Example Items Chemistry Chemistry Example Items are a representative set of items for the ACP. Teachers may use this set of items along with the test blueprint as guides to prepare students for the ACP. On the last page, the correct answer and content SE is listed. The specific part of an SE that an Example Item measures is not necessarily the only part of the SE that is assessed on the ACP. None of these Example Items will appear on the ACP. Teachers may provide feedback with the form available on the Assessment website: assessment.dallasisd.org. First Semester 2016–2017 Code #: 3101 STAAR STAAR CHEMISTRY REFERENCE MATERIALS TM State of Texas Assessments of Academic Readiness ATOMIC STRUCTURE Speed of light = (frequency)(wavelength) c = fλ Energy = (Planck’s constant)(frequency) Energy = E photon = hf (Planck’s constant)(speed of light) E photon = (wavelength) BEHAVIOR OF GASES Total pressure of a gas = ( sum of the partial pressures of the component gases ) PT = P1 + P2 + P3 + . . . (Pressure)(volume) = (moles)(ideal gas constant)(temperature) (Initial pressure)(initial volume) s )(initial temperature) (Initial moles (Initial pressure)(initial volume) (Initial volume) (Initial temperature) (Initial volume) (Initial moles) = = (final pressure)(final volume) = hc λ (final moles)(final temperature) = (final pressure)(final volume) PV = nRT PV 1 1 n1T1 = 1 1 T1 (final temperature) (final volume) V1 n1 (final moles) n2T2 PV = P V V1 (final vo l ume) P2V2 2 2 = = V2 T2 V2 n2 SOLUTIONS Molarity = moles of solute liter of solution M = Ionization constant of water = ( Volume of solution 1 pH = )( ) ( molarity of solution 1 = ( hydrogen ion concentration volume of solution 2 )( )( hydroxide ion concentration molarity of solution 2 −logarithm (hydrogen ion concentration) ) ) mol L K w = [H+][OH−] V1M1 = V2M2 pH = −log[H+] THERMOCHEMISTRY ( Heat gained or lost = (mass) ( specific heat ) ( enthalpy Enthalpy of reaction = of products )( change in temperature enthalpy − of reactants ) ) Q = mcp∆T ∆H = ∆H of (products) − ∆H of (reactants) STAAR CHEMISTRY REFERENCE MATERIALS OTHER FORMULAS Density = mass volume ( ( Percenterror= Percentyield= D = accepted value − experimental value accepted value actual yield theoretical yield ) ) (100) (100) CONSTANTS AND CONVERSIONS 23 Avogadro’s number = 6.02 × 10 particles per mole −34 h = Planck’s constant = 6.63 × 10 8 c = speed of light = 3.00 × 10 K J ⋅s m s −14 w = ionization constant of water = 1.00 × 10 alpha particle (α) = 4 He 2 beta particle (β) = 0 e −1 ( ) mol 2 L neutron = 1 n 0 standardtemperatureandpressure(STP)=0°Cand1atm 0°C=273K volume of ideal gas at STP = 22.4 L mol 3 1 cm = 1 mL = 1 cc 1atm=760mmHg=101.3kPa R = ideal gas constant = 0.0821 L ⋅ atm mol ⋅ K = 8.31 L ⋅ kPa mol ⋅ K = 62.4 L ⋅ mm Hg mol ⋅ K 1calorie(cal)=4.18joules(J) 1000calories(cal)=1Calorie(Cal)=1kilocalorie(kcal) RULES FOR SIGNIFICANT FIGURES 1. Non-zerodigitsandzerosbetweennon-zerodigitsarealwayssignificant. 2. Leadingzerosarenotsignificant. 3. Zerostotherightofallnon-zerodigitsareonlysignificantifadecimalpointisshown. 4. Forvalueswritteninscientificnotation,thedigitsinthecoefficientaresignificant. 5. Inacommonlogarithm,thereareasmanydigitsafterthedecimalpointasthereare significantfiguresintheoriginalnumber. m V Compoundsof NH+ andthealkalimetalcations Compoundsof NH+ andthealkalimetalcations Compoundsof NH4+ ,thealkalimetalcations, SO2− 4 Insoluble compounds contain CrO2− 4 Cr2O2− 7 OH− ClO3− ClO2− CrO2− 4 CN− Cr2O2− 7 HCO3− OH− ClO− NO3− NO2− ClO4− MnO− 4 PO3− 4 SO2− 4 SO2− 3 Chlorate Chlorite Chromate Cyanide Dichromate Hydrogencarbonate Hydroxide Hypochlorite Nitrate Nitrite Perchlorate Permanganate Phosphate Sulfate Sulfite None ClO3− ClO4− − S2− PO3− 4 CO2− 3 I− Cl− Br None ClO2− Ca2+,Sr 2+ 2+ ,and Ba2+ ,and Ba2+ Compoundsof NH4+ ,thealkalimetalcations, Ca2+,Sr 4 4 4 Compoundsof NH+ andthealkalimetalcations 4 Compoundsof NH+ andthealkalimetalcations Common exceptions Compoundsof Sr 2+ ,Ba2+ , Pb2+ ,and Hg2+ 2 Compoundsof Ag+ , Pb2+ ,and Hg2+ 2 Compoundsof Ag+ , Pb2+ ,and Hg2+ 2 Compoundsof Ag+ , Pb2+ ,and Hg2+ 2 None None None CN− ClO− None NO3− None CO2− 3 None Carbonate C2H3O2− , CH COO− 3 NH4+ Gold Platinum Silver Mercury Copper (Hydrogen) Lead Tin Nickel Cobalt Iron Chromium Zinc Manganese Aluminum Magnesium Sodium Calcium Barium Potassium Lithium Metal Common exceptions Soluble compounds contain NH4+ C2H3O2− , CH3COO− ACTIvITY SERIES SOLubILITY Of COMMON IONIC COMPOuNdS IN WATER Ammonium Acetate POLYATOMIC IONS STAAR CHEMISTRY REfERENCE MATERIALS Increasing Activity 7 6 5 4 3 2 1 3 104 103 88 (262) (226) Radium (223) Francium (267) Rf 7 7B Actinide Series Lanthanide Series 60 231.036 Protactinium 232.038 Thorium (227) Actinium 91 Pa Ac Th 89 90 140.908 Cerium 144.242 (145) 61 Pm Hassium (270) 108 Hs 190.23 Osmium Os 76 Ruthenium 101.07 44 Ru Iron 55.845 Fe 26 8 Silicon 28.086 Si Uranium 238.029 U 92 Neptunium (237) 93 Np Praseodymium Neodymium Promethium 140.116 138.905 Nd 59 Lanthanum La Pr 58 Bohrium (271) Seaborgium (272) 107 Bh (268) Sg 106 Rhenium 186.207 Re 75 Dubnium 105 183.84 Tungsten 180.948 Tantalum 74 W Db (98) 43 Tc Manganese 54.938 Mn 25 Molybdenum Technetium 95.96 42 Mo Chromium 51.996 Cr 24 6 6B Ta 73 Niobium 92.906 41 Nb Vanadium 50.942 V 23 5 5B Atomic mass Symbol Ce 57 Lawrencium Rutherfordium Lr Ra 87 Fr 178.49 Hafnium Lutetium Barium Cesium 174.967 137.328 132.905 Hf Ba Lu 72 71 Cs 56 55 Zirconium 91.224 40 Zr Yttrium 88.906 87.62 Strontium 85.468 Rubidium Y 39 Sr 38 Rb 37 47.867 Titanium 44.956 Scandium 40.078 Calcium 39.098 Potassium 22 Ti 21 4 4B Sc 19 3 3B Ca 20 Sodium K 24.305 Magnesium 22.990 Mg 12 11 Na 9.012 Beryllium 6.941 Lithium Li Be 4 Hydrogen 1.008 2 2A H Name 10 11 1B 12 2B 13 3A 14 4A 15 5A 16 6A 17 7A (281) Ds 110 Platinum 195.085 Pt 78 Palladium 106.42 46 Pd Nickel 58.693 Ni 28 (280) 111 Rg Gold 196.967 Au 79 Silver 107.868 47 Ag Copper 63.546 Cu 29 Plutonium (244) 94 Pu Samarium 150.36 62 Sm (247) Curium (243) 96 Cm Americium 95 Am 157.25 Gadolinium 151.964 64 Gd Europium 63 Eu Meitnerium Darmstadtium Roentgenium (276) Mt 109 Iridium 192.217 Ir 77 Rhodium 102.906 45 Rh Cobalt 58.933 Co 27 9 8B Thallium 204.383 Tl 81 Indium 114.818 49 In Gallium 69.723 Ga 31 Lead 207.2 Pb 82 Tin 118.711 50 Sn Germanium 72.64 Ge 32 Silicon 28.086 Si 14 Carbon 12.011 C 6 Bismuth 208.980 Bi 83 Antimony 121.760 51 Sb Arsenic 74.922 As 33 30.974 Phosphorus P 15 Nitrogen 14.007 N 7 Berkelium (247) 97 Bk Terbium 158.925 65 Tb Californium (251) 98 Cf Dysprosium 162.500 66 Dy Einsteinium (252) 99 Es Holmium 164.930 67 Ho Fermium (257) 100 Fm Erbium 167.259 68 Er Mass numbers in parentheses are those of the most stable or most common isotope. Mercury 200.59 Hg 80 Cadmium 112.412 48 Cd Zinc 65.38 Zn 30 Aluminum 26.982 Al 13 Boron 10.812 B 5 Mendelevium (258) 101 Md Thulium 168.934 69 Tm Polonium (209) Po 84 Tellurium 127.60 52 Te Selenium 78.96 Se 34 Sulfur 32.066 S 16 Oxygen 15.999 O 8 Radon (222) 86 Rn Xenon 131.294 54 Xe Krypton 83.798 36 Kr Argon 39.948 18 Ar Neon 20.180 10 Ne Helium Updated Spring 2011 Nobelium (259) 102 No Ytterbium 173.055 70 Yb Astatine (210) At 85 Iodine 126.904 I 53 Bromine 79.904 Br 35 Chlorine 35.453 Cl 17 Fluorine 18.998 F 9 4.003 He 2 14 1 Atomic number 18 8A 1 1A PERIODIC TABLE OF THE ELEMENTS STAAR CHEMISTRY REFERENCE MATERIALS EXAMPLE ITEMS Chemistry, Sem 1 1 2 3 Which is a chemical property of copper? A It is a mineral. B It reacts with nitric acid. C It is a liquid at 1083ºC. D It is malleable and ductile. What is the number of atoms in three grams of gold? A 9.17 1021 B 1.806 1024 C 6.02 1023 D 2.29 1022 The equation for the synthesis reaction of aluminum and oxygen is shown. ? Al (s) + ? O2 (g) ? Al2O3 (s) Which list shows the order of coefficients needed to balance this equation? 4 A 2, 3, 1 B 2, 1, 2 C 4, 1, 2 D 4, 3, 2 The table shows the percent composition of a compound containing hydrogen and oxygen. Element Percent Composition Hydrogen 11.19% Oxygen 88.81% What is the empirical formula for this compound? A H2O B H2O2 C H11O6 D H11O89 Dallas ISD - Example Items EXAMPLE ITEMS Chemistry, Sem 1 5 6 7 8 9 How many grams are there in one mole of Aluminum? A 3.01 1023 B 6.02 1025 C 13.0 D 26.982 A 14-karat gold ring consists of 14 parts gold and 10 parts copper. This alloy can be separated by density when melted. Which type of matter is the 14-karat gold ring? A Compound B Pure substance C Homogeneous mixture D Heterogeneous mixture What is the formula of calcium permanganate? A CaMnO4 B Ca(MnO4)2 C Ca3MnO4 D Ca3(MnO4)3 Which chemical family or group on the Periodic Table contains the least reactive elements? A Group 1 B Group 3 C Group 17 D Group 18 The Electron Sea Model explains why metals — A accept electrons easily B are excellent conductors C are mostly brittle D form ionic compounds Dallas ISD - Example Items EXAMPLE ITEMS Chemistry, Sem 1 10 11 What is the name of the molecular compound with the formula P2O5? A Pentaphosphorus dioxide B Decaphosphorus pentoxide C Diphosphorus pentoxide D Diphosphorus monoxide Equal volumes of a liquid and a gas are placed in separate containers, and equal pressure is applied as shown in the illustration. Which statement describes the result of this experiment? 12 A The liquid has less mass than the gas. B The liquid has more mass than the gas. C The gas is less compressible than the liquid. D The gas is more compressible than the liquid. What is the Lewis electron dot structure for the covalent compound sulfur dioxide? A B C D Dallas ISD - Example Items EXAMPLE ITEMS Chemistry, Sem 1 13 14 Which represents the ground state electron configuration for manganese? A 1s2 2s2 2p6 3s2 3p6 4s2 3d5 B 1s2 2s2 2p6 3s2 3p6 4s2 4d5 C 1s2 2s2 2p6 3s2 3p6 4s7 D 1s2 2s2 2p6 3s2 3p6 4d7 The molar mass of a compound that has an empirical formula of KNO2 is 255 g/mole. What is the compound’s molecular formula? A KNO2 B K2N2O4 C K3N3O9 D K3N3O6 Use the electromagnetic spectrum to answer the next question. 15 Which type of electromagnetic waves have the greatest energy? A Gamma rays B Microwaves C Radio waves D Visible light Dallas ISD - Example Items EXAMPLE ITEMS Chemistry, Sem 1 16 17 What is the percent composition of phosphorus in the compound Ca3(PO4)2? A 10.0% B 20.0% C 30.0% D 50.0% If a beam of blue light has a frequency of 6.67 1014 Hz, its wavelength is — A 4.50 10–7 m B 4.50 10–6 m C 3.00 108 m D 2.22 106 m Dallas ISD - Example Items EXAMPLE ITEMS Chemistry, Sem 1 18 The table shows the two isotopes of an element. Isotope Mass (amu) Percent Abundance x 10.013 19.8% y 11.009 80.2% Average Atomic Mass Average Mass ? What is the average atomic mass of the element? (Round to the nearest tenth) Record the answer and fill in the bubbles on the grid provided. Be sure to use the correct place value. Dallas ISD - Example Items EXAMPLE ITEMS Chemistry, Sem 1 ? Answer SE Process Skills ? Answer SE Process Skills 1 1 B 4A -- 11 11 D 4C 2H, 2I 2 2 A 8B 2G 12 12 B 7C 2I 3 3 D 8D 2G 13 13 A 6E -- 4 4 A 8C 2H 14 14 D 8C 2G 5 5 D 8A 2H 15 15 A 6B 2H, 2I 6 6 C 4D -- 16 16 B 8C 2G 7 7 B 7B -- 17 17 A 6C 2G 8 8 D 5B 2H 18 18 10.8 6D 2H, 2G 9 9 B 7D -- 10 10 C 7A -- Dallas ISD - Example Items
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