Name_____________________________________________________period________ Unit 14 worksheet: acids/bases 1. Name each of the following and label them as a weak/strong acid or weak/strong base b. Ca(OH) 2 a. H 3 PO 4 a.Phosphoric acid, weak d. nitric acid, strong c. Al(OH) 3 d. HNO 3 b.calcium hydroxide, strong base e. ammonia, weak base e. NH 3 f. LiOH c. aluminum hydroxide, weak f. lithium hydroxide, strong 2. What are some properties of acids? Taste sour 3. What are some properties of bases? Taste bitter, slippery 4. Explain the difference between a monoprotic , diprotic and triprotic acid and give an example of each. Monoprotic has one H (HCl), diprotic has 2 H (H 2 SO 4 ), triprotic has 3 H (H 3 PO 4 ) 5. Which of the following has the highest concentration of [H+]? 0.1 M HCl or 0.1 M HF 6. Which of the following has the highest concentration of [H 3 O+]? 2.0 M HNO 2 or 2.0 M HBr 7. What is the [H+] in each? a. 0.5 M HCl 0.5 M b. 0.002 M HNO 3 0.002 M 8. What is the [OH-] in each? a. 0.5 M NaOH 0.5M b. 0.03 M Ca(OH) 2 0.06M HCN + H 2 O ↔ H 3 O+ + CNHCl H+ + Cl10. Which of the solutions has the lowest pH? 2.0 M HCl, 3.0 M HBr, 4.0 M HNO 3 , 4.0 M HF 9. 11. Which of the solutions has the highest pH? 2.0 M HCl, 3.0 M HBr, 4.0 M HNO 3 , 4.0 M HF 12. Which of the solutions has the lowest pH? 2.0 M NaOH, 3.0 M KOH, 4.0 M LiOH, 4.0 M NH 3 13. Which of the solutions has the highest pH? 2. 0 M NaOH, 3.0 M KOH, 4.0 M LiOH, 4.0 M NH 3 14. What is the pH of a 1 x 10-3 M HNO 3 solution? 3 15. What is the pH of a 0.0034 M HNO 3 solution? 2.5 16. What is the pH of a 1 x 10-2 M NaOH solution? 12 17. What is the pH of a 0.0054 M NaOH solution? 11.7 18. What is the hydrogen ion concentration of a solution with a pH of 5? Is it an acid or a base? 1 x 10-5, acid 19. What is the hydrogen ion concentration of a solution with a pH of 6.63? Is it an acid or a base? 2.3 x 10-7 M acidic 20. What is the hydroxide ion concentration of a solution with a pH of 8? Is it an acid or base? 1 x 10 -6 M basic 21. What is the hydroxide ion concentration of a solution with a pH of 3.4? Is it an acid or base? 2.51 x 10-11, acid 22. Which of the following solutions would have the lowest pH? 0.10 M HCl, 0.009 M HNO 3 , 0.340 M HBr 23. What happens to the pH when the hydrogen ion concentration increases? decreases 24. Determine the pH of the following solutions and label if they are acidic or basic a. [H+] = 1 x 10 -6 b. [OH-] = 1 x 10 -3 c. [H+] = 2.3 x 10 -3 6, acid 11, base 2.64, acid e. pOH = 11 f. pOH = 3.4 d. [OH-] = 3.4 x 10 -6 8.5; basic 3, acid 10.6, basic + 25. Determine the [H ] for the following solution and label if they are acidic or basic a. [OH-] = 1 x 10 -8 b. [OH-] = 2.3 x 10 -6 c. pH = 2 -6 1 x 10 , acidic 4 x 10 -9 , basic 1 x 10 -2, acidic d. pOH = 5 e. pH = 3.4 f. pOH = 4.2 1 x 10 -9, basic 4.0 x 10 -4, acidic 1.6 x 10 -10, basic 26. How many mL of 0.340 M HBr would be needed to titrate 14.91 mL of 0.265 M Mg(OH) 2 ? 23.2 mL 27. What is the concentration of sulfuric acid solution if 34.1 mL of it is needed to reach the endpoint when titrated with 14.3 mL of 0.876 M aluminum hydroxide? 0.55 M 28. What is the concentration of a hydrobromic acid solution if 13 mL are needed to react with 34 mL of a 0.89 M sodium hydroxide solution? 2.3 M Review: 29. a. Write a balanced reaction when magnesium metal reacts with hydrobromic acid Mg + 2HBr MgBr 2 + H 2 b. How many moles of each product are produced if 5.4 mol of magnesium react? 5.4 mol of magnesium bromide and 5.4 mol of hydrogen 30. a. Write a balanced reaction when nitric acid react with aluminum hydroxide 3HNO 3 + Al(OH) 3 3H 2 O + Al(NO 3 ) 3 b. How many grams of nitric acid are needed to react with 2.3 mol of aluminum hydroxide? 430 g 31. Tell the shape of each, tell if they are polar or nonpolar, tell what intermolecular forces hold them together, and tell which one would have the lowest boiling point. a. H 2 O b. NH 3 c. CH 4 Bent trigonal pyramidal tetrahedral Polar polar nonpolar Hydrogen bond and LD hydrogen bond and LD London dispersion CH 4 has the lowest boiling point 32. What is the difference between and exothermic and endothermic reaction? Exothermic releases energy and feels warm; endothermic absorbs energy and feels cold 33. H 2 + F 2 <-> 2HF ΔH -538 kJ a. Will raising the temperature cause the amount of product to increase? No b. How will the equilibrium shift if hydrogen is added to the reaction? right c. How will the equilibrium shift if HF is removed from the reaction? right d. What will happen to the amount of hydrogen if the temperature is decreased? decreases e. Will the temperature of the surroundings increase or decrease as the reaction moves forward? increase 34. If 1 mol of each of the solutes listed below is dissolved in 1 kg of water, which solute will have the greatest effect on the freezing point of its respective solution? a. KBr b. C 6 H 12 O 6 c. MgCl 2 d. CaSO 4 35. d
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