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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 10.08.2016
*
Version number 42
Revision: 08.08.2016
SECTION 1: Identification of the substance/mixture and of the company/
undertaking
· 1.1 Product identifier
· Trade name: POLURAN FINISH 90
· Article number: 790
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
· Sector of Use
SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites
· Application of the substance / the mixture Paint
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Baril Coatings BV
Zilverenberg 9
NL-5234 GL 's-Hertogenbosch
· Further information obtainable from:
Product Safety Department
R&D department
· 1.4 Emergency telephone number:
NVIC: +31(030) 2748888
Only for the purpose of informing medical personnel in cases of acute intoxications.
Uitsluitend bestemd om professionele hulpverleners te informeren bij acute vergiftigingen.
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 3
H226 Flammable liquid and vapour.
GHS07
Skin Irrit. 2
H315 Causes skin irritation.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS02 GHS07
· Signal word Warning
· Hazard statements
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P101
If medical advice is needed, have product container or label at hand.
P102
Keep out of reach of children.
P103
Read label before use.
(Contd. on page 2)
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Printing date 10.08.2016
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Revision: 08.08.2016
Trade name: POLURAN FINISH 90
(Contd. of page 1)
P210
Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241
Use explosion-proof electrical/ventilating/lighting/equipment.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P321
Specific treatment (see on this label).
P501
Dispose of contents/container in accordance with local/regional/national/
international regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures
· Description: Resin mixture
· Dangerous components:
CAS: 1330-20-7
xylene
15-<20%
EINECS: 215-535-7
Flam. Liq. 3, H226;
Acute Tox. 4, H312; Acute Tox.
Index number: 601-022-00-9 4, H332; Skin Irrit. 2, H315
Reg.nr.: 01-2119488216-32
CAS: 108-65-6
2-methoxy-1-methylethyl acetate
7-<10%
EINECS: 203-603-9
Flam. Liq. 3, H226
Index number: 607-195-00-7
Reg.nr.: 01-2119475791-29
CAS: 100-41-4
ethylbenzene
3-<5%
EINECS: 202-849-4
Flam. Liq. 2, H225;
STOT RE 2, H373; Asp. Tox. 1,
Index number: 601-023-00-4 H304;
Acute Tox. 4, H332; Aquatic Chronic 3, H412
Reg.nr.: 01-2119489370-35
CAS: 64742-95-6
Solvent naphtha (petroleum), light arom.
1-<2,5%
EINECS: 265-199-0
Flam. Liq. 3, H226;
Asp. Tox. 1, H304;
Aquatic
Index number: 649-356-00-4 Chronic 2, H411;
Acute Tox. 4, H332; Skin Irrit. 2,
Reg.nr.: 01-2119455851-35 H315; STOT SE 3, H335-H336
CAS: 64742-49-0
Naphtha (petroleum), hydrotreated light
0,25-0,5%
EINECS: 265-151-9
Flam. Liq. 1, H224;
Asp. Tox. 1, H304
Index number: 649-328-00-1
Reg.nr.: 01-2119475133-43
· Additional information: For the wording of the listed hazard phrases refer to section 16.
SECTION 4: First aid measures
· 4.1 Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation: In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
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Trade name: POLURAN FINISH 90
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SECTION 5: Firefighting measures
· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixture
No further relevant information available.
· 5.3 Advice for firefighters
· Protective equipment: No special measures required.
SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
· 7.1 Precautions for safe handling No special precautions are necessary if used correctly.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep container tightly sealed.
· 7.3 Specific end use(s) No further relevant information available.
*
SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
1330-20-7 xylene
IOELV Short-term value: 442 mg/m³, 100 ppm
Long-term value: 221 mg/m³, 50 ppm
Skin
(Contd. on page 4)
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Trade name: POLURAN FINISH 90
(Contd. of page 3)
108-65-6 2-methoxy-1-methylethyl acetate
IOELV Short-term value: 550 mg/m³, 100 ppm
Long-term value: 275 mg/m³, 50 ppm
Skin
100-41-4 ethylbenzene
IOELV Short-term value: 884 mg/m³, 200 ppm
Long-term value: 442 mg/m³, 100 ppm
Skin
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
· Respiratory protection: Not required.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Eye protection:
Tightly sealed goggles
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Fluid
Form:
According to product specification
Colour:
· Odour:
Characteristic
· Odour threshold:
Not determined.
· pH-value:
Not determined.
(Contd. on page 5)
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Trade name: POLURAN FINISH 90
(Contd. of page 4)
· Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
Undetermined.
137 °C
· Flash point:
30 °C
· Flammability (solid, gaseous):
Not applicable.
· Ignition temperature:
315 °C
· Decomposition temperature:
Not determined.
· Self-igniting:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive. However, formation of explosive
air/vapour mixtures are possible.
· Explosion limits:
Lower:
Upper:
1,1 Vol %
7,0 Vol %
· Vapour pressure at 20 °C:
6,7 hPa
· Density at 20 °C:
· Relative density
· Vapour density
· Evaporation rate
1,131 g/cm³
Not determined.
Not determined.
Not determined.
· Solubility in / Miscibility with
water:
Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic:
Kinematic at 20 °C:
Not determined.
100 s (ISO 6 mm)
· Solvent content:
Organic solvents:
VOC (EC)
32,9 %
32,92 %
Solids content:
· 9.2 Other information
67,0 %
No further relevant information available.
SECTION 10: Stability and reactivity
· 10.1 Reactivity No further relevant information available.
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: No dangerous decomposition products known.
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
(Contd. on page 6)
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(Contd. of page 5)
· LD/LC50 values relevant for classification:
1330-20-7 xylene
Oral
LD50
4300 mg/kg (rat)
Dermal
LD50
2000 mg/kg (rabbit)
64742-95-6 Solvent naphtha (petroleum), light arom.
Oral
LD50
>6800 mg/kg (rat)
Dermal
LD50
>3400 mg/kg (rab)
Inhalative LC50/4 h >10,2 mg/l (rat)
· Primary irritant effect:
· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Harmful to fish
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage
system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
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according to 1907/2006/EC, Article 31
Printing date 10.08.2016
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Revision: 08.08.2016
Trade name: POLURAN FINISH 90
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*
SECTION 14: Transport information
· 14.1 UN-Number
· ADR,RID,ADN, ADN, IMDG
· IATA
Void
UN1263
· 14.2 UN proper shipping name
· ADR,RID,ADN, ADN, IMDG
· IATA
Void
PAINT
· 14.3 Transport hazard class(es)
· ADR,RID,ADN, IMDG
· Class
· ADN
· ADN/R Class:
Void
Void
-
· IATA
· Class
· Label
3 Flammable liquids.
3
· 14.4 Packing group
· ADR,RID,ADN, IMDG
· IATA
Void
III
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user
Not applicable.
· 14.7 Transport in bulk according to Annex II
Not applicable.
of Marpol and the IBC Code
· Transport/Additional information:
*
· ADR/RID/ADN
· Remarks:
> 450 l: 3 F1, III
· IMDG
· Remarks:
> 30 l: 3, III
· UN "Model Regulation":
Void
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS02 GHS07
· Signal word Warning
· Hazard statements
H226 Flammable liquid and vapour.
(Contd. on page 8)
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Trade name: POLURAN FINISH 90
(Contd. of page 7)
H315 Causes skin irritation.
H412 Harmful to aquatic life with long lasting effects.
· Precautionary statements
P101
If medical advice is needed, have product container or label at hand.
P102
Keep out of reach of children.
P103
Read label before use.
P210
Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241
Use explosion-proof electrical/ventilating/lighting/equipment.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P321
Specific treatment (see on this label).
P501
Dispose of contents/container in accordance with local/regional/national/
international regulations.
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Qualifying quantity (tonnes) for the application of lower-tier requirements 5.000 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 50.000 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 20
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
· Relevant phrases
H224 Extremely flammable liquid and vapour.
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H373 May cause damage to the hearing organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
· Department issuing SDS: product safety department
· Contact: Mr. Frank van Hofwegen
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
SVHC: Substances of Very High Concern
Flam. Liq. 1: Flammable liquids – Category 1
Flam. Liq. 2: Flammable liquids – Category 2
Flam. Liq. 3: Flammable liquids – Category 3
Acute Tox. 4: Acute toxicity – Category 4
Skin Irrit. 2: Skin corrosion/irritation – Category 2
(Contd. on page 9)
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Revision: 08.08.2016
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(Contd. of page 8)
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
Asp. Tox. 1: Aspiration hazard – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered.
EU