Redox Pty Ltd - Safety Data Sheet Lead Oxide Grey Revision 2

Safety Data Sheet
Lead Oxide Grey
Revision 2, Date 01 Jul 2013
1. IDENTIFICATION
Product Name
Lead Oxide Grey
Other Names
Mixture - All components listed on AICS
Uses
Use of lead metal in lead oxide production under industrial conditions
Use of lead oxides in lead stabiliser production under industrial conditions
Use of lead oxides in lead acid battery production
Use of lead oxides in crystal glass production
Use of lead oxides in production of ceramic ware
Use of lead oxides in rubber production
Use of lead oxides in explosive manufacture
Professional use of adsorbents
Professional use of paints and pigments
Professional use of lead oxides as laboratory agents and in chemical analysis
Chemical Family
No Data Available
Chemical Formula
PbO + Pb
Chemical Name
Lead Oxide Grey
Product Description
Lead monoxide with high content in lead metal.
Contact Details of the Supplier of this Safety Data Sheet
Organisation
Location
Telephone
Redox Pty Ltd
2 Swettenham Road
Minto NSW 2566
Australia
+61-2-97333000
Redox Pty Ltd
11 Mayo Road
Wiri Auckland 2104
New Zealand
+64-9-2506222
Redox Inc.
2132A E. Dominguez Street
Carson CA 90810
USA
+1-424-675-3200
Redox Chemicals Sdn Bhd
Level 2, No. 8, Jalan Sapir 33/7
Seksyen 33, Shah Alam Premier Industrial Park
40400 Shah Alam
Sengalor, Malaysia
+60-3-5614-2111
Emergency Contact Details
For emergencies only; DO NOT contact these companies for general product advice.
Organisation
Location
Telephone
Poisons Information Centre
Westmead NSW
1800-251525
131126
Chemcall
Australia
1800-127406
+64-4-9179888
Chemcall
Malaysia
+64-4-9179888
Chemcall
New Zealand
0800-243622
+64-4-9179888
National Poisons Centre
New Zealand
0800-764766
CHEMTREC
USA & Canada
1-800-424-9300 CN723420
+1-703-527-3887
2. HAZARD IDENTIFICATION
Redox Pty Ltd
Corporate Office Sydney
Locked Bag 15 Minto NSW 2566 Australia
2 Swettenham Road Minto NSW 2566 Australia
All Deliveries: 4 Holmes Road Minto NSW 2566 Australia
Form 21047, Revision 3, Page 1 of 11, 15-Jun-2017 02:12:17
Phone
Fax
E-mail
Web
ABN
+61 2 9733 3000
+61 2 9733 3111
[email protected]
www.redox.com
92 000 762 345
Australia
Adelaide
Brisbane
Melbourne
Perth
Sydney
New Zealand
Auckland
Christchurch
Hawke’s Bay
Malaysia
Kuala Lumpur
USA
Los Angeles
Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013
Poisons Schedule (Aust)
6
Globally Harmonised System
Hazard Classification
Hazardous according to the criteria of the Globally Harmonised System of Classification and Labelling of
Chemicals (GHS)
Hazard Categories
Carcinogenicity - Category 2
Germ Cell Mutagenicity - Category 2
Specific Target Organ Toxicity (Repeated Exposure) - Category 2
Toxic To Reproduction - Category 1A
Pictograms
Signal Word
Danger
Hazard Statements
H341
Suspected of causing genetic defects.
H351
Suspected of causing cancer.
H360fD
May damage the unborn child. Suspected of damaging fertility.
H373
May cause damage to organs through prolonged or repeated exposure.
P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P260
Do not breathe fume/gas/mist/vapours/spray.
P281
Use personal protective equipment as required.
P308 + P313
IF exposed or concerned: Get medical advice/ attention.
P314
Get medical advice/attention if you feel unwell.
Storage
P405
Store locked up.
Disposal
P501
Dispose of contents/container in accordance with local / regional / national /
international regulations.
Precautionary Statements
Prevention
Response
National Transport Commission (Australia)
Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code)
Dangerous Goods Classification
Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods
by Road & Rail (ADG Code)
Environmental Protection Authority (New Zealand)
Hazardous Substances and New Organisms Amendment Act 2015
HSNO Classifications
Health
Hazards
Form 21047, Revision 3, Page 2 of 11, 15-Jun-2017 02:12:17
6.1C
Substances that are acutely toxic- Toxic
6.6B
Substances that are suspected human mutagens
6.7B
Substances that are suspected human carcinogens
6.8A
Substances that are known or presumed human reproductive or developmental
toxicants
6.8C
Substances that produce toxic human reproductive or developmental effects on
or via lactation
6.9A
Substances that are toxic to human target organs or systems
6.9B
Substances that are harmful to human target organs or systems
Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013
Environmental
Hazards
9.1A
Substances that are very ecotoxic in the aquatic environment
9.3B
Substances that are ecotoxic to terrestrial vertebrates
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients
Chemical Entity
Formula
CAS Number
Proportion
Lead monoxide (PbO)
No Data Available
1317-36-8
72.00 - 82.00 %
Metal Lead Powdered (Pb)
No Data Available
7439-92-1
18.00 - 28.00 %
4. FIRST AID MEASURES
Description of necessary measures according to routes of exposure
Swallowed
Rinse mouth with water. Seek medical attention.
Eye
Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. Take care not to rinse
contaminated water into the non-affected eye. Seek medical attention.
Skin
Remove contaminated clothing. Wash affected area with plenty of Soap and water for at least 15 minutes. Seek
medical attention if irritation develops or persists. Wash clothing before reuse.
Inhaled
Remove victim from exposure to fresh air. Wash lips and nose. In case of irritation of respiratory ways, mucous
membrane or indisposition, consult a physician.
Advice to Doctor
Treat symptomatically based on judgement of doctor and individual reactions of patient.
Medical Conditions Aggravated
by Exposure
Toxic for Reproduction Category 1: May cause harm to the unborn child.
5. FIRE FIGHTING MEASURES
General Measures
Clear fire area of all non-emergency personnel. Stay upwind. Keep out of low areas. Eliminate ignition sources. Move
fire exposed containers from fire area if it can be done without risk. Avoid the inhalation of toxic fumes.
Flammability Conditions
Product is a non-flammable solid.
Extinguishing Media
In case of fire, use appropriate extinguishing media most suitable for surrounding fire conditions. Do NOT use
halogen products and water spurt.
Hazardous Products of
Combustion
No Data Available
Special Fire Fighting
Instructions
HAZCHEM: 2Z
Do NOT allow fire fighting water to reach waterways, drains or sewers. Store fire fighting water for treatment.
Personal Protective Equipment
Fire fighters should wear a positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting
clothing (includes fire fighting helmet, coat, trousers, boots and gloves) or chemical splash suit.
Flash Point
No Data Available
Lower Explosion Limit
No Data Available
Upper Explosion Limit
No Data Available
Auto Ignition Temperature
No Data Available
Hazchem Code
2Z
6. ACCIDENTAL RELEASE MEASURES
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Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013
General Response Procedure
Eliminate all sources of ignition. Increase ventilation. Avoid generating dust. Stop leak if safe to do so. Isolate the
danger area. Use clean, non-sparking tools and equipment.
Clean Up Procedures
Contain and sweep/shovel up spills with dust binding material. Transfer to a suitable, labelled container and dispose
of promptly as hazardous waste.
Containment
Stop leak if safe to do so.
Environmental Precautionary
Measures
Do not allow product to reach drains, sewers or waterways. If product does enter a waterway, advise the
Environmental Protection Authority or your local Waste Authority.
Evacuation Criteria
Evacuate all unnecessary personnel.
Personal Precautionary
Measures
Personnel involved in the clean up should wear full protective clothing as listed in section 8.
7. HANDLING AND STORAGE
Handling
Ensure an eye bath and safety shower are available and ready for use. Observe good personal hygiene practices and
recommended procedures. Wash thoroughly after handling. Take precautionary measures against static discharges
by bonding and grounding equipment. Avoid contact with eyes, skin and clothing. Do not inhale product vapours.
Avoid prolonged or repeated exposure. Apply adequate filter equipment, ventilation and personal protection to avoid
the inhalation.
Storage
Store in a cool, dry, well-ventilated area. Keep containers tightly closed when not in use. Inspect regularly for
deficiencies such as damage or leaks. Protect against physical damage. Store away from incompatible materials as
listed in section 10. Keep away from food or drinks. Storage in original closed containers, or in other suitable ones,
isolated from wet and chemical products. This product has a UN classification of 2291 and a Dangerous Goods
Class 6.1 Toxic according to The Australian Code for the Transport of Dangerous Goods By Road and Rail.
Container
Store in original packaging as approved by manufacturer.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
General
The following exposure standard has been established by The Australian Safety and Compensation Council (ASCC);
Lead, inorganic dusts & fumes (as Pb). CAS: 7439-92-1 TWA = 0.15mg/m3
OELs - Lead and inorganic compounds (as Pb):
Limit values - 8 hours mg/m3 Limit values - short term mg/m3
Austria
0.1 inhalable aerosol
0.4 inhalable aerosol
Belgium
0.15
Denmark
0.05 inhalable aerosol
0.10 inhalable aerosol
European Union 0.15 inhalable aerosol
France
0.1 inhalable aerosol
Germany (AGS) 0.1 inhalable aerosol
Hungary
0.15 inhalable aerosol
0.60 inhalable aerosol
0.05 respirable aerosol
0.2 respirable aerosol
Italy
0.15 inhalable aerosol
Poland
0.05
Spain
0.15 inhalable aerosol
Sweden
0.1 inhalable aerosol
0.15 respirable aerosol
Switzerland
0.1 inhalable aerosol
0.8 inhalable aerosol
United Kingdom 0.15
DN(M)ELs for workers:
Exposure pattern
Route
DNEL/DMEL
Most sensitive
(appropriate unit) endpoint
Acute - systemic
Dermal (mg/kg bw /day)
NA
NA
NA
effects
Inhalation (mg/m3)
NA
NA
NA
Acute - local effects
Dermal (mg/cm2)
NA
NA
NA
Inhalation (mg/m3)
NA
NA
NA
Long-term - systemic
Systemic (ug lead /dL
NOAEL = 40 ug/dL
40 ug/dL
Adult neurological
effects
blood)
function
NOAEL = 10 ?g/dL
10 ug/dL
Developmental effect
on foetus of
pregnant women
Long-term - local
Dermal (mg/cm2)
NA
NA
NA
effects
Inhalation (mg/m3)
NA
NA
NA
Form 21047, Revision 3, Page 4 of 11, 15-Jun-2017 02:12:17
Descriptors
Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013
Organisational measures:
Blood lead monitoring: Set in place a certified monitoring regime which covers all site activities; Define a policy for
submitting workers to regular blood lead monitoring, including increased frequency for workers undertaking high-risk
jobs and workers with elevated blood lead levels; Ensure all workers have a blood test prior to working on site. Set an
"action level" that is typically 5 ug/dL below the exposure limit deemed to be safe. If the action level is exceeded,
appropriate measures are to be taken, to prevent further increases in blood lead. If the safe threshold is exceeded,
continue or begin ban on overtime, ensure strict hygiene procedures are followed, undertake detailed inspections to
ensure correct use of personal protective equipment, undertake detailed inspections to ensure recommended
workplace procedures are followed, move employee to workplace where exposure is expected to be lower or remove
from lead environment altogether, further increase blood lead sampling frequency, and continue frequent sampling
until results are below the first action level.
Exposure Limits
No Data Available
Biological Limits
Biological action levels, inorganic lead
EU
70 ug/dL
Spain
70 ug/dL
Germany 40 ug/dL
30 ug/dL (for woman, age below 45 years)
UK
60 ug/dL
30 ug/dL (for woman of reproductive capacity)
France
40 ug/dL
30 ug/dL (for woman of reproductive capacity)
Engineering Measures
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local
exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Adequate ventilation should be provided so that exposure limits
are not exceeded.
Personal Protection Equipment
RESPIRATOR: Wear an approved air-purifying respirator with filter Type P2 if engineering controls are inadequate
(AS1715/1716).
EYES: Safety glasses with side shields (AS1336/1337).
HANDS: Protective gloves, Neoprene or Leather (AS2161).
CLOTHING: Long-sleeved protective coveralls and safety footwear. For workers in areas of significant exposure,
provide sufficient working clothes to enable daily change into clean clothes. In such cases all work clothing should
be cleaned by the employer on a daily basis and is not permitted to leave the work site. (AS3765/2210).
Work Hygienic Practices
Personal Hygiene: Ensure workers follow simple hygiene rules (e.g. do not bite nails and keep them cut short, avoid
touching or scratching face with dirty hands or gloves); Ensure workers do not wipe away sweat with hands or arms;
Ensure workers use disposable tissues rather than a handkerchief; Prohibit drinking, eating and smoking in
production areas, or access to eating and non-production areas in working clothes; Ensure workers wash hands,
arms, faces and mouths (but preferably shower) and change into clean clothing before entering eating areas; For high
exposure workplaces, separate rooms for cleaning hands, removal of clothes, showers and clean clothes may be
necessary; Ensure workers handle dirty working clothes with care; Allow no personal belongings to be taken into
production areas, or items that have been used in production areas to be taken home. Ensure general shop
cleanliness is maintained by frequent washing/vacuuming. Clean every workplace at the end of every shift.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State
Solid
Appearance
Powder
Odour
N/A
Colour
Brown / grey
pH
9.9 - 10.0
Vapour Pressure
No Data Available
Relative Vapour Density
No Data Available
Boiling Point
1472 °C
Melting Point
886 °C
Freezing Point
No Data Available
Solubility
Practically Insoluble 20°C
Specific Gravity
No Data Available
Flash Point
No Data Available
Auto Ignition Temp
No Data Available
Evaporation Rate
No Data Available
Bulk Density
No Data Available
Form 21047, Revision 3, Page 5 of 11, 15-Jun-2017 02:12:17
Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013
Corrosion Rate
No Data Available
Decomposition Temperature
No Data Available
Density
9.5 g/cm3 UNE-EN ISO 787-10
Specific Heat
No Data Available
Molecular Weight
No Data Available
Net Propellant Weight
No Data Available
Octanol Water Coefficient
No Data Available
Particle Size
No Data Available
Partition Coefficient
No Data Available
Saturated Vapour Concentration No Data Available
Vapour Temperature
No Data Available
Viscosity
No Data Available
Volatile Percent
No Data Available
VOC Volume
No Data Available
Additional Characteristics
Solubility in 0.07 mol/l HCl: 100 % ISO 6713
Potential for Dust Explosion
No Data Available
Fast or Intensely Burning
Characteristics
No Data Available
Flame Propagation or Burning
Rate of Solid Materials
No Data Available
Non-Flammables That Could
No Data Available
Contribute Unusual Hazards to a
Fire
Properties That May Initiate or
Contribute to Fire Intensity
No Data Available
Reactions That Release Gases
or Vapours
No Data Available
Release of Invisible Flammable
Vapours and Gases
No Data Available
10. STABILITY AND REACTIVITY
General Information
Reactivity: Lead monoxide is not a reactive substance and no reactive hazards are expected.
Chemical Stability
Product is stable under normal conditions of use, storage and temperature.
Conditions to Avoid
Avoid excessive exposure to heat.
Materials to Avoid
Strong oxidizing agents.
Hazardous Decomposition
Products
No Data Available
Hazardous Polymerisation
No Data Available
11. TOXICOLOGICAL INFORMATION
General Information
The toxicity of this substance has been assessed using test data on orange lead and also using read-across from
studies with similar inorganic lead compounds.
Toxicokinetic assessment: Inorganic lead compounds are slowly absorbed by ingestion and inhalation and poorly
absorbed through the skin. If absorbed, lead will accumulate in the body with low rates of excretion, leading to longterm build up. Part of risk management is to take blood
samples from workers for analysis to ensure that exposure levels are acceptable.
Toxicity data for orange lead (lead tetroxide): LD50 (oral, rat) > 10 000 mg/kg
Acute toxicity: Sparingly soluble inorganic lead compounds have generally been found to be of relatively low acute
Form 21047, Revision 3, Page 6 of 11, 15-Jun-2017 02:12:17
Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013
toxicity by ingestion, in contact with skin, and by inhalation. Nevertheless current EU regulations require this
substance to be classified as harmful by ingestion and inhalation.
Skin corrosion/irritation: Studies of similar sparingly soluble inorganic lead compounds have shown that they are not
corrosive or irritating to the skin of rabbits. This is supported by the lack of reports of irritant effects from occupational
settings. No symptoms of respiratory irritation were noted during long-term inhalation studies involving lead monoxide.
Serious eye damage/irritation: Studies of orange lead and similar sparingly soluble inorganic lead compounds have
shown that they are not corrosive or irritating to the eyes of rabbits.
Respiratory/skin sensitisation: There is no evidence that sparingly soluble inorganic lead compounds cause
respiratory or skin sensitisation.
Germ cell mutagenicity: The evidence for genotoxic effects of highly soluble inorganic lead compounds is
contradictory, with numerous studies reporting both positive and negative effects. Responses appear to be induced
by indirect mechanisms, mostly at very high concentrations that lack physiological relevance.
Carcinogenicity: There is evidence that highly soluble inorganic lead compounds may have a carcinogenic effect,
particularly on the kidneys of rats. However, the mechanisms by which this effect occurs are still unclear.
Epidemiology studies of workers exposed to inorganic lead compounds have found a limited association with
stomach cancer. This has led to the classification by IARC that inorganic lead compounds are probably carcinogenic
to humans (Group 2A).
Reproductive toxicity: Exposure to high levels of inorganic lead compounds may cause adverse effects on male and
female fertility, including adverse effects on sperm quality. Prenatal exposure to inorganic lead compounds is also
associated with adverse effects on neurobehavioural
development in children.
STOT-single exposure: Sparingly soluble inorganic lead compounds have generally been found to be of relatively low
acute toxicity by ingestion, in contact with skin, and by inhalation, with no evidence of any local or systemic toxicity
from such exposures.
STOT-repeated exposure: Inorganic lead compunds are cumulative poisons and may be absorbed into the body
through ingestion or inhalation. Inorganic lead compounds have been documented in observational human studies to
produce toxicity in multiple organ systems and body function including the haemotopoetic (blood) system, kidney
function, reproductive function and the central nervous system.
Aspiration hazard: Lead compunds are a solid and aspiration hazards are not expected to occur.
Ingestion
Harmful if swallowed.
Inhalation
Harmful by inhalation.
Carcinogen Category
No Data Available
12. ECOLOGICAL INFORMATION
Ecotoxicity
Reliable acute aquatic toxicity test results (tests conducted with soluble lead salts)
Test organism
Species
Endpoint
Value
Algae
Pseudokirchneriella subcapitata
72h EC50 (pH>6.5-7.5) 52.0 ug Pb/L
72h EC50 (pH<7.5-8.5) 233.1 ug Pb/L
Invertebrates
Daphnia magna
48h EC50 (pH>7.5-8.5) 107.5 ug Pb/L
Ceriodaphnia dubia
48h EC50 (pH>5.5-8.5) 73.6 ug Pb/L
Fish
Oncorhynchus mykiss
96h LC50 (pH>6.5-8.5) 107.0 ug Pb/L
Pimephales promelas
96h LC50 (pH>5.5-8.5) 194.2 ug Pb/L
Listed values are for tests performed at most sensitive pH.
Reliable chronic toxicity test results (tests conducted with soluble lead salts)salts)
Compartment
Species
Value (EC10, NOEC)
Freshwater
Hyalella azteca (42d, mortality)
8.2 ug Pb/L (dissolved lead)
Marine water
Mytilus trossolus
9.2 ug Pb/L (dissolved lead)
(48h, developmental abnormalities)
Freshwater sediment
Tubifex tubifex (28d, reproduction)
573 mg Pb/kg dw
Marine sediment
Neanthes arenaneodentata (28d, growth) 680 mg Pb/kg dw
Terrestrial (plants)
Hordeum vulgare (yield based on root)
57 mg Pb/kg dw
STP Micro-organisms (Protozoa) Protozoan community (24h-LC10)
1.0 mg Pb/L
Listed reports are for most sensitive organisms.
The following Predicted No Effect Concentrations have been derived for the above environmental compartments:
Compartment
PNEC Value
Freshwater
6.5 ug Pb/L (dissolved lead)
Marine water
3.4 ug Pb/L (dissolved lead)
Form 21047, Revision 3, Page 7 of 11, 15-Jun-2017 02:12:17
Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013
Freshwater sediment
with/without bioavailability correction)
Marine water sediment
Terrestrial
STP Micro-organisms
41.0/174.0 mg Pb/kg dw
164.2 mg Pb/kg dw
147.0 mg Pb/kg dw
0.1 mg Pb/L
The environmental effects of this substance have been assessed using read-across from studies with similar
inorganic lead compounds.
Toxicity: Inorganic lead compounds are expected to be acutely toxic in the environment and also to present a long
term hazard to aquatic organisms. Toxicity will depend on the level of free lead ion in solution, which in turn is
affected by pH, water hardness, salinity, etc. Lead toxicity is expected to be greater in softer waters.
Persistence/Degradability
Inorganic lead compounds are an inorganic substance and does not degrade. It is persistent in the environment.
Biodegradation is not relevant for inorganic substances.
Mobility
Practically insoluble in water.
Inorganic lead compounds are sparingly soluble and is expected to be adsorbed onto soils and sediments. Mobility is
expected to be low.
Environmental Fate
Do not allow product to reach sewage system.
Environmental Protection
One or more of the following measures may if necessary be taken to reduce emissions to water:
Chemical precipitation: used primarily to remove the metal ions
Sedimentation
Filtration: used as final clarification step
Electrolysis: for low metal concentration
Reverse osmosis: extensively used for the removal of dissolved metals
Ion exchange: final cleaning step in the removal of heavy metal from process wastewater
One or more of the following measures may if necessary be taken to reduce emissions to air:
Electrostatic precipitators using wide electrode spacing: Wet electrostatic precipitators:
Cyclones, but as primary collector Fabric or bag filters: high efficiency in controlling fine particulate (melting): achieve
emission values Membrane filtration techniques can achieve
Ceramic and metal mesh filters. PM10 particles are removed
Wet scrubbers
Lead compound removal from treatment works should be at least the minimum default 84% removal used in the
CSR. Solid material collected from on-site treatment must be sent for metal recovery or treated as hazardous waste.
Waste water treatment sludge must be recycled, incinerated or landfilled and not used as agricultural fertiliser.
Bioaccumulation Potential
Inorganic lead is considered to be bioaccumulating in the environment, and may accumulate in aquatic and terrestrial
plants and animals.
The PBT and vPvB criteria in Annex XIII of the REACH Regulation do not apply to inorganic substances.
Environmental Impact
No Data Available
13. DISPOSAL CONSIDERATIONS
General Information
Dispose of in accordance with all local, state and federal regulations. All empty packaging should be disposed of in
accordance with Local, State, and Federal Regulations or recycled/reconditioned at an approved facility.
Special Precautions for Land Fill Contact a specialist disposal company or the local waste regulator for advice. Must be disposed as hazardous
chemical waste. Do not allow product to reach sewage system.
14. TRANSPORT INFORMATION
Land Transport (Australia)
ADG
Proper Shipping Name
LEAD COMPOUND, SOLUBLE, N.O.S. (Lead Monoxide)
Class
6.1 Toxic and Infectious Substances - Toxic Substances
Subsidiary Risk(s)
No Data Available
EPG
34 Toxic Substances
Form 21047, Revision 3, Page 8 of 11, 15-Jun-2017 02:12:17
Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013
UN Number
2291
Hazchem
2Z
Pack Group
III
Special Provision
No Data Available
Land Transport (New Zealand)
NZS5433
Proper Shipping Name
LEAD COMPOUND, SOLUBLE, N.O.S. (Lead Monoxide)
Class
6.1 Toxic and Infectious Substances - Toxic Substances
Subsidiary Risk(s)
No Data Available
EPG
34 Toxic Substances
UN Number
2291
Hazchem
2Z
Pack Group
III
Special Provision
Land Transport (United States of America)
US DOT
Proper Shipping Name
LEAD COMPOUND, SOLUBLE, N.O.S. (Lead Monoxide)
Class
6.1 Toxic and Infectious Substances - Toxic Substances
Subsidiary Risk(s)
No Data Available
ERG
151 Substances - Toxic (Non-Combustible)
UN Number
2291
Hazchem
2Z
Pack Group
III
Special Provision
No Data Available
Sea Transport
IMDG
Proper Shipping Name
LEAD COMPOUND, SOLUBLE, N.O.S. (Lead Monoxide)
Class
6.1 Toxic and Infectious Substances - Toxic Substances
Subsidiary Risk(s)
No Data Available
UN Number
2291
Hazchem
2Z
Pack Group
III
Special Provision
No Data Available
EMS
FA,SA
Marine Pollutant
Yes
Air Transport
IATA
Proper Shipping Name
LEAD COMPOUND, SOLUBLE, N.O.S. (Lead Monoxide)
Class
6.1 Toxic and Infectious Substances - Toxic Substances
Subsidiary Risk(s)
No Data Available
UN Number
2291
Hazchem
2Z
Pack Group
III
Special Provision
No Data Available
Form 21047, Revision 3, Page 9 of 11, 15-Jun-2017 02:12:17
Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013
National Transport Commission (Australia)
Australian Code for the Transport of Dangerous Goods by Road & Rail (ADG Code)
Dangerous Goods Classification
Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods
by Road & Rail (ADG Code)
15. REGULATORY INFORMATION
General Information
No Data Available
Poisons Schedule (Aust)
6
Environmental Protection Authority (New Zealand)
Hazardous Substances and New Organisms Amendment Act 2015
Approval Code
HSR002504
National/Regional Inventories
Australia (AICS)
Listed
Canada (DSL)
Not Determined
Canada (NDSL)
Not Determined
China (IECSC)
Not Determined
Europe (EINECS)
Not Determined
Europe (REACh)
Not Determined
Japan (ENCS/METI)
Not Determined
Korea (KECI)
Not Determined
Malaysia (EHS Register)
Not Determined
New Zealand (NZIoC)
Not Determined
Philippines (PICCS)
Not Determined
Switzerland (Giftliste 1)
Not Determined
Switzerland (Inventory of Notified
Substances)
Not Determined
Taiwan (NCSR)
Not Determined
USA (TSCA)
Not Determined
16. OTHER INFORMATION
Related Product Codes
LEOXID4500
Revision
2
Revision Date
01 Jul 2013
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Safety Data Sheet Lead Oxide Grey Revision 2, Date 01 Jul 2013
Key/Legend
< Less Than
> Greater Than
AICS Australian Inventory of Chemical Substances
atm Atmosphere
CAS Chemical Abstracts Service (Registry Number)
cm² Square Centimetres
CO2 Carbon Dioxide
COD Chemical Oxygen Demand
deg C (°C) Degrees Celcius
EPA (New Zealand) Environmental Protection Authority of New Zealand
deg F (°F) Degrees Farenheit
g Grams
g/cm³ Grams per Cubic Centimetre
g/l Grams per Litre
HSNO Hazardous Substance and New Organism
IDLH Immediately Dangerous to Life and Health
immiscible Liquids are insoluable in each other.
inHg Inch of Mercury
inH2O Inch of Water
K Kelvin
kg Kilogram
kg/m³ Kilograms per Cubic Metre
lb Pound
LC50 LC stands for lethal concentration. LC50 is the concentration of a material in air which causes the death of
50% (one half) of a group of test animals. The material is inhaled over a set period of time, usually 1 or 4 hours.
LD50 LD stands for Lethal Dose. LD50 is the amount of a material, given all at once, which causes the death of 50%
(one half) of a group of test animals.
ltr or L Litre
m³ Cubic Metre
mbar Millibar
mg Milligram
mg/24H Milligrams per 24 Hours
mg/kg Milligrams per Kilogram
mg/m³ Milligrams per Cubic Metre
Misc or Miscible Liquids form one homogeneous liquid phase regardless of the amount of either component
present.
mm Millimetre
mmH2O Millimetres of Water
mPa.s Millipascals per Second
N/A Not Applicable
NIOSH National Institute for Occupational Safety and Health
NOHSC National Occupational Heath and Safety Commission
OECD Organisation for Economic Co-operation and Development
Oz Ounce
PEL Permissible Exposure Limit
Pa Pascal
ppb Parts per Billion
ppm Parts per Million
ppm/2h Parts per Million per 2 Hours
ppm/6h Parts per Million per 6 Hours
psi Pounds per Square Inch
R Rankine
RCP Reciprocal Calculation Procedure
STEL Short Term Exposure Limit
TLV Threshold Limit Value
tne Tonne
TWA Time Weighted Average
ug/24H Micrograms per 24 Hours
UN United Nations
wt Weight
Form 21047, Revision 3, Page 11 of 11, 15-Jun-2017 02:12:17