TABLE I. ALKANES AND CYCLOALKANES
a) Gases and Liquids (Listed in order of increasing b.p.* )**
No
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
Name
Methane
Ethane
Propane
Cyclopropane
2-Methylpropane (Isobutane)
n-Butane
2,2-Dimethylpropane (Neopentane)
Cyclobutane
1,1-Dimethylcyclopropane
2-Methylbutane
trans-l ,2-Dimethylcyclopropane
Ethylcyclopropane
n-Pentane
Methylcyclobutane
m- 1 ,2-Dimethy (cyclopropane
Spiropentane
Cyclopentane
2,2-Dimethylbutane
1,1,2-Trimethylcyclopropane
2,3-Dimethylbulane
2-Methylpentane
3-Methylpentane
1 ,2,3-Trimethylcyclopropane
n-Hexane
Ethylcyclobutane
Methylcyclopentane
2,2-Dimethylpentane
2,4-Dimethylpentane
Cyclohexane
2,2,3-Trimethylbutane
3,3-Dimethylpentane
1 ,1-Dimethylcyclopentane
2,3-Dimethylpentane
2-Methylhexane
(ran.s-l,3-Dimethylcyclopentane
c/s-l,3-Dimethylcyclopentane
3-Methylhexane
lrans-l ,2-Dimethylcyclopentane
3-Ethylpentane
Quadricyclane (Quadncyclo [2,2, 1 ,02 6,03 5 ]
heptane)
n-Heptane
2,2,4-Trimethylpentane
cis-l ,2-Dimethylcyclopentane
Methylcyclohexane
Ethylcyclopentane
1,1,3-Trimethylcyclopentane
2,2-Dimethylhexane
2,5-Dimethylhexane
l,(ra/w-2,cis-4-Trimethylcyclopentane
2,4-Dimethylhexane
2,2,3-Trimelhylpentane
l,rrans-2,o.v-3-Trimethylcyclopentane
3,3-Dimethylhexane
2,3,4-Trimethylpentane
1,1,2-Trirnelhylcyclopentane
2,3,3-Trimethylpentane
2,3-Dimethylhexane
3-Ethyl-2-methylpentane
Boiling
point, °C
Melting
point, *C
-161 49
-8863
-4207
-3286
-11 73
-050
9503
1308 7 4 ',125
2063
27852
29
3594
36074
363
37
38977
49262
49741
56 7 ?M
57988
60271
63282
65 7755
6874
7064
71 812
79 197
805
80738
80882
86064
87846
89784
90052
90773
91 725
91 850
91 869
93475
98
-18248T
-18327 7
-18769 T
-12742
-1596
-13835
-1655
-80
- 108 96
-1599
98427
99238
99532
100934
103 466
104893
10684
109 103
10929
109 429
109 841
1102
1 1 1 969
113467
113729
11476
115607
11565
•Derivative data given in order m p , crystal color, solvent from which crystallized
*T = triple point, S = at saturation pressure
-14941
-129721
-1409
- 107 06
-93 879
-9987
-128538
-15367
-95 348
-14285
-142455
-123811
-119242
6554
-24912
-13446
-69795
-118276
-133702
-133975
-11758
-118604
-9061
- 107 38
-53892
-126593
-138446
-14244
-121 18
-91 20
-13078
-11227
-112705
-126 1
-1092T
-21 64
-10070
-11496
nD°
3326s
342s
37520°
3668
35373
3713
3786
35748
3830
3822
41200
40645
36876
3848 1 9 S
37495
37145
37652
3945"
37486
4020
4097
38215
38145
42623
38944
39092
41356
39196
38485
40894
41074
38864
41200
39339
4804
38764
39145
42217
42312
41981
41119
39349
39246
41060
39534
40295
4138
40009
40422
42298
40750
40113
40401
Df
05005s
0 720-™
0 5572s
0 5788s
0 5910s
0 7038°
06589
061967
06769
06839
0 62624
06933
06928
0755
0 74538
064916
06822 I9S
066164
065315
066431
0 6946l8
0 65937
07280
074864
0 67385
0 67270
0 77855
069011
0 69327
075448
0 69508
0 67859
074479
0 74880
068713
075144
069816
0 68376
0 69192
0 77262
0 76939
076647
0 74825
0 69528
0 69354
0 74727
070036
071602
07535
07100
071906
0 77252
072619
071214
071932
TABLE I. ALKANES AND CYCLOALKANES
a) Gases and Liquids (Listed in order of increasing b.p.*) (Continued)
No
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
Name
l,as-2,trans-4-Tr\mettiylcyclofeataae
l,fi.v-2,(ra/w-3-Triitiethylcyclopentane
2-Methylheptane
4-Methylheptane
3,4-Dimethylhexane
l,ru-2,m-4-Trimetliylcvclopentane
3-Ethyl-3-methylpentane
3-Ethylhexane
3-Methylheptane
Cycloheptane (Suberane)
trans- 1 ,4-Dimethylcy clohexane
1,1-Dimethylcyclohexane
ru-M-Dimetliylcyclohexane
fra/tt-l-Ethyl-3-methylcyclopentane
(rani-l-Ethyl-2-methylcyclopentane
cw-l-Ethyl-3-methylcyclopentane
1-Ethyl-l-methylcyclopcntane
2,2,4,4-Tetramethylpentane
l,CM-2,cw-3-Trimethylcyclopentane
trans-l ,2-Dimethy Icyclohexanc
2,2,5-Trimethylhexane
CM-l,4-Dimethylcycl0hexane
/ra/jj-13-Dimcthylcyclohexane
n-Octane
Isopropylcyclopentane
2,2,4-Trimethylhexane
ro-l-Ethyl-2-methylcyclopentane
as-l ,2-Dimethylcyclohexane
2,4,4-Tnmethylhexane
n-Propylcyclopentane
2,3,5-Trimerhylhexane
Ethylcyclohexane
2,2-Dimethylheptane
2,2,3,4-TetramethylpCTtane
2,4-Dimethylheptane
Methylcycloheptane
2,2,3-Trime(hvlhexanc
4-Ethyl-2-methylhexane
3-Ethyl-2,2-dimcthylpentane
4,4-Dimethvlheptane
2.6-Dimethylheptane
2,5-Dimethylheptane
3,5-Dimethylheptane
Bicyclo[4.2.0]octane
m-Bicyclo[3.3.0)octane
2,4-Dimethyl-3-ethylpentane
1 , 1 ,3-Trimeth v Icyclohexane
33-Dimethylheptane
2,2,5,5-Tetramethylhexane
23J-Trimethylhexane
3-E(hyl-2-methylhexanc
(rara-13.S-Trimethylcyclohexane
2.3,4-Trime(hylhcxane
as-l ,3,5-Trimethylcyclohexaiie
/ran.s-l,2,4-Trimethylcyclohexane
2,2,3,3-Tetramethylpentane
4-Ethyl-3-meehylhexane
3J,4-Trimcthylhexane
23-Dimethylheptane
Boiling
point, °C
116731
1175
117647
117709
117725
118
118259
118534
118925
118 20
119351
119543
120088
1208
121 2
121 4
121 522
122284
1230
123419
124084
124 321
12445
125665
126419
12654
128050
129 728
13038
1308
131 34
131 783
13269
133016
1335
133 5
1336
1338
13383
1352
13521
1360
1360
1360
136-65
13673
137-8
1373
1375
13768
138
138 5-9"4
1390
140-0 5 752
140-1
140 274
1404
14046
1405
'Derivative data given in order m p , crystal color, solvent from which crystallized
Melting
point, "C
-13255
-112
-10904
-120955
-9087
-1205
-798
-36962
- 33 495
-75573
-108
- 143 80
-6654
-11643
-88 194
-10578
- 87 436
-90 108
-56795
- 1 1 1 375
-120
- 105 95
-50023
-11338
-1187
-1278
- 1 1 1 323
-1130
-121 09
-992
-1029
-1222
-11680
-99
-101 2
ng>
41855
4218
39494
39792
40406
422
40775
40162
39848
4449
42090
42900
42294
4186
4219
4203
42718
40694
4262
42695
39972
42966
43085
39743
42582
4033
42933
43596
40745
4266
4061
43304
4016
41472
4033
4410
4105
4068
4123
4076
4007
4038
4067
4613
4595 "
4137
4362
4085
40550
4141
4120
42740H
4144
43010H
43121 H e
42360
416
14178
14085
Df
0 76345
07704
0 69792
070463
071923
0766
0 72742
071358
0 70582
0 8275°
0 76255
078094
076603
07619
07690
07724
078093
071947
07792
077601
0 70721
0 78285
0 78472
0 70252
0 77653
07156
0 78522
0 79627
072381
07761
07219
0 78792
07105
0 73895
0716
08052
07292
0723
07348
0725
07089
0715
0723
08573
0 86382S
07379
0 78682S
0725
071875
0738
0731
07720
07392
07773
07813
0 75666
0742
07454
07260
TABLE I. A L K A N E S AND C Y C L O A L K A N E S
a) Gases and Liquids (Listed in order of increasing b.p.*) (Continued)
No
118
U9
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
1 38
139
140
141
142
143
144
145
146
147
148
149
150
151
152
153
154
155
156
157
158
159
160
161
162'
163
164
165
166
167
168
169
170
171
172
173
174
175
176
Name
3,4-Dimethylheptane
3-Ethyl-3-methylhexane
4-Ethylheplane
2,3,3,4-Tetramethylpentane
23-Dimethyl-3-ethylpentane
»ran.s-l,2,3-Triniethylcyclohexane
l-Isopropyl-3-methylcyclopentane(Pulegan)
4-Methyloctane
l-Isopropyl-2-methylcyclopentane
3-Ethylheptane
2-Methyloctane
nj-l,2J-Trimethylcyclohexane
3-Methyloctane
2,4,6-Trimethylheptane
cu-l,2,4-Trimethylcyclohexane
3,3-Diethylpentane
2,2-Dimethyl-4-«thylhexane
2,2,4-Trimelhylheptane
2,2,4,5-Tetramethylhexane
2,2,5-Trimetbylheptane
2,2,6-Trimethylheptane
2,23,5-Tetramethylhexane
Nopinane (7,7-Dimethylbicyclo[3 1 1 [heptane)
lram-l-Elhyl-4-nie(hylcyclohexane
Cyclooctane
l-Ethyl-2-methylcyclohexane
n-Nonane
l,3J-Trimethylbicyclo|2.2.1)heptane(Fenchane)
rrans-l-Ethyl-4-methylcyclohexane
ns-1,1 J,5-Tetramethylc>clohexane
oj-l-Ethyl-4-methylcyclohexane
2,5,5-Trimethylheptane
2,4,4-Tnmetbylheptane
23,3,5-Tetramethylhe*ane
2,2,4,4-Tetramethylhexane
Isopropylcydohexane
1 ,M3-Tetramethylcyclohexane
2,23,4-Tetramethylhexane
2,2-Dimethyloctane
3-Ethyl-2,2,4-trime(hylpentane
33,5-Trimethylheptane
2,3,6-Trimethylheptane
2,4-Dimethyloctane
</,/-( is-l-Ethyl-3-methylcyclohexane
</,/-2,5-Dimethyloctane
1 ,1 3,5-Tetramethylcyclohexane
n-Butylcyclopen(ane
n-Propylcyclohexane
2,3,5-Trimethylheptane
2,5-Dimethyl-3-eIhylhexane
2,4,5-Trimethylheptane
2,4-Dimethyl-3-isopropylpentane
2,2,3-Trimethylheptane •
2,4-Dimethyl-4-ethylhexane
2,2-Dimethyl-3-ethylhexane
2,23,4,4-Pentamethylpentane
1 , 1 ,3,4-Tetramethy Icyclohexane
S-Ethyl-2-methylheplane
2,7-Dimethyloctane
Boiling
point, °C
1406
1406
141 2
141 551
142
142 3 5792
142 4
14248
142 5"9
1430
14326
144-6753
144 18
1448
146
146 168
Melting
point, °C
4111
4142
-102 123
-1132
-804
-1076
-33 11
147
1477
1478
148
1482
1484
1497.7
14905- 15
150"°
150 2
15081
151 2
151 69
-808
14(43)
-53519
1524-5
15255 60
1528
153
153
1533
1545
-898
1548-50
1549
155
1553
1556
1557
1558 60
15597
156-8
1564 5
15656
156724
157
157
157
157
158
158
159
1593
1595-61
1597
1599
'Derivative data given in order m p , crystal color, solvent from which crystallized
nff
- 107 985
-9490
4096
42222
419
43582 He
4236
4061
4279
4093
4031
43682He
4062
4071
43209
42051
4131
4092
41318
409
4059
4142
4641
4304
4586
432
40542
44714
4382
4319
4374
4136
412
4196
4208
44095
4374
4226
4082
4223
4170
4125
1 4090
1 4432
1 4160
4370
4316
43705
416
416
4160
42463
417
419
420
43069
4380
4134
4086
Dl"
07314
0741
0730
075473
0754
07914
0 773022
07199
07792
0727
07134
07930
07207
07225
0786
0 75359
0733
07275
073546
0726
07195
07378
08611H
07798
08349
0784
071763
08345
07972
07813
07969
07368
0733
0746
07470
080232
07936
07548
07245
07571
07428
07345
0 725918
08094
07370
07929
07846
079360
0741
0741
0741
0 75830
07420
0747
0749
0 76703
07976
0736
07242
TABLE I. A L K A N E S AND C Y C L O A L K A N E S
a) Gases and Liquids (Listed in order of increasing b.p.*) (Continued)
No
177
178
179
180
181
182
183
184
185
186
187
188
189
190
191
192
193
194
195
196
197
198
199
200
201
202
203
204
205
206
207
208
209
210
211
212
213
214
215
216
217
218
219
220
221
222
223
224
225
226
227
228
229
230
231
Name
3,6-Dimethyloctane
3,5-Dimethyloctane
4-Isopropylheptane
2,3,3-Trimethylheptane
4-Ethyl-2-methylheptane
2,6-Oimethyloctane
2,2,3,3-Tetramethylhexane
(raw-l-Isopropyl-4-methylcyclohexane
(/)-Menthane)
4,4-Dimethyloctane
2,3.4, 5-Tetramcthylhexane
S-Ethyl-3-methylheptane
3,3-DimethyIoctane
4,5-Dimethyloctane
3,4-Diethylhexane
4-Propylheptane
l,l,4-Trimethylcycloheptane(Eucarvane)
fra«.s-l,2,3>5-Tetramethylcyclohexane
2,3,4,4-Tclrame(hylhcxane
2,3,4-Trimethvlheptane
3-Isopropyl-2-methylhexane
2,2,7-Trimethylbicyclo[2.2.1]heptane(a-Fenchane)
3-Ethyl-3-methylheptane
2,4-Dimethyl-3-«thylhexane
3,4.4-Trimethylheptane
3,3,4-Trimethylheptane
3,4,5-Trimethylheptane
23-Dimethyl^-ethylhexane
1 -Methyl-3-propylcyclohexane
2,3-Dimethyloctane
dJ-Pinane
2,3,3,4- Telramethylhexane
3,3-DimeHiyl-4-ethylhexane
5-Methylnonane
4-Methylnonane
3-Ethyl-2-methylheptane
3,4-DimethyIoctane
d-a-Pinane
^,/-l-Isopropyl-3-methyicyclohexane
(</,/-m-Menthane)
2,2,3,3,4-Pentamelhylpc'ntane
//•ani-l,2,4,S-Tetramethylcyclohexane
3,3-Diethylhexane
2-Methylnonane
rf-l-Isopropyl-3-methylcyclohexane
((/-m-Menthane)
3-Ethyl-4-methylheptane
4-Ethyl-3-methylheptani'
4-EthyM-tncthylheptanc
/-/J-Pinane
3-Methylnonane
3-Ethyloctane
4-Ethyloctane
3-Ethyl-2,2,3-trimethylpentane
/-l-Isopropyl-3-methylcyclohexane (/-m-Menthane)
cis-l-Isopropyl-4-methylcyclohexane
(m-^-Menthani1)
c«-l,2,3,5-Tetramethylcyclohexane
2,3-Dimethyl-3-ethylhexane
Boiling
point, °C
Melting
point, °C
<
160
160
160
160
160
160-05
1603
161
1
1
1
1
1
1
1
1
161
1 4144
161
161
1 424
1 414
1 4165
14173
1 420
1 4150
1 4420
1 44657 He
1 4270
1 421
1 421
1 4590
1 4208
161 2
162
162
162
162 3"°
162 4
1622
163
163
1 6 3 5 45 7 5 3
1638
164
164
164
164
164
164-5(171 3)
1644 46 7 6 4
4145'"
413
417
4202
413
4113
42818
4393
1 424
1 424
1 424
1 424
1 424
14377
1 4152
1 4609
1 4297
D,'
07363
0736
0741
07488
0736
07285
0 76446
0792
07347
0757
0737
07390
07458
0754
07364
08011
08140
07639
0751
0751
08579
07501
0759
0757
0757
1 4122
1 4123
1 418
1 4182
1 4630
1 4424
0759
0759
0 789521
07377
08551
07694
0764
07326
07323
0746
0746
08560
0 796524
167
1
]
1
1
1
078009
08100
0767
07281
0811623
167
167
167
167 5-8 748
1678
168
168
168
168
1685
1 422
1 422
1421
1 4605
1 4125
1 416
1 416
1 436
1 4358
1 4515
0753
0753
0752
08567
07334
0740
0740
0781
07938
0816
1 44847He
1 427
08166
0765
1645 5 0
1646
165
165 1
1657
166
166
166 65 7 6 2
1 427
-877
-987
166 7
166 1
1662-80
1663
1668
168-70762
169
•Derivative data given in order m p , crystal color solvent from which crystallized
-745
-848
43606
44446He
428
4099
44623
TABLE I . A L K A N E S A N D C Y C L O A L K A N E S
a) Gases and Liquids (Listed in order of increasing b.p.*) (Continued)
No
Boiling
point, °C
Name
232 l-Isopropyl-4-methylcyclohexane
(p-Menthane)
233 3,4-Dimethyl-3-ethylhexane
234 3,3,4.4-Tetramethylhexane
235 Cyclononane
236 l-lsopropyl-2-methylcyclohexane(o-Memhane)
237 m-l,2,4,5-Tetramethylcyclohexane
238 1-Methyl-l-propylcyclohexane
239 /t-Decane
240 I-Methyl-4-propylcyclohexane
241 l-Methyl-2-propylcyclohexane
242 /i-Pentylcyclopentane
243 n-Butylcyclohexane
244 rrani-Decahydronaphthalene((raM-Decalin)
245 Isoamylcyclohexane
246 as-Decahydronaphthalene(as-Decahn)
247 n-Undecane (n Hendecane)
248 Cyclodecane
249 n-Pentylcyclohexane
250 n-Hexylcvclopentane
251 9-Methyl-;ra/n-decahydronaphthalene
252 l,l(l-[)iitiethyl-/rattv-decahydronaphthalene
253 9-Methyl-m-decahydronaphthalene
254 H-Dodecane
255 1,10-Dimethyl-m-decahvdronaphthalene
256 n-Hexylcyclohexane
257 n-Heptvlcyclopentane
258 9-K(hyl-/ra«A-decahydronaphthalenf
259 9-Ethyl-cw-decahydronaphthalene
260 l-Methyl-frans-decahydronaphthalene
261 n-Tridecane
262 Bicyclohexyl
263 «-Octylcyclopenlane
264 w-Heptvlcyclohexane
265 n-Tetradecane
266 n-Nonylcyclopentane
267 n-Octylcyclohexane
268 n-Pentadecane
269 n-Decylcyclopentane
270 n-Nonylcyclohexane
271 fl-Undecylcyclopentane(n-Hendecylcyclopentane)
272 n-Decylcyclohexane
273 2-Methylheptadecane
274 fl-Dodecylcyclopentane
275 n-Undecylcyclohexane (n-Hendecylcyclohexane)
276 n-Tridecylcyclopentane
277 n-Dodecylcyclohexane
278 rt-Tetradecylcyclopentane
169 70
97
171
171'"
172
174 123
1743-7 1
175 5 6 0 7 f c
180 60 10
180947
18725
193
19569
19589
201
2028
-29661
-83
-74725
-3040
-4301
- 25 594
96
-575
203
205.77'"
213 83'"
215 85'°
2 1 6 2 7 8 , 5 1 84'
220,8899"'
2240,920"'
224
225 9306'"
233 99'°
235, 101'°
23544 6635'
236 5 7 5 , 100'°
243
244
23557,8013'
262
264
27063,9326'
2793
-9 587 (-12)
-43
-5392
3 5-40
5863
9926
282
296
299
3 1 1 , 178 5 1 5
312
316
327
331
341
'Derivative data given in order m p , crystal color, solvent from which crystallized
o
1 4375"
170
170
170-2
n
n 20
58
5
125
9
431
4368
4328"
447 "
44647 He
4440
41189
4393
4468 ">
4358
44075
4695
4423
4810
41716
4692
4437
4392
4631
4659
4804
42160
4812
4462
4421
466
480
4270
4256
4795
4446
4484
4289
4467
4503
4319
44862
4519
4503
45338
4394"
4518
4547
4531
4559
4543
Df
07929
0772
07824
08534' 5 '
08135"
08122
08101
0 73005
0798
08130"
07912
079918
08699
08023
08965
074017
08577 2 0 4
08037
07965
08620
08633
08910
0 74869
08896
08076
08010
08610
08860
07564
08848
08048
08109
07628
08081
08138
07685
081097
08163
08135
081858
07838' 5
08158
08206
08178
08223
08196