S AFETY DAT A SHEET Fischer-Tropsch (FT) Reactor Wax SECTION 1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Trade name Synonyms Use Company Address Telephone E-mail address SECTION 2 Fischer-Tropsch (FT) Reactor Wax FT wax (C10-C30), Unfinished FT wax, Paraffin wax, Synthetic Wax Research & Development Sasol (USA) Corporation - Tulsa Pilot Plant 1820 N. 161st E. Avenue, Tulsa, OK 74116-4827 CHEMTREC North America Transportation Emergency (24-hr) CHEMTREC World Wide Other Emergencies (24-hr) MSDS and Product Information (8:00am-4:30pm CST) Health and Safety Information (7:30am-4:00pm CST) [email protected] (800) 424-9300 (703) 527-3887 (337) 494-5142 (918) 257-2350 (281) 588-3492 HAZARDS IDENTIFICATION Not a hazardous substance or mixture according to OSHA HCS 2012. SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS Components Paraffin waxes and Hydrocarbon waxes CAS-No. 8002-74-2 Weight percent 100 See Section 8 for Exposure Guidelines and Section 15 for Regulatory Classifications. SECTION 4 FIRST AID MEASURES Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Inhalation Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. In case of shortness of breath, give oxygen. Call a physician immediately. Ingestion If swallowed, call a poison control centre or doctor immediately. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. SECTION 5 FIREFIGHTING MEASURES FLAMMABLE PROPERTIES Fire/explosion NFPA Class IIIB combustible liquid. Suitable Revision Date 12/03/2014 Water spray, Foam, Dry chemical, Carbon dioxide (CO2) Version 1.1 Print Date 12/03/2014 110000005042 Page 1 of 8 S AFETY DAT A SHEET Fischer-Tropsch (FT) Reactor Wax extinguishing media Protective equipment and precautions for firefighters Further information SECTION 6 Wear self-contained breathing apparatus and protective suit. Keep containers and surroundings cool with water spray. Prevent further leakage or spillage if safe to do so. Evacuate personnel to safe areas. ACCIDENTAL RELEASE MEASURES Methods and materials for containment and cleaning up SECTION 7 Evacuate the area and eliminate all sources of ignition. Use personal protective equipment. Spilled material will solidify. Pick up and arrange disposal without creating dust. Do not flush into surface water or sanitary sewer system. HANDLING AND STORAGE Safe handling advice Ensure all equipment is electrically grounded before beginning transfer operations. Keep away from heat and sources of ignition. Storage/Transport pressure Ambient Load/Unload temperature Ambient SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING MEASURES Air contaminant levels should be controlled below the PEL or TLV for this product (see Exposure Guidelines). PERSONAL PROTECTIVE EQUIPMENT Eyes Wear as appropriate: Goggles, Face-shield Skin Inhalation Wear suitable protective clothing, gloves and eye/face protection. Wear as appropriate: Impervious gloves When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Use NIOSH approved respiratory protection. EXPOSURE GUIDELINES Components Exposure limit(s) Paraffin waxes and ACGIH TLV (8-hour) 2 mg/m3 Hydrocarbon waxes PEL= TLV= EL= Permissible Exposure Limits Threshold Limit Value Excursion Limit Revision Date 12/03/2014 Version 1.1 TWA= STEL= WEEL= Time Weighted Average (8 hr.) Short Term Exposure Limit (15 min.) Workplace Environmental Exposure Level Print Date 12/03/2014 110000005042 Page 2 of 8 S AFETY DAT A SHEET Fischer-Tropsch (FT) Reactor Wax SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance solid; 20 °C, 1,013 hPa Colour white Form solid Odour Odour Threshold Flash point Flammability odourless no data available > 183 °C, > 361 °F; Upper explosion limit: no data available Lower explosion limit: no data available Boiling point/boiling range Melting point/range no data available 92 - 97 °C, 198 - 207 °F; Auto-ignition temperature no data available Decomposition temperature no data available Flammability (solid, gas) no data available Vapour pressure no data available Vapour density no data available Density 0.76 g/cm3 Specific gravity no data available Water solubility insoluble Viscosity Viscosity, dynamic pH no data available 2 mPa.s 7 Evaporation rate no data available Partition coefficient: noctanol/water no data available Revision Date 12/03/2014 Version 1.1 Print Date 12/03/2014 110000005042 Page 3 of 8 S AFETY DAT A SHEET Fischer-Tropsch (FT) Reactor Wax SECTION 10 Reactivity Chemical stability Conditions to avoid Hazardous decomposition products Materials to avoid Hazardous polymerisation SECTION 11 Acute dermal toxicity Acute inhalation toxicity STABILITY AND REACTIVITY Stable at normal ambient temperature and pressure. No decomposition if stored and applied as directed. Keep away from heat and sources of ignition. Carbon monoxide Flue gas Aldehydes in the case of incomplete combustion Oxidizing agents Reducing agents None. TOXICOLOGICAL INFORMATION LD50 rabbit: > 3,600 mg/kg Test substance: Synthetic wax; (literature value) no data available Acute oral toxicity LD50 rat: > 5,000 mg/kg Test substance: Synthetic wax; (literature value) Skin corrosion/irritation Not irritating Eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Primary irritation (rabbit): 2 (Max. score is 110.) Test substance: Synthetic wax Mild eye irritation no data available Genotoxicity in vitro: no data available Genotoxicity in vivo: no data available Assessment Mutagenicity: no data available Reproductive toxicity Revision Date 12/03/2014 Reproductive toxicity: no data available Version 1.1 Print Date 12/03/2014 110000005042 Page 4 of 8 S AFETY DAT A SHEET Fischer-Tropsch (FT) Reactor Wax Assessment Reproductive toxicity: no data available Teratogenicity: no data available Assessment teratogenicity: no data available STOT - single exposure no data available STOT - repeated exposure no data available Aspiration toxicity no data available Carcinogenicity SECTION 12 Toxicity to fish Toxicity to aquatic invertebrates Toxicity to algae Assessment carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. ECOLOGICAL INFORMATION LL50 (Pimephales promelas (fathead minnow)) 96 hours: > 100 mg/l EL50 (Daphnia magna (Water flea)) 48 hours: > 10,000 mg/l EL50 (Pseudokirchneriella subcapitata (green algae)) 72 hours: > 100 mg/l Chronic toxicity to fish no data available Chronic toxicity to aquatic invertebrates no data available Biodegradation Inherently biodegradable. OECD Test Guideline 301F (28 d): 31 % Bioaccumulation no data available Mobility in soil no data available Other adverse effects no data available SECTION 13 Revision Date 12/03/2014 DISPOSAL CONSIDERATIONS Version 1.1 Print Date 12/03/2014 110000005042 Page 5 of 8 S AFETY DAT A SHEET Fischer-Tropsch (FT) Reactor Wax Waste Code Any unused product or empty containers may be disposed of as non-hazardous in accordance with state and federal requirements. Re-evaluation of the product may be required by the user at the time of disposal, since the product uses, transformations, mixtures, contamination, and spillage may change the classification. If the resulting material is determined to be hazardous, please dispose in accordance with state and federal (40 CFR 262) hazardous waste regulations. Disposal methods Dispose of only in accordance with local, state, and federal regulations. Land disposal of this product is restricted. Do not contaminate any lakes, streams, ponds, groundwater or soil. Empty containers. Empty containers and original plastic liners may contain product residue. Handling of empty containers and liners should be in a manner to minimize dust generation. Safe handling procedures as outlined in the MSDS should be followed at all times. Consult the appropriate official for information regarding disposal requirements., Safe handling procedures as outlined in the MSDS should be followed at all times., Consult the appropriate official for information regarding disposal requirements. SECTION 14 TRANSPORT INFORMATION DOT Not regulated. IATA Not regulated. IMDG Not regulated. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Remarks SECTION 15 no data available REGULATORY INFORMATION U.S. FEDERAL REGULATIONS OSHA Hazards (HCS 1994) Non-hazardous substance TSCA Inventory Listing Components Paraffin waxes and Hydrocarbon waxes CAS-No. 8002-74-2 SARA 302 Status Components CAS-No. Weight percent SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 311/312 Classification Non-hazardous substance SARA 313 Chemical Components Revision Date 12/03/2014 CAS-No. Version 1.1 Print Date 12/03/2014 Weight percent 110000005042 Page 6 of 8 S AFETY DAT A SHEET Fischer-Tropsch (FT) Reactor Wax SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US. EPA CERCLA Hazardous Substances (40 CFR 302) Components none Reportable Quantity Weight percent INTERNATIONAL REGULATIONS WHMIS Classification WHMIS hazardous composition: No ingredients are hazardous according to the CPR criteria. European Union The product does not need to be labelled in accordance with EC directives or respective national laws. Australia. Inventory of Chemical Substances (AICS) Listed Japan. Inventory of Existing and New Chemical Substances (ENCS) Listed Japan. Industrial Safety & Health Law (ISHL) Inventory Listed Canada. Domestic Substances List (DSL) Inventory Listed Canadian Non-Domestic Substance Listing (NDSL) Not listed European Inventory of Existing Commercial Chemical Substances (EINECS) Listing Listed Philippines. Inventory of Chemicals / Chemical Substances (PICCS) Listed Korea. Existing Chemicals Inventory (KECI) Listed China. Inventory of Existing Chemical Substances (IECSC) Listed Mexico. National Inventory of Chemical Substances (INSQ) Listed New Zealand. Inventory of Chemicals (NZIoC) Listed Switzerland. Inventory of Notified New Substances (CHINV) Listed Taiwan. National Exisiting Chemical Inventory (NECI) Listed Please note: The names and CAS numbers which are used for this product in the stated inventories may deviate from the information which is listed in Section 3. STATE REGULATIONS California Prop. 65 Components none Revision Date 12/03/2014 CAS-No. Version 1.1 Print Date 12/03/2014 110000005042 Page 7 of 8 S AFETY DAT A SHEET Fischer-Tropsch (FT) Reactor Wax SECTION 16 OTHER INFORMATION HAZARD RATINGS HMIS® NFPA Health 1 1 Flammability 1 1 Physical Hazard/ Instability 0 0 THE DATA AND INFORMATION CONTAINED HEREIN ARE BEING FURNISHED FOR INFORMATIONAL PURPOSES ONLY, UPON THE EXPRESS CONDITION THAT EACH CUSTOMER SHALL MAKE ITS OWN ASSESSMENT OF APPROPRIATE USE AND APPROPRIATE SHIPPING, TRANSFER AND STORAGE MATERIALS AND PROCEDURES FOR SASOL CHEMICALS (USA) LLC'S PRODUCTS. ALTHOUGH BASED ON INFORMATION SOURCES WHICH SASOL CHEMICALS (USA) LLC CONSIDERS ACCURATE AND RELIABLE, SASOL CHEMICALS (USA) LLC MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, INCLUDING ANY WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, REGARDING THE VALIDITY OF THIS INFORMATION, THE INFORMATION SOURCES UPON WHICH THE SAME ARE BASED, OR THE RESULTS TO BE OBTAINED, AND EXPRESSLY DISCLAIMS LIABILITIES FOR DAMAGES OR INJURIES RESULTING FROM THE USE THEREOF. Revision Date 12/03/2014 Version 1.1 Print Date 12/03/2014 110000005042 Page 8 of 8
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