Name ______________________________________________ Date _____________________ Period______ Writing Formulas and Naming Ionic Compounds, Covalent Compounds and Acids IONIC COMPOUNDS: Ionic compouds start with a metal or ammonium (cation +) Steps for writing FORMULAS for ionic (metal + non-metal) compounds: 1. Write the METAL (cation) or ammonium (cation) first and the NON-METAL (anion) second. 2. Write the CHARGE for each ion. 3. Cross the charges to become subscripts on the opposite ion. If you must add a subscript after a polyatomic ion, it must be placed in parentheses and then the subscript is added outside the parentheses. Ex: Aluminum nitrate Al+3 (NO3)-1 Ex: Tin (IV) sulfate Sn+4 (SO4)-2 = = Al(NO3)3 Sn2(SO4)4 = Sn(SO4)2 Must Reduce Steps for NAMING ionic compounds 1. Write the name of the metal (cation) or ammonium. If the cation is NOT group 1, 2, Ag, Zn, Cd, or Al, USE roman numerals to indicate its charge. 2. Shorten the name of the non-metal (monatomic anion) and add the suffix "ide". If the anion is a polyatomic ion, simply write the name of the polyatomic ion. Ex: CaBr2 = Calcium bromide Ex: Pb(SO4)2 = Lead (IV) sulfate Calcium is in group 2. Do not indicate its charge in the name. Lead is considered an “other metal.” Must indicate its charge in the name. Determine its charge from the anion. COVALENT (MOLECULAR) COMPOUNDS: Covalent compounds start with a non-metal. Steps for writing FORMULAS for covalent (non-metal + non-metal) compounds: 1. Use the following prefixes to indicate the number of atoms of each element present in a covalent (molecular) compound. Number 1 2 3 4 5 3 Example: Prefix Mono Di Tri Tetra Penta Number 6 7 8 9 10 Prefix Hexa Hepta Octa Nona Deca 5 TRInitrogen PENToxide = N3O5 Steps for NAMING covalent (non-metal + non-metal) compounds: 1. Use the prefixes above to indicate the number of atoms of each element present in a covalent (molecular) compound. Exception – Never use mono with the first element. Change the ending on the second non-metal to “-ide.” Examples: N2Br4 = DInitrogen TETRAbromide CO2 = Carbon DIoxide ACIDS: Acids start with hydrogen. Steps for writing FORMULAS for acids: 1. Binary Acids (hydrogen and a non-metal) a. Name begins with “hydro” i. Write the cation (always H+1 for acids). Write the anion. ii. Cross the charges to become subscripts on the opposite ion. Example: Hydrobromic Acid = H+1 Br-1 = H+1 Br-1 HBr = 2. Ternary Acids (hydrogen and a polyatomic ion) a. Name DOES NOT begin with “hydro” i. Write the cation (always H+1 for acids). ii. Write the anion. Determine the polyatomic ion from the name of the acid. If it is ______ic Acid, then the polyatomic ion name ends in _____ate. If it is _____ous Acid, then the polyatomic ion name ends in _____ite. iii. Cross the charges to become subscripts on the opposite ion. Example: Chromic Acid = H+1 CrO4-2 = H+1 CrO4-2 = H2CrO4 Name does not begin with “hydro” so it contains a polyatomic ion. Since the acid name ends with –ic, the polyatomic ion name ends with –ate (chromate). Example: Nitrous Acid = H+1 NO2-1 = H+1 NO2-1 = HNO2 Name does not begin with “hydro” so it contains a polyatomic ion. Since the acid name ends with –ous, the polyatomic ion name ends with –ite (nitrite). Steps for NAMING acids: 1. Binary Acids (hydrogen and a non-metal) a. Anion name ends in –ide, change to hydro________ic Acid. Example: HCl = Hydrochloric Acid Chloride 2. Ternary Acids (hydrogen and a polyatomic ion) a. Anion name ends in –ate, change to _____ic Acid –ite, change to _____ous Acid Example: HClO3 = Chloric Acid Chlorate Example: HClO2 = Chlorous Acid Chlorite Write the formulas for the following compounds: Cation Anion a. Potassium acetate _______ _______ ___________________ b. Hypochlorous acid _______ _______ ___________________ c. Nitrogen heptabromide Formula ___________________ d. Lithium phosphate _______ _______ ___________________ e. Carbonic acid _______ _______ ___________________ f. Lead (IV) dichromate _______ _______ ___________________ g. Carbon monoxide ___________________ h. Zinc permanganate _______ _______ ___________________ i. Copper (II) nitrite _______ _______ ___________________ j. Silver chlorate _______ _______ ___________________ k. Dinitrogen pentoxide ___________________ l. Hydrochloric acid _______ _______ ___________________ m. Calcium Hydroxide _______ _______ ___________________ n. Manganese (III) Chloride _______ _______ ___________________ o. Strontium nitride _______ _______ ___________________ Name the following compounds: a. SO2 ___________________________________ b. Hg(NO3)2 ___________________________________ c. (NH4)2S ___________________________________ d. K2O ___________________________________ e. HClO2 ___________________________________ f. SiO2 __________________________________ g. Pb(CrO4)2 ___________________________________ h. Al(NO3)3 ___________________________________
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