Earth and Planetary Science Letters 250 (2006) 38 – 52 www.elsevier.com/locate/epsl Ultra-rapid formation of large volumes of evolved magma C. Michaut ⁎, C. Jaupart Institut de Physique du Globe de Paris, France Received 25 January 2006; received in revised form 12 July 2006; accepted 12 July 2006 Available online 1 September 2006 Editor: R.D. van der Hilst Abstract We discuss evidence for, and evaluate the consequences of, the growth of magma reservoirs by small increments of thin (⋍ 1–2 m) sills. For such thin units, cooling proceeds faster than the nucleation and growth of crystals, which only allows a small amount of crystallization and leads to the formation of large quantities of glass. The heat balance equation for kineticcontrolled crystallization is solved numerically for a range of sill thicknesses, magma injection rates and crustal emplacement depths. Successive injections lead to the accumulation of poorly crystallized chilled magma with the properties of a solid. Temperatures increase gradually with each injection until they become large enough to allow a late phase of crystal nucleation and growth. Crystallization and latent heat release work in a positive feedback loop, leading to catastrophic heating of the magma pile, typically by 200 °C in a few decades. Large volumes of evolved melt are made available in a short time. The time for the catastrophic heating event varies as Q− 2, where Q is the average magma injection rate, and takes values in a range of 105–106 yr for typical geological magma production rates. With this mechanism, storage of large quantities of magma beneath an active volcanic center may escape detection by seismic methods. © 2006 Elsevier B.V. All rights reserved. Keywords: magma reservoirs; crystallization kinetics; thermal evolution; catastrophic melting; magma input rate 1. Introduction Eruption of large volumes of highly evolved melts during caldera formation requires the presence of sizable magma reservoirs beneath active volcanoes. Yet, these reservoirs often elude the most detailed geophysical surveys, [1]. According to petrological and geochronological data, they develop over large lengths of time [2–4], which is not consistent with physical models for the cooling of large magma bodies, [5–7]. Magma ascent through the Earth's crust proceeds mostly through dyke propagation, ⁎ Corresponding author. E-mail address: [email protected] (C. Michaut). 0012-821X/$ - see front matter © 2006 Elsevier B.V. All rights reserved. doi:10.1016/j.epsl.2006.07.019 which can transport large quantities of magma in short pulses of activity. Field evidence demonstrates that some plutons develop incrementally as sheeted sill complexes, [8–11], see Table 1. Where field exposures and late-stage modifications have completely obliterated traces of internal intrusive contacts, geochronological studies suggest that such bodies may get assembled over more than 1 Ma [12]. Thermal models for the progressive growth of magma reservoirs have been developed by several authors [13–15]. Such models have dealt with either discrete injections of thick magma sheets (⋍ 100 m) or continuous infilling of a reservoir, and rely on equilibrium crystallization calculations. They predict many features that are consistent with the observations, including peaks of activity associated C. Michaut, C. Jaupart / Earth and Planetary Science Letters 250 (2006) 38–52 39 Table 1 Sheeted sill complexes Location Sierra Nevada Batholith, Onion Valley, California Upper sill complex Lower sill complex Everest region, eastern Nepal Southeast coast plutonic complex, British Columbia Scuzzy pluton margins Icelandic cone-sheet swarms Geitafell Volcano, SE Thverartindur Central Volcano Composition Sill thickness Refs Hornblende gabbro Hornblende gabbro Leucogranite 0.1–1.5 (m) 2–4 (m) From cm to several m [10] [49] Tonalite cm to 100 (m) [23] Gabbro Gabbro 0.5 to 1 (m) 0.9 (m) on average [50] [25] with each injection event, partial melting of country rock and progressive changes of magma composition over long time-intervals. They do not predict the sharp changes of erupted lava composition that may occur and intriguing features of igneous complexes such as internal quench textures and episodic phases of crystallization [16]. By construction, they imply that melt reservoirs remain present throughout the lifetime of active volcanic centers, which is difficult to reconcile with seismic evidence. These paradoxical observations have motivated us to develop a new model for the growth of a magma reservoir by thin sills where crystallization is controlled by the sluggish kinetics of crystal nucleation and growth, [17,18]. The model relies on the quenching of magma such that a large proportion of glass remains and is applicable mostly to magma intrusions in the upper crust, in contrast to Annen and Sparks [13]. Successive thin injections lead to the accumulation of quenched magma with little crystallization. Kinetic controls on crystallization are such that the rates of nucleation and growth start from zero at the liquidus temperature, reach a maximum at some finite undercooling and tend to negligible values at large undercoolings. Rapid cooling to low temperatures thus impedes crystallization and leads to glass formation. In natural magmatic systems, the temperature evolution depends on heat loss to the surroundings and latent heat release, [19]. Latent heat release works in two different ways depending on the thermal path. For a cooling path following contact with cold surroundings, i.e. starting from high temperatures, latent heat release acts to slow down cooling and to decrease the crystallization rate, [19]. Here, we are interested in another thermal path starting from low temperatures. Beginning with chilled magma, punctuated emplacement of small magma batches acts to increase temperatures slowly until crystallization sets in. In this case, crystallization occurs whilst temperatures are rising and latent heat release enhances heating and crystallization in a positive feedback loop. We develop a quantitative thermal model which illustrates this process. In this paper, we first discuss field evidence for the formation of magma reservoirs out of sheeted sill complexes, focussing on sill thicknesses. We then review available data on the kinetics of nucleation and growth in natural magmas and show that the cooling and crystallization of many sill complexes is kinetically controlled. We focus on basalts for the purposes of this study, but show that the same physical mechanism is likely to operate in andesites and other evolved magmas. The study is set up to describe the new physical mechanism in the clearest manner and to evaluate the influence of each control parameter. We develop a quantitative thermal model and discuss solutions for a large range of parameters. We discuss how the vagaries of magma emplacement in a natural setting may lead to different thermal evolutions. Requirements for the applicability of the model to natural situations are established. The paper closes with a short section on peculiar observations in magmatic and volcanic systems that can be explained by the model. 2. Cooling and crystallization of magma In this paper, we consider a new crystallization mechanism due to emplacement in colder continental crust. Evolved melts with large water contents may also crystallize in response to decompression once they reach water saturation [20]. We discuss briefly the behaviour of such melts in a separate section. 2.1. Sheeted sill complexes At the Onion Valley complex, Sierra Nevada Batholith, California, thin basaltic sills of 0.1- to 1.5-m thick form the margins of a large intrusion and are chilled against inter-sill septa or against one another with finer-grained to aphanitic margins [10]. In most of the sills, textural evidence indicates that the cores of plagioclase crystals initially grew in strongly undercooled melt. In the middle part of the intrusion, sills tend to be thicker (2–4 m) and include pillow-shaped masses which suggest emplacement of thin 40 C. Michaut, C. Jaupart / Earth and Planetary Science Letters 250 (2006) 38–52 flow units. In the pluton center, no clear intrusive contacts can be traced, but comb-layering and quench textures suggest that part of the crystallization sequence occurred at large degrees of undercooling. Such features are best interpreted as due to individual injection events with large temperature contrasts between the incoming and resident magmas. Similar observations in other intrusive bodies have been interpreted in the same way, for example elsewhere in the Sierra Nevada Batholith, [21], and in the Kap Edvard Holm Layered Gabbro Complex, East Greenland, [22]. In the Scuzzy pluton, Southeast Coast Plutonic Complex, British Columbia, the outer marginal zone is made of a spectacular sill complex with individual units that are typically 1–2-m thick, [23]. Away from the margins, the interior is made of massive igneous rocks, but one should not deduce from this that the bulk of the pluton was injected in one piece. Upon closer scrutiny, the massive interior contains a large number of thin countryrock lenses which once separated different magma batches. Thus, it may very well be that evidence for a sheeted sill structure got obliterated and, in fact, the present physical mechanism explains how this may occur. Shallow intrusives provide complementary information on the typical thickness of individual magma pulses. Preservation of individual contacts is enhanced by the shorter-lived activity, smaller background temperatures and possibly by enhanced cooling due to hydrothermal circulation. The typical thickness of individual intrusions occurring as dykes, sills or sheets, is about 1 m, [24]. In the root of the Thverartindur Central Volcano, Iceland, for example, a cone-sheet swarm is made of 1128 individual sills with an average thickness of 0.9 m, [25]. Table 1 recapitulates sill thicknesses that have been determined in a variety of igneous complexes. One should note that thin intrusions are documented in different environments as well as in magmas of different compositions. Another way to evaluate the thickness of individual intrusions relies on the bulk magma production rate, which has been determined at a number of continental volcanoes by Crisp [26]. Assuming that the caldera size is equal to the area of the magma chamber, the rate of growth of reservoirs in the vertical direction lies between 10− 2 and 10− 3 m yr− 1 in the vast majority of cases. Over the lifetime of a volcanic system, which is typically a few times 100,000 yr, such rates lead to pluton thicknesses of a few kilometers that are consistent with the geological record. One may further assume that injection events are associated with volcanic unrest or eruptions. Using a repetition time between 100 and 1000 yr, the average intrusion thickness is constrained to be between 10 cm and 10 m, which is consistent with the data in Table 1. 2.2. The rates of crystal nucleation and growth in silicate melts Nucleation and growth rates are zero at the liquidus because crystallization requires a finite energy. At small undercoolings, close to the liquidus, the free energy of the solid phase or the energy difference between crystal and liquid is the main control on both nucleation and growth. At low temperature, the limiting process is chemical diffusion, [27]. Both the nucleation and growth rates increase with the increasing undercooling until they reach a maximum and then decrease to zero at large undercoolings. Direct determinations of the rates of crystal nucleation and growth in silicate melts are scarce (Table 2). Very few measurements of the maximum growth rate have been attempted in the laboratory and we are aware of none for the maximum nucleation rate. A careful and systematic study was carried out for the Ab–An system [28], a synthetic system for which liquidus temperatures are much higher than those of natural magmas over a large composition range. For plagioclase crystals that have the same composition as those found in natural melts, the maximum growth rate is about 5 × 10− 5 cm s− 1, [28]. One well-known fact is that, for a given mineral, the peak growth rate is smaller in a complex multicomponent melt than in its own melt [27,29]. One should therefore treat the Ab–An growth rates as upper bounds for plagioclase crystals in natural magmas. Available data and laboratory experiments on basaltic melts indicate that olivine, pyroxene and plagioclase are ranked in decreasing order with regard to their ease of nucleation [30]. The growth and nucleation rates of olivine, pyroxene and plagioclase crystals have been measured in basaltic lava lakes and flows, either in situ or through the analysis of crystal size distributions [31–33]. For olivine, values are in the ranges of 10− 11 to 10− 10 cm s− 1 and 10− 6 to 10− 5 cm− 3 s− 1 respectively. These measurements have been made at small amounts of undercooling in magmas that had already started to crystallize. As can be seen in Table 2, independent estimates are consistent with one another but do not allow reconstruction of the full nucleation and growth functions. Another method has been used to determine the peak rates of nucleation and growth in natural magmas. Following emplacement in colder country rock, magma cooling and crystallization proceed in a highly transient thermal regime with cooling rates that decrease away from the contact. One consequence is that crystal sizes increase with increasing distance from the margin, which provides a powerful constraint on crystallization kinetics in natural conditions. By comparing crystal size measurements in mafic intrusions and numerical crystallization calculations, C. Michaut, C. Jaupart / Earth and Planetary Science Letters 250 (2006) 38–52 41 Table 2 Nucleation and growth rates in silicate melts Y (cm s− 1) I (cm− 3 s− 1) Refs . aboratory experiments on synthetic systems L Ab–An Plagioclase An30 Plagioclase An40 Ab–An Plagioclase An50 Ab–An Ym = 1 × 10− 5 Ym = 5 × 10− 5 Ym = 2 × 10− 6 / / / [28] [28] [51] . atural systems–natural conditions N Plagioclase Basaltic lava lake in situ Plagioclase Basaltic lava lake Olivine Basaltic lava lake Plagioclase Basaltic lava lake Pyroxene Basaltic lava lake Plagioclase Basaltic lava flow Pyroxene Basaltic lava flow 10− 10–10− 9 6 × 10− 11–10− 10 3 × 10− 11–2 × 10− 10 3 × 10− 9–8 × 10− 7 10− 9–2 × 10− 8 2 × 10− 11–5 × 10− 8 2 × 10− 11–4 × 10− 8 10− 2–1 3 × 10− 2 9 × 10− 7–6 × 10− 6 3 × 10− 4–3 × 10− 2 2 × 10− 4–3 × 10− 3 10− 3–4 × 10− 1 10− 3–8 × 10− 2 [31] [32] [33] [52] [52] [53] [53] . aboratory experiments on natural systems L Plagioclase Basalt Pyroxene Basalt 10− 11–10− 10 10− 9–10− 8 10− 6–10− 4 10− 6–10− 4 [52] [52] . heoretical calculations of crystal size variations T Opx and Plag. Diabase dykes Ym ≈ 10− 7 Im ≈ 1 [17] Mineral System I and Y are average values measured in small samples at small undercoolings, Im and Ym are maximum rates over the whole crystallization interval. Brandeis and Jaupart [17] were able to constrain the peak rates of nucleation and growth to be about 1 cm− 3 s− 1 and 10− 7 cm s− 1 respectively for both pyroxene and plagioclase crystals. These values are indeed much larger than local ones determined at small undercoolings (Table 2). So far, we have focussed on basaltic melt compositions because of the rather large number of studies devoted to them. Table 3 lists values of peak crystal growth rates in evolved magmas. The data suggest that peak growth rates are similar to those of more mafic melts and decrease with increasing water content. Values for a water-rich andesitic melt are unambiguously smaller than those for more primitive basaltic compositions. 2.3. Kinetic controls on magma crystallization Here, we explain the basic physical principle by comparing the time-scales for cooling and for crystal- lization. This principle is later put to test with a full numerical solution of the governing equations. Denoting the rates of nucleation and growth by I and Y respectively, the crystallization time-scale is [17]: s ¼ ðIY 3 Þ−1=4 ð1Þ Cooling and crystallization proceed in transient thermal conditions involving two different kinetic timescales. For large undercoolings, the relevant characteristic time, τm, relies on the peak rates of nucleation and growth, noted Im and Ym respectively. From the data in Table 2, τm is ≈ 2 × 105 s in basalts, or about 2 d. This corresponds to the most rapid crystallization obtained by maintaining both rates at their peak values. This cannot achieved in practice, however, because the two peak values are not reached at the same degree of undercooling [27]. Thus, τm provides a lower bound to the true crystallization time. At Table 3 Laboratory determinations of peak rates of nucleation and growth in evolved melts Mineral Plagioclase Plagioclase Plagioclase Plagioclase Alkali Fs Alkali Fs Alkali Fs Ym (cm s− 1) System a Andesite + 6.4% H20 Granite (synthetic) + 3.5% H20 Granodiorite (synthetic) + 6.5% H20 Granodiorite (synthetic) + 12% H20 Granite (synthetic) + 3.5% H20 Granodiorite (synthetic) + 6.5% H20 Granodiorite (synthetic) + 12% H20 ‡Not measured. a Crystallization is induced by decompression. −9 1.7 × 10 10− 6 5 × 10− 7 ≈ 10− 8 2 × 10− 7 10− 7 ≈ 10− 8 Im (cm− 3 s− 1) −2 3.2 × 10 ‡ ‡ ‡ ‡ ‡ ‡ Refs [42] [54] [54] [54] [54] [54] [54] 42 C. Michaut, C. Jaupart / Earth and Planetary Science Letters 250 (2006) 38–52 small undercoolings, which prevails some time after emplacement in thick magma bodies, the rates of nucleation and growth are necessarily smaller than their peak values. Thus, the characteristic kinetic time τ must be much larger than τm. From Table 2, this characteristic crystallization time is τ ≈ 4 × 108 s for olivine in natural basalts. For plagioclase crystals, it is in a range of 107 to 108 s, i.e. from 0.3 to 3 yr. As expected, these values are larger than τm. The true crystallization time in transient thermal conditions is bracketed by τm and τ and will be noted τk. According to [19,34], this crystallization time is about 106 s (i.e. 11 d) or more for basaltic magmas. For quenching to occur, cooling must occur on time scales that are too short to allow a significant amount of crystallization. For thin sills of thickness d, conduction is the dominant heat transport mechanism and the characteristic cooling time is: sd c 1 d2 4j ð2Þ One should note that a sill loses heat from both margins and that this cooling time must be regarded as an upper bound. The true cooling time may be much smaller than this in shallow environments due to hydrothermal circulation. The ratio of the cooling time to the kinetic time, called the Avrami number, is the relevant dimensionless number to assess kinetic controls on crystallization [17,18]: 4 2 4 sd d Aυ ¼ ¼ IY 3 sk 4j ð3Þ Analysis shows that quenching occurs if Aυ b 1 [17,18]. For a typical sill thickness of 1 m, τd = 3 × 105 s. With τk = 106 s, Aυ b 1, implying that little crystallization occurs and that a large fraction of the injected magma gets quenched. More precise documentation of how crystallization proceeds in transient conditions is made below with numerical calculations. The effects of changing the kinetic time-scale and the characteristic cooling time are also discussed then. Some verification of these ideas in natural conditions can be obtained by looking at the systematic variation of crystal size away from the margins of an intrusion, as was done by [19,34] for example. One relevant study was made by Dunbar et al. [35] who studied the cooling of an artificial Ca-rich mafic body with a 1.5-m thickness and a 3-m diameter, i.e. an average width of about 2 m. In this study, cooling depended on thermal boundary conditions and the peculiar shape of the melt body, parameters that were specific to the experimental setup. The important result is that rapid cooling over about 6 d led to the formation of 12% glass in the interior of the body. We shall illustrate below how thin sills achieve more rapid cooling leading to a larger proportion of glass. Another example of interest is provided by the ∼30- to 70-m thick Ginkgo flow of the Columbia River Basalts [36]. Crystallinity is only about 11% at the margin of the feeder dyke and is slightly higher in distal flow samples. The data demonstrate that a large fraction of this lava was quenched to glass upon emplacement and further that crystallization progressed slowly during the flow. Basaltic pillow lavas also document glass formation. Such samples correspond to the lava that drains from the thin tip of long flows, however, and their complex history of degassing and cooling prevents simple inferences. 3. Thermal model 3.1. Governing equations We do not consider the mechanics of emplacement and focus on a horizontal sill geometry. We consider a succession of thin magma injections. At t = 0, the first sill is emplaced instantaneously at depth ZS. Another injection follows at t =τi and so on. At each emplacement event, rocks located below the sill complex are instantaneously displaced downwards. Such motion has a small effect on the temperature distribution, as will be demonstrated later. Between two emplacement episodes, heat transport occurs by conduction alone. For thin sills that are laterally extensive, one may neglect horizontal heat transport and temperature obeys the following equation: qCp AT A2 T AU ¼ k 2 −qL At Az At ð4Þ where T is temperature, z the vertical coordinate, t time, Cp heat capacity, ρ magma density, k thermal conductivity, U the melt fraction and L latent heat. Density changes between crystals, magma and glass are neglected. The crystallization rate, AU At , drops to zero when T =TL, where TL is the liquidus temperature, and can be written as a function of the rates of nucleation and growth, which themselves depend on the undercooling T* =T /TL [37]. This equation must be solved over very thin units and extremely long time intervals, implying very large calculation times (typically several months). As discussed in the Appendix, we use a 10-cm grid spacing for sill complexes that grow to be thicker than 1 km. For simplicity, we lump together nucleation and growth into a single kinetic crystallization function f (T*), (Fig. 1): AU f ðT *Þ ¼ −U At sk ð5Þ C. Michaut, C. Jaupart / Earth and Planetary Science Letters 250 (2006) 38–52 43 where TL is in °C, C is composition in wt.% silica and Ce is the eutectic composition (Ce = 75 wt.% SiO2). Crystals have an average silica content of 40 wt.% SiO2 and mass conservation allows calculation of the residual melt composition, C: U C ¼ C0 −Cs ð1−U Þ ð7Þ with C0, the initial composition, and Cs, crystal composition, in wt.% SiO2. Melting of country rock is not kinetically controlled and, following a common simplification, we assume that the melt fraction is a linear function of temperature over the melting interval: AT A2 T A T −TSr qCP ¼ k 2 −qL ð8Þ At Az At TLr −TSr with T Lr and T Sr the solidus and liquidus temperatures of country rock. Values for the various parameters and physical properties are given in Table 4. 3.2. Time scales and parameters Fig. 1. a) Effective function for both nucleation and growth rates as a T * * functionh of undercooling i TL with T and TL in K. f ðT Þ ¼ i hT ¼ K K 3 2 CT *exp − T ðT −1Þ2 exp − T * ; with K2 = 10− 3, K3 = 30, and C such * * that max( f ) =1. Note the nucleation delay (arrow). b) Simplified phase diagram. The dashed line corresponds to the maximum crystallization rate. where τk is a characteristic time for crystal nucleation and growth. Dimensionless function f (T*) is normalized, such that the maximum crystallization rate is s1j . Complexities in the phase diagram are important for the detailed crystallization sequence but cannot affect significantly the rather straightforward thermal behaviour. Thus, for simplicity purposes, we take a binary eutectic solution with a starting magma composition far from the eutectic, such that crystallization occurs over a large temperature range. The liquidus temperature is given by (Fig. 1): TL ¼ 1000 − 20 ðC−Ce Þ 3 ð6Þ The primitive melt has a basaltic composition and is initially at the liquidus, at TL = 1187 °C (Fig. 1). Each intrusion of thickness d gets emplaced at the same depth, on top of the preceding ones, (Fig. 2). Other emplacement configurations, at the bottom of the pile for example, induce little changes in the results. We return to the emplacement sequence in the Discussion section. Before the first injection, the crust is in thermal equilibrium with a prescribed basal heat flow. We do not consider the effects of radiogenic heat production, which induce small temperature changes over the range of times and crustal depths of relevance to this problem. The pre-existing geothermal gradient g0 is set at a value of 15 °C km− 1, which corresponds to surface heat flow Φ ≈ 40 mW m− 2 which typifies stable continental regions before magmatic and tectonic activity. As long as this background thermal gradient is small compared to TL /ZS, which corresponds to geological reality, its exact value has no significant effect on the numerical results. Boundary conditions are a fixed temperature at the surface (z = 0) and a fixed heat flux Φ at the base. This problem has three time-scales, the characteristic time for crystallization, τk, the diffusion time-scale τd, and the time between two injections, τi. A fourth timescale corresponds to diffusion over the thickness of roof rocks ZS, which is of secondary importance. The problem is therefore characterized by two dimensionless numbers. One is the Avrami number, which has already been defined. The second dimensionless number, σ = τi / τd, compares the time between two 44 C. Michaut, C. Jaupart / Earth and Planetary Science Letters 250 (2006) 38–52 Table 4 Values for the physical properties Physical property Thermal conductivity Heat capacity Latent heat of crystallization Magma density Solidus temperature of country rock Liquidus temperature of country rock 3.3. Numerical method Symbol Value −1 −1 k Cp L ρ T Sr 2.5 (W K m ) 1.3 × 103 (J kg− 1 K− 1) 4.18 × 105 (J kg− 1) 2500 (kg m− 3) 800 (°C) T Lr 1100 (°C) injections and the cooling time. For σ ≪ 1, magma injection can be treated as continuous, which does not allow chilling. For σ ≫ 1, magma has been cooled by the time the next injection comes, which is relevant to volcanic systems. The rate of magma injection per unit area is Q = d / τi. In the calculations, the intrusion thickness d and the injection rate Q were varied and the other parameters were fixed. τk was set at a representative value of 106 s, as discussed above, and ZS at 5 km. In order to facilitate the physical analysis, the sill thickness and the time between two injections were kept constant in each numerical run. In nature, however, these parameters may both change with time and consequences are evaluated in the Discussion section. Governing Eqs. (4) and (8) are solved numerically with a Crank–Nicholson implicit finite-difference scheme (Appendix A). Because the computational domain is much thicker than the size of the thermal anomaly that develops, the results are not sensitive to the bottom boundary condition. Accounting for crystallization kinetics within thin units requires small grid sizes and time-steps, and hence extremely lengthy calculations. To reduce the computation time, we use an analytical solution to the governing equations when the crystallization rate is negligible and there is no latent heat release. In this case, the timeevolution of an arbitrary vertical temperature profile may be derived analytically: Z l ðz−yÞ2 −ðzþyÞ2 1 − T ðz; t−t1 Þ ¼ pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi T ð y; t1 Þ e 4jðt−t1 Þ −e4jðt−t1 Þ dy 2 kjðt−t1 Þ 0 ð9Þ where t1 is some arbitrary time. In this equation, the integral is calculated numerically using the trapezoid method. 4. A sample calculation Here, we present results for one particular set of parameters, d = 1 m and τi = 40 yr, and discuss the Fig. 2. Schematic representing the emplacement configuration and boundary conditions. The initial thermal gradient is 15 °C km− 1. Temperature is kept to zero at the surface and a fixed heat flux Φ is maintained at the base of the computational domain. Below the sill complex, country rock gets displaced downwards by each intrusion event. C. Michaut, C. Jaupart / Earth and Planetary Science Letters 250 (2006) 38–52 45 effects of changing these parameters in the following section. The time-averaged rate of heat supply per unit area is given by: /¼ qCp DTd si ð10Þ where ΔT is the temperature drop following cooling. Taking a representative value of 600 K for this temperature drop and using the parameter values specified above and in Table 4, ϕ ≈ 1 W m− 2. The background heat flux is much smaller than this and hence plays a minor role in the thermal evolution of the system. 4.1. Temperature evolution The first few sills all follow the same thermal and crystallization evolution illustrated in Fig. 3. Cooling rates are very large and lead to quenching at the margins. Magma is rapidly carried to very large undercoolings and few crystals grow in the interior of each sill. Crystallinity for this particular case is initially about 3%. Fig. 4 shows vertical temperature profiles through the crust after 150, 600, 1000 and 1566 injections. Both the amplitude and the depth-extent of the thermal anomaly increase with time. At the end of this sequence, which is ≈ 63,000 yr long, the thickness of the magma pile is 1566 m and the largest temperature is 694 °C, for which the crystallization rate is still very small. Thus, the whole magma pile is made of glass with a small crystal content and has the properties of a solid. At the base of the computational domain, temperatures decrease with time at a small rate reflecting the downward motion of country rock due to sill emplacement (see Fig. 2). The magnitude of this far-field temperature change is only 22 °C after 1566 injections, which is negligible compared to the magmatic thermal anomaly. Fig. 5 shows the residual crystal fraction after 150, 1000 and 1674 sill injections. By construction, each sill is hotter than the surroundings when it gets emplaced. The cooling rate is related to the thermal gradient and decreases away from the contact as well as with time, which allows a small amount of crystallization. Temperatures in the magma pile increase with each new injection, which acts to decrease the cooling rate. Thus, the time available for crystal nucleation and growth before quenching increases within each successive injection and the amount of crystals generated in each new sill gradually increases. Sills no. 150 and 1000 both have chilled margins and weakly crystallized interiors. After emplacement of sill no. 1674, however, Fig. 3. Cooling (top) and crystallization (bottom) of a single 1-m thick intrusion emplaced at a depth of 5 km at different times (indicated in hours) after emplacement. temperatures are such that crystal nucleation and growth occur even at the margins. As the magma pile grows, temperatures rise at a decreasing rate, as befits diffusive heat transport (Fig. 6). After a large number of injections, temperatures are sufficiently large for nucleation and growth to kick in and the system enters the positive feedback loop described earlier. For the present set of parameters, this catastrophic heating event occurs after 1675 injections, corresponding to a time of 67,000 yr, and the temperature rise is dramatic indeed: 200 °C in 40 yr (Fig. 6). Because of the positive thermal feedback loop, crystallization proceeds rapidly over a large thickness, leading to a sizable volume of evolved melt. In a few decades, therefore, one goes from a thick layer of chilled basalt to a large partially molten region. After this heating event, subsequent magma inputs occur in surroundings that are at temperatures close to the solidus, and the system enters a new phase. 46 C. Michaut, C. Jaupart / Earth and Planetary Science Letters 250 (2006) 38–52 Fig. 4. Vertical temperature profiles for d = 1 m and τi = 40 years after 150, 600, 1000 and 1566 injections, i.e. at t = 6 × 103, 24 × 103, 40 × 103 and 6.26 × 104 yr. At the end of this injection sequence, the pile of uncrystallized chilled magma is 1566-m thick (shaded area). Fig. 6. Maximum temperature in the magma pile as a function of time. From t = 0 to t ≈ 60 × 103 yr, the temperature increase is gradual. At t ≈ 60 × 103 yr, temperatures are large enough for crystal nucleation and growth. Latent heat release and crystallization kinetics work in a positive feedback loop leading to a catastrophic temperature increase of more than 200 °C in 40 yr. 4.2. Amount of melt generated The catastrophic heating event also affects the country rock, which melts. Thus, two different magmas are generated simultaneously from two different sources, and hence with different compositions and isotopic characteristics. The amount of melt generated increases with τi, the time between intrusions (Fig. 7). For d = 1 m and scaling by a characteristic cross-sectional area, magma input rates at a large number of continental volcanoes imply that τi is between 100 and 1000 yr, [26]. In such conditions, large amounts of evolved magma are generated: 140 m of pure melt for τi = 100 yr. In comparison, the Crater Lake caldera collapse event led to the eruption of 40 km3 of magma, [38]. Scaled to the cross-sectional area of the reservoir and allowing for the phenocryst content, this represents a thickness of 400 m, which would be achieved for τi ≈ 300 yr (keeping the same d value of 1 m). 4.3. Time to the catastrophic event Fig. 5. Amount of residual liquid or glass remaining in sills no. 150, 1000 and 1674. Prior to sill no. 1674, the margins of each sill gets completely chilled and few crystals grow in the interior. At the time of sill no. 1674, temperatures are large enough for the nucleation and growth of crystals and the margins also crystallize a little. We have run a number of calculations for different values of τi and d. Times between two injections and sill thicknessses ranged from 1 to 100 yr and 1 to 2 m respectively. We found that the time of catastrophic melting varies as Q− 2 and is weakly sensitive to the sill thickness (Fig. 8). This result can be explained by a very simple physical argument. Denoting by ΔT the temperature drop, the amount of heat lost to the surroundings per unit area is ρCpdΔT. This heat is evacuated by diffusion between two successive intrusions, over time τi. The largest heat flux is obtained at the roof and is carried through a thermal boundary layer of thickness δ which develops in the country rock. This pffiffiffiffiffiboundary layer grows by diffusion, such that df jt . The dominant heat balance is thus: qCp dDT TL fk pffiffiffiffi ffi si jt ð11Þ C. Michaut, C. Jaupart / Earth and Planetary Science Letters 250 (2006) 38–52 47 where k is thermal conductivity. This simple relation implies that ΔT decreases with time (i.e. temperatures rise in the surroundings) because of the increasingly inefficient conductive heat flux. The catastrophic melting event occurs at time t = τc such that ΔT = ΔTc, the critical value for the kinetic heat kick. Rearranging and using the fact that d / τi = Q, we obtain: TL 2 −2 Q ð12Þ sc f j DTc which implies that τc ∝ Q− 2, as shown by the calculations (Fig. 8). Note that this equation predicts that the critical time depends on d and τi only through the injection rate Q, as in the numerical results. For geological rates of injection calculated from [26], (≈ 10− 3 to 2 × 10− 2 m yr− 1), the time to the catastrophic melting event is in a range of 105 to more than 106 yr. For instance, a critical time of 1 Ma is reached for an injection rate of 5.10− 3m yr− 1, or 1 m every 200 yr. Such large values are consistent with time scales obtained from geochronological studies of volcanic and magmatic systems, and will be discussed further below. 4.4. Key characteristics of runaway devitrification The thermal mechanism described here, which has been called Runaway Devitrification by one reviewer of this paper, has many interesting features. Large volumes of evolved liquid magma are generated in a short time after a very long build-up phase (typically 105 yr or more). Melting of country rock proceeds at an accelerated rate. One key aspect is that heating of the chilled magma Fig. 8. Critical time (in years) for the catastrophic heating and melting event as a function of rate of injection Q in m yr− 1. Results have been obtained for two different sill thicknesses (1 or 2 m) and for different values of τi, the time between injections. Geological values of magma production rates, from [26], are indicated by the horizontal range. proceeds to almost the same temperature everywhere, leading to a nearly homogeneous batch of evolved magma. In contrast, crystallization of a large magma body due to cooling against cold surroundings leads to sharp temperature and compositional gradients, [39,40]. Over a long-term perspective, a magmatic system may go through two different phases, before and after the catastrophic melting. Before this event, only minor differentiation can occur. During the melting event, magma compositions change rapidly due to fractional crystallization and contamination with country rock. After this event, a large thermal halo has developed around the injection site and temperatures remain consistently large (Fig. 6). Thus, new magma injections are not cooled efficiently and a liquid reservoir can be sustained by small magma inputs. 5. Discussion We have used a simple physical model in order to identify key controls on runaway devitrification. Application to specific geological cases requires a host of input parameters including the water content of encasing rocks and the starting magma composition, which is outside the scope of this paper. Here, we discuss the applicability of the model to geological conditions. Fig. 7. Maximum volume of pure liquid per unit area formed by fractionation only (solid line), or fractionation + wall-rock melting (dashed line), as a function of τi, the time between two injections. Calculations are for a sill thickness d of 1 m. 5.1. Prerequisites For the present mechanism to work, the sill thickness must not exceed a critical value. For the same kinetic 48 C. Michaut, C. Jaupart / Earth and Planetary Science Letters 250 (2006) 38–52 time, i.e. τk = 106 s, calculations with d = 2 m exhibit the same behaviour, but not those for d = 4 m; in that case, all sills crystallize following emplacement. Another condition is that the thermal contrast between magma and host rock must be large enough for chilling. For d= 1 m, we find that the initial country rock temperature must be less than about 500 °C, corresponding to large parts of the continental crust. The best way to test the model, of course, is to compare predictions and observations, which will be done in an independent section below. The model essentially depends on sill thickness and the kinetic rates of crystal nucleation and growth, as well as on thermal diffusivity, which may vary slightly among natural magmas and may change as crystallization proceeds. Evaluation of the effects of changing one or all these parameters is best done with the Aυ number. For example, the same solution is obtained if one simultaneously decreases the kinetic time-scale by a factor of 4 and the sill thickness by a factor of 2 because the Aυ number stays the same. In the following, we shall use the sill thickness as control variable for the crystallization behaviour but the results can be easily recast as a function of the other parameters through the Aυ number. 5.2. Field evidence Lava samples emplaced at the Earth's surface or very shallow intrusions may not be appropriate because they are likely to have undergone decompression-induced crystallization at small pressures [20]. By its very nature, the mechanism explains why evidence may be hard to find. Firstly, the catastrophic melting event is likely to eradicate most traces of the initial sill complex. Secondly, the magmatic system is likely to remain active past this event with further disruption to the intrusive record. For example, the Onion Valley mafic complex, Sierra Nevada Batholith, California, formed in at least five episodes, with the first one preserved only as dismembered blocks within later units [10]. Thicker units that are found in the middle part of this intrusion preserve internal chilled contacts in a few places. We also note that the margins of the complex are most likely to preserve the initial sheeted sill structure. For example, the Urquhart and Scuzzy plutons, British Columbia, have sheeted margins and more homogeneous plutonic interiors [23]. 5.3. The characteristics of emplacement: Sill thickness and time In each run, all parameters were kept constant for clarity purposes. The assumption which may seem the most contrived is perhaps the constant sill thickness. Variations of sill thickness have consequences that are easy to understand. Indeed, it may very well be that some differences in the behaviour of natural magmatic systems can be ascribed to vagaries of emplacement characteristics. The main issue is the emplacement of sills that are much thicker than those studied here. As stated above, the present mechanism does not work if all sills are thick and what is at stake, therefore, is the number of such sills. Accounting for the large lifetime of magmatic systems, which typically exceed 100,000 yr, and for pluton thicknesses, which are typically in a range of 3–5 km, there can only be a small number of thick injections widely separated in time. No calculations are needed to find out what happens in two limit cases. Suppose for example that the first sill is 100-m thick, say, and that it is followed by thin ones. The first sill cools rapidly (≈ 200 yr, [6]). If it has completely crystallized when the next thin sill comes in, thermal evolution can be understood using the above results: the problem boils down to that of temperature in the surroundings, which has already been discussed. The other limit-case corresponds to a series of thin sills followed by a large one. In this case, the large sill may trigger catastrophic melting of the chilled magma pile. Determining the time between successive injections in a fossil magmatic system is likely to prove difficult. We know, however, that continental volcanoes have a large number of eruptions and that many of them seem to be triggered by a new injection of magma, as shown by mafic enclaves and their chilled contacts. Young volcanic systems, which are most relevant to the present analysis, are usually characterized by a long initial phase of basaltic volcanism followed by the emission of differentiated lavas, as at Mount Adams, for example [41]. Such behaviour raises the problem of how magma storage zones develop, which may be rationalized with the present model. 5.4. Complicating factors Here, we discuss a few complications that may occur in nature, with emphasis on the mechanism itself and not on quantitative details, which can only be addressed with other numerical calculations. We have verified that results are weakly sensitive to the details of the emplacement sequence within the magma pile. For example, forcing injection at the base of the magma pile instead of at the roof does not modify significantly the temperature evolution. One may also entertain emplacement at a random location within the magma pile, with consequences that are easy to predict. In this case, each sill would cool faster because the adjacent sills would be colder than for a fixed emplacement location. The end result would be a wider thermal C. Michaut, C. Jaupart / Earth and Planetary Science Letters 250 (2006) 38–52 anomaly and a smaller heating rate than in the examples of Fig. 4. In other words, randomization of the emplacement depth smoothes out temperature differences within the growing magma pile. We have assumed that each sill is in contact with previous sills, with no country rock sandwiched in between. Interlayering of magma and country rock slows down heating of the magma pile and hence increases the time for catastrophic melting. One consequence is that magma gets contaminated in situ by country rock, to which we return below. If successive sills get emplaced at distances that are large compared to the individual sill thickness, catastrophic heating would be prevented by the large heat capacity of the magma-country rock assemblage. Magma may already contain a few phenocrysts when it gets emplaced in the upper crust, due to prior storage in a deeper reservoir or to a complex ascent history. In this case, of course, the amount of glass formed would be smaller and the heating pulse would be more subdued. One other simplification is that we have lumped the crystallization kinetics of all minerals in a single function, but this may be oversimplified. For example, one could envisage easy nucleation of the liquidus phase, such as olivine in basalts, with further crystallization impeded or prevented by very sluggish kinetics. Such intricacies may be important for petrological interpretations but require kinetic data for a number of different crystal phases that is lacking (Tables 2 and 3). Evidence from the variations of crystal size away from intrusion margins, [19], does suggest that pyroxene and plagioclase crystals do not differ markedly from one another from the standpoint of crystallization kinetics. 5.5. Other magma compositions The present mechanism can also operate in other magmas. As shown in Table 1, incremental growth of plutons is documented in tonalites and leucogranites. Using the peak rates from [42], τm ≈ 107 s for andesites, which is larger than the basaltic value by more than one order of magnitude. As explained above, the true crystallization time must be larger than this and we expect the formation of significant amounts of glass in andesitic sills that are up to 10 m in thickness. 6. Comparison with observations and geological implications 6.1. Sharp heating events in active magmatic systems One symptom of the present mechanism is a sharp heating pulse before an eruption of differentiated lava. 49 Evidence for such a pulse has been found at a number of volcanoes, [43–45]. The Fish Canyon Tuff provides an illuminating example, [46]. This large volume deposit (5000 km3) is made of a surprisingly homogeneous crystal-rich dacite with near solidus mineral assemblages. Evidence for a late-stage heating pulse include resorbed quartz crystals as well as reverse zoning in plagioclase and hornblende phenocrysts, [47]. 6.2. Crystallization bursts The most specific symptom of the present mechanism is a short episode of crystallization occurring a long time after the beginning of magma emplacement. In this respect, the most striking observation comes perhaps from the 13 ka-old caldera-forming eruption of Laacher See Volcano, Germany. The probability function for the ages of a large number of sanidine phenocrysts shows a sharp crystallization burst prior to eruption, in marked contrast with earlier crystallization episodes, (Fig. 9), [48]. We note that this crystal explosion occurs after about 105 yr of magmatic history, which is consistent with the time-scales of our model. 6.3. Contamination by wall-rocks Contamination by wall-rock material is a ubiquitous feature of natural magmatic systems. The present mechanism enhances this phenomenon through two independent effects: a sharp heating event and the very nature of the emplacement mechanism. Sudden heating favors wall-rock melting, as shown by the following argument. In a diffusive regime, heating material from an interface at a constant heat flux ϕ leads to a temperature anomaly ΔTb at the interface that increases with time as: / pffiffiffiffiffi jt ð13Þ DTb f k Over time t, the amount of heat supplied is ΔH = ϕt and the expression for the temperature anomaly may be recast as follows: DTb f DH 1 pffiffiffiffiffi qCp jt ð14Þ This shows that, for a fixed amount of heat, ΔTb increases as the heating time t decreases. In addition, it is clear that contamination would be enhanced if successive sills do not abut against one another, but leave thin lenses of country rock between them. Those layers would melt with the rest of the magma 50 C. Michaut, C. Jaupart / Earth and Planetary Science Letters 250 (2006) 38–52 Acknowledgements This paper benefited greatly from comments and criticisms by Jon Blundy, Tim Druitt, Steve Sparks and one anonymous reviewer. Appendix A. A Numerical method Fig. 9. Probability function for the apparent age of crystallization of sanidine phenocrysts from the Laacher See Tephra, Eifel volcanic field, Germany, determined with 14C, from [48]. A clear peak at an age of 13 ka coincides with the caldera-forming eruption which produced the deposits. Before this event, crystallization ages exhibit a few minor peaks and are spread over a very large time interval (as much as 110 ka). Diffusion Eqs. (4) and (8) are solved with a finitedifference Crank–Nicholson method, with both explicit and implicit “Forward Time Centered Space” schemes for time-stepping. To integrate forward in time, from step n to the next (n + 1), all terms in the equations are written at step n + (1/2). The method has second-order accuracy in time, with a truncation error of O[(Δz)2 + (κΔt)2], and is stable for large time-steps Δt. The difficulty comes from the kinetic terms in Eq. (4), which are written at time t = n + (1/2) as follows: i LDt AU nþ1 AU n LDt h nþ1 þ Uj f ðTjnþ1 Þ þ Ujn f ðTjn Þ ¼− 2Cp At j At j 2Cp sk ð15Þ during the catastrophic heating event. For a given reservoir (pluton) thickness, it is obvious that the larger the number of individual sills is, the larger the amount of country rock that can get trapped within the magma pile. In that sense, the extent of contamination may well provide much information on emplacement characteristics. 7. Conclusions We have described a new mechanism for the formation of molten magma reservoirs, which relies on the injection of thin sills or dykes. In such conditions, crystallization kinetics act in an interesting way, first by preventing crystallization in each thin unit and then by enhancing it over a large number of units after a lengthy time interval. With this mechanism, magmatic heat gets released in two distinct events: sensible heat serves to warm up country rock and latent heat provides the final push for melting. The requirements for this mechanism seem to have been met in several well-studied plutons. Evidence for thin sills may be eradicated by the sharp burst of heating and crystallization that is predicted by this model. Changes in the injection sequence, including variations of sill thicknesses and emplacement location, lead to a range of thermal behaviours for nascent magmatic systems. The model has many implications that deserve separate investigations, such as the sudden change from solid to liquid in a thick magma pile and the rapid transition from basaltic to very evolved melts. Ujn + 1 and f (Tjn + 1) are first calculated using an explicit scheme: Dt nþ1 n n Uj ¼ exp logðUi Þ− f ðTj Þ sk f ðTjnþ1 Þ ¼ f ðTjn Þ þ df ðT n Þ½Tjnþ1 −Tjn dT j At the end of the calculation, values of Tjn + 1 obtained are used to correct for the values of f(Tjn + 1) and Ujn + 1 which is calculated as follows: logðUjnþ1 Þ ¼ logðUjn Þ− Dt ½ f ðTjnþ1 Þ þ f ðTjn Þ 2sk ð16Þ These new values are then introduced in a second calculation loop for Tjn + 1, and Ujn + 1. The kinetic term is thus calculated with an explicit scheme with a truncation error of the order of O(κΔt). The Crank– Nicholson method is stable for all values of ratio k ¼ jDt and, in particular, for λ ≈ 0.5, when (Δz)2 is of the ðDxÞ2 same order as κΔt. Therefore, handling the kinetic term as explained above is accurate enough. Calculations must yield accurate values of temperature and crystal content within each sill, including the first ones that are emplaced with very large thermal contrasts, and within the surrounding wall rock. With time, a thermal halo develops around the injection site and affects an C. Michaut, C. Jaupart / Earth and Planetary Science Letters 250 (2006) 38–52 increasingly larger thickness. We set the computational domain so that its lower boundary is deeper than the thermal halo and so that it always contains a zone of a few km thick unaffected by the thermal anomaly (i.e. where the thermal gradient is equal to g0). To restrict the total computation time, we start with a small domain (typically 10 km in thickness) and increase the domain size as time progresses. 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