SUBJECT NATURAL SCIENCES TITLE OF LEARNING OBJECT CURRICULAR AXIS STANDARD COMPETENCIES LEARNING OBJECTIVES GRADE 9TH LEARNING UNIT HOW TO RELATE THE COMPONENTS OF THE WORLD How does water transform the minerals in rocks Living environment Record my observations and results by using diagrams, graphs and tables. 1. To make short presentations of the acid compounds (oxyacid and hydracids) and hydroxides contained in products used in the industry or at home. 2. To explain in short conversations, the influence of acids (oxyacids- hydracids) and hydroxides in natural and humaninduced phenomena in the planet. SKILLS/ KNOWLEDGE 3. To establish relations between metals, non-metals and the formation of acids and hydroxides. S/K 1: Illustrate the paths to obtain acids (oxyacids and hydracids) and hydroxides and establishes relations with the organization of the periodic table of elements. S/K2: Provide examples of applications and uses of acids and hydroxides. S/K3: Differentiate the various ways in which an acid or a hydroxide can be named. S/K4: Represent and describes the chemical equations of salt formation. S/K 5: Explain acid rain and inquires about the natural and human processes behind it. LEARNING FLOW S/K 6: Enquire about the weathering process. Introduction Objectives Activity 1: Obtaining acids ( oxyacids - hydracid) and hydroxides Salt formation Applications in industry and domestic activities Activity 2: Nomenclature of acids (oxyacids - hydracid), hydroxides and salt. Activity 3: •Acid rain • Weathering Abstract Homework Evaluation Glossary ASSESSMENT GUIDELINE This learning object is intended for the student to find a simple, didactic and contextual guide. Likewise, students must develop the guide completely, including the different activities of this LO, by using the diverse tools and autonomous work suggested here. This will ensure successful understanding of the topic. Stage Introduction Learning flow Introduction Teaching/Learning Activities Recommended Resources The teacher presents the corresponding text so that it is familiar to the student. Animation The intention is to make this topic easy and understandable. Introduction On a daily basis, people use substances made up of acids and bases at a domestic, as well as an industrial level. In the countryside, farmers use fertilizers composed of nitric and sulfuric acids in their crops. For obtaining the glass needed for making cups or house windows, they use hydrofluoric acid. In addition, calcium hydroxide is often used in dentistry procedures, among other. For instance, when we do the house cleaning, it is common to use products like cleansers or bleaches for floors or restrooms. Have you noticed you cannot sniff these substances? Have you realized people pour little quantities of these substances on surfaces? Generally, these substances need to be mixed with plenty of water. It is usual to hear about a salt called sodium hypochlorite, this is the essential component of cleansers or bleach, and it is highly corrosive, with a strong odor and should be used with caution. Development Activity 1 As you will see, both acids, hydroxides and salts are part of many products used at home and in the industry. In this section, you will learn how these substances are formed, why they are called in such particular ways and how they are related to human activities and natural phenomena. The teacher shows students the importance of acids, hydroxides and salts in everyday life ; relate different examples to domestic and industrial level . S/K 1: Illustrates the paths to obtain acids (oxyacid and hydracids) and hydroxides and establishes relations with the organization of the periodic table of elements. S/K 2: Provides examples of implementation and uses of acids and hydroxides. Students’ material and animation resource about the geological eras. S/K 4: Represents and describes the chemical equations of salt formation. The first activity addresses the issues about acids. To do this, the teacher can use the tables and examples given in the same way, so that the student have a better understanding. Initially, the teacher begins by explaining the topic with a brief explanation THE OBTAINING OF ACIDS (OXYACIDSHYDRACIDS) AND HYDROXIDES ACIDS: Acids are chemical substances that have the following features: They taste bitter They are corrosive for your skin They redden certain vegetal colorants They dissolve other substances They attack metals by releasing H2 They lose their properties when reacting with bases Acids are substances which transfer protons (H+) in an aqueous medium, they taste bitter and have an inferior pH than 7 (Mondragón et al, 2005, pag 226 According to the classic theory of electrolytic ionization, developed by Arrenhius (1859- 1927), the electrolytes dissolved in water dissociate directly in charged particles (positive and negative) called ions. Those electrolytes with ions that cause the dissolution to be acid o basic are of great interest for the analytic chemistry. According to the same theory, the ions that give origin to the acid behavior are the protons.(Mondragón et al, 2005, pag 228). HX H+ + XExample: HCl (aqueous solution) Cl- + H+ H2SO4 (aqueous solution) SO42- + 2H Figure 1. Bottle of hydrochloric acid, normally known as muriatic acid;it is often used in industrial proceses such as pickling of Steel and treatment of minerals. Acids are divided into: Acids Hydracids Oxyacids Figure 2. Classification of acids. (Own creation, 2016). Hydracids: They are compounds which are formed when some non-metals (elements belonging to group VI A and VII A, with less oxidation. 1- and 2- ) react with hydrogen. The general hydracids is: equation X-n + H2 for obtaining HnX Its general formula is: HnX Where: H= Hydrogen, X = Element Non- Metal, n= Oxidation state of non-metal Examples: Cl + H2 2HCl Hydrochloric Acid Se + H2 H2Se Hydroselenic acid The elements are: Sulfur, selenium and tellurium from group VI A. They have an oxidation state of 1-. Fluorine, chlorine, bromine and iodine from group VII A. They have an oxidation state of 1-. Oxyacid: They are ternary compounds formed when an acidic oxide reacts with water, its structure consists of hydrogen, oxygen and a nonmetallic element; in these chemicals, nonmetal occupies the central position and has positive oxidation number. Oxygen will always have oxidation state 2- and Hydrogen 1+ (Mondragon et al, 2005 , p. 301). The general equation of an oxyacid is: X2On + H2O It is general formula is: HXO HXO Where: H= Hidrógeno, X= Element NonMetal, O= Oxygen, Examples: N2O5 + H2O H2N2O6 HNO3 Nitric oxide + water ( simplifying subscript) Nitric Acid SO2 + H2O H2SO3 Sulfur Dioxide + Water Sulfurous Acid Did you know that…? A binary compound is one which chemical formula is composed of two kinds of elements; for example, (CO) carbon monoxide, produced when we start vehicle engines; and a ternary compound is one which chemical formula is composed of three kinds of elements. For example, Fe (OH) 2, used in water purification of the metallurgical sector. HYDROXIDES Hydroxides have features like : They taste bitter They Turn litmus paper blue They feel Soapy when you touch them They Release hydroxyl ions when dissolved in water They are obtained as a product of reaction between a basic oxide and water: basic oxide + water hydroxide. They are ionic compounds whose link is established between a cation (metal) and one or more hydroxyl ions (OH-) (Cardenas et al, 2001, p. 185). The general equation of an hydroxide is: M2On + H2O M(OH)n Basic oxide + water Hydroxide Its general formula is: M(OH)n Where: M= Metal, n= Metal oxidation state , OH = hydroxyl ions Examples: K2O + H2O 2KOH Basic oxide + water Potassium hydroxide Fe2O3 + 3H2O 2Fe(OH)3 Ferric oxide + Water Ferric Hydroxide Learning activity Through this learning activity, you will strengthen your knowledge about the formation of the compounds already presented by analyzing the formulation of each. So that eventually you can classify them. In pairs, do the following exercises: Write in front of each of the compounds listed in Table 1 their corresponding classification: oxyacid, hydracid and hydroxide. COMPOUNDS CLASSIFICATION H2 + F2 HF (Hydrofluoric acid) MgO + H2O Mg(OH)2 (Magnesium hydroxide) H2 + S H2S (Sulphuric acid) Cl2O3 + H2O HClO2 (Chlorous acid) Al2O3 + 3H2O 2Al(OH)3 (Aluminum hydroxide) Cl2O7 + H2O HClO4 (Perchloric acid ) Table 1. Learning activity. Relationship of compounds and its classification. (Own Authorship , 2016) Solution: 1. 2. 3. 4. Hydracid Hydroxide Hydracid Oxyacid 5. Hydroxide 6. Oxyacid SALT FORMATION They have features like (Herrera et al, 1984 , p . 54): -In solid state, they do not conduct electricity (insulators). In liquid state, they are classified as soluble, slightly soluble and insoluble. - They are compounds produced when an acid reacts to a hydroxide, they can be divided into : Oxoacid salts It is produced from a tertiary compound formed by a metal, a nonmetal and oxygen Halid salt It is produced from a hydracid with a hydroxide formed by a metal and a nonmetal (halogen) Salts Figure 5. Classification of the salts . (Own Authorship, 2016) General equation of oxoacid salts: HXO + M(OH)n XMO Oxoacid + Hydroxide Oxoacid salt Its general formula is: XMO Where: Being X= non- metal which gives the name to the acid source, M = Metal replacing the hydrogen source of acid, and O = Oxygen. Examples: H2SO4 + Mg(OH)2 MgSO4 Sulfuric Acid + Magnesium hydroxide salt Halide salts general equation : HnX + M(OH)n XM Hydracid + Hydroxide Halide Salt Its general formula is: XM Where: X= Non-metal and M= metal Examples: HF + KOH KF Potassium fluoride HCl + Na(OH) NaCl Sodium chloride In this unit you should explain the uses of some compounds previously seen in the industry and at home. Begin with a brief introduction, which needs to be accompanied by several photos for greater understanding of the industrial context as students look at them. INDUSTRIAL AND DOMESTIC APPLICATIONS We will analyze different uses of some oxyacids, hydracids, hydroxides and salts on daily activities. For example: Hydrofluoric acid (hydracid) is used on the industry for glass or crystal preparation or carving. Equally, as catalyst on petrochemical industry and in some cases as dissolvent Nitric Acid is an Oxyacid used as lab reactive, it is used in fabrication of explosives such as nitroglycerine and trinitrotoluene, and it is used as fertilizer and as part of metallurgic processes. Sodium Hydroxide, is a white solid that absorbs quickly carbon dioxide and water; it has highly corrosive qualities, it’s used for neutralizing acids, Hydrolyze fats and making soap Sodium hypochlorite, is a salt, which is frequently used at home, also as oxidant in the water purification process. It ‘s also used as disinfectant. Did you know that…..? Sodium Hydroxide is frequently used in textile fibers, paper, detergent, and chemical products fabrication. Sulfuric acid is used in the making process of paint and pigments, synthetic fibers and dyes. It’s also used in the metallurgic industry. An exercise where students strengthen the concepts studied and thinks of their use at home is proposed, also where they identify products used at home, which contain some of the compounds seen previously; ln addition, they should describe and associate the compound to everyday use in their contexts. LEARNING ACTIVITY: The aim of this actitivty is to relate the concepts studied (Chemical compounds and nomenclature) to your familiar, school or neighborhood context (, Etc.) 1. Look for information about the uses of the next substances, use books or specialized web pages to help you; the information you will get from your research must be recorded in a table that will have to include: Classification, chemical formula and type of nomenclature. The following are the substances to check: a. Iron Hydroxide (III) b. Hydrobromic Acid c. Calcium Tetraoxosulfate (IV) 2. Share the obtained information by showing the table you made to your classmates and tal about the information it contains. Activity 2 S/K 3: Differentiates the various ways in which an acid or a hydroxide can be Students’ Material, named. Infography: The second activity addresses the issues about acids. To do this, the teacher can use the tables and examples given in the same way, so that the student have a better understanding. Initially, the teacher begins by explaining the topic with a brief explanation. NOMENCLATURE OF ACIDS (OXYACIDS HYDRACIDS) AND HYDROXIDES The nomenclature is responsible for naming chemical compounds according to the chemical function they represent; i.e: (hydracids, oxyacid and hydroxides). The rules will depend on the nomenclature system employed. Three types of nomenclature will be analyzed (Figure 1). Two of them (except the traditional nomenclature) proposed by the IUPAC ( International Union of Pure and Applied Chemistry) (Philips et al, 2000, p 477), which standardizes and recommends rules to follow for some types of nomenclature: To name chemical compounds, it is necessary to know the valences with which these elements can work according to their oxidation states. In Figure 4, the main oxidation numbers of elements are presented along with the group in the periodic table: In the case of the compounds in question (hydracids, oxyacids and hydroxides), the compounds may be appointed as follows : Note: more information after the text Activity 3 S/K 5: Explains the acid rain and inquires about the natural and human processes which generate it. S/K 6: Inquires about the weathering process. This unit presents descriptions of the weathering processes, acid rain and the involvement of the compounds seen in each of the processes. The first is explained from the point of view of contribution of human activities and the second is denoted as a natural process. A video is proposed as a way to support your work. The video is about acid rain and its formation. The chemical compounds seen here, not only exist in domestic or industrial products, some of them take part in lots of natural phenomena such as volcano eruptions, or in some cases, are produced by the irresponsible growing of human activity. In the next part, there will be two cases to analize (acid rain and weathering) about natural phenomena, which involve the chemical compounds seen here. Students’ Material, Infography and animation Acid Raind and Weathering ACID RAIN In Colombia, it is getting more frequent to see the acid rain phenomenon; sometimes, it is considered it only happens in big cities like Bogotá; however, this phenomenon has been registrated in cities like Medellín or Manizales; Please, watch the next video where the processes and characteristics of acid rain are described. You will see the chemical compounds that form it, the most frequent human activities that generate it and the formulation of possible solution to reduce its effects. https://www.youtube.com/watch?v =CUbq5MQ8Kd0.(INVESJOVEN XXI, 2011). Recovered from: https://www.youtube.com/watch?v=CUbq 5MQ8Kd0. As it is shown in figure 10, both vehicles and industries generate sulfur and nitrogen acids, these acids ascend to the atmosphere suffering chemical transformations and later mixing with water. In the clouds, the rain that contains the acid substances is formed, this rain will fall in form of humidity, snow and rain over the living beings and the ground in general. Learning Activity The main purpose of this activity is to get all the possible solutions, shown on the proposed video, to stop acid rain phenomenon produced by the human activities. 1. Watch the video about acid rain. (INVESJOVEN XXI, 2011) 2. Answer the next question: ¿According to the video, Which would be possible solutions to end this phenomenon? 3. Work with 3 classmates and share your opinion about the question in section 2; then choose 3 of the solutions presented on the video. Please, keep in mind those that are easy to implement and have the lower cost. 4. Share with your classmates the choices you made, you will have to take in count the use of words like (transmit, expand, mitigate, anthropic, introduce, transform or control) To finish present which are the weathering processes that occur in the nature. WEATHERING Use this data to generate reflection on students and provoke dialogue about what is familiar to them, maybe they have lived similar situations. Consider… Colombia also presents the acid rain phenomenon. It has happened up to now in Bogotá, Manizales, Medellín and Sogamoso (Boyacá). In figure 11, the different stages of ground development can be observed. The different horizons of ground start to form from mother rock weathering, subsequently, the first living organisms are instaled, contributing with organic substances and essential compounds, (Sinnya, 2010) The weathering process can be seen chemically or physically, however, in this section we will talk about the chemical characteristics of it. The earth is dynamic organism, and the weathering process occurs continuously on it. However, the importance of such a slow process is oftenly underestimated since rocks are in continuous weathering process. Abstract Abstract Assignment/ homework Homework Students’ Material, Infography This task includes the topics taught in activity 2 , the intention is to strengthen from an experiential task, which comes from their real life so that they demonstrate the skills obtained in the activity. Through a research task on the use of substances studied. Students relate the concepts (chemical compounds and nomenclature), integrating them in context, particularly at home. The ratio of the compound with products they use at home, such as facial or body creams, detergents, cleansers will be denoted, etc. Check with your classmates and family. For you to do this homewrok satisfactorily, it is necessary you review all the content in the LO presented in activity 2. The main objective is to make you you associate the studied concepts (chemical compounds and nomenclature) with your context (familiar, social or simply personal). In addition, It is necessary that you keep in mind the nomenclature involved and the relation Text of the compounds with home products like facial or body cream, detergent, cleaning products, etc. Now, read carefully the instructions and proceed to do your homework. 1. Look for information about hydracids, oxyacids, hydroxides, halide salts or oxysalts used in 3 products you find at home. You can check the labels of cleaning products, detergents, soap, facial cleaning cream, shampoo and other products of common domestic use. In these labels you will find the compound’s name on the ingredients section, it will be shown with the type of nomenclature that the product maker chose. The research must include: 1. Compound’s name according to the type of nomenclature shown in the label. 2. Chemical formula 3. Classification (Oxyacid, hydracid, hydroxide, halide salt or Oxysalt.) 4. Common use that is given to the product at home. (try to name the most uses you can) Example: On mouthwash label, the ingredients section shows ‘Sodium sulfate’. • Compound name: Sodium sulfate (stock nomenclature) • Chemical formula: Na2SO4 • Clasification: Oxysalt. • Home use: We use it as mouthwash after brushing our teeth or for refreshing our thoat when it is irritated. We prefer the green mint flavor. Solution: The student entrenches the concepts seen above and relates them in the home context, identifying products used at home that contain some of the compounds seen before. In addition, describes and relates the compounds to Evaluation/ Assessment Evaluation everyday use in his context. Below you will find an assessment. The Text purpose is to measure by your own means, the knowledge you acquired along the LO. To do this, you need to have revised completely the LO. Likewise, you will need to demonstrate your knowledge by answering the questions you will find below. Finally, it is key you have used the learning activities and aids offered. You will find 5 questions with different structures such as matching, completing, and closed questions. 1. Match the information in column A with the information in column B (Write in column B the corresponding number of column A in brackets) Column A They redden litmus paper. the Column B ( ) Oxyacid H2Te ( ) Hydracid H2CO3 ( ) Acids H2Te ( ) Oxysalt Ca(NO3)2 () Te + H2O 2. Complete: The phenomenon of _______________ _______________; is generated by human activities, the vehicles and industries release gases to the atmosphere such as:__________ __ __________ and __________ __ ___________; which, combined with water, generate rainfalls over the ground and living beings. 3. The MgBr2 is a halide salt, the correct way to name it is: a. Magnesic bromide b. Magnesium Bromide c. Magnesium dibromide d. All of the above 4. In the development of chemical weathering in rocks, some processes like these are involved: a. Oxidation, dissolution and hydrolysis. b. Weathering, sulfidation, Hydrolysis. c. Stonization, oxidation, dissolution. d. None of the above 5. Complete the table according to every item. Chrome hydroxide (II) Permanganic acid Ammonia Glossary Glossary ELECTROLYTE: Those species that conduct the electricity when they are in aqueous solution forms. They show an unnatural behavior regarding the colligative properties. The strong electrolytes are substances that conduct the electricity very well on diluted aqueous solutions. The electric current flows through the aqueous solution by ionic movement. ION: Electrically charged particle formed by an atom or molecule that is not electrically neutral. OXIDATION STATE: Oxidation state (OS) indicates the oxidation grade of an atom, which is part of a compound or another chemical species. Formally, it is the hypothetical electric charge the atom would have if all of its bonds with different elements were 100% ionic. ANION: Ion that has negative charge and comes from a negative element. Multimedia CATION: Ion that has positive charge and comes from an electropositive element. CATALYST: Body that causes the catalysis. It can refer to: (enzyme) In chemistry, the substance that, in a process called catalysis, modifies the speed of a chemical reaction. There are two types of catalysts, the ones that increase the speed of a reaction are called positive catalysts and the ones that reduce the speed are known as negative catalysts or inhibitors that can be grouped. Vocabulary box Vocabulary box Oxyacid: They are ternary compounds Multimedia formed when an acidic oxide reacts with water, its structure consists of hydrogen, oxygen and a nonmetallic element; in these chemicals, nonmetal occupies the central position and has positive oxidation number. Oxygen will always have oxidation state 2- and Hydrogen 1+ Hydracids: They are compounds formed when some non-metals (elements belonging to group VI A and VII A, with less oxidation. 1- and 2- ) react with hydrogen. Hydroxide: It is a diatomic anion with chemical formula OH-. It consists of an oxygen and hydrogen atom held together by a covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile and a catalyst. Hydrolysis: Is the reaction of any substance to water. In weathering, the silicate groups formed by silica suffer the hydrolysis process. Dissolution: Just as sugar dissolves on water, some minerals do as well. If a small quantity of acid is added, the corrosive potential of water grows. English review topic Bibliography English review topic Bibliography Oxidation: As metallic objects and steel oxidize when they are exposed to water; Magnesium, iron and sulfur oxidize in contact with water. Passive voice. Index CÁRDENAS S.Fidel A, GALVEZ. S. Carlos Text and hyperlink A. 2001. Chemistry and environment 1. Edition 2. Bogotá DC. Ed. Mc Graw Hill. HERRERA V. Severiano, BARRETO C Aura, TORRES D. Ignacio. 1984. Chemistry 1. Editorial Norma. 2ed. Bogotá. MONDRAGÓN M. César H, PEÑA G. Luz Yadira, SANCHEZ Martha, ARBELÁEZ E. Fernando. 2005. Inorganic chemistry. 2nd edition. Bogotá. Ed. Santillana. PHILIPS John S. Víctor S. STROZAK, Cheryl WISTROM. Chemistry concepts and applications. Ed. Mc Graw Hill. México. 2000. Nomenclature Oxyacids Nomenclature Description Examples It is named with the word "acid" preceded by the root 1. P (valences 3+ y 5+) of the nonmetallic element, indicating the valence with which it acts, as follows: P valence 3+ forms: P2O3 One valence: “ ... ic acid” Two valences: Traditional Lower valence: “ hypo … ous acid” Intermediate valence: “ … ous acid” Higher valence: “… ic acid ” Four valences: P valence 5+ forms: P2O5 P2O5 + H2O → HPO3 Lower valence: “ … ous acid” Higher valence: “ … ic acid” Three valences: P2O3 + H2O → HPO2 Phosphorous acid First valence: “ hypo … ous acid” Second valence: “ … ous acid” Third valence: “ … ic acid” Fourth valence: “per … ic acid” Phosphoric acid 2. Br (valences 1+, 3+, 5+, 7+) HBrO: hypobromous acid HBrO2: bromous acid HBrO3: bromic acid HBrO4: perbromic acid 3. Cr (valence 6+) H2CrO4: chromic acid Stock The Word acid preceded by the prefix that indicates the number of oxygens plus the word “oxo” followed word prefix indicating the number of atoms of the non-metallic element, followed by the root of the nonmetallic element in “ic” and Roman numerals indicating the valence . Oxygen prefix ( di ,tri, tetra) + oxo root element + ic ( valence element ) + Acid Systematic The nomenclature starts with the Word hydrogen followed by the prefix indicating the number of oxygen atoms, followed by the word oxo, plus the prefix indicating the number of atoms of the non-metallic element, followed by the root of the non-methane ending in ate and Roman numerals showing the valence of the non-metallic element. 1. HClO2: Dioxochloric (III) Acid 2. H2SO4: Tetraoxosulfuric (IV) Acid 3.H3PO4: Tetraoxophosphoric(V) Acid 1.H2SO2: Hydrogen dioxosulfate (II) 2.H2SO3: Hydrogen trioxosulfate (IV) 3. H2SO4: Hydrogen tetraoxosulfate (VI) Hydrogen + prefix oxygen + Oxo + root element + ate + ( valence X) Did you know that...? Hypobromous acid (HBrO): Important compound in the manufacture of deodorants. Tetraoxosulfuric (IV) Acid (H2SO4): Important in the manufacture of detergents and explosives Hydracid Nomenclature Nomenclature Description 1. Place the symbol of Hydrogen on the left and nonmetal on the right, since it has a negative oxidation number. 2. The states of oxidation are exchanged, placing them as subscripts with no load. Traditional In the case of hydracids, both nomenclatures coincide in the following aspects 3. Subscript 1 is not written. 4. When in gaseous state, they are named by adding the ending "ide" to the non-metal name, preceded by the word hydrogen. 5. Hydracids disolved in water are named under the Word "Acid", preceded by the name of the metal, the prefix "Hydro", and the sufix "ic" Examples In gaseous state: HCl = Hydrogen chloride HI = Hydrogen iodide H2Te = Hydrogen telluride In combination with water: HCl= hydrochloric acid HI= hydroiodic acid H2Te= hydrotelluric acid Did you know that...? There are some hydracids with their own name, which are not tied to some sort of nomenclature; they are considered hydracids because when dissolved in water, they do not produce acidic solutions (Philips et al, 2000, p 371). They are presented in Table. Common or systematic name Formula Water H2O Ammonia NH3 Phosphine PH3 Arsine AsH3 Stibnite SbH3 Methane CH4 Silane SiH4 Hydroxide Nomenclature Nomenclature Description It begins with the element and the word "hydroxide" taking into account the valence with which it acts. One valence "ic… Hydroxide" Two valences: Traditional Lower valence: "...ous Hydroxide" Higher valence: "...ic Hydroxide" Three valences: First valence: "hypo...ous Hydroxide" Second valence: "...ous Hydroxide" Third valence: "... ic Hydroxide" Four valences: First valence: "hypo...ous Hydroxide" Second valence: "...ous Hydroxide" Third valence: "... ic Hydroxide" Fourth valence:"per...ic Hydroxide" Examples 1. Mg2+ + (OH)1- → Mg(OH)2 Magnesic Hydroxide 2. Pt2+ + (OH)1-→ Pt(OH)2 Platinous Hydroxide Pt4+ + (OH)1- → Pt(OH)4 Platinic Hydroxide 3. V2+ + (OH)1-→ V(OH)2 Hypovanadous hydroxide V3+ + (OH)1- → V(OH)3 Vanadous Hydroxide V4+ + (OH)1-→ V(OH)4 Vanadic Hydroxide V5+ + (OH)1- → V(OH)5 Pervanadic Hydroxide It begins with the metallic element and the valence in Roman numerals in parentheses element and the word "hydroxide" Stock 1. Hg(OH): Mercury (I) Hydroxide 2. Sn(OH)2: Tin (II) Hydroxide 3. Be (OH)2 :Beryllium hydroxide When the metallic element only has a valence, it is not indicated in Roman numerals. It has only one valence. For this reason, it is not indicated 1.Fe(OH)3: Iron trihydroxide Systematic The numerical prefixes (di-, tri-, tetra, etc.) are placed before the word hydroxide . 2. Be(OH)2: Beryllium dihydroxide Did you know that...? Potassium hydroxide K(OH): Is used in soaps, alkaline batteries and cleaning products such as degreasers. Oxoacid salts nomenclature Description Nomenclature It is named similar to oxyacid acid from which way the ous is replaced for ite, and the termination ic is replaced for ate, preceded by the metal element completed: Traditional Stock Systematic -ic (if it has 1 valence). -ous, - ic (if it has 2 valences) It is similar to the traditional nomenclature but preceded by the metallic element, indicating a valence with which acts with Roman numerals in parentheses. It is called with the name of the anion preceded by the name of the cation and followed by the prefix, Examples 1. NaClO2 Sodium chlorite It comes from chlorous acid (HClO2); ous is substituded for ite, preceded by the metal element finished in ium is replaced, because it only has 1 valence. 2. Fe2(SO4)3 Ferric sulfate Derived from the sulfuric acid (H2SO4); ic is replaced by ate, preceded by the metal element ending in ic , since iron has two valences, in this case it acts with the higher valence 3. 1. Fe2(SO4)3 Iron (III) sulphate 1. FeSO2 which indicates the number of atoms of nonmetallic elements. The number of ions is indicated by greek prefixes (bi, tri, tetra, penta, hexa, hepta, octa, etc.) Iron Dioxosulfate (II) 2. FeSO3 Iron Trioxosulfate (IV) 3. FeSO4 Iron Tetraoxosulfate (VI) Did you know that...? Ferric sulfate (Fe2(SO4)3) It has a very wide field of applications; for the production of colorants in paints, medically it is used as an astringent, in horticulture it is used to remove the mosses. Nomenclature of halide salts Nomenclature Traditional Stock Systematic Description The ending ide is added to the non-metal, the greek root of metal (ous, ic) is preserved. The non-metal ide element of origin is added, the valence of the metal is kept in parentheses. Prefixes di, tri, tetra, etc. are preserved; ide is added to the root of the non-metal, and the name of the metal is added. Examples 1. FeCl3 Ferric chloride 2.CaBr2 Calcium bromide 1. FeCl3 Iron (III) chloride 2. CaBr2 Calcium Bromide 1. FeCl3 Iron trichloride 2. CaBr2 Calcium dibromide
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