No Data Available Fast or Intensely Burning Characteristics No Data Available Flame Propagation or Burning Rate of Solid Materials No Data Available Non-Flammables That Could No Data Available Contribute Unusual Hazards to a Fire Properties That May Initiate or Contribute to Fire Intensity No Data Available Reactions That Release Gases or Vapours No Data Available Release of Invisible Flammable Vapours and Gases No Data Available 10. STABILITY AND REACTIVITY General Information Reactivity: Lead monoxide is not a reactive substance and no reactive hazards are expected. Chemical Stability Product is stable under normal conditions of use, storage and temperature. Conditions to Avoid Avoid excessive exposure to heat. Materials to Avoid Strong oxidizing agents. Hazardous Decomposition Products No Data Available Hazardous Polymerisation No Data Available 11. TOXICOLOGICAL INFORMATION General Information The toxicity of this substance has been assessed using test data on orange lead and also using read-across from studies with similar inorganic lead compounds. Toxicokinetic assessment: Inorganic lead compounds are slowly absorbed by ingestion and inhalation and poorly absorbed through the skin. If absorbed, lead will accumulate in the body with low rates of excretion, leading to longterm build up. Part of risk management is to take blood samples from workers for analysis to ensure that exposure levels are acceptable. Toxicity data for orange lead (lead tetroxide): LD50 (oral, rat) > 10 000 mg/kg Acute toxicity: Sparingly soluble inorganic lead compounds have generally been found to be of relatively low acute Form 21047, Revision 3, Page 6 of 11, 15-Jun-2017 02:12:17 Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013 toxicity by ingestion, in contact with skin, and by inhalation. Nevertheless current EU regulations require this substance to be classified as harmful by ingestion and inhalation. Skin corrosion/irritation: Studies of similar sparingly soluble inorganic lead compounds have shown that they are not corrosive or irritating to the skin of rabbits. This is supported by the lack of reports of irritant effects from occupational settings. No symptoms of respiratory irritation were noted during long-term inhalation studies involving lead monoxide. Serious eye damage/irritation: Studies of orange lead and similar sparingly soluble inorganic lead compounds have shown that they are not corrosive or irritating to the eyes of rabbits. Respiratory/skin sensitisation: There is no evidence that sparingly soluble inorganic lead compounds cause respiratory or skin sensitisation. Germ cell mutagenicity: The evidence for genotoxic effects of highly soluble inorganic lead compounds is contradictory, with numerous studies reporting both positive and negative effects. Responses appear to be induced by indirect mechanisms, mostly at very high concentrations that lack physiological relevance. Carcinogenicity: There is evidence that highly soluble inorganic lead compounds may have a carcinogenic effect, particularly on the kidneys of rats. However, the mechanisms by which this effect occurs are still unclear. Epidemiology studies of workers exposed to inorganic lead compounds have found a limited association with stomach cancer. This has led to the classification by IARC that inorganic lead compounds are probably carcinogenic to humans (Group 2A). Reproductive toxicity: Exposure to high levels of inorganic lead compounds may cause adverse effects on male and female fertility, including adverse effects on sperm quality. Prenatal exposure to inorganic lead compounds is also associated with adverse effects on neurobehavioural development in children. STOT-single exposure: Sparingly soluble inorganic lead compounds have generally been found to be of relatively low acute toxicity by ingestion, in contact with skin, and by inhalation, with no evidence of any local or systemic toxicity from such exposures. STOT-repeated exposure: Inorganic lead compunds are cumulative poisons and may be absorbed into the body through ingestion or inhalation. Inorganic lead compounds have been documented in observational human studies to produce toxicity in multiple organ systems and body function including the haemotopoetic (blood) system, kidney function, reproductive function and the central nervous system. Aspiration hazard: Lead compunds are a solid and aspiration hazards are not expected to occur. Ingestion Harmful if swallowed. Inhalation Harmful by inhalation. Carcinogen Category No Data Available 12. ECOLOGICAL INFORMATION Ecotoxicity Reliable acute aquatic toxicity test results (tests conducted with soluble lead salts) Test organism Species Endpoint Value Algae Pseudokirchneriella subcapitata 72h EC50 (pH>6.5-7.5) 52.0 ug Pb/L 72h EC50 (pH<7.5-8.5) 233.1 ug Pb/L Invertebrates Daphnia magna 48h EC50 (pH>7.5-8.5) 107.5 ug Pb/L Ceriodaphnia dubia 48h EC50 (pH>5.5-8.5) 73.6 ug Pb/L Fish Oncorhynchus mykiss 96h LC50 (pH>6.5-8.5) 107.0 ug Pb/L Pimephales promelas 96h LC50 (pH>5.5-8.5) 194.2 ug Pb/L Listed values are for tests performed at most sensitive pH. Reliable chronic toxicity test results (tests conducted with soluble lead salts)salts) Compartment Species Value (EC10, NOEC) Freshwater Hyalella azteca (42d, mortality) 8.2 ug Pb/L (dissolved lead) Marine water Mytilus trossolus 9.2 ug Pb/L (dissolved lead) (48h, developmental abnormalities) Freshwater sediment Tubifex tubifex (28d, reproduction) 573 mg Pb/kg dw Marine sediment Neanthes arenaneodentata (28d, growth) 680 mg Pb/kg dw Terrestrial (plants) Hordeum vulgare (yield based on root) 57 mg Pb/kg dw STP Micro-organisms (Protozoa) Protozoan community (24h-LC10) 1.0 mg Pb/L Listed reports are for most sensitive organisms. The following Predicted No Effect Concentrations have been derived for the above environmental compartments: Compartment PNEC Value Freshwater 6.5 ug Pb/L (dissolved lead) Marine water 3.4 ug Pb/L (dissolved lead) Form 21047, Revision 3, Page 7 of 11, 15-Jun-2017 02:12:17 Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013 Freshwater sediment with/without bioavailability correction) Marine water sediment Terrestrial STP Micro-organisms 41.0/174.0 mg Pb/kg dw 164.2 mg Pb/kg dw 147.0 mg Pb/kg dw 0.1 mg Pb/L The environmental effects of this substance have been assessed using read-across from studies with similar inorganic lead compounds. Toxicity: Inorganic lead compounds are expected to be acutely toxic in the environment and also to present a long term hazard to aquatic organisms. Toxicity will depend on the level of free lead ion in solution, which in turn is affected by pH, water hardness, salinity, etc. Lead toxicity is expected to be greater in softer waters. Persistence/Degradability Inorganic lead compounds are an inorganic substance and does not degrade. It is persistent in the environment. Biodegradation is not relevant for inorganic substances. Mobility Practically insoluble in water. Inorganic lead compounds are sparingly soluble and is expected to be adsorbed onto soils and sediments. Mobility is expected to be low. Environmental Fate Do not allow product to reach sewage system. Environmental Protection One or more of the following measures may if necessary be taken to reduce emissions to water: Chemical precipitation: used primarily to remove the metal ions Sedimentation Filtration: used as final clarification step Electrolysis: for low metal concentration Reverse osmosis: extensively used for the removal of dissolved metals Ion exchange: final cleaning step in the removal of heavy metal from process wastewater One or more of the following measures may if necessary be taken to reduce emissions to air: Electrostatic precipitators using wide electrode spacing: Wet electrostatic precipitators: Cyclones, but as primary collector Fabric or bag filters: high efficiency in controlling fine particulate (melting): achieve emission values Membrane filtration techniques can achieve Ceramic and metal mesh filters. PM10 particles are removed Wet scrubbers Lead compound removal from treatment works should be at least the minimum default 84% removal used in the CSR. Solid material collected from on-site treatment must be sent for metal recovery or treated as hazardous waste. Waste water treatment sludge must be recycled, incinerated or landfilled and not used as agricultural fertiliser. Bioaccumulation Potential Inorganic lead is considered to be bioaccumulating in the environment, and may accumulate in aquatic and terrestrial plants and animals. The PBT and vPvB criteria in Annex XIII of the REACH Regulation do not apply to inorganic substances. Environmental Impact No Data Available 13. DISPOSAL CONSIDERATIONS General Information Dispose of in accordance with all local, state and federal regulations. All empty packaging should be disposed of in accordance with Local, State, and Federal Regulations or recycled/reconditioned at an approved facility. Special Precautions for Land Fill Contact a specialist disposal company or the local waste regulator for advice. Must be disposed as hazardous chemical waste. Do not allow product to reach sewage system. 14. TRANSPORT INFORMATION Land Transport (Australia) ADG Proper Shipping Name LEAD COMPOUND, SOLUBLE, N.O.S. (Lead Monoxide) Class 6.1 Toxic and Infectious Substances - Toxic Substances Subsidiary Risk(s) No Data Available EPG 34 Toxic Substances Form 21047, Revision 3, Page 8 of 11, 15-Jun-2017 02:12:17 Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013 UN Number 2291 Hazchem 2Z Pack Group III Special Provision No Data Available Land Transport (New Zealand) NZS5433 Proper Shipping Name LEAD COMPOUND, SOLUBLE, N.O.S. (Lead Monoxide) Class 6.1 Toxic and Infectious Substances - Toxic Substances Subsidiary Risk(s) No Data Available EPG 34 Toxic Substances UN Number 2291 Hazchem 2Z Pack Group III Special Provision Land Transport (United States of America) US DOT Proper Shipping Name LEAD COMPOUND, SOLUBLE, N.O.S. (Lead Monoxide) Class 6.1 Toxic and Infectious Substances - Toxic Substances Subsidiary Risk(s) No Data Available ERG 151 Substances - Toxic (Non-Combustible) UN Number 2291 Hazchem 2Z Pack Group III Special Provision No Data Available Sea Transport IMDG Proper Shipping Name LEAD COMPOUND, SOLUBLE, N.O.S. (Lead Monoxide) Class 6.1 Toxic and Infectious Substances - Toxic Substances Subsidiary Risk(s) No Data Available UN Number 2291 Hazchem 2Z Pack Group III Special Provision No Data Available EMS FA,SA Marine Pollutant Yes Air Transport IATA Proper Shipping Name LEAD COMPOUND, SOLUBLE, N.O.S. (Lead Monoxide) Class 6.1 Toxic and Infectious Substances - Toxic Substances Subsidiary Risk(s) No Data Available UN Number 2291 Hazchem 2Z Pack Group III Special Provision No Data Available Form 21047, Revision 3, Page 9 of 11, 15-Jun-2017 02:12:17 Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013 National Transport Commission (Australia) Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code) Dangerous Goods Classification Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code) 15. REGULATORY INFORMATION General Information No Data Available Poisons Schedule (Aust) 6 Environmental Protection Authority (New Zealand) Hazardous Substances and New Organisms Amendment Act 2015 Approval Code HSR002504 National/Regional Inventories Australia (AICS) Listed Canada (DSL) Not Determined Canada (NDSL) Not Determined China (IECSC) Not Determined Europe (EINECS) Not Determined Europe (REACh) Not Determined Japan (ENCS/METI) Not Determined Korea (KECI) Not Determined Malaysia (EHS Register) Not Determined New Zealand (NZIoC) Not Determined Philippines (PICCS) Not Determined Switzerland (Giftliste 1) Not Determined Switzerland (Inventory of Notified Substances) Not Determined Taiwan (NCSR) Not Determined USA (TSCA) Not Determined 16. OTHER INFORMATION Related Product Codes LEOXID4500 Revision 2 Revision Date 01 Jul 2013 Form 21047, Revision 3, Page 10 of 11, 15-Jun-2017 02:12:17 Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013 Key/Legend < Less Than > Greater Than AICS Australian Inventory of Chemical Substances atm Atmosphere CAS Chemical Abstracts Service (Registry Number) cm² Square Centimetres CO2 Carbon Dioxide COD Chemical Oxygen Demand deg C (°C) Degrees Celcius EPA (New Zealand) Environmental Protection Authority of New Zealand deg F (°F) Degrees Farenheit g Grams g/cm³ Grams per Cubic Centimetre g/l Grams per Litre HSNO Hazardous Substance and New Organism IDLH Immediately Dangerous to Life and Health immiscible Liquids are insoluable in each other. inHg Inch of Mercury inH2O Inch of Water K Kelvin kg Kilogram kg/m³ Kilograms per Cubic Metre lb Pound LC50 LC stands for lethal concentration. LC50 is the concentration of a material in air which causes the death of 50% (one half) of a group of test animals. The material is inhaled over a set period of time, usually 1 or 4 hours. LD50 LD stands for Lethal Dose. LD50 is the amount of a material, given all at once, which causes the death of 50% (one half) of a group of test animals. ltr or L Litre m³ Cubic Metre mbar Millibar mg Milligram mg/24H Milligrams per 24 Hours mg/kg Milligrams per Kilogram mg/m³ Milligrams per Cubic Metre Misc or Miscible Liquids form one homogeneous liquid phase regardless of the amount of either component present. mm Millimetre mmH2O Millimetres of Water mPa.s Millipascals per Second N/A Not Applicable NIOSH National Institute for Occupational Safety and Health NOHSC National Occupational Heath and Safety Commission OECD Organisation for Economic Co-operation and Development Oz Ounce PEL Permissible Exposure Limit Pa Pascal ppb Parts per Billion ppm Parts per Million ppm/2h Parts per Million per 2 Hours ppm/6h Parts per Million per 6 Hours psi Pounds per Square Inch R Rankine RCP Reciprocal Calculation Procedure STEL Short Term Exposure Limit TLV Threshold Limit Value tne Tonne TWA Time Weighted Average ug/24H Micrograms per 24 Hours UN United Nations wt Weight Form 21047, Revision 3, Page 11 of 11, 15-Jun-2017 02:12:17
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