Name: ___ANSWER KEY____________ Block: _____ Date: _________________ Honors Chemistry Unit 5 Test Review Chemical Reactions 1. For the following reactions, write, balance, and/or classify the type of reaction. Include phase states when indicated. a. 2KOH(aq) + H2 SO 4(aq) K 2 SO 4(aq) + H2 O (l) Acid/Base b. 2SiO 2Si + O 2 Decomposition c. Ca (s) + 2CuNO 3(aq) Ca(NO 3 ) 2(aq) + 2Cu (s) d. 4Al (s) + 3O 2(g) 2Al 2 O 3(s) Single Replacement Synthesis e. Aqueous silver nitrite reacts with aqueous potassium bromide to yield aqueous potassium nitrite and solid silver bromide. AgNO 3(aq) + KBr (aq) KNO 3(aq) + AgBr (s) Double Replacement f. Hydrofluoric acid reacts with aqueous copper (II) hydroxide to produce water and aqueous copper (II) fluoride. HF (aq) + Cu(OH) 2(aq) H 2 O (l) + CuF 2(aq) Acid/Base g. Titanium (IV) bromide reacts with chlorine gas to produce titanium (IV) chloride and bromine gas. TiBr 4(aq) + Cl 2(g) TiCl 4(aq) + Br 2(g) Single Replacement 2. What are the coefficients for the following reaction? 6 3 2 3. What type of reaction: a. Produces water and a salt? Acid/Base b. Breaks apart a substance into smaller substances? c. Can produce a precipitate, gas, or liquid? Decomposition Double Replacement d. Would you use the activity series to predict the products? Single Replacement e. Takes place in the presence of oxygen and produces carbon dioxide and water? Combustion f. Combines two or more substances to form a different substance? g. Can net ionic equations be written from? Synthesis Double Replacement 4. Why do chemical equations need to be balanced? Because of the Law of Conservation of Matter, chemical equations need to be balanced in order to show all the elements involved in a chemical reaction. 5. Use any of the following elements or compounds to write and balance a combustion reaction. C 5 H12 , Na, CO 2 , OH-, H+, K, Cl 2 , O 2 , C 4 H8 C 5 H 12 + 8O 2 5CO 2 + 6H 2 O or C 4 H 8 + 6O 2 4CO 2 + 4H 2 O 6. Use any of the following elements to write and balance a reaction that is an acid-base reaction. Mg, Na, K, Al, OH-, H+, Br, Cl, I HBr, Cl, or I + Mg, Na, K, or AlOH Salt + H 2 O One example: HCl + Mg(OH) 2 MgCl 2 + H 2 O 7. What are the four symbols for the different phase states and what do the each represent? s – solid aq – aqueous (dissolved solution) l – liquid g – gas 8. Find and correct the mistake in the equation Li 3 N + 3Cl 3LiCl + N. Both Cl and N should be diatomic molecules: 2Li 3 N + 3Cl 2 6LiCl + N 2 9. Which metal will react spontaneously with HCl (aq) ? Au Ag Cu Mg 10. Write a combination of two solutions that do NOT produce a reaction. There are many different possibilities, just looking that all compounds are soluble. Here is one possibility: NH 4 I (aq) + NaNO 3(aq) NH 4 NO 3(aq) + NaI (aq) 11. Write the balanced molecular, complete ionic, and net ionic of the following equations, include phase states: a. Na 2 CO 3(aq) + Mg(OH) 2(aq) 2NaOH (aq) + MgCO 3(s) Complete: 2Na+ (aq) + CO 3 2- (aq) + Mg2+ (aq) + 2OH- (aq) 2Na+ (aq) + 2OH- (aq) + MgCO 3(s) Net Ionic: Mg2+ (aq) + CO 3 2- (aq) MgCO3(s) b. NaClO3(aq) + Ca3(PO4)2(aq) Na3PO4(aq) + Ca(ClO3)2(s) c. Hydrochloric acid reacts with sodium hydroxide Molecular: HCl(aq) + NaOH(aq) NaCl(aq) + H2O(l) Complete: H+(aq) + Cl-(aq) + Na+(aq) + OH-(aq) Na+(aq) + Cl-(aq) + H2O(l) Net Ionic: H+(aq) + OH-(aq) H2O(l) d. Silver nitrate reacts with iron (II) phosphate Molecular: 6AgNO3(aq) + Fe3(PO4)2(s) 2Ag3PO4(s) + 3Fe(NO3)2(aq) Complete: 6Ag+(aq) + 6NO3-(aq) + Fe3(PO4)2(s) 2Ag3PO4(s) + 3Fe2+(aq) + 6NO3-(aq) Net Ionic: 6Ag+(aq) + Fe3(PO4)2(s) 2Ag3PO4(s) + 3Fe2+(aq) 12. A reaction produces solid silver chloride. Write, balance, and draw a reaction that has two aqueous reactants that will produce solid silver chloride and another product. There are many different options for this answer, but here is one: Molecular: 2AgNO3(aq) + MgCl2(aq) Mg(NO3)2(aq) + 2AgCl(s) Ag NO3 NO3- + Ag + NO3Mg2+ NO3 2AgCl Mg2+ ClCl Complete: Ag+(aq) + NO3-(aq) + Na+(aq) + Cl-(aq) Na+(aq) + NO3-(aq) + AgCl(s) Net Ionic: Ag+(aq) + Cl-(aq) AgCl(s) 13. A reaction produces solid iron (II) carbonate. Write, balance and classify a reaction in which aqueous iron (II) chloride reacts with another reactant to produce iron (II) carbonate and another product. There are many different options for this answer, but all should be double replacements. Here is one option: Molecular: FeCl2(aq) + Na2CO3(aq) FeCO3(s) + 2NaCl(aq) Complete: Fe3+(aq) + 2Cl-(aq) + 2Na+(aq) + CO32-(aq) FeCO3(s) + 2Na+(aq) + 2Cl-(aq) Net Ionic: Fe3+(aq) + CO32-(aq) FeCO3(s) 14. Describe what a spectator ion is. A spectator ion is an ion that does not participate in a reaction. It is present in both the reactants and products. 15. Students preformed a lab to determine the reactivity of an unknown metal. Using the data below, write out the activity series of the metals tested in the lab including the unknown metal. ((Do yourself a favor and don’t look at an activity series except to check your answer) Cu(NO3)2 Reaction NR Reaction Reaction Reaction Reaction X Cu Fe K Na Zn Fe(NO3)3 Reaction NR NR Reaction Reaction Reaction KNO3 NR NR NR NR NR NR NaNO3 NR NR NR Reaction NR NR Most reactive K, Na, Zn, X, Fe, Cu Zn(NO3)2 NR NR NR Reaction Reaction NR Least Reactive 16. Predict the product, assign oxidation numbers, and identify the element that is oxidized and the element that is reduced in the following equations: a. Ba(s) + Mg(OH)2 Mg(s) + Ba(OH)2 0 +2 -2 +1 0 Oxidized – Ba +2 -2 +1 Reduced – Mg b. Iron (III) sulfide reacts with aluminum metal Fe2S3 + Al(s) Fe(s) + Al2S3 +3 -2 0 0 Oxidized – Al +3 -2 Reduced – Fe c. Calcium metal reacts with potassium oxide Ca(s) + K2O No Reaction 17. In which reaction are electrons transferred from one reactant to another reactant? a. 2Ca(s) + O2(g) 2CaO(s) 0 0 b. AgNO3(aq) + KCl(aq) AgCl(s) + KNO3(aq) +2 -2 +1 +5 -2 b. HCl(aq) + NaOH(aq) NaCl(aq) + H2O(l) +1 -1 +1 -2 +1 +1 -1 +1 -2 + c. H3O +1 -2 (aq) + +1 -1 +1 -1 OH-(aq) 2H2O(l) -2 +1 +1 -2 +1 +5 -2
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