E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties Abstract Students will learn about characteristic properties by first conducting an investigation to determine the relative density of water, oil, rubbing alcohol, and a green bead. Then, they will observe how quickly a green bead moves through test tubes filled with water, oil, and corn syrup to determine which liquids have higher viscosity. Finally, they will use appropriate tools to separate iron filings from a soil sample, dissolve salt, and separate sand. Time: 30 Minutes Objectives: Chemistry Sciences: A. Building Blocks of Matter 1. The learner will conclude there are more than 100 known elements that combine in a multitude of ways to produce compounds, which account for all living and non-living substances. 2. The learner will demonstrate that atoms combine to form molecules and molecules formed from different atoms combine to form compounds. 3. The learner will recognize a substance has characteristics, such as density, viscosity, boiling point, and solubility, all of which are independent of the amount of the sample. Lesson Plan Appendices Characteristic Properties Objectives Met 1 2 3 l 1 E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties Instructor Materials • 1 Foam brick that looks like foam • 1 Foam brick that looks like a brick Student Materials Density (Per team of 4 students) • 1 - 100mL graduated cylinder with 20 mL of vegetable oil • 1 - 100mL graduated cylinder for measuring • Funnel • 1 Cup of water, dyed blue • 1 Cup of 91% rubbing alcohol, dyed green • 1 Green bead • 1 Plastic tub lined with a trash bag • 2 Paper towels • Safety goggles (per student) • Gloves (per student) • Station cards Viscosity (Per student) • 1 Test tube with cooking oil and a green bead in it, labeled “A” • 1 Test tube with water and a green bead in it, labeled “B” • 1 Test tube with corn syrup and a green bead in it, labeled “C” • Test tube holder • Safety goggles (per student) • Gloves (per student) • Station cards 2 E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties Solubility (Per team of 4 students) • 2 Soil samples with a mixture of sand, salt, and iron filings – one larger than the other • Coffee filter • 2 Magnets • 4 oz cup with about 1 tsp of water • 4 oz cup for iron filings • 12 oz cup (empty) • Safety goggles (per student) • Gloves (per student) • Station cards 3 E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties Instructor Background Information: Key Vocabulary Characteristic Properties—A characteristic property is a chemical or physical property that helps identify and classify substances. The characteristic properties of a substance are always the same whether the sample you are observing is large or small. Examples of characteristic properties include freezing/melting point, boiling/condensing point, density, magnetism, and solubility. Density—The amount of mass per unit volume. Something that is more tightly packed is denser than something that has more space between the molecules. Solubility —The ability of a substance to dissolve. The quantity of a substance that may be dissolved in a given amount of solvent. Solute—A substance dissolved in a solution. For solutions of fluids, the solvent is present in greater amount than the solute. Solvent—The component of a solution that is present in the greatest amount. It is the substance in which the solute is dissolved. Viscosity—The property of a fluid that resists the force tending to cause the fluid to flow. 4 E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties Density Density is a relationship of mass to volume expressed in the equation Density = mass (g) volume (mL) In other words, density is defined as the amount of mass per unit volume. Something that is more tightly packed is denser than something that has more space between the molecules. At the atomic level, the higher the number of protons and neutrons in the atom, the greater the atomic mass, which can be observed on the Periodic Table of Elements. Further, the strength of the atomic bonds can play a role in density as stronger bonds result in more atoms crowded together. The same holds true with molecular bonds. More tightly bonded molecules mean less space between them, which typically results in high density. Metals are a good example of tightly bonded atoms. Density can also change as a result of variations in pressure and temperature; therefore, it is said to be a dynamic property. The best way to understand this is to think in terms of gases. If a set amount of a gas is moved from a small container to a larger one, the gas will tend to spread out. The smaller container exerts a higher level of pressure, packing the gas molecules closer together; when that pressure is no longer acting on the gas, the molecules will spread out, thus reducing the density. Temperature also can play a role as high temperatures increase kinetic energy. In turn, this causes molecules to spread out, thus affecting density. An important consideration when teaching density is to emphasize the difference between mass and weight. Weight is relative to gravitational pull while mass is a constant. Because density is a relationship of mass to volume expressed in the equation Density = mass (g)/volume (mL), this distinction must be clear. Weight is not a reliable means of determining density and neither is size. Sometimes students may wrongly conclude that larger objects automatically have greater density or that an object that sinks in one type of liquid will automatically sink in all liquids. 5 E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties Viscosity Viscosity is the property of a fluid’s resistance to flow. Viscosity is described as the ratio of shearing stress to the velocity gradient. Shearing stress results from the force of one side of a surface pressing against the side of another surface. When a fluid is moving, the outside layer of the fluid will move at the same velocity as the movement, if any, of the surface it is pressing against. If it is a pipe that is stationary, the outer layer of the fluid inside will not be moving while the inner layers will be moving. The difference in movement between the outer and inner layers is called the velocity gradient. If there is little difference between the layers, the flow is called a laminar flow. The simplest way to measure viscosity is to put a known quantity of fluid into a funnel and measure how long it takes to flow through. This is called kinematic viscosity and is actually a measurement of how a fluid resists flow under the influence of gravity. Solubility Solubility is the ability of a substance to dissolve. Usually, we think in terms of dissolving something in water; however, different solvents can affect solubility. Matter can be classified based on how the characteristic property of its solubility is affected in different solvents. The substance (chemical) being dissolved is called a solute, and the liquid it is being dissolved in is called a solvent. Solubility is expressed in quantitative terms. For example, a solute is stirred into a known amount of solvent, (100mL). When more than 0.1g of the solute dissolves (disappears), it is said to be soluble. If less than 0.1g of the solute dissolves, it is said to be either insoluble or sparingly soluble. When a substance is miscible, it is understood to be soluble without limits. Immiscible is synonymous with insoluble. 6 E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties Instructor Preparation: Set Up üü Collect the necessary supplies for each group of four students. Caution students that they should not drink any solutions utilized as part of an investigation. Caution students that rubbing alcohol can be harmful if misused. Avoid contact with skin. While working with the iron filings, warn the students to keep fingers away from eyes. Density • 1-100mL graduated cylinder with 20 mL of vegetable oil • 1 cup of water tinted with blue food coloring • 1 cup of 91% rubbing alcohol tinted with green food coloring • 1 plastic tub, lined with a trash bag and two paper towels Viscosity • 4 test tubes marked “Sample A” with cooking oil and a green bead in each • 4 test tubes marked “Sample B” with water and a green bead in each • 4 test tubes marked “Sample C” with light corn syrup and a green bead in each Solubility • 2 - 6oz clear plastic cups labeled “Water,” 1 tablespoon of water in each • 2 - 6oz clear plastic cups labeled “Used Iron Filings” • 1 plastic bag with ¼ cup of sand, 1 tsp. salt, and ¼ tsp. iron filings • 1 plastic bag with 2 teaspoons sand, ½ tsp. salt, and ¼ tsp. iron filings • 2 magnets • 2 basket-type coffee filters Activity Preparation üü Density—At each station, place one empty graduated cylinder, one graduated cylinder with vegetable oil, a funnel, the cup of blue water, the cup of green rubbing alcohol, and a green bead on top of the paper towels. Also place a pair of gloves and goggles for each student. Put the lined plastic container on one end of the table. 7 E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties üü Viscosity—At the same station where the density equipment is placed, put the test tubes in a test tube holder. üü Solubility—At each station, place two 12 oz plastic cups, a coffee filter with the larger soil sample, a coffee filter with the smaller soil sample, the cups with water (students work in pairs), and a pair gloves and goggles for each student. Set magnets and cups for used iron filings to the side. 8 E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties Lesson: Introduction: 5 minutes 1. Hold up a glass of water. Ask: What is this? (A glass of water.) Ask: How do you know? (It’s clear liquid in a glass.) Ask: How do you know for sure it’s water? What else could it be? (Vinegar, rubbing alcohol, acid.) We would need to test its characteristic properties to determine for sure that it is actually water and not something else. 2. Ask: Does anyone know what a characteristic property is? (Allow students a moment to offer their ideas. Explain, characteristic properties are physical or chemical properties that scientist use to identify unknown substances. They remain the same regardless of the amount or size of the sample. Some characteristic properties of this glass of water would be its density and viscosity.) 3. Ask: Can someone explain what density means? (Density is the amount of mass of an object in relation to the space it takes up.) Help the class get a visual idea of density by giving an example of density such as a fully packed classroom compared to a nearly empty one. Then, explain that density can be different based on the state of matter. 4. Explain to the class that they will be conducting an investigation to observe the density of three unknown liquids. Point out the graduated cylinders, so the students are familiar with what equipment they will be using. Remind the class to carefully read the instructions on their station cards. 5. Ask: Does anyone know what viscosity means? (Viscosity is how fast a fluid flows. Viscosity is how much a fluid resists flow.) Density is taught as Station 1A, while viscosity is taught as Station 1B. The stations are combined because each activity only takes five minutes. The total station time needs to be 10 minutes to match the Solubility station. Low viscosity means the fluid flows very fast; high viscosity means the fluid flows very slowly. Point out the test tubes at the station and remind students to read their station cards. 6. Solubility is taught as its own station. Ask: What is the definition of solubility? (Solubility is a measure of a substance’s ability to dissolve.) 9 E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties 7. Explain to the class that they will be working with soil samples and will need to read their station cards to properly separate the substances in the soil sample. Stations: 10 Minutes each station Station 1A (Density)—5 Minutes Figure 1: Station 1A—Density Set-up Optional: To simplify student tasks, you can assign each group member a number, one through four, to coordinate with the steps of these stations. If you choose not to assign numbers, you should ensure that each member has an opportunity to participate. 8. One student picks up the graduated cylinder with the yellow liquid in it. 9. Using the funnel, another student measures 10 mL of blue liquid into the empty graduated cylinder and then hands it back to the first student who will pour it on top of the yellow liquid. 10. Using the funnel, a third group member measures 30 mL of green liquid into the empty graduated cylinder and then hands it back to the first student to pour it on top of the yellow liquid. 11. The students should observe how the liquids separate into three layers, as seen in Figure 2. 12. The final group member should then drop the green bead into the graduated cylinder. Everyone should observe where it goes. 10 E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties Figure 2: Density Graduated Cylinder 13. The teams will analyze and report the results by answering three questions and completing the table in their activity logs. Students will use the table on the station card to identify the liquids in the graduated cylinder. To ease the transition from station to station, it would help to have multiple sets of equipment for students to use. 14. Students empty the graduated cylinder with the stacked liquids into the plastic bin and retrieve the green bead for the next crew. Station 1B (Viscosity)—5 Minutes Figure 3: Station 1B - Viscosity Set-up 15. Each person at the table should take one of each of the test tubes (labeled “Sample A,” “Sample B,” and “Sample C”) and tip them to observe how the liquid flows in each test tube. 11 E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties 16. Next, they should identify if the viscosity of each is either high or low and complete the table in their activity log. Station 2 (Solubility)—10 Minutes 17. Students should read the following scenario from their station card: Optional Scenario: Your robot collected two different samples from the ground near the volcanic eruption. Your job is to determine what is in the soil and make sure that it is not contaminated. From researching, you know that the soil should contain iron, sand, and salt. You will need to test the two samples to find out if they contain these substances. Work in pairs. 18. Students should then follow the directions on their station card to complete a table. (This is their plan for separating the soil samples). 19. Once they have completed the table, the pairs will empty their soil sample into the coffee filter. Give each pair of students a magnet and a cup labeled “Used Iron Filings.” Allow them time to remove the iron filings and scrape them off the magnet and into the cup. 20. Students should then hold their soil sample (with iron filings removed) over the 12 oz plastic cup and pour water over it to dissolve the salt. 21. Once they have completed the activity, students should answer the questions in their activity logs to report their observations. Figure 4: Station 2—Solubility 12 E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties Conclusion: 5 Minutes 22. Begin with a discussion of characteristic properties and explain to the class that characteristic properties help us identify substances because they do not change. Density, viscosity, and solubility are all considered characteristic properties. Density and Viscosity Station 23. Hold up the two “bricks.” Ask: Which of these two materials is more dense, a foam brick or a real brick? What is the difference? (A real brick would have more density. They are different because the real brick has more mass than the foam brick, but it takes up the same amount of space. Some students may answer that it weighs more. Use this as a teachable moment to discuss weight and mass.) Ask: Which liquid had the highest density? How do you know? (Student answers should include that water had the highest density because it went to the bottom of the graduated cylinder, and its density was 1.00 gm/mL, which was the highest number on the table.) Strategic Questions: Why did the rubbing alcohol stay on top? (It had the lowest density.) Will changing the amounts of any of the liquids affect their density? Why or why not? (No, because characteristic properties, such as density, will not change regardless of the amount of the substance.) 24. Identify the yellow liquid as cooking oil and the green liquid as rubbing alcohol. Ask: Did the amount of each liquid make a difference to how they stacked up in the graduated cylinder? (No, because the amount of a substance does not change its characteristic properties.) Ask: Why did the water go through the oil to the bottom, but the rubbing alcohol didn’t? What caused this difference? (The density of the oil is less than the density of the water, which means the molecules are not as tightly bonded, leaving space for the water to move through it. On the other hand, the molecules in the rubbing alcohol are spaced farther apart, so it could not move through the oil.) Ask: What about the bead; where did it end up? Why didn’t it go all the way to the bottom? What can we tell about its density? (The bead floated between the water and the oil. Its density is less than water but greater than the oil. We can estimate its density around 0.95 g/mL.) 13 E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties Strategic Questions: A liquid that hardly budges has which viscosity, high or low? (High.) Can you think of some liquids with a high viscosity? (Honey, pancake syrup, molasses.) 25. Move onto a discussion of viscosity and review that liquids that do not flow easily have a high viscosity, while liquids with low viscosity flow quickly. Ask: What might you put on your pancakes that does not flow easily? (Syrup.) Ask: What liquid with a low viscosity might you drink? (Milk, orange juice, water.) 26. Then, go through the test tube samples and ask the class to identify the viscosity of each liquid. • Sample A can be either a high or low viscosity. However, because liquids are only classified in this activity as either having high or low viscosity, medium is not an option. • Sample B is a low viscosity. The students can observe the bead moves very quickly through the liquid. • Sample C is a high viscosity. The students can observe the bead moves very slowly through the liquid. Solubility Strategic Questions: Does the amount or size of a sample affect its solubility? (No, because characteristic properties are not affected by the amount or size of the substance.) 27. Review the definition of solubility (a substance’s ability to dissolve), and remind the class that characteristic properties do not change regardless of the amount of the substance. 28. Ask the class if they were successful in separating the three substances. Then, ask if the amount of the sample made a difference to their success? Explain that the characteristic properties of each substance wouldn’t change even if we had a dump truck full of mixed up sand, salt, and iron filings. With the correct tools, we could still be successful. We could use a magnet to separate the iron filling from the sand, and we could still rinse the salt out with water. 14 Characteristic Properties Assessment Suggested Final Assessment Questions 1. How might understanding characteristic properties help scientists identify unknown substances? 2. Does the amount of a substance affect its density? Why or why not? 3. If a liquid flows slowly, does it have a high or low viscosity? 4. Which is not an example of a characteristic property? a. Density b. Viscosity c. Size d. Solubility 15 Characteristic Properties Assessment Suggested Final Assessment Questions Application 1. How might understanding characteristic properties help scientists identify unknown substances? Characteristic properties do not change and are, therefore, very helpful to separate and identify substances. Knowledge 2. Does the amount of a substance affect its density? Why or why not? No, because density is a characteristic property and is independent of the size of the sample. Knowledge 3. If a liquid flows slowly, does it have a high or low viscosity? High. Comprehension 4. Which is not an example of a characteristic property? a. Density b. Viscosity c. Size d. Solubility 16 Activity Log Characteristic Properties Station #1: What is density & viscosity? The density of a substance describes the mass of the substance in the amount of space it takes up. Viscosity is determined by how much a liquid resists flow. Liquids that do not flow easily have high viscosity. Liquids that flow quickly have low viscosity. After pouring the liquids into the graduated cylinder... 1. Which liquid has the highest density? o Green o Yellow o Blue 2. Which liquid has the lowest density? o Green o Yellow o Blue 3. The density of the bead is between which two liquids? o Green o Yellow Density of Liquids (1A) Color Identity Density (g/mL) o Blue Viscosity of Liquids (1B) Sample Blue A Yellow B Green C Viscosity (high, low) Characteristic Properties Activity Log Station #2: What is solubility? Your plan for separating the three substances: Step Substance 1 Iron 2 Salt 3 Sand Characteristic Properties Tool 1. Were you successful in separating the three substances? Why or why not? __________________________________________________________________ __________________________________________________________________ 2. Did the amount of iron, sand, or salt affect your ability to separate them? Why do you think this is? __________________________________________________________________ __________________________________________________________________ 3. What substance is in the water? _______________________________________ Can you see the substance? __________________________________________ Why or why not? ___________________________________________________ __________________________________________________________________ Activity Log Characteristic Properties Station #1: What is density & viscosity? The density of a substance describes the mass of the substance in the amount of space it takes up. Viscosity is determined by how much a liquid resists flow. Liquids that do not flow easily have high viscosity. Liquids that flow quickly have low viscosity. After pouring the liquids into the graduated cylinder... 1. Which liquid has the highest density? o Green o Yellow R Blue 2. Which liquid has the lowest density? R Green o Yellow o Blue 3. The density of the bead is between which two liquids? o Green R Yellow R Blue Density of Liquids (1A) Viscosity of Liquids (1B) Color Identity Density (g/mL) Sample Viscosity (high, low) Blue Water 1.00 A Either high or low Yellow Vegetable Oil 0.91 B Low Green Rubbing Alcohol 0.78 C High Characteristic Properties Activity Log Station #2: What is solubility? Your plan for separating the three substances: Step Substance Characteristic Properties Tool 1 Iron Magnetic Magnet 2 Salt Dissolves Water 3 Sand Doesn’t Dissolve Filter Paper 1. Were you successful in separating the three substances? Why or why not? __Yes, because we used the correct tools._______________________________________ __________________________________________________________________ 2. Did the amount of iron, sand, or salt affect your ability to separate them? Why do you think this is? __No, because characteristic properties stay the same regardless of the size of the sample. _____ __________________________________________________________________ 3. What substance is in the water? __Salt__________________________________ Can you see the substance? __No______________________________________ Why or why not? __Because, it dissolves into the solvent._________________________ __________________________________________________________________ E 3.1.1.2. Chemistry Sciences: A. Building Blocks of Matter Lesson Plan: Characteristic Properties References: Characteristic Property. (n.d.). Wikipedia. Retrieved from http://en.wikipedia.org/wiki/ Characteristic_property Elert, G. (2012). The Physics Hypertextbook. Retrieved from (http://physics.info/viscosity/ Grotzer, Tina et al. (2005). Understandings of Consequence Project: Causal Patterns in Density Phenomena. Retrieved from http://www.pz.harvard.edu/ucp/curriculum/density/i_challenges. htm Ophart, C.E. (2003) What is Density? Retrieved from http://www.elmhurst.edu/~chm/ vchembook/120Adensity.html Pressure and Density. (2012). Retrieved from http://www.kidsgeo.com/geography-for-kids/0084pressure-and-density.php Rogers, E., Stofall, I., Jones, L., Chabay, R., Kean, E., Smith, S. (2000) Fundamentals of Chemistry. Retrieved from http://www.chem.wisc.edu/deptfiles/genchem/sstutorial/Text11/Tx112/tx112. html Related Materials and Educational Resources: Fake foam brick • http://www.amazon.com Iron filings • www.sanjosescientific.com (SKU: 4942-35A Recommended) 21 Station #1A: Density Person Person Person 1 2 3 Pick up the graduated cylinder with the yellow liquid. Using the funnel, measure 10 mL of blue liquid in the other cylinder and give it to Person #1 to pour on top of yellow liquid. Using the funnel, measure 10 mL of green liquid in the other cylinder and give it to Person #1 to pour on top of yellow liquid. STOP Observe Person Observe how the liquids stack in the graduated cylinder. Drop the green bead into the graduated cylinder. Observe where it goes. 4 5 ANSWER questions 1-3 in your Activity Log. 6 Identify the liquids using the table below. Fill in the table in your Activity Log. Density of Liquids: Rubbing Alcohol: .78g/ mL Vegetable Oil: .91g/mL 7 Water:1.00g/mL Pour the entire contents of the graduated cylinder into the waste container. Wipe up any spills with paper towels. Leave all items on the table as you found them. Station #1B: Viscosity 1 Each crew member take a test tube labeled “Sample A.” 2 Tip the test tube back and forth. 3 Observe how the liquid flows in the test tube. 4 Repeat steps 1-3 with the test tubes labeled “Sample B” and “Sample C.” 5 Identify the viscosity of each sample as either high or low. 6 Complete the table in your Activity Log. Station #2: Characteristic Properties (Solubility) Your robot collected two different samples from the ground near the volcanic eruption. Your job is to determine what is in the soil and make sure that it is not contaminated. From researching, you know that the soil should contain iron, sand, and salt. You will need to test the two samples for these substances. Work in pairs. Your plan: 1 In your Activity Log, write your plan for testing and separating the three substances. The characteristic properties and tools you might use are listed in the blue box below. CHARACTERISTIC PROPERTIES Dissolves (soluble) Magnetic Doesn’t dissolve (insoluble) Carry out plan: 2 TOOLS Water Magnet Filter Paper a. Pour the soil onto the filter paper. b. Allow each crew member to remove a small amount of the iron and put them in the cup labeled “used iron filings.” Take turns until all iron is removed. c. Place the filter over the red cup and hold onto the filter very tightly. d. Carefully pour water over the filter. e. OBSERVE what happens. f. Throw the filter paper in the trash. 3 ANSWER questions 1 - 3 in your Activity Log.
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