CONVERSION TABLES MOISTURE CONTENT The forestry sector has traditionally used the value of moisture content on dry basis (DB), while in the sector of bioenergy the moisture content is usually assessed on wet basis (WB): Dry basis Dry basis (humitat – humedadfeuchtigkeit – moisture content dry basis – humidité sur base sèche) X·100 Wet basis Wet basis (contingut d’aigua-contenido de agua - wassergehalt – moisture content wet basis – humidité sur masse brute) Figure 1. Difference of the calculation of moisture content based on dry and wet basis Source: AFIB-CTFC Table 1. Equivalences between the two concepts of moisture Equivalences between values of moisture content in dry basis and wet basis %WB 0 5 10 15 20 25 30 35 40 45 50 55 60 65 %DB 0 5 10 15 20 25 30 40 50 60 70 80 90 100 %DB 0,0 5,3 11,1 17,6 25,0 33,3 42,9 53,8 66,7 81,8 100,0 122,2 150,0 185,7 %WB 0,0 4,8 9,1 13,0 16,7 20,0 23,1 28,6 33,3 37,5 41,2 44,4 47,4 50,0 Source: AFIB-CTFC The moisture from the freshly cut wood is round 45% wet basis for the conifers, little less for the oaks and holm oaks (Q. ilex). Regarding the season, trees in winter has moisture contents lower than in the seasons of vegetative activity. Àrea d'Aprofitaments Fusters i Biomassa - http://afib.ctfc.cat/ Centre Tecnològic Forestal de Catalunya - http://www.ctfc.cat/ Ctra de Sant Llorenç de Morunys, km 2 (Direcció Port del Compte) , ES-25280 SOLSONA (Lleida) - Telf: +34 973 48 17 52 · Fax: +34 973 48 04 31 e-correu: [email protected] i [email protected] Butlletí Infobiomassa - http://infobio.ctfc.cat/ · Rok-FOR - http://www.rokfor.eu/ · Wood E3 - http://www.woode3.eu WOOD DENSITY The density of wood is the mass per unit volume and is measured in kg/dm3 or tonnes/m3. When talking about basic density of wood, it refers to the absolute dry (0% of moisture content) mass of wood referred to the green volume.. Table 2. Equivalences between different wood densities of wood moisture content Specie Abies alba Pinus uncinata Pinus sylvestris Pinus nigra Pinus halepensis Pinus pinea Pinus pinaster Pinus insignis Fagus sylvatica Betula pendula Quercus ilex Quercus sp. (oaks) Castanea sativa Fraxinus angustifolia Populus sp. Platanus x hispanica Conifers Deciduous Basic (t0/m3) 0,51 0,50 0,48 0,51 0,55 0,51 0,44 0,46 0,69 0,60 0,87 0,73 0,59 0,67 0,43 0,65 0,51 0,67 Wood density 50%WB 30%WB (t50/m3) (t30/m3) 0,87 0,62 0,86 0,61 0,81 0,58 0,88 0,63 0,93 0,66 0,87 0,62 0,74 0,53 0,78 0,56 1,16 0,83 1,03 0,73 1,47 1,05 1,24 0,88 1,00 0,71 1,13 0,81 0,74 0,53 1,11 0,79 0,87 0,62 1,14 0,82 The basic density was considered as a weighted average between the density of bark and wood bulk density; the fiber saturation point is considered at 30%DB. Source: AFIB-CTFC from SIBosC (CREAF-DMAH, 2011) and CPF (2004) Àrea d'Aprofitaments Fusters i Biomassa - http://afib.ctfc.cat/ Centre Tecnològic Forestal de Catalunya - http://www.ctfc.cat/ Ctra de Sant Llorenç de Morunys, km 2 (Direcció Port del Compte) , ES-25280 SOLSONA (Lleida) - Telf: +34 973 48 17 52 · Fax: +34 973 48 04 31 e-correu: [email protected] i [email protected] Butlletí Infobiomassa - http://infobio.ctfc.cat/ · Rok-FOR - http://www.rokfor.eu/ · Wood E3 - http://www.woode3.eu CALORIFIC VALUES The potential energy value of biomass materials is determined by its chemical composition and is measured in units of energy per mass of fuel (e.g. J/g). For convenience this measure is usually expressed as MJ/kg or GJ/t, but in the commercial field, frequently used units are kWh/tonne and kcal/kg. We must differentiate between the gross calorific value (qGR) and net calorific value (qNET). The qGR is the amount of energy released when a unit mass is burned with oxygen, where water being produced in the burning process is in liquid form. In condensing to liquid, energy is released. The concept is similar to qNET, where the water released in the combustion process is in gaseous state. The qGR will always be greater than the qNET. qNETis commonly used because the water is almost always in gaseous state in the flue gases of the boiler. Table 3: Energy equivalences Joule (J) Joule (J) Calorie (cal) Kilowatt hour (kWh) Ton of oil equivalent (toe) Calorie (cal) Ton of oil equivalent (toe) 0,239·10-10 1·10-10 8,60·10-5 1 Kilowatt hour (kWh) 1 0,239 4,184 1 6 0,860·106 3,600·10 41,840·109 1010 Source: Rodríguez, 2006 -6 0,278·10 1,162·10-6 1 11,622·103 The net calorific value of a ton anhydrous (0% moisture) of wood is about 5.000-5.600 kWh/t (4.300-4.815 kcal/kg). Table 4 Calorific values (en kWh/t) at different moistures Moisture wet basis Specie 0 20 30 35 40 45 Quercus ilex Quercus sp (oaks) Pinus sylvestris Pinus nigra Pinus halepensis Pinus pinea Populus sp. Castanea sativa Fagus sylvatica Conifers Deciduous 5.307 4.975 5.338 5.296 5.082 5.374 4.815 5.184 4.951 5.272 5.078 4.110 3.844 4.135 4.101 3.930 4.164 3.716 4.012 3.825 4.082 3.927 3.512 3.279 3.533 3.504 3.354 3.558 3.167 3.425 3.262 3.487 3.351 3.212 2.996 3.232 3.205 3.066 3.256 2.892 3.132 2.981 3.190 3.063 2.913 2.714 2.931 2.906 2.778 2.953 2.618 2.839 2.699 2.892 2.775 2.614 2.431 2.631 2.607 2.490 2.651 2.343 2.546 2.418 2.595 2.488 50 2.314 2.148 2.330 2.309 2.202 2.348 2.068 2.253 2.136 2.297 2.200 Source: AFIB-CTFC from: Biocalor-Hargassner, ETA Heiztechnik GmbH, Energuía, Pla de biomassa, Projecte Biosouth and Technologie-und Förderzentrum The higher moisture content, the lower the calorific values, both derived from the relative decrease in the amount of wood per unit mass of fuel, and also because of the need to use some energy from the wood to evaporate the water. Àrea d'Aprofitaments Fusters i Biomassa - http://afib.ctfc.cat/ Centre Tecnològic Forestal de Catalunya - http://www.ctfc.cat/ Ctra de Sant Llorenç de Morunys, km 2 (Direcció Port del Compte) , ES-25280 SOLSONA (Lleida) - Telf: +34 973 48 17 52 · Fax: +34 973 48 04 31 e-correu: [email protected] i [email protected] Butlletí Infobiomassa - http://infobio.ctfc.cat/ · Rok-FOR - http://www.rokfor.eu/ · Wood E3 - http://www.woode3.eu
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