CHAPTER 10 THE MOLE The mole (mol) is one of the seven base units in the SI system. It measures the amount of substance. The form in which a substance exists is its “representative particle”. Representative particles can be atoms, ions, molecules, formula units, or anything else. Units of measure 1 dozen = 12 1 gross = 144 1 ream = 500 1 mole = 6.02 x 1023 The mole is the “chemist’s dozen”. It is a convenient way to count extremely large numbers of atoms, molecules or ions. Just as one dozen is 12 representative particles, 23 a mole is 6.02 x 10 representative particles. 602,000,000, 000,000,000, 000,000!!!!! Examples: 1 mole Fe = 6.022 x 1023 atoms of Fe 1 mole H2O molecules = 6.022 x 1023 molecules of water 1 mole Na+ ions = 6.022 x 1023 Na+ ions 1 mole eggs = 6.022 x 1023 eggs 6.02 X 1023 Watermelon Seeds: Would be found inside a melon slightly larger than the moon. 6.02 X 1023 Donut Holes: Would cover the earth and be 5 miles (8 km) deep. 6.02 X 1023 Pennies: Would make at least 7 stacks that would reach the moon. 6.02 X 1023 Grains of Sand: Would be more than all of the sand on Miami Beach. 6.02 X 1023 Blood Cells: Would be more than the total number of blood cells found in every human on earth. Review: Diatomic Elements Certain elements are only stable in pairs or with other elements in a compound. These elements are called the diatomic elements. There are 7 diatomic elements: Hydrogen, bromine, oxygen, nitrogen, chlorine, iodine, and fluorine (Memory trick: HOFBrINCl or Infamous 7) Avogadro’s Number 6.02 x 1023 is called Avogadro’s number. It is named after Amadeo Avogadro who did work in the 1800’s that allowed 6.02 x 1023 to be calculated. Gram atomic mass (gam) -the average atomic mass of an element in grams -mass of one mole of atoms of a monatomic element -use the periodic table and take masses to 0.01 g Example: C =12.01 g = mass of 6.022 x 1023atoms 12.01 g/mol is the gram atomic mass (molar mass) of carbon Gram molecular mass (gmm) -mass of one mole of a molecule -sum of the atomic masses of each atom in the molecule 1 mol H2O: 2 mol H 1 mol O =2 x 1.01 g H/mol = 2.02 g =1 x 16.00 g O/mol = 16.00 g 18.02 gH2O #7. What is the gram molecular mass of CH3OH? C 1 x 12.01 = 12.01 H 4 x 1.01 = 4.04 O 1 x 16.00 = 16.00 32.05 g Gram formula mass (gfm) -mass of one mole of an ionic compound -sum of the atomic masses of each atom in a formula unit #8. What is the gfm of magnesium phosphate? Mg3(PO4)2 3 mol Mg 3 x 24.31 g = 72.93 g 2 mol P 2 x 30.97 g = 61.94 g 8 mol O 8 x 16.00 g =128.00 g 262.87 g Gram formula mass is a generic term and can be used for either ionic or molecular compounds. Molar mass or molecular weight are terms also used to mean the same thing. Molar mass: aka • • • • • • Gram formula mass Gram molar mass Gram molecular mass Gram formula weight Gram atomic mass Molecular weight #9. What is the molar mass of ammonium sulfate? (NH4)2SO4 2 mol N 2 x 14.01 = 28.02 8 mol H 8 x 1.01 = 8.08 1 mol S 1 x 32.07 = 32.07 4 mol O 4 x 16.00 = 64.00 132.17 g Stop for now…..
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