INDIAN SCHOOL AL WADI AL KABIR
DEPARTMENT OF SCIENCE 2016-17
CLASS XII
CHEMISTRY
DATE: 30.08.16
CHAPTER: THE SOLID STATE - QUESTION BANK
VERY SHORT ANSWER TYPE QUESTIONS ( 1 MARK EACH)
1. What is the number of atoms per unit cell in a body centered cubic structure?
2. Name an element with which silicon can be doped to give a p-type semiconductor.
3. A cubic solid is made of two elements X and Y. Atoms Y are at the corners of the cube and X at the
body centre. What is the formula of the compound?
4. Why is common salt sometimes yellow instead of being pure white?
5. Why are Frenkel defects not found in pure alkali halides?
6. What makes alkali metals halides sometimes coloured which are otherwise colourless?
7. What is the effect of Schottky and Frenkel defects on the density of crystalline solids?
8. Why is Frenkel defect found in AgCl?
9. Why are solids rigid ?
10. Name the non stoichiometric point defect responsible for colour in alkali halides.
11. Define the term space lattice?
12. Why is glass considered a super cooled liquid ?
13. What is the coordination number of an octahedral void?
14. What type of solids are electrical conductors, malleable and ductile?
SHORT ANSWER TYPE QUESTIONS : ( 2 MARKS EACH)
15. . How can you determine the atomic mass of an unknown metal if you know its density and the
dimension of its unit cell? Explain your answer.
16. How does amorphous silica differ from quartz?
17. Define the term amorphous .Give a few examples of amorphous solids.
18. What is a semiconductor? Describe two main types of semiconductors, giving examples.
19. Explain how vacancies are introduced in an ionic solid when a cation of higher valency is added as
an impurity in it
20. What type of substances would make better permanent magnets, ferromagnetic or ferromagnetic?
Justify your answer.
21. Assign reason why some of the very old glass objects appear slightly milky instead of being
transparent.
22. An element crystallizes in a structure having fcc unit cell with edge length of 200 pm. Calculate its
density, if 200 g of this element contains 24 x 1023 atoms.
23. The length of the unit cell edge of a body centered metal crystal is 352 pm. Calculate the radius of an
atom of a metal.
24. An element (Z=60) having face centered cubic unit cell has a density of 6.23 g/cm3.What is edge
length of unit cell.
25. State the difference between Schottky and Frenkel defects. Which of the two changes the density of
the solids?
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26. An element crystallizes in the simple cubic structure .Its density is 8 g/cm3 and its 200 g contains
24x10 23 atoms .Calculate the edge length.
27. How does electrical resistivity of the following class of materials vary with temperature?
Semiconductor, metallic conductor, insulator.
28. What is the coordination number of an octahedral void?
29. Which of the following lattices has the highest packing efficiency :
(i) FCC (ii) BCC (iii) simple cubic.
30. Atoms of element B form hcp lattice and those of the element A occupy 2/3rd of tetrahedral voids
.What is the formula of the compound formed by these elements A and B?
SHORT QUESTIONS (3 MARKS ONLY)
31. A compound is formed by two elements M and N. The element N forms ccp and atoms of M occupy
1/3rd of tetrahedral voids.What is the formula of the compound?
32. A solid A is very hard electrical insulator in solid as well as in molten state and melts at extremely
high temperature. What type of solids is it.
33. In terms of band theory what is the difference:
(i) Between a conductor and an insulator (ii) Between a conductor and a semiconductor?
34. Distinguish between Hexagonal and monoclinic unit cell.
35. What makes a glass different from a solid such as quartz?
Under what conditions could quartz be converted into glass?
36.
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37.
What type of stoichiometric defect is shown by: ZnS and AgBr?
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HOME ASSIGNMENT FOR THE WEEK
1. Analysis shows that a metal oxide has the empirical formula M0.94 O1.00. Calculate
the percentage of M2+ and M3+ ions in the crystal.
2. An element crystallizes in bcc structure. If edge length of cell is 1.469 x 10-8 cm
and density 19.3g /cm3 , then calculate the atomic mass of the element.
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