Experimental foundations of subatomic physics A. Andronic X-rays, radioactivity, the electron • Prelude • X-rays • Radioactivity • The electron Experimental knowledge at end of XIXth century A. Andronic the gravitational field Galileo’s falling bodies Newton’s Principia, 1687; Halley’s comet predictions, 1705 enough (so to say:) to get the Rosetta probe (controlled from Darmstadt:) to travel 10 years and 7 billion km to meet (at 10 km distance) a comet’s nucleus 4 km long and land on it ...for the first time ever on a comet 1: 03.04, 10: 08.14, 11: 11.14, 12: 12.15 Comet 67P, 19 http://en.wikipedia.org/wiki/Rosetta_(spacecraft) Sep. 2014 Experimental knowledge at end of XIXth century A. Andronic the electro-magnetic field Faraday, Maxwell, Hertz; radio: Marconi, Braun, Nobel Prize 1909 glows in rarefied gases (first observed by Faraday, 1838) under high voltages (Rühmkorff coil) in Geissler / Crookes tubes (10−6 atm): cathode rays main line of research (Hittorf, Goldstein; Lenard, Nobel Prize, 1905) http://en.wikipedia.org/wiki/Crookes_tube Experimental knowledge at end of XIXth century A. Andronic • Chemical elements (classification, Mendeleev, 1869) caloric capacities, photoelectric effect (discovered by Hertz) absorption and emission lines (Fraunhofer; Kirchhoff, Bunsen; Balmer) • Law of energy conservation (Joule, Mayer, Helmholtz) Planck’s PhD Thesis: “The assumption of absolutely indivisible components of matter contradicts the principle of conservation of energy” momentum was found to be conserved too Experimental knowledge at end of XIXth century A. Andronic ...and then there was light Isaac Newton (1642-1726) imagined it as corpuscles, Christiaan Huygens (1629-1695) as waves reflexion, refraction, diffraction, dispersion Thomas Young (1773-1829), Augustin-Jean Fresnel (1788-1827), Josef von Fraunhofer (1787-1826), Gustav Kirchhoff (1824-1887) What is just about to come A. Andronic ...was anticipated by Newton in Opticks, 1680: “The Attractions of Gravity, Magnetism and Electricity, reach to very sensible distances, and so have been observed by vulgar Eyes, and there may be others which reach to so small distances as hitherto escape Observation.” (quoted by A. Pais, Inward Bound, 1986) we will go to distances about 1 billion times smaller than what was known at end of XIXth century Discovery of X-rays A. Andronic Wilhelm Conrad Roentgen 1895, Würzburg, Germany Nobel Prize 1901 studied cathode rays, which were known to have short range in air, and found penetrating rays, which he called X rays, with properties: - no reflexion or refraction - no deflection in magnetic field - originated at the tube’s spot where cathode rays hit ...all done in a few weeks (then no more research on X rays) Impact of X-rays A. Andronic • Diffraction of X-rays (Max von Laue, 1912; Nobel Prize 1914) • Analysis of crystal structure (W.H. Bragg, W.L. Bragg; Nobel Prize 1915) • X-rays emitted after irradiation are unique for every element (Charles Barkla, Edimburgh, UK, Nobel Prize 1917; discovered polarization of X-rays) • precision X-ray spectroscopy (Karl Manne Georg Siegbahn, Uppsala, Nobel Prize 1924) • X-ray imaging of astrophysical objects (Ricardo Giacconi, Nobel Prize 2002) • Usage in medicine (already in WWI) Discovery of radioactivity A. Andronic Henri Becquerel, 1896, Paris, France; Nobel Prize 1903 was studying phosphorescence, exposing potassium uranyl disulfate to sunlight the effect was that photographic plates were blackened even covered in black paper ...during some cloudy days the photographic plates stayed in a drawer, developing them showed a big surprise penetrating rays like those of Roentgen, but without a Crookes tube! “sans cause excitatrice”, as Becquerel demonstrated that phosphorescence did not matter Radioactivity follow-up A. Andronic During 1986 Becquerel demonstrated that the new “rays” - come from the substance - did not depend on type of chemical uranium compound - effect did not decrease in time (after several years) - effect was weaker for larger distances - discharged charged bodies (electroscopes), like X-rays also a mistake: Becquerel found reflexion and refraction wondered about where is the energy coming from The unit of radioactivity: Becquerel = 1 disintegration per second Radioactivity follow-up A. Andronic Marie and Pierre Curie (1898, Paris) discovered: - thorium is radioactive (independently by Gerhard C. Schmidt, Erlangen) - 2 new elements: polonium, radium - with stronger radioactivity than uranium (not by chance, but by observing that pitchblende and chalcite are more radioactive than uranium and concluding that another element may be at play) jump-started the discipline of radiochemistry - radioactivity proportional to quantity of uranium - radioactivity is an atomic property introduced the term “radioactivity” Nobel Prize, 1903; Nobel Prize Chemistry 1911, M. Curie M. Curie died (1934) with health effects of radiation (worked without any protection, handled considerable amount of radioactivity) effects were known already in 1900 (Walkhoff, Giesel, Becquerel, Curie) Radioactivity follow-up A. Andronic Ernest Rutherford (1898-1908, Cambridge, Montreal; & co.) discovered: - reflection and refraction are not present (soon Becquerel concurred) - two components of radioactivity of uranium: one with a low penetration power, α, and another highly-penetrating, β - identified α with He (He had been identified on earth only in 1895) - the radioactive decay law - element transmutation by radioactivity Nobel Prize Chemistry: Rutherford, 1908; Frederick Soddy, 1921 Paul Villard (1900, Paris) discovered a 3rd type or radioactivity (of radium): γ Rutherford and Andrade demonstrated its similarity to X-rays in 1914 Impact of radioactivity A. Andronic • fundamental laws of nature were discovered based on radioactivity • essential for chains of element production (in stars) • source of inner earth warmth (47 TW at surface, 1/2 radiogenic ...173000 TW solar) produced by 40K, 238,235U, 232Th • radioactive carbon dating • radioactive isotopes are used in medical investigations and treatment Discovery of the electron A. Andronic J.B. Perrin, 1895: cathode rays are negatively-charged particles, magnetic deflection (Nobel Prize, 1922) P. Zeeman, 1896: light multiplets in magnetic field; e/m <0 (Nobel Prize 1902 with H.A. Lorentz) Wiechert, Kaufmann (1897) were close to a measurement of e/m (assumed v) J.J. Thomson 1897, Cambridge, England Nobel Prize 1906 cancellation of electric and magnetic deflection of cathode rays gives velocity; electric deflection, gives e/m ...770 times larger than for hydrogen same for particles produced by ultraviolet light (1899) e separately in cloud chamber (1899) Discovery of the electron A. Andronic F qE qV a= = = m m mh v = v0 + at; d t= vx qV d vy = = vx tan θ mh vx Impact of electron A. Andronic • first elementary particle • Kaufmann demonstrates that electron and β rays (radium) are identical • R.A. Millikan, 1910: measures e with precision (Nobel Prize, 1923) now: e = 1.602176565(35) × 10−19 C, precision 22 ppb (2.2 × 10−8) • J. Stark, 1913: electric splitting of spectral lines • Electronics ...invention of the transistor: William Bradford Shockley, John Bardeen and Walter Houser Brattain, 1947, USA (Nobel Prize 1956) (now 1 mil. transistors per cm2) • High-precision (10−5) electron spectroscopy to investigate vibrational energies of molecules emitting X-rays, Kai M. Siegbahn (Nobel Prize 1981) • Electron microscopy, Ernst Ruska (Nobel Prize 1986) 50 pm resolution, compared to 200 nm for light Summary of radioactivity A. Andronic http://www.cyberphysics.co.uk/topics/radioact/Radio/deflection_fields.htm Electric field: same charges repel, opposite charges attract Magnetic field: left (right) hand rule for negative (positive) charges (thumb is velocity, index to B field orientation, particle deflected out of hand)
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